ES2186190T3 - Polimeros anfifilos a base de poliesteres con grupos acetalicos introducidos por condensacion, que son liquidos a temperatura ambiente, asi como su empleo en agentes de lavado y limpieza. - Google Patents
Polimeros anfifilos a base de poliesteres con grupos acetalicos introducidos por condensacion, que son liquidos a temperatura ambiente, asi como su empleo en agentes de lavado y limpieza.Info
- Publication number
- ES2186190T3 ES2186190T3 ES98936424T ES98936424T ES2186190T3 ES 2186190 T3 ES2186190 T3 ES 2186190T3 ES 98936424 T ES98936424 T ES 98936424T ES 98936424 T ES98936424 T ES 98936424T ES 2186190 T3 ES2186190 T3 ES 2186190T3
- Authority
- ES
- Spain
- Prior art keywords
- groups
- group
- carbon atoms
- polyesters
- constituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 3
- 239000007788 liquid Substances 0.000 title abstract 2
- 239000012459 cleaning agent Substances 0.000 title 1
- 230000005494 condensation Effects 0.000 title 1
- 238000009833 condensation Methods 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 6
- 125000005702 oxyalkylene group Chemical group 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 125000004036 acetal group Chemical group 0.000 abstract 2
- 239000000203 mixture Chemical group 0.000 abstract 2
- 125000006353 oxyethylene group Chemical group 0.000 abstract 2
- -1 poly (oxyethylene) Polymers 0.000 abstract 2
- 150000003077 polyols Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 150000001346 alkyl aryl ethers Chemical group 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 125000003435 aroyl group Chemical group 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920002601 oligoester Polymers 0.000 abstract 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
- D06M15/5075—Polyesters containing sulfonic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
- C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6886—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Polyesters Or Polycarbonates (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Poliésteres líquidos anfífilos a temperatura ambiente, caracterizados porque los poliésteres anfífilos están caracterizados por la fórmula aditiva empírica I (CAP)x(T)z(I)q(D)r(P)s(En)t(A)y(PG)v (I), en la que (CAP) representa grupos terminales que bloquean el polímero en el extremo, y son a) grupos sulfoaroilo, b) grupos con la fórmula MO3-S-(O)u-(CH2)p-(RO)w-, en la que M representa un ion metálico, un ion alcalino, o un ion amonio substituido, y R representa etileno, o mezclas de etileno y propileno, u representa 0 o 1, p representa 0 o 1, y w representa un número de 1 a 100, c) grupos poli(oxietilen)monoalquiléter, en los cuales el grupo alquilo contiene 1 a 24 átomos de carbono, y el grupo polioxietileno está constituido por 2 a 200 unidades oxietileno, d) grupos acilo y aroilo con 4 a 40 átomos de carbono, e) grupos hidroxiacilo e hidroxiaroilo con 2 a 25 átomos de carbono, f) poli(oxialquilen)monoalquilfenoléter, en los cuales el grupoalquilo contiene 6 a 18 átomos de carbono, y el grupo polioxialquileno está constituido por 0 a 80 unidades oxialquileno, g) mezclas de los mismos, y x representa valores de 0 a 2, (T) representa un grupo arilendicarbonilo, y z representa un número mayor que 0 a 50, (I) representa un grupo aniónico interno, y q representa un número de 0 a 30, (D) representa un grupo acetálico, y r representa un número mayor que 0 a 80, siendo obtenible el grupo acetálico mediante reacción de ésteres formílicos o dialdehídos, o bien sus acetales, con glicerina, (P) representa un grupo poliol con al menos 3 grupos hidroxilo, y s representa un número de 0 a 80, siendo la fracción de poliol menor que un 30 % en moles, referido a la suma de unidades monómeras, (En)representa un grupo poli(oxialquilen)oxi, que está constituido por 2 a 100 grupos oxialquileno, preferentemente grupos oxietileno, significando t un número de 0 a 25, y conteniendo los grupos alquilo 2 a6 átomos de carbono, (A) representa un grupo 1,n-alquilendicarbonilo, que está constituido por 2 a 24 átomos de carbono, e y representa un número de 0 a 15, (PG)representa un grupo oxipropilenoxi, y v representa un número de 0 a 80, y poseyendo los oligo/poliésteres pesos moleculares de 500 a 100 000.