ES2661107T3 - Proceso de polimerización en solución con utilización energética mejorada - Google Patents
Proceso de polimerización en solución con utilización energética mejorada Download PDFInfo
- Publication number
- ES2661107T3 ES2661107T3 ES14776731.3T ES14776731T ES2661107T3 ES 2661107 T3 ES2661107 T3 ES 2661107T3 ES 14776731 T ES14776731 T ES 14776731T ES 2661107 T3 ES2661107 T3 ES 2661107T3
- Authority
- ES
- Spain
- Prior art keywords
- solvent
- passing
- stream
- ethylene
- deactivated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000010528 free radical solution polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract 20
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 5
- 239000005977 Ethylene Substances 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 5
- 239000004711 α-olefin Substances 0.000 abstract 5
- 239000006193 liquid solution Substances 0.000 abstract 4
- 229920000573 polyethylene Polymers 0.000 abstract 4
- 239000012535 impurity Substances 0.000 abstract 3
- 238000011144 upstream manufacturing Methods 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000011084 recovery Methods 0.000 abstract 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 description 15
- QLNAVQRIWDRPHA-UHFFFAOYSA-N iminophosphane Chemical compound P=N QLNAVQRIWDRPHA-UHFFFAOYSA-N 0.000 description 8
- 125000001424 substituent group Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 101150075118 sub1 gene Proteins 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- -1 alkoxy radical Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000004658 ketimines Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- OLRJXMHANKMLTD-UHFFFAOYSA-N silyl Chemical compound [SiH3] OLRJXMHANKMLTD-UHFFFAOYSA-N 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/001—Removal of residual monomers by physical means
- C08F6/003—Removal of residual monomers by physical means from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/02—Recovery or working-up of waste materials of solvents, plasticisers or unreacted monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2827839A CA2827839C (en) | 2013-09-19 | 2013-09-19 | A solution polymerization process with improved energy utilization |
| CA2827839 | 2013-09-19 | ||
| PCT/IB2014/064323 WO2015040522A1 (en) | 2013-09-19 | 2014-09-08 | A solution polymerization process with improved energy utilization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2661107T3 true ES2661107T3 (es) | 2018-03-27 |
| ES2661107T9 ES2661107T9 (es) | 2018-06-21 |
Family
ID=51626103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES14776731.3T Active ES2661107T3 (es) | 2013-09-19 | 2014-09-08 | Proceso de polimerización en solución con utilización energética mejorada |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9574025B2 (enExample) |
| EP (1) | EP3055336B9 (enExample) |
| JP (1) | JP6419789B2 (enExample) |
| KR (1) | KR102192150B1 (enExample) |
| CN (1) | CN106414509B (enExample) |
| BR (1) | BR112016006015B1 (enExample) |
| CA (1) | CA2827839C (enExample) |
| DK (1) | DK3055336T3 (enExample) |
| ES (1) | ES2661107T3 (enExample) |
| MX (1) | MX378396B (enExample) |
| NO (1) | NO3055336T3 (enExample) |
| WO (1) | WO2015040522A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6674030B2 (ja) | 2015-09-29 | 2020-04-01 | エクソンモービル・ケミカル・パテンツ・インク | スパイラル熱交換器を用いた重合 |
| CN108602900B (zh) * | 2015-12-21 | 2021-01-05 | 博里利斯股份公司 | 一种用于在溶液聚合过程中回收烃的方法 |
| BR112018012872B1 (pt) * | 2015-12-21 | 2022-07-26 | Borealis Ag | Processo de mesclagem em linha para polímeros |
| US10047178B2 (en) * | 2017-02-07 | 2018-08-14 | Exxonmobil Chemical Patents Inc. | Mitigation of catalyst inhibition in olefin polymerization |
| CA2969280C (en) * | 2017-05-30 | 2023-12-12 | Nova Chemicals Corporation | Non adiabatic 2-phase (liquid-liquid) polymerization process |
| CA3079922C (en) * | 2017-12-04 | 2022-12-06 | Borealis Ag | A method of recovering olefins in a solution polymerisation process |
| KR102302841B1 (ko) | 2017-12-04 | 2021-09-16 | 보레알리스 아게 | 용액 중합 공정에서의 올레핀 회수 방법 |
| KR102106806B1 (ko) | 2018-02-09 | 2020-05-06 | 주식회사 엘지화학 | 공액디엔계 중합체 제조방법 및 공액디엔계 중합체 제조장치 |
| EP3659686A1 (en) * | 2018-11-29 | 2020-06-03 | Borealis AG | Separator and process for separating volatile compounds from a polymer solution |
| US11299561B2 (en) | 2019-02-11 | 2022-04-12 | Exxonmobil Chemical Patents Inc. | Biphasic polymerization processes and ethylene-based polyolefins therefrom |
