ES2524821T3 - Poliisocianatos hidrófilos modificados con nanopartículas - Google Patents
Poliisocianatos hidrófilos modificados con nanopartículas Download PDFInfo
- Publication number
- ES2524821T3 ES2524821T3 ES10712002.4T ES10712002T ES2524821T3 ES 2524821 T3 ES2524821 T3 ES 2524821T3 ES 10712002 T ES10712002 T ES 10712002T ES 2524821 T3 ES2524821 T3 ES 2524821T3
- Authority
- ES
- Spain
- Prior art keywords
- polyisocyanates
- polyisocyanate
- modified
- groups
- hydrophilic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005056 polyisocyanate Substances 0.000 title claims abstract description 195
- 229920001228 polyisocyanate Polymers 0.000 title claims abstract description 195
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 48
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- 238000000034 method Methods 0.000 claims abstract description 28
- 238000002360 preparation method Methods 0.000 claims abstract description 27
- 229920000570 polyether Polymers 0.000 claims abstract description 25
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 22
- 230000008569 process Effects 0.000 claims abstract description 16
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 12
- 239000001257 hydrogen Substances 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 7
- 239000010452 phosphate Substances 0.000 claims abstract description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 5
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims abstract description 5
- 239000010954 inorganic particle Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 56
- 239000003995 emulsifying agent Substances 0.000 claims description 38
- 239000004814 polyurethane Substances 0.000 claims description 22
- -1 monomethylene Chemical group 0.000 claims description 21
- 229920002635 polyurethane Polymers 0.000 claims description 18
- 150000001298 alcohols Chemical class 0.000 claims description 17
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 15
- 125000005442 diisocyanate group Chemical group 0.000 claims description 11
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000012948 isocyanate Substances 0.000 claims description 8
- 150000002513 isocyanates Chemical class 0.000 claims description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 229920000151 polyglycol Polymers 0.000 claims description 7
- 239000010695 polyglycol Substances 0.000 claims description 7
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- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 4
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 3
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 claims description 2
- PJWWRFATQTVXHA-UHFFFAOYSA-N Cyclohexylaminopropanesulfonic acid Chemical compound OS(=O)(=O)CCCNC1CCCCC1 PJWWRFATQTVXHA-UHFFFAOYSA-N 0.000 claims description 2
- MKWKNSIESPFAQN-UHFFFAOYSA-N N-cyclohexyl-2-aminoethanesulfonic acid Chemical compound OS(=O)(=O)CCNC1CCCCC1 MKWKNSIESPFAQN-UHFFFAOYSA-N 0.000 claims description 2
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- HXSACZWWBYWLIS-UHFFFAOYSA-N oxadiazine-4,5,6-trione Chemical group O=C1ON=NC(=O)C1=O HXSACZWWBYWLIS-UHFFFAOYSA-N 0.000 claims description 2
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- 235000021317 phosphate Nutrition 0.000 claims 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
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- 239000000194 fatty acid Substances 0.000 claims 1
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- 239000003973 paint Substances 0.000 description 51
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 47
- 239000007787 solid Substances 0.000 description 43