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19735715A DE19735715A1 (de) | 1997-08-18 | 1997-08-18 | Amphiphile Polymere auf Basis von Polyestern mit einkondensierten acetalischen Gruppen, die bei Raumtemperatur flüssig sind, sowie ihr Einsatz in Wasch- und Reinigungsmitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2186190T3 true ES2186190T3 (es) | 2003-05-01 |
Family
ID=7839278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98936424T Expired - Lifetime ES2186190T3 (es) | 1997-08-18 | 1998-07-15 | Polimeros anfifilos a base de poliesteres con grupos acetalicos introducidos por condensacion, que son liquidos a temperatura ambiente, asi como su empleo en agentes de lavado y limpieza. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6537961B1 (es) |
| EP (1) | EP1005519B1 (es) |
| JP (1) | JP2001515125A (es) |
| CN (1) | CN1270625A (es) |
| AT (1) | ATE226242T1 (es) |
| DE (2) | DE19735715A1 (es) |
| DK (1) | DK1005519T3 (es) |
| ES (1) | ES2186190T3 (es) |
| HU (1) | HUP0004311A3 (es) |
| WO (1) | WO1999009125A1 (es) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19906367A1 (de) * | 1999-02-16 | 2000-08-17 | Clariant Gmbh | Verwendung von Kammpolymeren als Schutzablösepolymere |
| DE19953457A1 (de) | 1999-11-05 | 2001-05-23 | Rwe Dea Ag | Verfahren zur Reinigung von Oberflächen |
| DE10043604A1 (de) * | 2000-09-02 | 2002-03-28 | Rwe Dea Ag | Fließfähige, amphiphile und nichtionische Oligoester |
| KR100902171B1 (ko) * | 2001-03-08 | 2009-06-10 | 더 트러스티스 오브 더 유니버시티 오브 펜실베니아 | 항-감염제로서의 표면적 친양쪽성 중합체 |
| EP1608313A4 (en) * | 2003-03-17 | 2009-05-06 | Univ Pennsylvania | AMPHIPHILIC SURFACE POLYMERS AND OLIGOMERS AND USES THEREOF |
| US7279455B2 (en) * | 2003-11-06 | 2007-10-09 | Ecolab, Inc. | Rinse aid composition and method of rising a substrate |
| DE10358097A1 (de) * | 2003-12-10 | 2005-07-14 | Sasol Germany Gmbh | Verfahren zum Verhindern bzw. Minimieren der Farbredeposition unter Verwendung von Polyestern |
| EP1711455A4 (en) | 2004-01-23 | 2007-11-07 | Univ Pennsylvania | POLYARYL AND POLYARYLALKYNYL OLIGOMERS AMPHIPHILES AT THE FACIAL LEVEL |
| DE102004056785A1 (de) * | 2004-11-24 | 2006-06-01 | Sasol Germany Gmbh | Fließfähige, amphiphile und nichtionische Oligoester |
| CA2599205A1 (en) * | 2005-02-25 | 2006-09-08 | The Trustees Of The University Of Pennsylvania | Facially amphiphilic polymers and oligomers, compositions thereof, and use thereof in methods of treating cancer |
| DE102005027604A1 (de) * | 2005-06-15 | 2006-12-28 | Clariant Produkte (Deutschland) Gmbh | Reinigungsmittel für harte Oberflächen |
| DE102005061058A1 (de) * | 2005-12-21 | 2007-07-05 | Clariant Produkte (Deutschland) Gmbh | Anionische Soil Release Polymere |
| DE102007013217A1 (de) | 2007-03-15 | 2008-09-18 | Clariant International Ltd. | Anionische Soil Release Polymere |
| US7521412B2 (en) | 2007-05-25 | 2009-04-21 | Ecolab Inc. | Dimensionally stable solid rinse aid |
| US8383570B2 (en) | 2007-05-25 | 2013-02-26 | Ecolab Usa Inc. | Enhanced melting point rinse aid solid compositions with synergistic preservative |
| US20110108068A1 (en) | 2007-05-25 | 2011-05-12 | Ecolab Usa Inc. | Enhanced melting point rinse aid solids |
