ES2185952T3 - Mcm-56 modificado, preparacion del mismo y su utilizacion. - Google Patents

Mcm-56 modificado, preparacion del mismo y su utilizacion.

Info

Publication number
ES2185952T3
ES2185952T3 ES97931077T ES97931077T ES2185952T3 ES 2185952 T3 ES2185952 T3 ES 2185952T3 ES 97931077 T ES97931077 T ES 97931077T ES 97931077 T ES97931077 T ES 97931077T ES 2185952 T3 ES2185952 T3 ES 2185952T3
Authority
ES
Spain
Prior art keywords
modified
mcm
relationship
active acid
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97931077T
Other languages
English (en)
Inventor
Arthur Warren Chester
Shiu Lun Anthony Fung
Charles Theodore Kresge
Wieslaw Jerzy Roth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
ExxonMobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Oil Corp filed Critical ExxonMobil Oil Corp
Application granted granted Critical
Publication of ES2185952T3 publication Critical patent/ES2185952T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

UNA COMPOSICION EN CAPAS DE MATERIA, MCM - 56, TIENE UNA DIFRACCION DE LOS RAYOS X QUE INCLUYE LAS LINEAS ENUMERADAS EN LA TABLA (II) Y HA SIDO MODIFICADA SELECTIVAMENTE, DE MANERA QUE LA RELACION ENTRE EL NUMERO DE LUGARES ACIDOS ACTIVOS EN SU SUPERFICIE EXTERIOR Y EL NUMERO DE LUGARES ACIDOS ACTIVOS SEA SUPERIOR A LA DEL MATERIAL NO MODIFICADO. CUANDO SE USA COMO ADITIVO DE UN CATALIZADOR DE ZEOLITA DE POROS DE GRAN TAMAÑO EN EL CRAQUEO CATALITICO DE UNA MATERIA PRIMA DE PETROLEO, EL MCM - 56 MODIFICADO PROPORCIONA UNA MEJOR RELACION RENDIMIENTO/OCTANO DE GASOLINA, UNA MEJOR SELECTIVIDAD DEL COQUE Y UN RENDIMIENTO MAYOR COMBINADO DE GASOLINA Y DE ALQUILATO POTENCIAL QUE UN CATALIZADOR IDENTICO QUE CONTENGA MCM - 56 NO MODIFICADO.
ES97931077T 1996-07-22 1997-06-09 Mcm-56 modificado, preparacion del mismo y su utilizacion. Expired - Lifetime ES2185952T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/684,673 US5779882A (en) 1996-07-22 1996-07-22 Modified MCM-56, its preparation and use

Publications (1)

Publication Number Publication Date
ES2185952T3 true ES2185952T3 (es) 2003-05-01

Family

ID=24749077

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97931077T Expired - Lifetime ES2185952T3 (es) 1996-07-22 1997-06-09 Mcm-56 modificado, preparacion del mismo y su utilizacion.

Country Status (9)