- 239000002904 solvent Substances 0.000 description 43
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 41
- 239000006185 dispersion Substances 0.000 description 26
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 25
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
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- 238000012360 testing method Methods 0.000 description 20
- 239000011230 binding agent Substances 0.000 description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 229910052681 coesite Inorganic materials 0.000 description 16
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- 229910052682 stishovite Inorganic materials 0.000 description 16
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- 238000000576 coating method Methods 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229940043232 butyl acetate Drugs 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000004132 cross linking Methods 0.000 description 10
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
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- 241001550224 Apha Species 0.000 description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 7
- 238000011065 in-situ storage Methods 0.000 description 7
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- QMYGFTJCQFEDST-UHFFFAOYSA-N 3-methoxybutyl acetate Chemical compound COC(C)CCOC(C)=O QMYGFTJCQFEDST-UHFFFAOYSA-N 0.000 description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
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- 239000004753 textile Substances 0.000 description 6
- 239000004971 Cross linker Substances 0.000 description 5
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 5
- 229920002396 Polyurea Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 5
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- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 4
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 4
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 4
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- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
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- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 4
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- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
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- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
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- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/289—Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/83—Chemically modified polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/90—Compositions for anticorrosive coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09004630A EP2236532A1 (de) | 2009-03-31 | 2009-03-31 | Nanopartikelmodifizierte hydrophile Polyisocyanate |
| EP09004630 | 2009-03-31 | ||
| PCT/EP2010/001806 WO2010112156A1 (de) | 2009-03-31 | 2010-03-23 | Nanopartikelmodifizierte hydrophile polyisocyanate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2524821T3 true ES2524821T3 (es) | 2014-12-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10712002.4T Active ES2524821T3 (es) | 2009-03-31 | 2010-03-23 | Poliisocianatos hidrófilos modificados con nanopartículas |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20120041142A1 (https=) |
| EP (2) | EP2236532A1 (https=) |
| JP (1) | JP5547273B2 (https=) |
| KR (1) | KR20120009474A (https=) |
| CN (1) | CN102449015A (https=) |
| ES (1) | ES2524821T3 (https=) |
