ES2322540T3 - Metodo para el tratamiento del suelo y/o de las aguas subterraneas. - Google Patents
Metodo para el tratamiento del suelo y/o de las aguas subterraneas. Download PDFInfo
- Publication number
- ES2322540T3 ES2322540T3 ES00943068T ES00943068T ES2322540T3 ES 2322540 T3 ES2322540 T3 ES 2322540T3 ES 00943068 T ES00943068 T ES 00943068T ES 00943068 T ES00943068 T ES 00943068T ES 2322540 T3 ES2322540 T3 ES 2322540T3
- Authority
- ES
- Spain
- Prior art keywords
- oxidizing agent
- source
- addition
- catalyst solution
- situ environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000002689 soil Substances 0.000 title claims description 44
- 239000007800 oxidant agent Substances 0.000 claims abstract description 73
- 238000011065 in-situ storage Methods 0.000 claims abstract description 51
- 239000003054 catalyst Substances 0.000 claims abstract description 43
- 239000000356 contaminant Substances 0.000 claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 24
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000002360 preparation method Methods 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 36
- 239000003673 groundwater Substances 0.000 claims description 25
- 239000003344 environmental pollutant Substances 0.000 claims description 17
- 231100000719 pollutant Toxicity 0.000 claims description 17
- 150000002978 peroxides Chemical group 0.000 claims description 15
- 229920006395 saturated elastomer Polymers 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 239000011435 rock Substances 0.000 claims description 9
- 239000004343 Calcium peroxide Substances 0.000 claims description 6
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims description 6
- 235000019402 calcium peroxide Nutrition 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 2
- 239000003002 pH adjusting agent Substances 0.000 claims description 2
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 claims description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 2
- 230000006641 stabilisation Effects 0.000 claims description 2
- 238000011105 stabilization Methods 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 60
- 230000003197 catalytic effect Effects 0.000 description 33
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 26
- 238000002347 injection Methods 0.000 description 24
- 239000007924 injection Substances 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 19
- 238000011109 contamination Methods 0.000 description 12
- 238000005755 formation reaction Methods 0.000 description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 230000002123 temporal effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- CUPCBVUMRUSXIU-UHFFFAOYSA-N [Fe].OOO Chemical class [Fe].OOO CUPCBVUMRUSXIU-UHFFFAOYSA-N 0.000 description 3
- 238000009303 advanced oxidation process reaction Methods 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011066 ex-situ storage Methods 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 239000000797 iron chelating agent Substances 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 102000016938 Catalase Human genes 0.000 description 2
- 108010053835 Catalase Proteins 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RTBHLGSMKCPLCQ-UHFFFAOYSA-N [Mn].OOO Chemical class [Mn].OOO RTBHLGSMKCPLCQ-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000033558 biomineral tissue development Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003863 metallic catalyst Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N Picolinic acid Natural products OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N anhydrous gallic acid Natural products OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 150000004827 dibenzo-1,4-dioxins Chemical class 0.000 description 1
- 150000004826 dibenzofurans Chemical class 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229940048879 dl tartaric acid Drugs 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 238000003895 groundwater pollution Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- CKFMJXZQTNRXGX-UHFFFAOYSA-L iron(2+);diperchlorate Chemical compound [Fe+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O CKFMJXZQTNRXGX-UHFFFAOYSA-L 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- LHOWRPZTCLUDOI-UHFFFAOYSA-K iron(3+);triperchlorate Chemical compound [Fe+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O LHOWRPZTCLUDOI-UHFFFAOYSA-K 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- -1 ozone peroxide Chemical class 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229940081066 picolinic acid Drugs 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/002—Reclamation of contaminated soil involving in-situ ground water treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/02—Extraction using liquids, e.g. washing, leaching, flotation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/06—Contaminated groundwater or leachate
