ES2869983T3 - Polímeros a base de etileno con bajo contenido de extraíbles con hexano - Google Patents

Polímeros a base de etileno con bajo contenido de extraíbles con hexano Download PDF

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Publication number
ES2869983T3
ES2869983T3 ES16742074T ES16742074T ES2869983T3 ES 2869983 T3 ES2869983 T3 ES 2869983T3 ES 16742074 T ES16742074 T ES 16742074T ES 16742074 T ES16742074 T ES 16742074T ES 2869983 T3 ES2869983 T3 ES 2869983T3
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Spain
Prior art keywords
ethylene
reactor
cta
zone
reaction zone
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ES16742074T
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English (en)
Spanish (es)
Inventor
Stefan Hinrichs
Doelder Cornelis F J Den
Nhi T Y Dang
Otto J Berbee
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/38Mixtures of peroxy-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00Characteristics for processes of polymerization
    • C08F2400/02Control or adjustment of polymerization parameters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08Low density, i.e. < 0.91 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
ES16742074T 2015-06-25 2016-06-23 Polímeros a base de etileno con bajo contenido de extraíbles con hexano Active ES2869983T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562184344P 2015-06-25 2015-06-25
PCT/US2016/038900 WO2016210055A1 (en) 2015-06-25 2016-06-23 Ethylene-based polymers with low hexane extractables

Publications (1)

Publication Number Publication Date
ES2869983T3 true ES2869983T3 (es) 2021-10-26

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
ES16742074T Active ES2869983T3 (es) 2015-06-25 2016-06-23 Polímeros a base de etileno con bajo contenido de extraíbles con hexano
ES16738267T Active ES2775506T3 (es) 2015-06-25 2016-06-23 Polímeros basados en etileno con bajo contenido de extraíbles con hexano

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES16738267T Active ES2775506T3 (es) 2015-06-25 2016-06-23 Polímeros basados en etileno con bajo contenido de extraíbles con hexano

Country Status (8)

Country Link
US (2) US10494460B2 (cg-RX-API-DMAC7.html)
EP (2) EP3313903B1 (cg-RX-API-DMAC7.html)
JP (5) JP7436135B2 (cg-RX-API-DMAC7.html)
KR (2) KR102612773B1 (cg-RX-API-DMAC7.html)
CN (2) CN107810208B (cg-RX-API-DMAC7.html)
BR (2) BR112017027866B1 (cg-RX-API-DMAC7.html)
ES (2) ES2869983T3 (cg-RX-API-DMAC7.html)
WO (2) WO2016210075A1 (cg-RX-API-DMAC7.html)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102284307B1 (ko) 2013-12-26 2021-08-04 다우 글로벌 테크놀로지스 엘엘씨 비대칭 폴리엔을 이용하여 에틸렌계 중합체의 제조를 위한 반응기 안정성을 개선하는 방법
JP2017502131A (ja) 2013-12-26 2017-01-19 ダウ グローバル テクノロジーズ エルエルシー 非対称ポリエンを使用して形成されるエチレン系ポリマー
WO2016210075A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables
WO2016209706A2 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Ethylene-b as ed polymers with low hexane extractables and low densities
EP3168238A1 (en) 2015-11-10 2017-05-17 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
ES2803232T3 (es) * 2016-04-22 2021-01-25 Dow Global Technologies Llc Método para producir polímeros a base de etileno tubulares de baja densidad y bajo contenido de volátiles para un procedimiento de revestimiento por extrusión limpio
EP3260473A1 (en) 2016-06-24 2017-12-27 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
EP3260472A1 (en) * 2016-06-24 2017-12-27 Dow Global Technologies LLC Ethylene-based polymers formed by high pressure free radical polymerizations
EP3630853B1 (en) 2017-06-02 2021-03-17 Dow Global Technologies LLC Ethylene-based polymers and processes for the same
CN110240654A (zh) 2018-03-07 2019-09-17 复旦大学 结合cd73的抗体-药物偶联物
WO2025064134A1 (en) * 2023-09-20 2025-03-27 Dow Global Technologies Llc Ethylene-based polymer and process for producing the same

