ES2224269T3 - Composicion de caucho y neumatico producido a partir de la misma. - Google Patents
Composicion de caucho y neumatico producido a partir de la misma.Info
- Publication number
- ES2224269T3 ES2224269T3 ES97941194T ES97941194T ES2224269T3 ES 2224269 T3 ES2224269 T3 ES 2224269T3 ES 97941194 T ES97941194 T ES 97941194T ES 97941194 T ES97941194 T ES 97941194T ES 2224269 T3 ES2224269 T3 ES 2224269T3
- Authority
- ES
- Spain
- Prior art keywords
- silane
- polysulfide
- coupling agent
- rubber
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 229920001971 elastomer Polymers 0.000 title claims abstract description 59
- 239000005060 rubber Substances 0.000 title claims abstract description 59
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 98
- 229920001021 polysulfide Polymers 0.000 claims abstract description 82
- 150000008117 polysulfides Polymers 0.000 claims abstract description 81
- 239000005077 polysulfide Substances 0.000 claims abstract description 80
- -1 PHOSPHORUS COMPOUND Chemical class 0.000 claims abstract description 24
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 16
- 239000011574 phosphorus Substances 0.000 claims abstract description 16
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 5
- 229920001194 natural rubber Polymers 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- 229910000077 silane Inorganic materials 0.000 claims description 97
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 51
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 24
- 239000000377 silicon dioxide Substances 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 23
- 239000006229 carbon black Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 11
- 125000004434 sulfur atom Chemical group 0.000 claims description 11
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 9
- 230000002787 reinforcement Effects 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 4
- 229920003051 synthetic elastomer Polymers 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005061 synthetic rubber Substances 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims description 2
- 150000003003 phosphines Chemical class 0.000 claims description 2
- 238000009826 distribution Methods 0.000 abstract description 11
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 12
- 238000009825 accumulation Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 230000008878 coupling Effects 0.000 description 9
- 238000010168 coupling process Methods 0.000 description 9
- 238000005859 coupling reaction Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 125000000101 thioether group Chemical group 0.000 description 8
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 8
- 238000001879 gelation Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241001441571 Hiodontidae Species 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000006237 Intermediate SAF Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31939996 | 1996-11-29 | ||
| JP31939996 | 1996-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2224269T3 true ES2224269T3 (es) | 2005-03-01 |
Family
ID=18109754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97941194T Expired - Lifetime ES2224269T3 (es) | 1996-11-29 | 1997-09-19 | Composicion de caucho y neumatico producido a partir de la misma. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6147166A (enExample) |
| EP (1) | EP0879848B1 (enExample) |
| JP (1) | JP3445620B2 (enExample) |
| KR (1) | KR100305604B1 (enExample) |
| CN (1) | CN1209826A (enExample) |
| DE (1) | DE69730012T2 (enExample) |
| ES (1) | ES2224269T3 (enExample) |
| WO (1) | WO1997048264A2 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997048267A2 (en) * | 1996-12-16 | 1997-12-24 | Bridgestone Corporation | Rubber composition and pneumatic tires produced therefrom |
| DE19858863A1 (de) * | 1998-12-19 | 2000-06-21 | Degussa | Organosilanpolysulfanen enthaltende Gummimischungen |
| JP4369547B2 (ja) * | 1999-02-02 | 2009-11-25 | 株式会社ブリヂストン | 重荷重用空気入りタイヤ |