Country Link
US (1) US5779882A (es)
EP (1) EP0914308B1 (es)
JP (1) JP4267701B2 (es)
AU (1) AU715251B2 (es)
CA (1) CA2260937C (es)
DE (1) DE69715210T2 (es)
ES (1) ES2185952T3 (es)
TW (1) TW372890B (es)
WO (1) WO1998003453A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6419891B1 (en) * 1999-10-18 2002-07-16 Exxonmobil Oil Corporation Synthetic crystalline MCM-69, its synthesis and use
US7132042B2 (en) * 2002-10-08 2006-11-07 Exxonmobil Research And Engineering Company Production of fuels and lube oils from fischer-tropsch wax
US6846778B2 (en) * 2002-10-08 2005-01-25 Exxonmobil Research And Engineering Company Synthetic isoparaffinic premium heavy lubricant base stock
US20040065584A1 (en) * 2002-10-08 2004-04-08 Bishop Adeana Richelle Heavy lube oil from fischer- tropsch wax
US7201838B2 (en) * 2002-10-08 2007-04-10 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
US7344631B2 (en) * 2002-10-08 2008-03-18 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
JP4733641B2 (ja) * 2003-09-23 2011-07-27 ユーオーピー エルエルシー 結晶性アルミノシリケート：ｕｚｍ−１３、ｕｚｍ−１７、ｕｚｍ−１９及びｕｚｍ−２５
US7615143B2 (en) * 2004-07-30 2009-11-10 Exxonmobil Chemical Patents Inc. Hydrothermally stable catalyst and its use in catalytic cracking
US8408216B2 (en) * 2004-12-22 2013-04-02 Philip Morris Usa Inc. Flavor carrier for use in smoking articles
TW200744986A (en) * 2006-02-14 2007-12-16 Exxonmobil Chemical Patents Inc Process for producing phenol and methyl ethyl ketone
JP5322307B2 (ja) 2006-05-08 2013-10-23 エクソンモービル・ケミカル・パテンツ・インク 改善された触媒組成物
WO2008073221A1 (en) * 2006-12-07 2008-06-19 W. R. Grace & Co. - Conn. Catalytic cracking catalyst compositions having improved bottoms conversion
WO2008101616A1 (en) * 2007-02-22 2008-08-28 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
WO2009024242A1 (en) * 2007-08-22 2009-02-26 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
WO2010011451A1 (en) * 2008-07-22 2010-01-28 Exxonmobil Chemical Patents Inc. Preparation of molecular sieve containing catalyst and its use in the production of alkylaromatic hydrocarbons
WO2010042269A1 (en) 2008-10-10 2010-04-15 Exxonmobil Chemical Patents Inc. Process for producing phenol and methyl ethyl ketone
FR2940266B1 (fr) * 2008-12-18 2010-12-31 Inst Francais Du Petrole Solide cristallise im-20 et son procede de preparation
KR101942128B1 (ko) * 2011-09-16 2019-01-24 엑손모빌 케미칼 패턴츠 인코포레이티드 개선된 ｍｃｍ-56 제조
TWI483775B (zh) * 2011-09-16 2015-05-11 Exxonmobil Chem Patents Inc 經改善之ｍｃｍ－５６製法
CN105217651B (zh) * 2014-07-03 2017-07-14 中国石油化工股份有限公司 硅铝分子筛scm‑6、其合成方法及其用途
EP3135373A1 (en) 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. Preparation and composition of a fluid catalytic cracking catalyst additive with lower phosphate content for enhanced lpg yield
US10413889B2 (en) 2015-11-24 2019-09-17 Indian Oil Corporation Limited Composition and process for preparation of cracking catalyst suitable for enhancing yields of light olefins

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5308471A (en) * 1991-08-15 1994-05-03 Mobil Oil Corporation Hydrocarbon upgrading process
US5234872A (en) * 1992-05-11 1993-08-10 Mobil Oil Corp. Method for producing zeolites with reduced surface acidity
US5284989A (en) * 1992-11-04 1994-02-08 Mobil Oil Corporation Olefin oligomerization with surface modified zeolite catalyst
US5371312A (en) * 1993-04-05 1994-12-06 Mobil Oil Corp. Shape selective hydrocarbon conversions over modified catalyst
US5362697A (en) * 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use

Also Published As

Publication number Publication date
DE69715210T2 (de) 2003-01-09
US5779882A (en) 1998-07-14
AU715251B2 (en) 2000-01-20
DE69715210D1 (de) 2002-10-10
TW372890B (en) 1999-11-01
EP0914308A4 (en) 2000-03-29
EP0914308A1 (en) 1999-05-12
CA2260937C (en) 2008-01-08
CA2260937A1 (en) 1998-01-29
JP2001525780A (ja) 2001-12-11
AU3480297A (en) 1998-02-10
JP4267701B2 (ja) 2009-05-27
EP0914308B1 (en) 2002-09-04
WO1998003453A1 (en) 1998-01-29

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