| WO (1) | WO2010112156A1 (https=) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2236531A1 (de) * | 2009-03-31 | 2010-10-06 | Bayer MaterialScience AG | Neue wäßrige 2K PUR-Beschichtungssysteme für verbesserten Korrosionsschutz |
| JP5770505B2 (ja) * | 2011-03-25 | 2015-08-26 | 株式会社Adeka | 水系ポリウレタン樹脂用ウレタンプレポリマー組成物及びこれを含有してなる水系ポリウレタン樹脂組成物 |
| KR101268414B1 (ko) | 2011-03-30 | 2013-05-28 | 주식회사 스노젠 | 불소 발수제용 친수성 블록화 이소시아네이트 가교제 조성물 및 그 제조방법 |
| JP6247492B2 (ja) * | 2012-11-06 | 2017-12-13 | ダウ グローバル テクノロジーズ エルエルシー | 水性皮革コーティング組成物および皮革をコーティングするための方法 |
| CN102925032B (zh) * | 2012-11-14 | 2015-03-18 | 长江水利委员会长江科学院 | 一种大坝混凝土表面抗泄水冲磨涂料及其涂刷方法 |
| JP5696735B2 (ja) * | 2013-03-25 | 2015-04-08 | 日油株式会社 | ウレタン硬化性組成物 |
| CN104448232B (zh) * | 2013-09-13 | 2017-12-15 | 万华化学集团股份有限公司 | 一种氨基磺酸改性的多异氰酸酯及其制备方法和用途 |
| CN103626956B (zh) * | 2013-11-22 | 2016-03-30 | 深圳市新纶科技股份有限公司 | 一种改性多异氰酸酯、水分散性交联剂及其制备方法 |
| CN106459337A (zh) * | 2014-06-24 | 2017-02-22 | 比克化学股份有限公司 | 具有潜在增稠趋势的聚氨酯双成分或多成分体系 |
| US9587143B2 (en) * | 2014-10-22 | 2017-03-07 | The United States Of America, As Represented By The Secretary Of The Navy | Two-component siloxane-based coatings containing polymers with urea linkages and terminal alkoxysilanes |
| US10888839B2 (en) | 2015-06-25 | 2021-01-12 | Korea University Research And Business Foundation | Average-density-adjustable structure, and material change and selective bonding process using same |
| CN109790277B (zh) * | 2016-09-23 | 2021-04-23 | 旭化成株式会社 | 多异氰酸酯组合物、封端多异氰酸酯组合物、涂覆组合物、水性涂覆组合物和涂覆基材 |
| JP6332823B1 (ja) * | 2017-10-26 | 2018-05-30 | 太陽精機株式会社 | 湿気硬化性ポリウレタンホットメルト接着剤及びその製造方法 |
| DE102018209444B3 (de) * | 2018-06-13 | 2019-07-25 | Fresenius Medical Care Deutschland Gmbh | Verfahren zum Vergießen von Hohlfasermembranen, Hohlfasermembranfilter und isocyanatgruppenhaltiges Addukt |
| CN111253552B (zh) | 2018-11-30 | 2023-08-22 | 科思创德国股份有限公司 | 改性聚异氰酸酯 |
| WO2020109189A1 (en) * | 2018-11-30 | 2020-06-04 | Covestro Deutschland Ag | Modified polyisocyanate |
| KR102419673B1 (ko) | 2019-01-21 | 2022-07-08 | 삼성에스디아이 주식회사 | 양자점, 이를 포함하는 경화성 조성물, 상기 조성물을 이용하여 제조된 경화막, 상기 경화막을 포함하는 컬러필터, 디스플레이 장치 및 상기 경화막의 제조방법 |
| KR102296792B1 (ko) | 2019-02-01 | 2021-08-31 | 삼성에스디아이 주식회사 | 무용매형 경화성 조성물, 이를 이용하여 제조된 경화막, 상기 경화막을 포함하는 컬러필터, 디스플레이 장치 및 상기 경화막의 제조방법 |
| CN109988495B (zh) * | 2019-03-29 | 2021-10-26 | 华南理工大学 | 纳米材料改性水性多异氰酸酯固化剂及制备与应用 |
| CN111978509B (zh) * | 2019-05-24 | 2022-04-12 | 旭化成株式会社 | 多异氰酸酯组合物、涂料组合物和涂膜 |
| KR102602724B1 (ko) | 2019-10-14 | 2023-11-14 | 삼성에스디아이 주식회사 | 양자점, 이를 포함하는 경화성 조성물, 상기 조성물을 이용하여 제조된 경화막 및 상기 경화막을 포함하는 컬러필터 |
| KR102504788B1 (ko) | 2019-10-14 | 2023-02-27 | 삼성에스디아이 주식회사 | 양자점, 이를 포함하는 경화성 조성물, 상기 조성물을 이용하여 제조된 경화막 및 상기 경화막을 포함하는 컬러필터 |
| US20230080775A1 (en) * | 2020-02-17 | 2023-03-16 | Covestro Deutschland Ag | Polyisocyanate preparations |
| US20210403678A1 (en) * | 2020-06-24 | 2021-12-30 | Evonik Operations Gmbh | Use of long-chain phosphoric acid esters in aqueous polyurethane dispersions |
| EP4001332A1 (en) * | 2020-11-18 | 2022-05-25 | Covestro Deutschland AG | A modified polyisocyanate |
| WO2022069561A1 (en) * | 2020-09-30 | 2022-04-07 | Covestro Deutschland Ag | A modified polyisocyanate |
| KR102390345B1 (ko) * | 2020-11-10 | 2022-04-22 | 테사 소시에타스 유로파에아 | 잠재 반응성 접착 화합물을 제조하기 위한 제제 |
| CN114517050B (zh) * | 2020-11-19 | 2025-05-13 | 宣伟(广东)新材料有限公司 | 木器用封闭底漆和含有由该封闭底漆形成的封闭底漆层的制品 |
| CN115466201B (zh) | 2021-06-11 | 2024-05-03 | 万华化学集团股份有限公司 | 一种磺酸改性多异氰酸酯及其制备方法 |
| EP4116349A1 (de) | 2021-07-07 | 2023-01-11 | Covestro Deutschland AG | Hydrophil-modifizierte silan- und thioallophanatstrukturen aufweisende polyisocyanate |
| CN116445062A (zh) * | 2023-02-03 | 2023-07-18 | 青岛爱尔家佳新材料股份有限公司 | 一种高弹耐候水性聚脲面漆及其制备方法 |
| CN118667495A (zh) * | 2024-06-13 | 2024-09-20 | 浙江多邦新材料有限公司 | 一种聚氨酯热熔烫金胶及其制备方法 |
