ES2651930T3 - Adhesivo de polímeros con dominios cristalinos, poliuretano amorfo y compuestos de silano - Google Patents

Adhesivo de polímeros con dominios cristalinos, poliuretano amorfo y compuestos de silano Download PDF

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Publication number
ES2651930T3
ES2651930T3 ES10711399.5T ES10711399T ES2651930T3 ES 2651930 T3 ES2651930 T3 ES 2651930T3 ES 10711399 T ES10711399 T ES 10711399T ES 2651930 T3 ES2651930 T3 ES 2651930T3
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ES
Spain
Prior art keywords
groups
polymer
polyurethane
weight
polyether diols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10711399.5T
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English (en)
Spanish (es)
Inventor
Oliver Hartz
Axel Weiss
Karl-Heinz Schumacher
Axel Meyer
Oral Aydin
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BASF SE
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BASF SE
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3234—Polyamines cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/6692—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0853—Ethylene vinyl acetate copolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/80—Compositions for aqueous adhesives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/08—Crosslinking by silane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/20—Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Polyurethanes Or Polyureas (AREA)
ES10711399.5T 2009-04-14 2010-03-30 Adhesivo de polímeros con dominios cristalinos, poliuretano amorfo y compuestos de silano Active ES2651930T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09157864 2009-04-14
EP09157864 2009-04-14
PCT/EP2010/054142 WO2010118948A1 (de) 2009-04-14 2010-03-30 Klebstoff aus polymeren mit kristallinen domänen, amorphem polyurethan und silanverbindungen

Publications (1)

Publication Number Publication Date
ES2651930T3 true ES2651930T3 (es) 2018-01-30

Family

ID=42270190

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10711399.5T Active ES2651930T3 (es) 2009-04-14 2010-03-30 Adhesivo de polímeros con dominios cristalinos, poliuretano amorfo y compuestos de silano

Country Status (6)

Country Link
US (1) US8916641B2 (enExample)
EP (1) EP2419466B1 (enExample)
JP (1) JP5755218B2 (enExample)
CN (1) CN102388075B (enExample)
ES (1) ES2651930T3 (enExample)
WO (1) WO2010118948A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2830784A1 (en) * 2011-03-25 2012-10-04 Bayer Intellectual Property Gmbh Polyurethane urea mixture for hair cosmetics
BR112014013558A2 (pt) * 2011-12-09 2017-06-13 Basf Se uso de dispersões aquosas de poliuretano para laminação de folha fina compósita, processo para produzir folhas finas compósitas, e, folha fina compósita
CN102516920A (zh) * 2011-12-12 2012-06-27 东莞市山力高分子材料科研有限公司 水性聚氨酯胶粘剂及其制备方法
US9669610B2 (en) * 2012-11-02 2017-06-06 Basf Se Use of aqueous polyurethane dispersions for laminating molded articles
WO2016186047A1 (ja) * 2015-05-15 2016-11-24 住友化学株式会社 水性分散体混合物
US9850407B2 (en) * 2015-09-08 2017-12-26 United States Gypsum Company Enhanced adhesive composition for re-enforcing joints in gypsum panel construction
JP6899833B2 (ja) 2016-02-03 2021-07-07 ビーエイエスエフ・ソシエタス・エウロパエアBasf Se 酸素遮断性被覆のための、ポリウレタンとフィロ珪酸塩とを含有する1成分水性被覆組成物
EP3755753B1 (de) * 2018-02-21 2022-07-27 Basf Se Verfahren zur herstellung von mit klebstoff beschichteten artikeln
US20240101879A1 (en) * 2021-01-19 2024-03-28 Covestro Deutschland Ag Storage-Stable 1K Spray Adhesives Based on Polyurethane Dispersions
FR3121933B1 (fr) * 2021-04-15 2024-02-16 Saint Gobain Weber France Dispersion aqueuse hybride autoréticulante contenant des particules de polyuréthane anionique et des particules de polymère (styrène)acrylique anionique
WO2022223438A1 (en) 2021-04-22 2022-10-27 Basf Se Process for preparing coated shaped bodies and their use
CN114891476B (zh) * 2022-06-02 2024-01-09 中科华宇(福建)科技发展有限公司 一种高耐水水性高分子异氰酸酯木用胶黏剂及其制备方法