| KR102577661B1 (ko) | 2019-08-21 | 2023-09-11 | 주식회사 엘지화학 | 올리고머 제조 방법 및 올리고머 제조 장치 |
| KR102602865B1 (ko) | 2019-08-21 | 2023-11-16 | 주식회사 엘지화학 | 올리고머 제조 방법 및 올리고머 제조 장치 |
| CN112500510A (zh) * | 2019-09-14 | 2021-03-16 | 南京延长反应技术研究院有限公司 | 基于溶液法制备聚乙烯的强化系统及工艺 |
| EP3971221B1 (en) | 2020-07-22 | 2024-06-19 | Lg Chem, Ltd. | Method and apparatus for recovering solvent |
| CN116472294A (zh) * | 2020-11-02 | 2023-07-21 | 陶氏环球技术有限责任公司 | 在聚烯烃生产期间控制吸收介质中的α-烯烃冷凝的方法 |
| CN115518401B (zh) * | 2022-10-26 | 2024-06-14 | 万华节能科技(烟台)有限公司 | 一种用于生产单组分聚脲所需潜固化剂的生产工艺 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2302305A1 (fr) | 1975-02-28 | 1976-09-24 | Charbonnages Ste Chimique | Procede perfectionne de polymerisation et de copolyme |
| JPS5783538A (en) | 1980-11-12 | 1982-05-25 | Kyowa Chem Ind Co Ltd | Polyolefin composition and agent thereof |
| JPS59166506A (ja) * | 1983-03-14 | 1984-09-19 | Mitsui Toatsu Chem Inc | 重合液組成物の連続的脱揮発方法 |
| GB8610126D0 (en) | 1986-04-25 | 1986-05-29 | Du Pont Canada | Isopropanolamines |
| US4731438A (en) | 1986-12-30 | 1988-03-15 | Union Carbide Corporation | Water treatment method for resin in a purge vessel |
| JPH02232205A (ja) * | 1989-03-06 | 1990-09-14 | Nippon Steel Chem Co Ltd | 揮発性物質の除去方法及びその装置 |
| JPH04142303A (ja) * | 1990-10-02 | 1992-05-15 | Nippon Steel Chem Co Ltd | 揮発性物質の除去方法 |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5434116A (en) | 1992-06-05 | 1995-07-18 | Tosoh Corporation | Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same |
| US5554775A (en) | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
| CA2227674C (en) | 1998-01-21 | 2007-04-24 | Stephen John Brown | Catalyst deactivation |
| US6881800B2 (en) * | 2000-10-25 | 2005-04-19 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| EP1630178A1 (en) * | 2004-08-10 | 2006-03-01 | Innovene Manufacturing Belgium NV | Polymerisation process |
| JP4323406B2 (ja) * | 2004-10-04 | 2009-09-02 | 住友化学株式会社 | 連続重合装置およびそれを用いた連続重合方法 |
| KR100994252B1 (ko) * | 2007-05-09 | 2010-11-12 | 주식회사 엘지화학 | 에틸렌 알파-올레핀 공중합체 |
| CN101711260B (zh) * | 2007-05-16 | 2012-07-18 | Lg化学株式会社 | 长链支化的乙烯-α烯烃共聚物 |
| CA2598960C (en) * | 2007-08-27 | 2015-04-07 | Nova Chemicals Corporation | High temperature process for solution polymerization |
| EP2072540A1 (en) * | 2007-12-20 | 2009-06-24 | Basell Poliolefine Italia S.r.l. | Solution polymerization process for preparing polyolefins |
| JP5486442B2 (ja) * | 2009-09-04 | 2014-05-07 | 出光興産株式会社 | 重合溶液の揮発成分除去装置、その方法、および、重合装置 |
| CA2688217C (en) | 2009-12-11 | 2016-07-12 | Nova Chemicals Corporation | Multi reactor process |
| EP2683764B1 (en) * | 2011-03-08 | 2018-07-04 | Dow Global Technologies LLC | Process for recycling solvent used in an ethylene-based polymerization reaction |
| CA2809718C (en) | 2013-03-15 | 2020-03-24 | Nova Chemicals Corporation | Improved energy utilization in a solution polymerization plant |
-
2013
- 2013-09-19 CA CA2827839A patent/CA2827839C/en active Active
-
2014
- 2014-09-08 KR KR1020167009786A patent/KR102192150B1/ko active Active
- 2014-09-08 BR BR112016006015-6A patent/BR112016006015B1/pt active IP Right Grant
- 2014-09-08 WO PCT/IB2014/064323 patent/WO2015040522A1/en not_active Ceased
- 2014-09-08 MX MX2016003508A patent/MX378396B/es unknown
- 2014-09-08 US US15/021,796 patent/US9574025B2/en active Active
- 2014-09-08 NO NO14776731A patent/NO3055336T3/no unknown
- 2014-09-08 DK DK14776731.3T patent/DK3055336T3/en active
- 2014-09-08 ES ES14776731.3T patent/ES2661107T3/es active Active
- 2014-09-08 EP EP14776731.3A patent/EP3055336B9/en active Active
- 2014-09-08 CN CN201480063345.XA patent/CN106414509B/zh active Active
- 2014-09-08 JP JP2016515475A patent/JP6419789B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| NO3055336T3 (enExample) | 2018-05-19 |
| ES2661107T9 (es) | 2018-06-21 |
| EP3055336B9 (en) | 2018-04-18 |
| KR102192150B1 (ko) | 2020-12-17 |
| MX2016003508A (es) | 2016-06-28 |
| CA2827839A1 (en) | 2015-03-19 |
| EP3055336B1 (en) | 2017-12-20 |
| CN106414509B (zh) | 2018-05-08 |
| JP6419789B2 (ja) | 2018-11-07 |
| US20160229930A1 (en) | 2016-08-11 |
| BR112016006015A2 (pt) | 2017-08-01 |
| MX378396B (es) | 2025-03-10 |
| CN106414509A (zh) | 2017-02-15 |
| KR20160058143A (ko) | 2016-05-24 |
| EP3055336A1 (en) | 2016-08-17 |
| JP2016531165A (ja) | 2016-10-06 |
| DK3055336T3 (en) | 2018-02-26 |
| BR112016006015B1 (pt) | 2021-07-27 |
| US9574025B2 (en) | 2017-02-21 |
| CA2827839C (en) | 2019-12-24 |
| WO2015040522A1 (en) | 2015-03-26 |
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