| DE102008028409A1 (de) * | 2008-06-17 | 2009-12-24 | Clariant International Ltd. | Verfahren zur Herstellung von Polyester-Granulaten |
| AU2010247013B2 (en) | 2009-05-12 | 2015-02-26 | Ecolab Usa Inc. | Fast drying and fast draining rinse aid |
| US8567161B2 (en) * | 2009-05-28 | 2013-10-29 | Ecolab Usa Inc. | Wetting agents for aseptic filling |
| US8871702B2 (en) | 2009-11-27 | 2014-10-28 | Clariant Finance (Bvi) Limited | Soil-release polymers having a grey-inhibiting effect and having high stability in solution |
| WO2011063945A1 (de) | 2009-11-27 | 2011-06-03 | Clariant International Ltd | Polyester-konzentrate mit hoher lösestabilität und vergrauungsinhibierender wirkung |
| US9567551B2 (en) | 2012-06-22 | 2017-02-14 | Ecolab Usa Inc. | Solid rinse aid composition and method of making same |
| US9011610B2 (en) | 2012-06-22 | 2015-04-21 | Ecolab Usa Inc. | Solid fast draining/drying rinse aid for high total dissolved solid water conditions |
| US10550354B2 (en) | 2015-05-19 | 2020-02-04 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
| CN109153947B (zh) | 2016-05-23 | 2021-03-16 | 埃科莱布美国股份有限公司 | 通过使用高分子量油包水乳液聚合物的减少雾化的碱性和中性清洁、消毒和杀菌组合物 |
| JP6791987B2 (ja) | 2016-05-23 | 2020-11-25 | エコラボ ユーエスエー インコーポレイティド | 高分子量油中水型乳化ポリマーを用いた、ミスティングが低減した酸性洗浄、除菌および消毒組成物の削減 |
| CA3054827C (en) | 2017-03-01 | 2023-02-14 | Ecolab Usa Inc. | Reduced inhalation hazard sanitizers and disinfectants via high molecular weight polymers |
| EP3489340A1 (en) | 2017-11-28 | 2019-05-29 | Clariant International Ltd | Renewably sourced soil release polyesters |
| CA3107070A1 (en) | 2018-07-25 | 2020-01-30 | Ecolab Usa Inc. | Rinse aid formulation for cleaning automotive parts |
| PL3680317T3 (pl) * | 2019-01-11 | 2023-02-06 | Henkel Ag & Co. Kgaa | Środki piorące chroniące kolor |
| WO2021011451A1 (en) | 2019-07-12 | 2021-01-21 | Ecolab Usa Inc. | Reduced mist alkaline cleaner via the use of alkali soluble emulsion polymers |
| BR112022020079A2 (pt) * | 2020-05-20 | 2022-11-29 | Clariant Int Ltd | Poliésteres de liberação da sujeira para uso em composições de detergentes |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1088984A (en) | 1963-06-05 | 1967-10-25 | Ici Ltd | Modifying treatment of shaped articles derived from polyesters |
| NL133089C (es) * | 1965-03-27 | |||
| US3959230A (en) | 1974-06-25 | 1976-05-25 | The Procter & Gamble Company | Polyethylene oxide terephthalate polymers |
| DE2448954C3 (de) * | 1974-10-15 | 1978-03-09 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Verminderung der Pilling-Neigung von Fasermaterialien aus Polyestern |
| US4159978A (en) | 1975-07-10 | 1979-07-03 | Rhone-Poulenc Industries | Polyacetal polymers and their application as soil release and anti-soil redeposition agents for textile substrates |
| US4427557A (en) | 1981-05-14 | 1984-01-24 | Ici Americas Inc. | Anionic textile treating compositions |
| CA1190695A (en) | 1981-05-14 | 1985-07-16 | George J. Stockburger | Anionic textile treating compositions |
| DE3324258A1 (de) | 1982-07-09 | 1984-01-12 | Colgate-Palmolive Co., 10022 New York, N.Y. | Nichtionogene waschmittelzusammensetzung mit verbesserter schmutzauswaschbarkeit |
| NZ207692A (en) | 1983-04-04 | 1986-04-11 | Colgate Palmolive Co | Soil-release promoting liquid detergent containing terephthalate polymers |
| US4569772A (en) | 1984-09-04 | 1986-02-11 | Colgate-Palmolive | Stabilization of polyethylene terephthalate-polyoxyethylene terephthalate soil release promoting polymers |
| US4571303A (en) | 1985-01-23 | 1986-02-18 | Colgate-Palmolive Company | Built nonionic detergent composition containing stabilized polyethylene terephthalate-polyoxyethylene terephthalate soil release promoting polymer |