| DE19916498A1 (de) * | 1999-04-12 | 2000-10-19 | Degussa | Organosilan-Abmischungen, sowie Kieselsäure enthaltende, vulkanisierbare Kautschukmischungen |
| US6561244B2 (en) * | 2001-02-01 | 2003-05-13 | The Goodyear Tire & Rubber Company | Tire having tread with colored groove configuration |
| US6561243B2 (en) * | 2001-02-01 | 2003-05-13 | The Goodyear Tire & Rubber Company | Tire having tread with colored sidewall in connection with a plurality of colored tread grooves |
| US6612351B1 (en) * | 2001-02-05 | 2003-09-02 | The Goodyear Tire & Rubber Company | Pneumatic tire having dual air retention quasi envelopes |
| US20040014869A1 (en) * | 2001-05-09 | 2004-01-22 | Wong Wai Keung | Method for preparing silica filled elastomeric compositions |
| RU2328511C2 (ru) * | 2001-11-26 | 2008-07-10 | Сосьете Де Текноложи Мишлен | Резиновая смесь для протектора шины и способ ее получения |
| KR20030049659A (ko) * | 2001-12-17 | 2003-06-25 | 한국타이어 주식회사 | 스터드레스 타이어 트레드용 고무 조성물 |
| KR100621210B1 (ko) | 2005-08-09 | 2006-09-07 | 한국타이어 주식회사 | 실리카 컴파운드 고무의 실란화율 분석방법 |
| CN102286179B (zh) * | 2007-10-19 | 2016-06-29 | 朗盛公司 | 包括三种组分的混合改性剂体系的丁基橡胶胶料 |
| KR20180059790A (ko) * | 2015-08-28 | 2018-06-05 | 아란세오 도이치란드 게엠베하 | 효율 증가된 탈황 시약 |
| DE102019213978A1 (de) * | 2019-09-13 | 2021-03-18 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung, Vulkanisat und Fahrzeugreifen |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA432867A (en) * | 1940-07-23 | 1946-01-29 | Monsanto Chemical Company | Vulcanizable gum composition |
| US3978103A (en) | 1971-08-17 | 1976-08-31 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Sulfur containing organosilicon compounds |
| JPS5120208A (en) * | 1974-08-12 | 1976-02-18 | Tatsuo Ikeno | Anshodehatsukosuru tojishitsutairu oyobi sonotairuomochiita mozaikuban |
| US3951927A (en) * | 1974-09-18 | 1976-04-20 | American Cyanamid Company | Vulcanizable elastomers from polythiodiethanol |
| DE2848559C2 (de) | 1978-11-09 | 1982-01-21 | Degussa Ag, 6000 Frankfurt | Reversionsfreie Vulkanisate ergebende Kautschukmischungen und deren Verwendung |
| DE3314742C2 (de) * | 1983-04-23 | 1987-04-02 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von an der Oberfläche modifizierten natürlichen, oxidischen oder silikatischen Füllstoffen und deren Verwendung |
| JP3021516B2 (ja) * | 1990-03-02 | 2000-03-15 | 株式会社ブリヂストン | 空気入りタイヤ |
| CA2105334C (en) * | 1993-04-02 | 2004-03-30 | Jean Bergh | Tire with silica reinforced tread |
| CA2104528A1 (en) * | 1993-05-05 | 1994-11-06 | Paul Harry Sandstrom | Tire with tread containing silica reinforcement |
| CA2129281A1 (en) * | 1994-05-11 | 1995-11-12 | Lawson Gibson Wideman | Silica reinforced rubber composition |
| US5534574A (en) * | 1995-03-10 | 1996-07-09 | The Goodyear Tire & Rubber Company | Silica reinforced rubber preparation and tire with tread thereof |
| JP3388531B2 (ja) * | 1996-11-29 | 2003-03-24 | 信越化学工業株式会社 | ポリスルフィドシランの脱硫方法 |
-
1997
- 1997-09-19 US US08/934,397 patent/US6147166A/en not_active Expired - Lifetime
- 1997-09-19 JP JP50270098A patent/JP3445620B2/ja not_active Expired - Fee Related
- 1997-09-19 CN CN97191939A patent/CN1209826A/zh active Pending
- 1997-09-19 ES ES97941194T patent/ES2224269T3/es not_active Expired - Lifetime
- 1997-09-19 EP EP97941194A patent/EP0879848B1/en not_active Expired - Lifetime
- 1997-09-19 KR KR1019980705204A patent/KR100305604B1/ko not_active Expired - Fee Related
- 1997-09-19 DE DE69730012T patent/DE69730012T2/de not_active Expired - Lifetime
- 1997-09-19 WO PCT/JP1997/003308 patent/WO1997048264A2/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE69730012D1 (de) | 2004-09-02 |
| CN1209826A (zh) | 1999-03-03 |
| EP0879848A4 (enExample) | 1998-12-30 |
| KR100305604B1 (ko) | 2001-11-22 |
| JP3445620B2 (ja) | 2003-09-08 |
| KR19990077070A (ko) | 1999-10-25 |
| WO1997048264A3 (en) | 1998-02-26 |
| WO1997048264A2 (en) | 1997-12-24 |
| EP0879848A2 (en) | 1998-11-25 |
| US6147166A (en) | 2000-11-14 |
| EP0879848B1 (en) | 2004-07-28 |
| DE69730012T2 (de) | 2004-11-25 |
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