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Catalysts (AREA)
- Cultivation Of Plants (AREA)
- Road Paving Structures (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/345,922 US6319328B1 (en) | 1999-07-01 | 1999-07-01 | Soil and/or groundwater remediation process |
| US345922 | 1999-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2322540T3 true ES2322540T3 (es) | 2009-06-23 |
Family
ID=23357109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00943068T Expired - Lifetime ES2322540T3 (es) | 1999-07-01 | 2000-06-22 | Metodo para el tratamiento del suelo y/o de las aguas subterraneas. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6319328B1 (enExample) |
| EP (1) | EP1212149B1 (enExample) |
| JP (1) | JP3793084B2 (enExample) |
| AT (1) | ATE424942T1 (enExample) |
| AU (1) | AU780219B2 (enExample) |
| CA (1) | CA2370097C (enExample) |
| DE (1) | DE60041772D1 (enExample) |
| DK (1) | DK1212149T3 (enExample) |
| ES (1) | ES2322540T3 (enExample) |
| WO (1) | WO2001002105A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7338563B2 (en) * | 1996-10-16 | 2008-03-04 | Clark Steve L | Process for cleaning hydrocarbons from soils |
| US6923914B2 (en) * | 1996-12-17 | 2005-08-02 | Global Biosciences, Inc. | Remediation of metal contaminants with hydrocarbon-utilizing bacteria |
| US7270499B2 (en) * | 1998-04-20 | 2007-09-18 | Greenberg Richard S | Soil and/or groundwater remediation process |
| EA002263B1 (ru) * | 1998-05-14 | 2002-02-28 | Зелль, Петер | Способ очистки вод, грунтов, осадочных отложений и/или шламов |
| FR2806939B1 (fr) * | 2000-03-30 | 2002-12-06 | Patrice Jean Albert Stengel | Procede et dispositif de depollution des sables ou des terres souilles par des hydrocarbures ou des germes infectieux |
| US6630105B1 (en) * | 2000-09-27 | 2003-10-07 | The United States Of America As Represented By The United States Department Of Energy | Method and apparatus for the gas phase decontamination of chemical and biological agents |
| JP4671073B2 (ja) * | 2001-02-28 | 2011-04-13 | 清水建設株式会社 | 有機物汚染土壌の原位置修復法 |
| DE10114177A1 (de) * | 2001-03-23 | 2002-09-26 | Degussa | Verfahren zur Aufbereitung schadstoffhaltiger Wässer |
| US7329532B2 (en) | 2001-07-27 | 2008-02-12 | Global Biosciences, Inc. | Remediation of sulfur-containing pollutants with hydrocarbon-utilizing bacteria |
| US7928277B1 (en) | 2002-02-11 | 2011-04-19 | Cox Jr Henry Wilmore | Method for reducing contamination |
| AU2003215360A1 (en) * | 2002-02-22 | 2003-09-09 | University Of Utah Research Foundation | Remediation with ozone of sediments containing organic contaminants |
| BR0312037A (pt) * | 2002-06-26 | 2005-03-29 | Fmc Corp | Oxidação de compostos orgânicos |
| AUPS329702A0 (en) * | 2002-07-01 | 2002-07-18 | Sdp Pty Ltd | Method of soil geochemistry analysis prospecting |
| US6960330B1 (en) | 2002-07-12 | 2005-11-01 | Cox Jr Henry Wilmore | Method for reducing H2S contamination |
| US7074959B2 (en) | 2002-08-01 | 2006-07-11 | New Mexico Highlands University | Methods and systems for remediating hydrazine-contaminated equipment and/or surfaces |
| US7175770B2 (en) * | 2003-03-17 | 2007-02-13 | Groundwater And Environmental Services, Inc. | Methods and systems for groundwater remediation |
| US7264419B2 (en) * | 2003-03-19 | 2007-09-04 | Applied Process Technology, Inc. | System and method for remediating contaminated soil and groundwater in situ |
| US20040197150A1 (en) * | 2003-04-04 | 2004-10-07 | Xpert Design And Diagnostics, Llc | Chemical oxidation of organic and inorganic contaminants by chelated transition metals catalyzed persulfate |
| US7160471B2 (en) * | 2003-05-06 | 2007-01-09 | Westinghouse Savannah River Company, Llc | In-situ generation of oxygen-releasing metal peroxides |
| AU2003260523A1 (en) * | 2003-08-22 | 2005-03-10 | Fmc Foret, S.A. | Method, devices and reagents which are used for wastewater treatment |
| US7662294B1 (en) | 2004-02-02 | 2010-02-16 | Cox Jr Henry Wilmore | Method for reducing organic contamination |
| SI1755799T1 (en) * | 2004-05-27 | 2018-04-30 | Solvay Sa | Combined chemical oxidation / supported bioremediation of contaminants |
| US7833423B2 (en) * | 2004-06-01 | 2010-11-16 | Regenesis Bioremediation Products | Enhanced oxidation process for removal of water and soil contaminants |
