ES325109A1 - Procedure for the preparation of 1,2,8,9-tetraazafenalenos. (Machine-translation by Google Translate, not legally binding) - Google Patents

Procedure for the preparation of 1,2,8,9-tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES325109A1
ES325109A1 ES0325109A ES325109A ES325109A1 ES 325109 A1 ES325109 A1 ES 325109A1 ES 0325109 A ES0325109 A ES 0325109A ES 325109 A ES325109 A ES 325109A ES 325109 A1 ES325109 A1 ES 325109A1
Authority
ES
Spain
Prior art keywords
group
mercapto
carboxylic acid
compound
translation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0325109A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
JR Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JR Geigy AG filed Critical JR Geigy AG
Publication of ES325109A1 publication Critical patent/ES325109A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/06Peri-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Indole Compounds (AREA)
  • Central Air Conditioning (AREA)

Abstract

Process for the preparation of 3-hydroxy- and 3-mercapto-1,2,8,9-tetraazaphenylene derivatives, of the formula I, ** (See formula) ** in which X means oxygen or sulfur, as well as their physiologically acceptable addition salts, characterized in that, a compound of the general formula II, ** (See formula) ** in which R2 means hydrogen or a lower alkyl group, one of the radicals A and B means the aldehyde group or one of its respective groups corresponding to the oxidation phase, the other radical meaning the carboxylic acid group or one of its respective groups which correspond to the oxidation phase, wherein the two neighboring carboxylic acid groups can be linked together as anhydride and an aldehydic group and the neighboring carboxylic acid group can, ester bonded together to form a lactone ring, is heated with at least the double molecular dose of hydrazine hydrate and 3-hydroxy-1,2,8,9-tetraazaphenylene is isolated from the reaction solution and, if desired, this compound is treated with an at least equimolar dose of phosphorus pentasulfide until, that the hydroxyl group is replaced by the mercapto group and, if desired, a hydroxylic compound or mercapto thus obtained is transformed, with an acid in organic or organic in an addition salt. (Machine-translation by Google Translate, not legally binding)
ES0325109A 1965-04-05 1966-04-04 Procedure for the preparation of 1,2,8,9-tetraazafenalenos. (Machine-translation by Google Translate, not legally binding) Expired ES325109A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US44576265A 1965-04-05 1965-04-05

Publications (1)

Publication Number Publication Date
ES325109A1 true ES325109A1 (en) 1967-02-16

Family

ID=23770102

Family Applications (5)

Application Number Title Priority Date Filing Date
ES0325110A Expired ES325110A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of derivatives 3-hidroxi- and 3-mercapto-1,2,8,9-tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)
ES0325109A Expired ES325109A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of 1,2,8,9-tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)
ES0325113A Expired ES325113A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of new 1,2,8,9 - tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)
ES0325111A Expired ES325111A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of new 1,2,8,9 - tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)
ES0325112A Expired ES325112A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of new 1,2,8,9 - tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES0325110A Expired ES325110A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of derivatives 3-hidroxi- and 3-mercapto-1,2,8,9-tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)

Family Applications After (3)

Application Number Title Priority Date Filing Date
ES0325113A Expired ES325113A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of new 1,2,8,9 - tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)
ES0325111A Expired ES325111A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of new 1,2,8,9 - tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)
ES0325112A Expired ES325112A1 (en) 1965-04-05 1966-04-04 Procedure for the preparation of new 1,2,8,9 - tetraazafenalenos. (Machine-translation by Google Translate, not legally binding)

Country Status (12)

Country Link
AT (3) AT259568B (en)
BE (3) BE679046A (en)
CH (3) CH481122A (en)
DE (3) DE1695064A1 (en)
DK (3) DK119313B (en)
ES (5) ES325110A1 (en)
FR (1) FR5595M (en)
GB (3) GB1138753A (en)
IL (3) IL25524A (en)
NL (3) NL6604484A (en)
NO (3) NO121495B (en)
SE (6) SE323688B (en)

Also Published As

Publication number Publication date
BE679047A (en) 1966-10-05
NO118493B (en) 1970-01-05
CH481122A (en) 1969-11-15
NL6604483A (en) 1966-10-06
SE350262B (en) 1972-10-23
SE318284B (en) 1969-12-08
NL6604482A (en) 1966-10-06
IL25526A (en) 1970-05-21
AT259568B (en) 1968-01-25
SE323689B (en) 1970-05-11
SE317387B (en) 1969-11-17
SE350263B (en) 1972-10-23
NO118492B (en) 1970-01-05
ES325111A1 (en) 1967-02-16
BE679046A (en) 1966-10-05
AT265297B (en) 1968-10-10
BE679045A (en) 1966-10-05
NO121495B (en) 1971-03-08
ES325113A1 (en) 1967-02-16
GB1138753A (en) 1969-01-01
DE1695065A1 (en) 1970-12-10
AT264530B (en) 1968-09-10
DE1695064A1 (en) 1970-12-10
SE323688B (en) 1970-05-11
IL25524A (en) 1970-06-17
CH475994A (en) 1969-07-31
DK120240B (en) 1971-05-03
GB1144881A (en) 1969-03-12
DE1695066A1 (en) 1970-12-10
FR5595M (en) 1967-12-04
DK119313B (en) 1970-12-14
NL6604484A (en) 1966-10-06
ES325112A1 (en) 1967-02-16
ES325110A1 (en) 1967-01-01
DK119504B (en) 1971-01-18
IL25525A (en) 1970-04-20
CH483432A (en) 1969-12-31
GB1138242A (en) 1968-12-27

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