ES2175681T3 - Procedimiento para la obtencion de polisobuteno reactivo y exento de halogeno. - Google Patents

Procedimiento para la obtencion de polisobuteno reactivo y exento de halogeno.

Info

Publication number
ES2175681T3
ES2175681T3 ES98907952T ES98907952T ES2175681T3 ES 2175681 T3 ES2175681 T3 ES 2175681T3 ES 98907952 T ES98907952 T ES 98907952T ES 98907952 T ES98907952 T ES 98907952T ES 2175681 T3 ES2175681 T3 ES 2175681T3
Authority
ES
Spain
Prior art keywords
elements
halogen
procedure
polymerization
subgroups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98907952T
Other languages
English (en)
Inventor
Christoph Sigwart
Thomas Narbeshuber
Karsten Eller
Manfred Barl
Rolf Fischer
Eugen Gehrer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2175681T3 publication Critical patent/ES2175681T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/025—Metal oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
    • C08F4/24—Oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO PARA PRODUCIR POLIISOBUTENO REACTIVO LIBRE DE HALOGENO, CON UN CONTENIDO TERMINAL DE DOBLE ENLACE DE MAS DE 50% MOLAR Y UN PESO MOLECULAR MEDIO DE 2.800 A 10.000 DALTON, POR POLIMERIZACION CATIONICA DE ISOBUTENO O MEZCLAS DE HIDROCARBURO QUE CONTIENEN ISOBUTENO EN FASE LIQUIDA, CARACTERIZADO PORQUE LA POLIMERIZACION SE EFECTUA A UNA TEMPERATURA DE -30 A +40 C, EN PRESENCIA DE UN CATALIZADOR DE POLIMERIZACION HETEROGENEO A PARTIR DE UNO O VARIOS OXIDOS DE LOS ELEMENTOS DE LOS SUBGRUPOS 5 Y 6 DE LA TABLA PE RIODICA DE ELEMENTOS, O EN PRESENCIA DE UN CATALIZADOR HETEROGENEO DE LA POLIMERIZACION QUE CONTENGA UNO O MAS COMPUESTOS OXIDICOS DE UNO O MAS ELEMENTOS DE LOS SUBGRUPOS 5 Y 6 DE LA T ABLA PERIODICA DE ELEMENTOS SOBRE UN COMPUESTO DE ZIRCONIO QUE CONTIENE OXIGENO DE DIVERSOS MATERIALES OXIDICOS Y NO ZEOLITICOS DE SOPORTE, CARACTERIZADO PORQUE EL CATALIZADOR NO CONTIENE NINGUNA CANTIDAD TECNICAMENTE ACTIVA DE HALOGENO.
ES98907952T 1997-02-06 1998-01-17 Procedimiento para la obtencion de polisobuteno reactivo y exento de halogeno. Expired - Lifetime ES2175681T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19704482A DE19704482A1 (de) 1997-02-06 1997-02-06 Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten

Publications (1)

Publication Number Publication Date
ES2175681T3 true ES2175681T3 (es) 2002-11-16

Family

ID=7819476

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98907952T Expired - Lifetime ES2175681T3 (es) 1997-02-06 1998-01-17 Procedimiento para la obtencion de polisobuteno reactivo y exento de halogeno.

Country Status (9)

Country Link
US (1) US6441110B1 (es)
EP (1) EP0958312B1 (es)
JP (1) JP2001510500A (es)
KR (1) KR100500874B1 (es)
CN (1) CN1116317C (es)
CA (1) CA2278835A1 (es)
DE (2) DE19704482A1 (es)
ES (1) ES2175681T3 (es)
WO (1) WO1998034966A1 (es)

Families Citing this family (27)

