ES2194411T3 - Procedimiento para la preparacion de esteres con acido acrilico y/o esteres con acido metacrilico de siloxanos que tienen funcionalidad hidroxi y/o de siloxanos modificados con poli (oxialquileno) y su utilizacion. - Google Patents

Procedimiento para la preparacion de esteres con acido acrilico y/o esteres con acido metacrilico de siloxanos que tienen funcionalidad hidroxi y/o de siloxanos modificados con poli (oxialquileno) y su utilizacion.

Info

Publication number
ES2194411T3
ES2194411T3 ES99121019T ES99121019T ES2194411T3 ES 2194411 T3 ES2194411 T3 ES 2194411T3 ES 99121019 T ES99121019 T ES 99121019T ES 99121019 T ES99121019 T ES 99121019T ES 2194411 T3 ES2194411 T3 ES 2194411T3
Authority
ES
Spain
Prior art keywords
esters
acrylic acid
meth
hydroxy
oxialquylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99121019T
Other languages
English (en)
Inventor
Burghard Dr Gruning
Geoffrey Hills
Wolfgang Dr Josten
Dietmar Dr Schaefer
Stefan Dr Silber
Christian Dr Weitemeyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
TH Goldschmidt AG
Goldschmidt GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TH Goldschmidt AG, Goldschmidt GmbH filed Critical TH Goldschmidt AG
Application granted granted Critical
Publication of ES2194411T3 publication Critical patent/ES2194411T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P9/00—Preparation of organic compounds containing a metal or atom other than H, N, C, O, S or halogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Silicon Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Paints Or Removers (AREA)

Abstract

Esterificación catalizada con enzimas de acrilato o metacrilato con siloxano hidroxi funcional y/o modificado con poloxialquileno, con la que se obtienen productos a utilizar, ej., en la producción de polímeros y revestimientos curados por radiación. Se hace uso de un procedimiento catalizado con enzimas para la esterificación y/o transesterificación de ácido (met)acrílico o ésteres de (met)acrilato con derivados de siloxano hidroxi funcionales y/o modificados con polioxialquileno. Un procedimiento para la esterificación y/o transesterificación catalizada con enzimas de ácido (met)acrílico o ésteres de (met)acrilato con derivados de siloxano hidroxi funcionales y/o modificados con polioxialquileno de fórmula (I): R2, R3 = grupos alquilo C1-24 o alquileno, iguales o diferentes, o grupos fenilo C6-24 opcionalmente sustituidos; R4 = O, NH, NR2, S o -(OSi(CH3)2O)u-; u = 1-200; R5 = alquilo C1-24 o alquileno, o el grupo -CnH2n-fR2f-R4-CmH2m-gR2g; f, g = 0-12; n, m = 1-18; R6 = -O-(C2H4-aR2aO)b(C2H2cO)d- (con los segmentos polioxialquileno en cualquier secuencia, especialmente como copolímeros en bloque y polímeros estadísticos o una combinación de los mismos) o -Oe-ChH2h-CI-H2I-jR9j; a = 0-3; b, d = 0-100; c = 2-12; (b+d) = 1-200; e = 0 ó 1; h, i = 0-24; j = 1-3; (w+e) = 0-1; R9 = -O-, OH, -CnH2h- o -CkH2k-l(OH)l; k = 0-24; l = 1-3; R8 = H o un residuo orgánico monovalente si y = 1 (con la condición de que esté presente al menos un grupo/molécula de hidrógeno), u OH o un residuo orgánico monovalente si y = 0 (con al menos un grupo/molécula de OH); v, z = 0-200; w, x, y = 0 ó 1; (w+x+y) = 1-3; R1 y/o R7 = (R4w-(R5)x-(R6)y-R8 si z = 0; w = 0 si x = 0.
ES99121019T 1998-11-03 1999-10-21 Procedimiento para la preparacion de esteres con acido acrilico y/o esteres con acido metacrilico de siloxanos que tienen funcionalidad hidroxi y/o de siloxanos modificados con poli (oxialquileno) y su utilizacion. Expired - Lifetime ES2194411T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19850507A DE19850507C1 (de) 1998-11-03 1998-11-03 Verfahren zur Herstellung von Acrylsäureestern und/oder Methacrylsäureestern von hydroxyfunktionellen Siloxanen und/oder polyoxyalkylenmodifizierten Siloxanen und deren Verwendung

Publications (1)

Publication Number Publication Date
ES2194411T3 true ES2194411T3 (es) 2003-11-16

Family

ID=7886439

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99121019T Expired - Lifetime ES2194411T3 (es) 1998-11-03 1999-10-21 Procedimiento para la preparacion de esteres con acido acrilico y/o esteres con acido metacrilico de siloxanos que tienen funcionalidad hidroxi y/o de siloxanos modificados con poli (oxialquileno) y su utilizacion.

