ES2721257T3 - Proceso de conversión que comprende al menos una etapa de hidrotratamiento en lecho fijo y una etapa de hidrocraqueo en reactores puenteables - Google Patents

Proceso de conversión que comprende al menos una etapa de hidrotratamiento en lecho fijo y una etapa de hidrocraqueo en reactores puenteables Download PDF

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ES2721257T3
ES2721257T3 ES17170033T ES17170033T ES2721257T3 ES 2721257 T3 ES2721257 T3 ES 2721257T3 ES 17170033 T ES17170033 T ES 17170033T ES 17170033 T ES17170033 T ES 17170033T ES 2721257 T3 ES2721257 T3 ES 2721257T3
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mpa
stage
reactor
temperature
atmospheric
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Wilfried Weiss
Pascal Chatron-Michaud
Elodie Tellier
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12Inorganic carriers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00Distillation of hydrocarbon oils
    • C10G7/06Vacuum distillation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1077Vacuum residues
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/205Metal content

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Un proceso continuo para tratar una carga hidrocarbonada que contiene al menos una fracción de hidrocarburos que tiene un contenido de azufre de al menos el 0,1% en peso, una temperatura de ebullición inicial de al menos 340 °C, y una temperatura de ebullición fina l de al menos 440 °C, que comprende las siguientes etapas: a) una etapa de hidrodesmetalización en presencia de la carga hidrocarbonada y de hidrógeno, y un catalizador de hidrodesmetalización, en donde al menos dos reactores permutables operan en las siguientes condiciones operativas: - temperatura comprendida entre 350 °C y 430 °C, - presión absoluta comprendida entre 11 MPa y 26 MPa, preferiblemente entre 14 MPa y 20 MPa, - WH (definida como el caudal volumétrico de la carga dividido por el volumen total del catalizador), comprendida entre 0,1 h-1 y 5 h-1, preferiblemente entre 0,15 h-1 y 3 h-1, y más preferiblemente entre 0, 2 h-1 y 2 h-1, b) una etapa de hidrotratamiento en lecho fijo que comprende al menos un reactor, en donde el efluente de la etapa a) se pone en contacto con al menos un catalizador de hidrotratamiento a una temperatura comprendida entre 350 20 °C y 430 °C, y bajo una presión absoluta comprendida entre 14 MPa y 20 MPa, c) una etapa de hidrocraqueo en lecho fijo del efluente de la etapa b) en presencia de un catalizador de hidrocraqueo, en donde al menos un reactor puenteable, es decir, un reactor que se puede detener mediante la implementación de un "baipás" mientras los otros reactores de la unidad aún están en funcionamiento, se implementa en las siguientes condiciones de operación: - una temperatura comprendida entre 350 °C y 430 °C, deteniéndose el reactor tan pronto como la temperatura de dicho reactor puenteable esté entre 405 °C y 425 °C, - presión absoluta comprendida entre 14 MPa y 20 MPa, d) una etapa de separación del efluente de la etapa de hidrocraqueo c) para obtener al menos una fracción gaseosa y al menos una fracción líquida pesada, enviándose dicha fracción líquida pesada a una destilación atmosférica que produce al menos un destilado atmosférico y un residuo atmosférico, donde dicho residuo atmosférico se envía total o parcialmente a la destilación al vacío produciendo un residuo de vacío, donde dichos residuos atmosféricos y de vacío se pueden enviar a un proceso de craqueo catalítico, o bien se pueden utilizar como fuel o como base de fuel.
ES17170033T 2016-06-09 2017-05-09 Proceso de conversión que comprende al menos una etapa de hidrotratamiento en lecho fijo y una etapa de hidrocraqueo en reactores puenteables Active ES2721257T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1655287A FR3052458B1 (fr) 2016-06-09 2016-06-09 Procede de conversion comprenant au moins une etape d'hydrotraitement en lit fixe et une etape d'hydrocraquage en reacteurs by passables

Publications (1)

Publication Number Publication Date
ES2721257T3 true ES2721257T3 (es) 2019-07-30

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ES17170033T Active ES2721257T3 (es) 2016-06-09 2017-05-09 Proceso de conversión que comprende al menos una etapa de hidrotratamiento en lecho fijo y una etapa de hidrocraqueo en reactores puenteables

Country Status (4)

