ES2619335T3 - Procedimiento para producir un revestimiento metálico - Google Patents
Procedimiento para producir un revestimiento metálico Download PDFInfo
- Publication number
- ES2619335T3 ES2619335T3 ES13727175.5T ES13727175T ES2619335T3 ES 2619335 T3 ES2619335 T3 ES 2619335T3 ES 13727175 T ES13727175 T ES 13727175T ES 2619335 T3 ES2619335 T3 ES 2619335T3
- Authority
- ES
- Spain
- Prior art keywords
- substrate
- chemical attack
- ionic liquid
- coating
- deposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 188
- 239000011248 coating agent Substances 0.000 title claims abstract description 184
- 238000000034 method Methods 0.000 title claims abstract description 79
- 239000000126 substance Substances 0.000 claims abstract description 197
- 239000000758 substrate Substances 0.000 claims abstract description 176
- 238000000151 deposition Methods 0.000 claims abstract description 127
- 230000007704 transition Effects 0.000 claims abstract description 126
- 239000002608 ionic liquid Substances 0.000 claims abstract description 123
- 230000008021 deposition Effects 0.000 claims abstract description 121
- 229910052751 metal Inorganic materials 0.000 claims abstract description 100
- 239000002184 metal Substances 0.000 claims abstract description 71
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 32
- 238000004070 electrodeposition Methods 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 25
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 22
- 239000010959 steel Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 claims abstract description 14
- 235000019743 Choline chloride Nutrition 0.000 claims abstract description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960003178 choline chloride Drugs 0.000 claims abstract description 14
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 claims abstract description 14
- 150000002500 ions Chemical class 0.000 claims abstract description 14
- 239000003792 electrolyte Substances 0.000 claims abstract description 8
- 239000011651 chromium Substances 0.000 claims description 44
- 230000007423 decrease Effects 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 3
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 claims 1
- 150000001455 metallic ions Chemical class 0.000 abstract 3
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 abstract 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 abstract 1
- 239000011636 chromium(III) chloride Substances 0.000 abstract 1
- 235000007831 chromium(III) chloride Nutrition 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 123
- 229910052804 chromium Inorganic materials 0.000 description 25
- 238000002474 experimental method Methods 0.000 description 19
- 239000007788 liquid Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 229910000599 Cr alloy Inorganic materials 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 6
- 239000000788 chromium alloy Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- -1 chromium (III) ions Chemical class 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052729 chemical element Inorganic materials 0.000 description 2
- 229960001231 choline Drugs 0.000 description 2
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-M 1,1-dioxo-1,2-benzothiazol-3-olate Chemical compound C1=CC=C2C([O-])=NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000000441 X-ray spectroscopy Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/66—Electroplating: Baths therefor from melts
- C25D3/665—Electroplating: Baths therefor from melts from ionic liquids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/36—Pretreatment of metallic surfaces to be electroplated of iron or steel
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
- C25F3/06—Etching of iron or steel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12458—All metal or with adjacent metals having composition, density, or hardness gradient
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- ing And Chemical Polishing (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12171315 | 2012-06-08 | ||
| EP12171315 | 2012-06-08 | ||
| PCT/EP2013/061663 WO2013182631A1 (en) | 2012-06-08 | 2013-06-06 | Method for producing a metal coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2619335T3 true ES2619335T3 (es) | 2017-06-26 |
Family