Country Status (7)

Country Link
US (1) US6288129B1 (es)
EP (1) EP0999230B1 (es)
JP (1) JP2000139488A (es)
AT (1) ATE237653T1 (es)
CA (1) CA2288384C (es)
DE (2) DE19850507C1 (es)
ES (1) ES2194411T3 (es)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4505895B2 (ja) * 1999-09-30 2010-07-21 チッソ株式会社 シリコーン変性ビニル系樹脂、その製造方法およびそれを含有するコーティング剤
WO2003074718A1 (en) * 2002-03-06 2003-09-12 Ciba Specialty Chemicals Holding Inc. Enzymatic process for preparing organosilicon group containing photoinitiators
US7205373B2 (en) * 2002-08-16 2007-04-17 Dow Corning Corporation Enzyme catalyzed organosilicon esters and amides
EP1539777B1 (en) * 2002-08-16 2012-06-06 Dow Corning Corporation Enzyme catalyzed organosilicon carbohydrates
US6962963B2 (en) * 2002-10-18 2005-11-08 University Of Massachusetts Enzymatic synthesis of polymers
DE10251729A1 (de) 2002-11-05 2004-05-13 Basf Coatings Ag UV-aktive Bindemittel
DE10257094A1 (de) 2002-12-05 2004-06-24 Basf Ag Enzymatische Herstellung urethangruppenhaltiger (Meth)acrylsäureester
RU2351615C2 (ru) * 2003-06-06 2009-04-10 Циба Спешиалти Кемикэлз Холдинг Инк. Новые поверхностно-активные полисилоксановые фотоинициаторы
DE102004024009A1 (de) * 2004-05-14 2005-12-01 Goldschmidt Gmbh Verwendung von neuen Polysiloxanen mit über SiOC-Gruppen gebundenen (Meth)acrylsäureestergruppen als Additive für strahlenhärtende Beschichtungen
FR2877007B1 (fr) * 2004-10-22 2006-12-08 Rhodia Chimie Sa Preparation de silicones et silanes fonctionnalises via une catalyse enzymatique
DE102007058713A1 (de) 2007-12-06 2009-06-10 Evonik Goldschmidt Gmbh Silicon(meth-)acrylat-Partikel, Verfahren zu deren Herstellung sowie deren Verwendung
JP5051383B2 (ja) * 2008-04-25 2012-10-17 信越化学工業株式会社 （メタ）アクリル変性シロキサン化合物及びそれを含有する硬化性組成物
JP4646152B2 (ja) * 2008-05-27 2011-03-09 信越化学工業株式会社 眼科デバイス製造用モノマー
DE102008042381A1 (de) * 2008-09-26 2010-04-01 Evonik Goldschmidt Gmbh Emulgator-Systeme für kosmetische und pharmazeutische Öl-in-Wasser-Emulsionen
DE102009003035A1 (de) * 2009-05-12 2010-11-18 Basf Se Verfahren zur Herstellung von urethangruppenhaltigen (Meth)acrylsäureestern
DE102009022630A1 (de) 2009-05-25 2010-12-02 Evonik Goldschmidt Gmbh Emulsionen auf Basis Silylgruppen tragender Hydroxylverbindungen
FR2946658B1 (fr) * 2009-06-11 2011-08-05 Commissariat Energie Atomique Dispositif microfluidique comportant deux couches hydrophobes assemblees l'une a l'autre et procede d'assemblage
DE102009045116A1 (de) 2009-09-29 2011-03-31 Evonik Degussa Gmbh Niederdruckvermahlungsverfahren
DE102010062156A1 (de) 2010-10-25 2012-04-26 Evonik Goldschmidt Gmbh Polysiloxane mit stickstoffhaltigen Gruppen
TWI506334B (zh) * 2011-02-28 2015-11-01 Coopervision Int Holding Co Lp 具有可接受程度之能量損失的聚矽氧水凝膠隱形眼鏡
SG192236A1 (en) * 2011-02-28 2013-09-30 Coopervision Int Holding Co Lp Wettable silicone hydrogel contact lenses
WO2012118673A2 (en) * 2011-02-28 2012-09-07 Coopervision International Holding Company, Lp Dimensionally stable silicone hydrogel contact lenses
JP7143080B2 (ja) 2015-08-31 2022-09-28 ビイク－ヒエミー ゲゼルシャフト ミツト ベシユレンクテル ハフツング ポリエーテル－ポリシロキサンマクロモノマー単位を含有するコポリマー、それらの調製方法並びに塗料組成物および高分子成形コンパウンドでのそれらの使用
CN110036057B (zh) * 2016-12-14 2021-11-30 罗门哈斯公司 用于制备聚硅氧烷(甲基)丙烯酸酯的非毒性催化剂
US11655341B2 (en) * 2017-10-24 2023-05-23 Shin-Etsu Chemical Co., Ltd. Method for preparing a radical-polymerizable organopolysiloxane, a radiation-curable organopolysiloxane composition, and a release sheet
WO2019086793A1 (fr) 2017-10-30 2019-05-09 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc comprenant une amine specifique et un systeme de reticulation a base de peroxyde et d'un derive d'acrylate
WO2019106292A1 (fr) 2017-11-29 2019-06-06 Compagnie Generale Des Etablissements Michelin Composition de caoutchouterie dont le systeme de reticulation comprend un coupage de peroxydes et un derive d'acrylate
EP3524651A1 (de) 2018-02-08 2019-08-14 Evonik Degussa GmbH Wässrige polyorganosiloxanhybridharz-dispersion
FR3085165B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085167B1 (fr) 2018-08-23 2020-07-31 Michelin & Cie Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085166B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
JP2020090580A (ja) * 2018-12-04 2020-06-11 信越化学工業株式会社 ω末端にポリアルキレンオキシド基を有する片末端メタクリル変性オルガノ（ポリ）シロキサン及びその製造方法。
EP3719076A1 (de) 2019-04-01 2020-10-07 Evonik Operations GmbH Wässrige polyorganosiloxanhybridharz-dispersion
FR3095447B1 (fr) 2019-04-26 2021-12-24 Michelin & Cie Bandage pour roue de véhicule transportable manuellement
US11732092B2 (en) 2020-10-19 2023-08-22 Evonik Operations Gmbh Upcycling process for processing silicone wastes