| JP4596524B2 (ja) * | 2004-10-08 | 2010-12-08 | オルガノ株式会社 | 汚染土壌浄化方法 |
| US7481974B2 (en) * | 2005-02-17 | 2009-01-27 | Charles Sizer | Method and apparatus for sterilizing containers |
| CN101180141A (zh) * | 2005-05-19 | 2008-05-14 | 三菱瓦斯化学株式会社 | 土壤及/或地下水的净化方法 |
| ITMI20051559A1 (it) * | 2005-08-10 | 2007-02-11 | Eni Spa | Procedimento per la rimozione di barriere impermeabili presenti nei pozzi petroliferi |
| US20080041794A1 (en) * | 2006-08-17 | 2008-02-21 | Dowling College | Methods of decontaminating water, catalysts therefor and methods of making catalysts |
| US8609926B1 (en) | 2006-11-21 | 2013-12-17 | Henry Wilmore Cox, Jr. | Methods for managing sulfide in wastewater systems |
| US7846408B1 (en) | 2006-11-21 | 2010-12-07 | Cox Jr Henry Wilmore | Compositions, methods, and systems for managing total sulfide |
| ITMI20080995A1 (it) * | 2008-05-28 | 2009-11-29 | Eni Spa | Metodo per la bonifica in situ di un'area contaminata da composti organici |
| US8293696B2 (en) * | 2009-02-06 | 2012-10-23 | Ecolab, Inc. | Alkaline composition comprising a chelant mixture, including HEIDA, and method of producing same |
| SMT201700517T1 (it) * | 2009-02-11 | 2018-01-11 | Natural Energy Systems Inc | Processo per la conversione di materiale organico in gas combustibile ricco di metano |
| FR2951096B1 (fr) * | 2009-10-09 | 2013-03-15 | Total Sa | Procede d'oxydation de composes organiques |
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| JP5733781B2 (ja) | 2010-03-31 | 2015-06-10 | 国立研究開発法人農業・食品産業技術総合研究機構 | コーヒー粕あるいは茶殻を原料とするフェントン反応触媒 |
| TWI551551B (zh) * | 2010-04-30 | 2016-10-01 | 三菱瓦斯化學股份有限公司 | 過氧化物活性化劑以及土壤及／或地下水之淨化方法 |
| JP2012239952A (ja) * | 2011-05-17 | 2012-12-10 | National Agriculture & Food Research Organization | 還元性有機物を原料とするフェントン反応触媒 |
| JP5888877B2 (ja) * | 2011-05-30 | 2016-03-22 | 株式会社Adeka | 化学物質分解剤組成物及びそれを用いた化学物質の分解処理方法 |
| CN105246830B (zh) | 2013-05-24 | 2017-10-31 | 索尔维公司 | 非氧化剂颗粒 |
| US9771284B2 (en) * | 2013-12-30 | 2017-09-26 | Environmental Technology and Investment Corporation | Situ chemical fixaton of metal contaminants |
| US10252303B2 (en) * | 2015-06-01 | 2019-04-09 | Michael Lindstrom | Method to remediate soil and groundwater |
| WO2017180621A1 (en) * | 2016-04-14 | 2017-10-19 | Phillips 66 Company | Method of remediating groundwater |
| WO2019168635A2 (en) * | 2018-03-01 | 2019-09-06 | Arkema Inc. | Soil treatment using peroxide |
| AU2020203659B2 (en) * | 2018-10-15 | 2021-04-08 | Anthony Doherty | Method of treating contaminated groundwater |
| JP7267112B2 (ja) * | 2019-06-04 | 2023-05-01 | ジオテクノス株式会社 | 汚染土壌の浄化方法 |
| CN112537839A (zh) * | 2020-11-17 | 2021-03-23 | 同济大学 | 一种过氧化钙-黄铁矿修复河网地区地下水重金属污染的办法 |
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|---|---|---|---|---|
| US5789649A (en) * | 1995-08-29 | 1998-08-04 | E. I. Du Pont De Nemours And Company | Method for Remediating contaminated soils |
| US5741427A (en) * | 1996-03-14 | 1998-04-21 | Anesys Corp. | Soil and/or groundwater remediation process |
| US5755977A (en) * | 1996-07-03 | 1998-05-26 | Drexel University | Continuous catalytic oxidation process |
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2000
- 2000-06-22 DK DK00943068T patent/DK1212149T3/da active
- 2000-06-22 CA CA002370097A patent/CA2370097C/en not_active Expired - Fee Related
- 2000-06-22 AU AU57593/00A patent/AU780219B2/en not_active Expired
- 2000-06-22 JP JP2001507588A patent/JP3793084B2/ja not_active Expired - Lifetime
- 2000-06-22 EP EP00943068A patent/EP1212149B1/en not_active Expired - Lifetime
- 2000-06-22 WO PCT/US2000/017231 patent/WO2001002105A1/en not_active Ceased
- 2000-06-22 DE DE60041772T patent/DE60041772D1/de not_active Expired - Lifetime
- 2000-06-22 ES ES00943068T patent/ES2322540T3/es not_active Expired - Lifetime
- 2000-06-22 AT AT00943068T patent/ATE424942T1/de not_active IP Right Cessation
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2001
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| CA2370097C (en) | 2006-11-21 |
| WO2001002105A1 (en) | 2001-01-11 |
| CA2370097A1 (en) | 2001-01-11 |
| DE60041772D1 (de) | 2009-04-23 |
| JP3793084B2 (ja) | 2006-07-05 |
| EP1212149B1 (en) | 2009-03-11 |
| DK1212149T3 (da) | 2009-06-08 |
| AU780219B2 (en) | 2005-03-10 |
| ATE424942T1 (de) | 2009-03-15 |
| JP2003503197A (ja) | 2003-01-28 |
| EP1212149A1 (en) | 2002-06-12 |
| US6319328B1 (en) | 2001-11-20 |
| AU5759300A (en) | 2001-01-22 |
| US20020002983A1 (en) | 2002-01-10 |
| EP1212149A4 (en) | 2004-09-29 |
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