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE607527A (cg-RX-API-DMAC7.html) 1960-08-29 1900-01-01
US3917577A (en) 1968-09-20 1975-11-04 Basf Ag Continuous production of ethylene homopolymers
DE1807493C3 (de) 1968-11-07 1980-05-22 Basf Ag, 6700 Ludwigshafen Verfahren zum kontinuierlichen Herstellen von Äthylenhomopolymerisaten
EP0292215B2 (en) 1987-05-19 1997-10-08 Hitachi Chemical Co., Ltd. Method for production of methacrylate ester
DD276598A3 (de) 1988-04-12 1990-03-07 Leuna Werke Veb Verfahren zur einstellung und regelung der einsatzgasstroeme fuer mehrzonenrohrreaktoren
US5102955A (en) * 1989-12-29 1992-04-07 Mobil Oil Corporation Broad distribution, high molecular weight low density polyethylene and method of making thereof
US5126391A (en) * 1990-04-27 1992-06-30 Mitsubishi Petrochemical Co., Ltd. Filler-containing stretched film
SE9103077D0 (sv) 1991-10-22 1991-10-22 Neste Oy Omaettad etensampolymer och saett foer framstaellning daerav
SE507045C2 (sv) 1996-05-31 1998-03-23 Borealis As Etensampolymer med förhöjd omättnadsgrad och sätt för framställning därav
DE69826103T3 (de) * 1998-01-12 2012-07-12 Dow Global Technologies Inc. Äthylenpolymere mittlerer Dichte, Verfahren zur Herstellung dieser Polymere und Verwendung von Carbonyl-haltigen Kettenübertragungsmitteln in diesem Verfahren
JP3678907B2 (ja) * 1998-03-10 2005-08-03 三菱製紙株式会社 感光材料用支持体
DE19829399A1 (de) 1998-07-01 2000-02-03 Buna Sow Leuna Olefinverb Gmbh Verfahren zur Herstellung von Ethylenhomo- und Ethylencopolymerisaten niederer Dichte
DE50102850D1 (de) 2000-03-16 2004-08-19 Basell Polyolefine Gmbh Verfahren zur herstellung von polyethylen
KR100833763B1 (ko) 2000-08-15 2008-05-29 아크조 노벨 엔.브이. 하이솔리드 아크릴, 스티렌 및 ldpe-형 수지를 제조하는데 사용되는 트리옥세판의 용도
AU2001282086A1 (en) 2000-08-15 2002-02-25 Akzo Nobel N.V. Use of trioxepans in the process to make high-solid acrylic, styrenic, and ldpe-type resins
US6596241B2 (en) 2001-12-19 2003-07-22 Exxonmobil Chemical Patents Inc Tubular polymerization reactors and polymers made therein
JP4621658B2 (ja) * 2003-04-03 2011-01-26 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 均質な材料を形成させるためのローター式方法
KR101391511B1 (ko) 2005-03-09 2014-05-07 사우디 베이식 인더스트리즈 코포레이션 튜브형 반응기 내 공정으로 제조된 에틸렌 공중합체
US7078467B1 (en) * 2005-06-14 2006-07-18 Univation Technologies, Llc Single catalyst low, medium and high density polyethylenes
EA013421B1 (ru) 2006-03-24 2010-04-30 Сауди Бейсик Индастриз Корпорейшн Композиция экструзионного покрытия
US7449287B1 (en) * 2008-01-30 2008-11-11 Eastman Kodak Company Pearlescent textured imaging supports
AU2009210677A1 (en) 2008-02-08 2009-08-13 The Scripps Research Institute Breaking immunological tolerance with a genetically encoded unnatural amino acid
CN102099385B (zh) * 2008-07-10 2015-01-07 北欧化工股份公司 一种聚合物的生产工艺以及用于电线电缆的聚合物
JP2010068637A (ja) 2008-09-11 2010-03-25 Mitsumi Electric Co Ltd 充電制御用半導体集積回路
US8535377B2 (en) 2009-03-31 2013-09-17 Imds Corporation Double bundle ACL repair system
BR112012020940B1 (pt) * 2010-02-22 2019-11-19 Dow Global Technologies Llc artigo fabricado com uma composição poliolefínica
EP2621963B1 (en) 2010-09-30 2016-07-06 Dow Global Technologies LLC Polymerization process to make low density polyethylene
JP5980219B2 (ja) * 2010-10-29 2016-08-31 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびその方法
US9238700B2 (en) 2010-12-22 2016-01-19 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers in the presence of free-radical polymerization initiator by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers
RU2572821C2 (ru) 2011-03-03 2016-01-20 Базелль Полиолефине Гмбх Способ получения гомополимеров или сополимеров этилена в трубчатом реакторе, по меньшей мере, с двумя реакционными зонами с различной концентрацией агента передачи цепи
EP3002300B1 (en) * 2011-10-19 2017-07-19 Dow Global Technologies LLC Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers
WO2013078018A2 (en) * 2011-11-23 2013-05-30 Dow Global Technologies Llc Low density ethylene-based polymers with broad molecular weight distributions and low extractables
WO2013078224A1 (en) 2011-11-23 2013-05-30 Dow Global Technologies Llc Low density ethylene-based polymers with extracts at lower molecular weights
US9593177B2 (en) 2011-12-09 2017-03-14 Borealis Ag Polyethylene
CN104136467B (zh) 2011-12-22 2016-01-20 陶氏环球技术有限责任公司 具有改善的熔体强度的基于乙烯的聚合物及其方法
EP2636691A1 (en) 2012-03-07 2013-09-11 Borealis AG Process and plant for manufacturing polyethylene-diene-copolymers
EA026457B1 (ru) 2012-04-02 2017-04-28 Бореалис Аг Способ свободнорадикальной полимеризации этилена высокого давления, при котором этилен полимеризуют совместно с полиненасыщенным олефином специальной марки
KR20140117524A (ko) 2012-04-02 2014-10-07 보레알리스 아게 억제제를 사용하는 에틸렌 중합 공정
ES2546988T3 (es) 2012-04-02 2015-09-30 Borealis Ag Procedimiento de copolimerización de etileno por vía radicalaria a presión elevada con una temperatura reducida de la mezcla de reacción antes de la introducción en la zona de reacción
JP6007319B2 (ja) * 2012-05-31 2016-10-12 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 押出コーティング用の低密度ポリエチレン
ES2639126T5 (es) 2012-05-31 2024-07-24 Borealis Ag Polímeros de etileno para recubrimiento por extrusión
JP6339565B2 (ja) 2012-06-27 2018-06-06 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびそのプロセス
JP6325566B2 (ja) * 2012-11-20 2018-05-16 ダウ グローバル テクノロジーズ エルエルシー 高い溶融強度を有する低密度エチレン系ポリマー
BR112015027619B1 (pt) * 2013-05-22 2021-05-18 Dow Global Technologies Llc composições contendo polímeros à base de etileno de baixa densidade, artigo e filme
WO2014190041A1 (en) 2013-05-22 2014-11-27 Dow Global Technologies Llc Low density ethylene-based polymer compositions with high melt strength and mid-high density control
WO2015166297A1 (en) 2014-04-30 2015-11-05 Exxonmobil Chemical Patents Inc. Process for manufacturing ethylene polymers and copolymers
WO2016012534A1 (en) 2014-07-24 2016-01-28 Sabic Global Technologies B.V. Method for preparing ethylene copolymer
WO2016210075A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Ethylene-based polymers with low hexane extractables