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4218294A (en) 1973-09-24 1980-08-19 Design Cote Corp. Radiation curable coating composition
GB1589064A (en) 1977-01-12 1981-05-07 Goldschmidt Ag Th Process for the manufacture of organopolysiloxanes
US4130708A (en) 1977-12-09 1978-12-19 Ppg Industries, Inc. Siloxane urethane acrylate radiation curable compounds for use in coating compositions
US4369300A (en) 1979-11-26 1983-01-18 Union Carbide Corporation Acrylated urethane silicone compositions
CA1134984A (en) 1979-11-26 1982-11-02 Richard G. Carter Acrylated urethane silicone compositions
WO1986002652A1 (en) 1984-10-22 1986-05-09 Desoto, Inc. Ultraviolet curable coating compositions containing ultraviolet curable additive
JPS6239621A (ja) * 1985-08-14 1987-02-20 Mitsubishi Rayon Co Ltd ポリエステルの重合方法
US4777265A (en) 1986-03-11 1988-10-11 Basf Aktiengesellschaft Preparation of acrylates and methacrylates
DE3932460A1 (de) 1988-09-30 1990-04-05 Desoto Inc Durch ultraviolettlicht haertbare ueberzugsmasse
US5091440A (en) 1989-12-08 1992-02-25 Wacker Silicones Corporation Acrylate- or methacrylate-functional organopolysiloxanes
DE4119331A1 (de) 1991-06-12 1992-12-17 Huels Chemische Werke Ag Verfahren zur herstellung waessriger, strahlenhaertender, anionischer urethanharnstoffacrylatdispersionen
DE4408152A1 (de) * 1994-03-11 1995-09-14 Studiengesellschaft Kohle Mbh Immobilisierte Lipasen in hydrophoben Sol-Gel-Materialien

Also Published As

Publication number Publication date
EP0999230B1 (de) 2003-04-16
EP0999230A2 (de) 2000-05-10
CA2288384C (en) 2009-09-22
DE59905050D1 (de) 2003-05-22
CA2288384A1 (en) 2000-05-03
EP0999230A3 (de) 2000-07-26
JP2000139488A (ja) 2000-05-23
DE19850507C1 (de) 2000-05-04
ATE237653T1 (de) 2003-05-15
US6288129B1 (en) 2001-09-11

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