| US4711730A (en) | 1986-04-15 | 1987-12-08 | The Procter & Gamble Company | Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents |
| GB8617255D0 (en) | 1986-07-15 | 1986-08-20 | Procter & Gamble Ltd | Laundry compositions |
| US4785060A (en) | 1986-08-28 | 1988-11-15 | Colgate-Palmolive Company | Soil release promoting pet-poet copolymer, method of producing same and use thereof in detergent composition having soil release promoting property |
| US4740326A (en) | 1987-02-19 | 1988-04-26 | The Procter & Gamble Company | Soil release polymer coated substrate containing a laundry detergent for improved cleaning performance |
| US4849257A (en) | 1987-12-01 | 1989-07-18 | The Procter & Gamble Company | Articles and methods for treating fabrics in dryer |
| EP0357280B1 (en) | 1988-08-26 | 1996-02-28 | The Procter & Gamble Company | Soil release agents having allylderived sulfonated end caps |
| US4956447A (en) | 1989-05-19 | 1990-09-11 | The Procter & Gamble Company | Rinse-added fabric conditioning compositions containing fabric sofening agents and cationic polyester soil release polymers and preferred cationic soil release polymers therefor |
| DE4001415A1 (de) * | 1990-01-19 | 1991-07-25 | Basf Ag | Polyester, die nichtionische tenside einkondensiert enthalten, ihre herstellung und ihre verwendung in waschmitteln |
| CA2092186C (en) | 1990-09-28 | 1997-12-09 | Robert Y. Pan | Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions |
| DE69208549T3 (de) | 1991-07-17 | 1999-04-22 | Unilever Nv | Wasserlösliches oder in Wasser dispergierbares Copolymer mit UV-Strahlen absorbierendem Monomer enthaltendes Wäschepflegemittel |
| DE4403866A1 (de) * | 1994-02-08 | 1995-08-10 | Basf Ag | Amphiphile Polyester, Verfahren zu ihrer Herstellung und ihre Verwendung in Waschmitteln |
| DE4441189A1 (de) * | 1994-11-18 | 1996-05-23 | Basf Ag | Verfahren zur Herstellung von feinteiligen Mischungen aus amphiphilen Polymeren und anorganischen Feststoffen |
| DE19506634A1 (de) * | 1995-02-25 | 1996-08-29 | Basf Ag | Verfahren zur Herstellung von feinteiligen Mischungen aus amphiphilen Polymeren und Polycarboxylaten und ihre Verwendung |
| HUP9802563A3 (en) * | 1995-09-01 | 1999-08-30 | Huels Chemische Werke Ag | Soil-releasing polymers made from polycarbonates and used as a component of formulations for removing oil and grease |
-
1997
- 1997-08-18 DE DE19735715A patent/DE19735715A1/de not_active Withdrawn
-
1998
- 1998-07-15 WO PCT/EP1998/004392 patent/WO1999009125A1/de active IP Right Grant
- 1998-07-15 DK DK98936424T patent/DK1005519T3/da active
- 1998-07-15 HU HU0004311A patent/HUP0004311A3/hu unknown
- 1998-07-15 ES ES98936424T patent/ES2186190T3/es not_active Expired - Lifetime
- 1998-07-15 AT AT98936424T patent/ATE226242T1/de not_active IP Right Cessation
- 1998-07-15 JP JP2000509792A patent/JP2001515125A/ja active Pending
- 1998-07-15 DE DE59805993T patent/DE59805993D1/de not_active Expired - Fee Related
- 1998-07-15 EP EP98936424A patent/EP1005519B1/de not_active Expired - Lifetime
- 1998-07-15 US US09/485,962 patent/US6537961B1/en not_active Expired - Fee Related
- 1998-07-15 CN CN98809110A patent/CN1270625A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0004311A3 (en) | 2001-11-28 |
| DE59805993D1 (de) | 2002-11-21 |
| DE19735715A1 (de) | 1999-02-25 |
| HUP0004311A2 (hu) | 2001-04-28 |
| CN1270625A (zh) | 2000-10-18 |
| DK1005519T3 (da) | 2003-02-17 |
| US6537961B1 (en) | 2003-03-25 |
| WO1999009125A1 (de) | 1999-02-25 |
| JP2001515125A (ja) | 2001-09-18 |
| EP1005519B1 (de) | 2002-10-16 |
| EP1005519A1 (de) | 2000-06-07 |
| ATE226242T1 (de) | 2002-11-15 |
| WO1999009125A8 (de) | 1999-05-06 |
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