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DE1495745C3 (de) 1963-09-19 1978-06-01 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung wäßriger, emulgatorfreier Polyurethan-Latices
US3412054A (en) 1966-10-31 1968-11-19 Union Carbide Corp Water-dilutable polyurethanes
BE758129A (fr) 1969-10-28 1971-04-01 Bayer Ag Sels d'acides 2-(beta-amino-propionamino)-alcane sulfoniques etleur utilisation comme composants de synthese anioniques dans la preparation dedispersions de polyurethanes sans agents emulsifiants
DE2034479A1 (de) 1970-07-11 1972-01-13 Bayer Polyurethan Kunststoffe und Verfahren zu ihrer Herstellung
DE2314513C3 (de) 1973-03-23 1980-08-28 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von wäßrigen Polyurethandispersionen
DE2314512C3 (de) 1973-03-23 1980-10-09 Bayer Ag, 5090 Leverkusen Thermoplastische, nichtionische, in Wasser despergierbare im wesentlichen lineare Polyurethanelastomere
DE2725589A1 (de) 1977-06-07 1978-12-21 Bayer Ag Verfahren zur herstellung von waessrigen polyurethan-dispersionen und -loesungen
DE2732131A1 (de) 1977-07-15 1979-01-25 Bayer Ag Verfahren zur herstellung von seitenstaendige hydroxylgruppen aufweisenden isocyanat-polyadditionsprodukten
DE2811148A1 (de) 1978-03-15 1979-09-20 Bayer Ag Verfahren zur herstellung von waessrigen polyurethan-dispersionen und -loesungen
DE2843790A1 (de) 1978-10-06 1980-04-17 Bayer Ag Verfahren zur herstellung von waessrigen dispersionen oder loesungen von polyurethan-polyharnstoffen, die nach diesem verfahren erhaeltlichen dispersionen oder loesungen, sowie ihre verwendung
DE3911827A1 (de) 1989-04-11 1990-10-25 Basf Ag Waessrige dispersionen von durch einwirkung von energiereicher strahlung vernetzbaren polyurethanen
US5258457A (en) * 1990-07-27 1993-11-02 Shell Oil Company Method of chemically crosslinking unsaturated polymers
DE4314111A1 (de) 1993-04-29 1994-11-03 Goldschmidt Ag Th alpha,omega-Polymethacrylatdiole, Verfahren zu ihrer Herstellung und deren Verwendung zur Herstellung von Polymeren, insbesondere Polyurethanen und Polyestern
BR9401951A (pt) * 1994-05-11 1995-12-05 Alba Quimica Ind E Com Ltda Adesivo de contato à base de água
US5525663A (en) * 1994-08-18 1996-06-11 Minnesota Mining And Manufacturing Company Reactive hot-melt adhesive and/or sealing composition and method of using same
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DE60000928T2 (de) * 2000-06-23 2003-08-14 National Starch And Chemical Investment Holding Corp., Wilmington Polymerdispersion enthaltend PU-Partikel und durch Emulsionspolymerisation olefinisch ungesättigter Monomerer erhaltenes Co- oder Terpolymer
US6635690B2 (en) * 2001-06-19 2003-10-21 3M Innovative Properties Company Reactive oligomers
US7182951B1 (en) * 2002-01-29 2007-02-27 Landec Corporation Selection and treatment of seeds
EP1598382A1 (de) 2004-05-17 2005-11-23 Sika Technology AG Einkomponentiger wässriger Dispersionsklebstoff
JP2007045866A (ja) * 2005-08-08 2007-02-22 Dai Ichi Kogyo Seiyaku Co Ltd 無孔質膜型透湿防水加工用水系ポリウレタン樹脂組成物及び透湿防水加工布帛の製造方法
KR101342236B1 (ko) 2006-01-19 2013-12-16 바스프 에스이 실란 및 카르보디이미드 기를 포함하는 폴리우레탄 접착제
BRPI0714244A2 (pt) 2006-07-12 2013-02-26 Basf Se adesivo aquoso,e, uso de adesivo
US9248470B2 (en) * 2006-07-31 2016-02-02 Safe Reflections, Inc. Colorized retroreflective material and method
US9051409B2 (en) * 2009-04-14 2015-06-09 Basf Se Use of polyurethane adhesive formed from polyester diols, polyether diols and silane compounds in the manufacture of film/foil-coated furniture
US20110200803A1 (en) * 2010-02-15 2011-08-18 Jieming Li Self-Primed Coating Formulation and Universal, Printable, Plastic Media Coated with the Formulation

Also Published As

Publication number Publication date
EP2419466A1 (de) 2012-02-22
WO2010118948A1 (de) 2010-10-21
JP2012523487A (ja) 2012-10-04
CN102388075B (zh) 2014-08-27
US8916641B2 (en) 2014-12-23
CN102388075A (zh) 2012-03-21
EP2419466B1 (de) 2017-09-13
JP5755218B2 (ja) 2015-07-29
US20120021213A1 (en) 2012-01-26

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