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Publication number Priority date Publication date Assignee Title
DE19834593A1 (de) * 1998-07-31 2000-02-03 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
US6346585B1 (en) * 1999-06-24 2002-02-12 The Lubrizol Corporation Ammonium heteropolyacid catalized polymerization of olefins
US7037999B2 (en) * 2001-03-28 2006-05-02 Texas Petrochemicals Lp Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
US6992152B2 (en) * 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
US6858188B2 (en) * 2003-05-09 2005-02-22 Texas Petrochemicals, Lp Apparatus for preparing polyolefin products and methodology for using the same
DE10211418A1 (de) * 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
US6884855B2 (en) † 2003-01-30 2005-04-26 Chevron Oronite Company Llc Sulfurized polyisobutylene based wear and oxidation inhibitors
CA2474959C (en) * 2003-08-07 2009-11-10 Infineum International Limited A lubricating oil composition
DE10361633A1 (de) * 2003-12-30 2005-07-28 Basf Ag Herstellung hochreaktiver Polyisobutene mit niedrigem Halogengehalt
US7867955B2 (en) * 2004-07-30 2011-01-11 Infineum International Limited Lubricating oil composition
US20100298507A1 (en) * 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby
WO2011054785A1 (de) 2009-11-04 2011-05-12 Basf Se Verfahren zur herstellung von homo- oder copolymeren
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
EP3022239B1 (de) * 2013-07-17 2017-04-05 Basf Se Hochreaktives polyisobutylen mit einem hohen gehalt an vinyliden-doppelbindungen in den seitenketten
KR101511708B1 (ko) 2013-08-28 2015-04-13 대림산업 주식회사 폴리부텐 제조 시 발생되는 할로겐의 제거 장치 및 방법
US9631038B2 (en) 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
JP2016065128A (ja) * 2014-09-24 2016-04-28 Ｊｘ日鉱日石エネルギー株式会社 ポリイソブチレンの製造方法、高反応性ポリイソブチレンの生成率向上方法、及びポリイソブチレンの製造装置
US9771442B2 (en) 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
EP3336111A1 (en) * 2016-12-16 2018-06-20 ARLANXEO Canada Inc. Initiator system for cationic polymerization of olefins
BR112019017261B1 (pt) 2017-02-21 2023-01-31 Ntp Tec, Llc Sistema catalisador e método de fabricação de uma composição de polímero
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10167352B1 (en) 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
SG11202004889UA (en) * 2017-12-14 2020-07-29 Arlanxeo Canada Inc Initiator system for cationic polymerization of olefins
US10174138B1 (en) 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
CA3105355C (en) 2018-06-29 2023-04-25 Ntp Tec, Llc Processes for the manufacture of isobutylene, polyisobutylene, and derivatives thereof
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers

Family Cites Families (21)

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Publication number Priority date Publication date Assignee Title
GB1115521A (en) 1963-10-03 1968-05-29 Union Carbide Corp Hydrocarbon conversion process
US3405191A (en) 1964-11-18 1968-10-08 Phillips Petroleum Co Selective polymerization of tertiary monoolefins
NL7002055A (en) 1970-02-13 1971-08-17 Oligomerisation of isobutene
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
US4288649A (en) 1979-08-23 1981-09-08 Standard Oil Company (Indiana) Isobutylene polymerization process
JPS56139429A (en) 1980-04-01 1981-10-30 Nippon Oil & Fats Co Ltd Preparation of isobutylene low polymer
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
DE3611230A1 (de) 1986-04-04 1987-10-08 Basf Ag Polybutyl- und polyisobutylamine, verfahren zu deren herstellung und diese enthaltende kraft- und schmierstoffzusammensetzungen
JPH0779958B2 (ja) * 1987-05-08 1995-08-30 住友電気工業株式会社 大型ダイヤモンドの合成方法
US5290873A (en) * 1990-04-16 1994-03-01 Kanegafuchi Chemical Industry Co., Ltd. Isobutylene polymer having unsaturated group and preparation thereof
BE1006694A5 (fr) 1991-06-22 1994-11-22 Basf Ag Procede de preparation de polyisobutenes extremement reactifs.
DE4132894A1 (de) 1991-10-04 1993-04-08 Basf Ag Verfahren zur herstellung eines traegerkatalysators fuer die polymerisation von (alpha)-olefinen
US5326920A (en) 1992-12-23 1994-07-05 Mobil Oil Corporation Isobutylene oligomerization using supported acid catalysts
WO1994028036A1 (en) 1993-05-20 1994-12-08 Exxon Chemical Patents Inc. Heterogeneous lewis acid-type catalysts
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EP0752912B1 (en) 1994-03-31 2001-08-01 Infineum USA L.P. Supported lewis acid catalysts derived from superacids useful for hydrocarbon conversion reactions
EP0920909A1 (en) 1994-03-31 1999-06-09 Exxon Chemical Patents Inc. Supported lewis acid catalysts for hydrocarbon conversion reactions
US5561095A (en) 1994-03-31 1996-10-01 Exxon Chemical Patents Inc. Supported lewis acid catalysts for hydrocarbon conversion reactions
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US5710225A (en) 1996-08-23 1998-01-20 The Lubrizol Corporation Heteropolyacid catalyzed polymerization of olefins
JP2001509185A (ja) * 1997-01-08 2001-07-10 ハーキュリーズ・インコーポレーテッド 炭化水素樹脂の製造のための触媒としての固体酸

Also Published As

Publication number Publication date
JP2001510500A (ja) 2001-07-31
KR100500874B1 (ko) 2005-07-14
EP0958312A1 (de) 1999-11-24
CN1246870A (zh) 2000-03-08
EP0958312B1 (de) 2002-04-10
US6441110B1 (en) 2002-08-27
WO1998034966A1 (de) 1998-08-13
KR20000070788A (ko) 2000-11-25
CA2278835A1 (en) 1998-08-13
DE19704482A1 (de) 1998-08-13
DE59803734D1 (de) 2002-05-16
CN1116317C (zh) 2003-07-30

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