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| GB8405320D0 (en) | 1984-02-29 | 1984-04-04 | Baxenden Chem | Blocked isocyanates |
| DE3521618A1 (de) | 1985-06-15 | 1986-12-18 | Bayer Ag, 5090 Leverkusen | In wasser dispergierbare polyisocyanat-zubereitung und ihre verwendung als zusatzmittel fuer waessrige klebstoffe |
| DE4036927A1 (de) | 1990-11-20 | 1992-05-21 | Basf Ag | Nichtwaessrige polyisocyanatzubereitung |
| DE4136618A1 (de) | 1991-11-07 | 1993-05-13 | Bayer Ag | Wasserdispergierbare polyisocyanatgemische |
| DE4213527A1 (de) | 1992-04-24 | 1993-10-28 | Bayer Ag | Wäßrige Überzugsmittel für elastische Einbrennlackierungen |
| DE4221924A1 (de) | 1992-07-03 | 1994-01-13 | Bayer Ag | In Wasser lösliche oder dispergierbare Polyisocyanatgemische und ihre Verwendung in Einbrennlacken |
| DE4237468A1 (de) | 1992-11-06 | 1994-05-11 | Bayer Ag | Alkoxysilan- und Aminogruppen aufweisende Verbindungen |
| DE19519396A1 (de) | 1995-05-26 | 1996-11-28 | Huels Chemische Werke Ag | Neue blockierte Polyisocyanate sowie ein Verfahren zu ihrer Herstellung |
| US5587502A (en) * | 1995-06-02 | 1996-12-24 | Minnesota Mining & Manufacturing Company | Hydroxy functional alkoxysilane and alkoxysilane functional polyurethane made therefrom |
| GB9520317D0 (en) | 1995-10-05 | 1995-12-06 | Baxenden Chem Ltd | Water dispersable blocked isocyanates |
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| DE19914884A1 (de) * | 1999-04-01 | 2000-10-05 | Bayer Ag | Polyurethan-Dispersionen mit Alkoxysilan-Endgruppen für Glasfaserschlichten |
| DE10024624A1 (de) | 2000-05-18 | 2001-11-22 | Bayer Ag | Modifizierte Polyisocyanate |
| DE10043433A1 (de) * | 2000-09-04 | 2002-03-21 | Bayer Ag | Wäßrige 2-K-PUR-Systeme |
| WO2003044099A1 (de) | 2001-11-23 | 2003-05-30 | Deutsche Amphibolin-Werke Von Robert Murjahn Gmbh & Co. Kg | Beschichtungsmasse enthaltend nanopartikel, verwendung der beschichtungsmasse und verfahren zur herstellung von beschichtungen |
| DE10226927A1 (de) | 2002-06-17 | 2003-12-24 | Bayer Ag | Blockierte Polyisocyanate |
| DE10350242A1 (de) | 2003-10-27 | 2005-05-19 | Basf Ag | Wasseremulgierbare Isocyanate mit verbesserten Eigenschaften |
| WO2006008120A1 (de) | 2004-07-16 | 2006-01-26 | Alberdingk Boley Gmbh | Wässrige bindemitteldispersion mit nanopartikeln, verfahren zu deren herstellung und deren verwendung |
| DE102005053678A1 (de) * | 2005-11-10 | 2007-05-16 | Bayer Materialscience Ag | Hydrophile Polyisocyanatgemische |
| DE102006054289A1 (de) * | 2006-11-17 | 2008-05-21 | Bayer Materialscience Ag | Nanopartikelmodifizierte Polyisocyanate |
-
2009
- 2009-03-31 EP EP09004630A patent/EP2236532A1/de not_active Withdrawn
-
2010
- 2010-03-23 ES ES10712002.4T patent/ES2524821T3/es active Active
- 2010-03-23 JP JP2012502493A patent/JP5547273B2/ja not_active Expired - Fee Related
- 2010-03-23 CN CN2010800240147A patent/CN102449015A/zh active Pending
- 2010-03-23 WO PCT/EP2010/001806 patent/WO2010112156A1/de not_active Ceased
- 2010-03-23 KR KR1020117025623A patent/KR20120009474A/ko not_active Ceased
- 2010-03-23 US US13/259,311 patent/US20120041142A1/en not_active Abandoned
- 2010-03-23 EP EP10712002.4A patent/EP2414419B1/de not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| EP2236532A1 (de) | 2010-10-06 |
| CN102449015A (zh) | 2012-05-09 |
| US20120041142A1 (en) | 2012-02-16 |
| EP2414419B1 (de) | 2014-10-01 |
| KR20120009474A (ko) | 2012-01-31 |
| JP2012522078A (ja) | 2012-09-20 |
| WO2010112156A1 (de) | 2010-10-07 |
| EP2414419A1 (de) | 2012-02-08 |
| JP5547273B2 (ja) | 2014-07-09 |
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