ES2787054T3 - Composición de polietileno y películas obtenidas a partir de esta - Google Patents
Composición de polietileno y películas obtenidas a partir de esta Download PDFInfo
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- ES2787054T3 ES2787054T3 ES15706603T ES15706603T ES2787054T3 ES 2787054 T3 ES2787054 T3 ES 2787054T3 ES 15706603 T ES15706603 T ES 15706603T ES 15706603 T ES15706603 T ES 15706603T ES 2787054 T3 ES2787054 T3 ES 2787054T3
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- Prior art keywords
- polyethylene composition
- polyethylene
- film
- catalyst
- alternatively
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- -1 polyethylene Polymers 0.000 title claims abstract description 174
- 239000000203 mixture Substances 0.000 title claims abstract description 161
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 144
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 141
- 239000003054 catalyst Substances 0.000 claims abstract description 60
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000005977 Ethylene Substances 0.000 claims abstract description 33
- 239000000155 melt Substances 0.000 claims abstract description 24
- 239000004711 α-olefin Substances 0.000 claims abstract description 24
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 18
- 238000009826 distribution Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 238000006116 polymerization reaction Methods 0.000 claims description 37
- 229920000642 polymer Polymers 0.000 claims description 32
- 150000002739 metals Chemical class 0.000 claims description 18
- 239000010936 titanium Substances 0.000 claims description 15
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 6
- 239000010955 niobium Substances 0.000 claims description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
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- 229910052735 hafnium Inorganic materials 0.000 claims description 4
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- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
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- 239000010937 tungsten Substances 0.000 claims description 4
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- 229910052749 magnesium Inorganic materials 0.000 description 41
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- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 6
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- 239000000047 product Substances 0.000 description 6
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- 238000002347 injection Methods 0.000 description 5
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- 239000000523 sample Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- QEGNUYASOUJEHD-UHFFFAOYSA-N 1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1 QEGNUYASOUJEHD-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
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- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
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- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
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- 239000012535 impurity Substances 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
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- 150000003609 titanium compounds Chemical class 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
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- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
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- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
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- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
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- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000010200 validation analysis Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/582—Tearability
- B32B2307/5825—Tear resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461937057P | 2014-02-07 | 2014-02-07 | |
| PCT/US2015/015053 WO2015120401A1 (en) | 2014-02-07 | 2015-02-09 | Polyethylene composition and films made therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2787054T3 true ES2787054T3 (es) | 2020-10-14 |
Family
ID=52463224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15706603T Active ES2787054T3 (es) | 2014-02-07 | 2015-02-09 | Composición de polietileno y películas obtenidas a partir de esta |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20170008985A1 (enExample) |
| EP (1) | EP3102627B1 (enExample) |
| JP (1) | JP6703949B2 (enExample) |
| CN (1) | CN106414565A (enExample) |
| AR (1) | AR099460A1 (enExample) |
| BR (1) | BR112016017364B1 (enExample) |
| CA (1) | CA2938445C (enExample) |
| ES (1) | ES2787054T3 (enExample) |
| MX (1) | MX2016009498A (enExample) |
| MY (1) | MY189833A (enExample) |
| WO (2) | WO2015119845A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3387169B1 (en) * | 2015-12-10 | 2019-10-23 | Dow Global Technologies, LLC | Polyethylene tapes, fibers or monofilaments comprising ethylene/alpha-olefin polymer |
| BR112018015379B1 (pt) * | 2016-02-12 | 2022-07-19 | Dow Global Technologies Llc | Filme de fundição, laminado e artigo |
| EP3214116B1 (en) | 2016-03-03 | 2021-06-23 | Dow Global Technologies LLC | Breathable films and method of making the same |
| WO2017222892A1 (en) * | 2016-06-22 | 2017-12-28 | Dow Global Technologies Llc | Multilayer films, and methods for making said multilayer films |
| MX2019003398A (es) * | 2016-09-27 | 2019-08-05 | Dow Global Technologies Llc | Peliculas que tienen propiedades mecanicas deseables y articulos fabricados a partir de las mismas. |
| MY191243A (en) | 2016-09-29 | 2022-06-10 | Dow Global Technologies Llc | Multilayer stretch films and methods thereof |
| US11577494B2 (en) | 2016-09-29 | 2023-02-14 | Dow Global Technologies Llc | Multilayer stretch films and methods thereof |
| CN110023353B (zh) | 2016-12-16 | 2022-07-22 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃互聚物组合物 |
| US11420429B2 (en) | 2017-12-20 | 2022-08-23 | Dow Global Technologies Llc | Multilayer cast films and methods of making thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5657633A (en) * | 1979-10-11 | 1981-05-20 | Mitsubishi Chem Ind | Polyolefin vessel |
| DE3528101A1 (de) * | 1985-08-06 | 1987-02-12 | Basf Ag | Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren (alpha)-monoolefinen mittels eines ziegler-katalysatorsystems |
| CN1245513A (zh) * | 1996-12-12 | 2000-02-23 | 陶氏化学公司 | 共聚体组合物及其平挤弹性膜 |
| JP5568464B2 (ja) * | 2007-04-10 | 2014-08-06 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレンフィルム及びそれを作製する方法 |
| EP2228395A1 (en) * | 2009-02-24 | 2010-09-15 | Borealis AG | Improved multi-stage process for producing multi-modal ethylene polymer composition |
| ES2609002T3 (es) * | 2011-06-01 | 2017-04-18 | Dow Global Technologies Llc | Procatalizadores Ziegler-Natta multimetálicos y catalizadores preparados a partir de los mismos para polimerizaciones de olefinas |
-
2015
- 2015-01-30 WO PCT/US2015/013658 patent/WO2015119845A1/en not_active Ceased
- 2015-02-09 US US15/116,343 patent/US20170008985A1/en not_active Abandoned
- 2015-02-09 EP EP15706603.6A patent/EP3102627B1/en active Active
- 2015-02-09 CN CN201580005704.0A patent/CN106414565A/zh active Pending
- 2015-02-09 CA CA2938445A patent/CA2938445C/en active Active
- 2015-02-09 JP JP2016548218A patent/JP6703949B2/ja active Active
- 2015-02-09 BR BR112016017364-3A patent/BR112016017364B1/pt active IP Right Grant
- 2015-02-09 AR ARP150100366A patent/AR099460A1/es active IP Right Grant
- 2015-02-09 MY MYPI2016001332A patent/MY189833A/en unknown
- 2015-02-09 MX MX2016009498A patent/MX2016009498A/es unknown
- 2015-02-09 ES ES15706603T patent/ES2787054T3/es active Active
- 2015-02-09 WO PCT/US2015/015053 patent/WO2015120401A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015119845A1 (en) | 2015-08-13 |
| AR099460A1 (es) | 2016-07-27 |
| EP3102627A1 (en) | 2016-12-14 |
| CA2938445A1 (en) | 2015-08-13 |
| JP6703949B2 (ja) | 2020-06-03 |
| MY189833A (en) | 2022-03-11 |
| US20170008985A1 (en) | 2017-01-12 |
| EP3102627B1 (en) | 2020-03-25 |
| BR112016017364A2 (pt) | 2017-08-08 |
| WO2015120401A1 (en) | 2015-08-13 |
| BR112016017364B1 (pt) | 2021-10-26 |
| CA2938445C (en) | 2022-05-31 |
| JP2017506273A (ja) | 2017-03-02 |
| MX2016009498A (es) | 2016-10-26 |
| CN106414565A (zh) | 2017-02-15 |
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