ID=48577050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13727175.5T Active ES2619335T3 (es) | 2012-06-08 | 2013-06-06 | Procedimiento para producir un revestimiento metálico |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9957632B2 (enExample) |
| EP (2) | EP3147390B1 (enExample) |
| JP (1) | JP6444860B2 (enExample) |
| KR (1) | KR102135750B1 (enExample) |
| DK (1) | DK2859138T3 (enExample) |
| ES (1) | ES2619335T3 (enExample) |
| HU (1) | HUE031121T2 (enExample) |
| PL (1) | PL2859138T3 (enExample) |
| RS (1) | RS55660B1 (enExample) |
| WO (1) | WO2013182631A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2534883A (en) * | 2015-02-03 | 2016-08-10 | Univ Leicester | Electrolyte for electroplating |
| JP6583808B2 (ja) * | 2015-02-20 | 2019-10-02 | 国立大学法人 東京大学 | 有機半導体膜の製造方法および製造装置 |
| CN105821453A (zh) * | 2016-04-27 | 2016-08-03 | 昆明理工大学 | 一种低共熔溶剂电沉积亮铬镀层的方法 |
| CN106086959B (zh) * | 2016-08-03 | 2018-06-12 | 南京理工大学 | 一种电化学还原沉积铝制备铝热剂的方法 |
| CN107254698A (zh) * | 2017-06-14 | 2017-10-17 | 东北大学 | 氯化胆碱‑六水合三氯化铬离子液体电沉积制备金属铬的方法 |
| EP3438330B9 (de) * | 2017-08-03 | 2024-08-14 | Groz-Beckert KG | Textilmaschinenwerkzeugteil und verfahren zur herstellung eines textilwerkzeugs |
| CN108048885B (zh) * | 2017-12-14 | 2019-10-25 | 安徽工业大学 | 一种基于乙酰丙酸-氯化胆碱低共熔溶剂的电镀镍磷合金方法 |
| JP7566251B2 (ja) * | 2019-07-12 | 2024-10-15 | 奥野製薬工業株式会社 | ３価クロムめっき方法 |
| US11965265B1 (en) * | 2020-01-30 | 2024-04-23 | The United States Of America As Represented By The Secretary Of The Navy | Hybrid electro-processing of a metal workpiece |
| CN112002752B (zh) * | 2020-07-27 | 2023-04-21 | 北海惠科光电技术有限公司 | 源漏电极的制备方法、阵列基板的制备方法和显示机构 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2873233A (en) | 1956-03-21 | 1959-02-10 | Philco Corp | Method of electrodepositing metals |
| US3294498A (en) * | 1963-09-24 | 1966-12-27 | Du Pont | Cr-fe diffusion coating ferrous metal substrate |
| US3694326A (en) | 1969-11-03 | 1972-09-26 | Allegheny Ludlum Steel | Pretreatment of stainless steel for electroplating |
| CH660326A5 (de) | 1983-01-13 | 1987-04-15 | Tecno Zuerich Ag | Saegeblatt fuer die bearbeitung von holz oder aehnlichen werkstoffen. |
| JPH04180593A (ja) * | 1990-11-14 | 1992-06-26 | Sumitomo Metal Ind Ltd | 亜鉛系めっき鋼板およびその製造方法 |
| US5413646A (en) | 1991-02-08 | 1995-05-09 | Blount, Inc. | Heat-treatable chromium |
| JPH0633296A (ja) * | 1992-07-15 | 1994-02-08 | Kawasaki Steel Corp | 鋼板への亜鉛系めっき方法 |
| GB0023708D0 (en) | 2000-09-27 | 2000-11-08 | Scionix Ltd | Hydrated salt mixtures |
| DE10159890B4 (de) | 2001-12-06 | 2006-02-16 | Federal-Mogul Burscheid Gmbh | Verfahren für das Beschichten von Aluminiumwerkstoffen mit Funktionsschichten aus Eisen |
| EP1984541A2 (en) | 2006-02-15 | 2008-10-29 | Akzo Nobel N.V. | Method to electrodeposit metals using ionic liquids |
| JP2007297668A (ja) * | 2006-04-28 | 2007-11-15 | Om Sangyo Kk | メッキ製品の製造方法 |
| ATE493523T1 (de) | 2007-08-02 | 2011-01-15 | Akzo Nobel Nv | Verfahren zur elektrodeponierung von metallen mithilfe ionischer flüssigkeiten unter verwendung eines zusatzstoffs |
| WO2009106269A1 (de) * | 2008-02-26 | 2009-09-03 | Ewald Dörken Ag | Beschichtungsverfahren für ein werkstück |
-
2013
- 2013-06-06 KR KR1020147032642A patent/KR102135750B1/ko not_active Expired - Fee Related
- 2013-06-06 HU HUE13727175A patent/HUE031121T2/en unknown
- 2013-06-06 PL PL13727175T patent/PL2859138T3/pl unknown
- 2013-06-06 US US14/406,146 patent/US9957632B2/en not_active Expired - Fee Related
- 2013-06-06 RS RS20170166A patent/RS55660B1/sr unknown
- 2013-06-06 JP JP2015515522A patent/JP6444860B2/ja not_active Expired - Fee Related
- 2013-06-06 EP EP16197790.5A patent/EP3147390B1/en not_active Not-in-force
- 2013-06-06 DK DK13727175.5T patent/DK2859138T3/en active
- 2013-06-06 EP EP13727175.5A patent/EP2859138B1/en not_active Not-in-force
- 2013-06-06 ES ES13727175.5T patent/ES2619335T3/es active Active
- 2013-06-06 WO PCT/EP2013/061663 patent/WO2013182631A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2859138B1 (en) | 2016-11-30 |
| EP3147390B1 (en) | 2020-09-16 |
| DK2859138T3 (en) | 2017-02-27 |
| EP3147390A1 (en) | 2017-03-29 |
| RS55660B1 (sr) | 2017-06-30 |
| EP2859138A1 (en) | 2015-04-15 |
| US9957632B2 (en) | 2018-05-01 |
| WO2013182631A1 (en) | 2013-12-12 |
| HUE031121T2 (en) | 2017-06-28 |
| US20150147586A1 (en) | 2015-05-28 |
| PL2859138T3 (pl) | 2017-05-31 |
| JP6444860B2 (ja) | 2018-12-26 |
| KR102135750B1 (ko) | 2020-07-22 |
| JP2015518925A (ja) | 2015-07-06 |
| KR20150017334A (ko) | 2015-02-16 |
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