Also Published As

Publication number Publication date
WO2016210075A1 (en) 2016-12-29
EP3313904A1 (en) 2018-05-02
KR20180021070A (ko) 2018-02-28
CN107787334A (zh) 2018-03-09
JP2018518577A (ja) 2018-07-12
ES2775506T3 (es) 2020-07-27
JP7436135B2 (ja) 2024-02-21
WO2016210055A1 (en) 2016-12-29
JP2018522972A (ja) 2018-08-16
CN107787334B (zh) 2020-07-24
CN107810208A (zh) 2018-03-16
CN107810208B (zh) 2020-07-24
EP3313903B1 (en) 2020-01-01
JP7510740B2 (ja) 2024-07-04
BR112017027564B1 (pt) 2022-02-01
US20180112017A1 (en) 2018-04-26
US10494460B2 (en) 2019-12-03
KR102612773B1 (ko) 2023-12-12
EP3313904B1 (en) 2021-04-21
US20180127523A1 (en) 2018-05-10
BR112017027866A2 (pt) 2018-08-28
KR20180021067A (ko) 2018-02-28
KR102577959B1 (ko) 2023-09-14
JP2024056727A (ja) 2024-04-23
BR112017027564A2 (pt) 2018-09-04
US10358512B2 (en) 2019-07-23
JP2022008573A (ja) 2022-01-13
BR112017027866B1 (pt) 2022-05-24
JP2024037861A (ja) 2024-03-19
EP3313903A1 (en) 2018-05-02

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