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US (1) US10266779B2 (es)
EP (1) EP3255123B1 (es)
ES (1) ES2721257T3 (es)
FR (1) FR3052458B1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US20180230389A1 (en) 2017-02-12 2018-08-16 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US10696906B2 (en) 2017-09-29 2020-06-30 Marathon Petroleum Company Lp Tower bottoms coke catching device
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
CA3109606C (en) 2020-02-19 2022-12-06 Marathon Petroleum Company Lp Low sulfur fuel oil blends for paraffinic resid stability and associated methods
FR3107530B1 (fr) * 2020-02-21 2022-02-11 Ifp Energies Now Procede optimise de traitement d’huiles de pyrolyse de plastiques en vue de leur valorisation
CN113293024B (zh) * 2020-04-26 2023-05-26 江西尊创新能源有限公司 一种三段式选择加氢脱氧制备生物柴油的方法
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US20220268694A1 (en) 2021-02-25 2022-08-25 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11692141B2 (en) 2021-10-10 2023-07-04 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
CA3188122A1 (en) 2022-01-31 2023-07-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4446008A (en) 1981-12-09 1984-05-01 Research Association For Residual Oil Processing Process for hydrocracking of heavy oils with iron containing aluminosilicates
FR2538814B1 (fr) 1982-12-30 1986-06-27 Inst Francais Du Petrole Procede de traitement d'une huile lourde ou d'une fraction d'huile lourde pour les convertir en fractions plus legeres
FR2538813A1 (fr) 1982-12-31 1984-07-06 Inst Francais Du Petrole Procede d'hydrotraitement convertissant en au moins deux etapes une fraction lourde d'hydrocarbures contenant des impuretes soufrees et des impuretes metalliques
US4818743A (en) 1983-04-07 1989-04-04 Union Oil Company Of California Desulfurization catalyst and the catalyst prepared by a method
JPS60219295A (ja) 1984-04-16 1985-11-01 Res Assoc Residual Oil Process<Rarop> 重質炭化水素油の水素化処理方法
JPS6128717A (ja) 1984-07-19 1986-02-08 Mazda Motor Corp 過給機付エンジン
US5089463A (en) 1988-10-04 1992-02-18 Chevron Research And Technology Company Hydrodemetalation and hydrodesulfurization catalyst of specified macroporosity
JPH0674135B2 (ja) 1989-02-07 1994-09-21 重質油対策技術研究組合 新規な鉄含有アルミノシリケート
FR2660322B1 (fr) 1990-03-29 1992-06-19 Inst Francais Du Petrole Procede d'hydrotraitement d'un residu petrolier ou d'une huile lourde en vue de les raffiner et de les convertir en fractions plus legeres.
US5622616A (en) 1991-05-02 1997-04-22 Texaco Development Corporation Hydroconversion process and catalyst
FR2681871B1 (fr) 1991-09-26 1993-12-24 Institut Francais Petrole Procede d'hydrotraitement d'une fraction lourde d'hydrocarbures en vue de la raffiner et de la convertir en fractions plus legeres.
JP2966985B2 (ja) 1991-10-09 1999-10-25 出光興産株式会社 重質炭化水素油の接触水素化処理方法
US5221656A (en) 1992-03-25 1993-06-22 Amoco Corporation Hydroprocessing catalyst
US5827421A (en) 1992-04-20 1998-10-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution and no added silica
JP2908959B2 (ja) 1993-04-07 1999-06-23 出光興産株式会社 新規触媒組成物
US6332976B1 (en) 1996-11-13 2001-12-25 Institut Francais Du Petrole Catalyst containing phosphorous and a process hydrotreatment of petroleum feeds using the catalyst
US6342152B1 (en) 1998-08-25 2002-01-29 Idemitsu Kosan Co., Ltd. Hydrogenation treatment process for crude oil and crude oil reformed thereby
US6589908B1 (en) 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
FR2839902B1 (fr) 2002-05-24 2007-06-29 Inst Francais Du Petrole Catalyseur d'hydroraffinage et/ou d'hydroconversion et son utilisation dans des procedes d'hydrotraitement de charges hydrocarbonees
US7651604B2 (en) * 2003-07-09 2010-01-26 Instituto Mexicano Del Petroleo Process for the catalytic hydrotreatment of heavy hydrocarbons of petroleum
FR2940143B1 (fr) 2008-12-18 2015-12-11 Inst Francais Du Petrole Catalyseurs d'hydrodemetallation et d'hydrodesulfuration et mise en oeuvre dans un procede d'enchainement en formulation unique
FR2983866B1 (fr) * 2011-12-07 2015-01-16 Ifp Energies Now Procede d'hydroconversion de charges petrolieres en lits fixes pour la production de fiouls a basse teneur en soufre
FR3013723B1 (fr) * 2013-11-27 2016-08-26 Ifp Energies Now Procede de production de combustibles marins a basse teneur en soufre a partir d'une coupe hydrocarbonee issue du craquage catalytique de type slurry, et faisant appel a une etape d'hydrotraitement specifique .

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Publication number Publication date
EP3255123B1 (fr) 2019-01-23
US20170355914A1 (en) 2017-12-14
EP3255123A1 (fr) 2017-12-13
US10266779B2 (en) 2019-04-23
FR3052458B1 (fr) 2019-12-27
FR3052458A1 (fr) 2017-12-15

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