ES2162372T3 - Componente catalitico solido para la polimerizacion de las olefinas. - Google Patents
Componente catalitico solido para la polimerizacion de las olefinas.Info
- Publication number
- ES2162372T3 ES2162372T3 ES98110432T ES98110432T ES2162372T3 ES 2162372 T3 ES2162372 T3 ES 2162372T3 ES 98110432 T ES98110432 T ES 98110432T ES 98110432 T ES98110432 T ES 98110432T ES 2162372 T3 ES2162372 T3 ES 2162372T3
- Authority
- ES
- Spain
- Prior art keywords
- reaction
- solid
- halogen
- formula
- olefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
LA INVENCION SE REFIERE AL PROCEDIMIENTO DE PREPARACION DE UNA COMPONENTE CATALITICA SOLIDA DE TIPO METALOCENO PARA LA POLIMERIZACION DE LAS OLEFINAS. COMPRENDE UNA ETAPA DE REACCION ENTRE UN SOPORTE Y UN DERIVADO DE FORMULA R 1 M 1 X SUP,1 3 , EN LA CUAL R 1 REPRESENTA UN RADICAL HIDROCA RBONADO, M 1 UN ATOMO DE SILICIO, GERMANIO O ESTAÑO, Y X SUP,1 UN ATOMO DE HALOGENO. LA COMPONENTE CATALITICA SOLIDA DE LA INVENCION PRESENTA UNA FUERTE ACTIVIDAD DE POLIMERIZACION O COPOLIMERIZACION DE LAS OLEFINAS Y PUEDE CONDUCIR A POLIMEROS O COPOLIMEROS DE GRAN MASA MOLECULAR Y BAJA POLIMOLECULARIDAD, POR EJEMPLO INFERIOR A 2,5.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9708204A FR2765225B1 (fr) | 1997-06-30 | 1997-06-30 | Composante catalytique solide pour la polymerisation des olefines |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2162372T3 true ES2162372T3 (es) | 2001-12-16 |
Family
ID=9508628
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98110432T Expired - Lifetime ES2162372T3 (es) | 1997-06-30 | 1998-06-08 | Componente catalitico solido para la polimerizacion de las olefinas. |
Country Status (11)
Country | Link |
---|---|
US (1) | US6057258A (es) |
EP (1) | EP0889065B1 (es) |
JP (1) | JPH11228613A (es) |
KR (1) | KR100502758B1 (es) |
CN (1) | CN1227271C (es) |
AT (1) | ATE204586T1 (es) |
CA (1) | CA2241352A1 (es) |
DE (1) | DE69801403T2 (es) |
ES (1) | ES2162372T3 (es) |
FR (1) | FR2765225B1 (es) |
NO (1) | NO982923L (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2769521B1 (fr) * | 1997-10-14 | 1999-12-10 | Rhodia Chimie Sa | Composition a base d'un oxyde metallique greffe, sa preparation et son utilisation dans un procede de polymerisation par ouverture de cycles oxygenes |
EP1102634B1 (en) * | 1998-07-10 | 2005-02-09 | Dupont Canada Inc. | Supported dendrimer catalyst and its use in hydroformylation or for carbon-carbon bond formation |
US6916752B2 (en) * | 2002-05-20 | 2005-07-12 | 3M Innovative Properties Company | Bondable, oriented, nonwoven fibrous webs and methods for making them |
SG130016A1 (en) * | 2002-09-24 | 2007-03-20 | Sumitomo Chemical Co | Modified particle, catalyst component for addition polymerization, catalyst for addition polymerization and process for producing addition polymer |
US6908876B2 (en) * | 2003-04-16 | 2005-06-21 | Saudi Basic Industries Corporation | Supported metallocene catalyst system for olefin polymerization, method for making and using the same |
EP1664137A1 (en) * | 2003-09-11 | 2006-06-07 | Basell Polyolefine GmbH | Multistep process for preparing heterophasic propylene copolymers |
TWI399297B (zh) * | 2005-01-27 | 2013-06-21 | Hybrid Plastics Inc | 利用多面體寡聚倍半矽氧烷矽醇之表面改質技術 |
EP2050755A1 (en) | 2007-10-19 | 2009-04-22 | Total Petrochemicals Research Feluy | Supported ionic liquids or activating supports |
EP2172493A1 (en) | 2008-10-02 | 2010-04-07 | Total Petrochemicals Research Feluy | Activating supports based on perfluorinated boronic acids |
EP2251362A1 (en) | 2009-05-07 | 2010-11-17 | Total Petrochemicals Research Feluy | Activating supports with controlled distribution of OH groups |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5466766A (en) * | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5399636A (en) * | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
JP2706036B2 (ja) * | 1993-06-29 | 1998-01-28 | 丸善ポリマー株式会社 | オレフィンブロック共重合体の製造方法 |
JPH07316219A (ja) * | 1994-05-24 | 1995-12-05 | Mitsui Petrochem Ind Ltd | オレフィン重合用固体触媒成分、該触媒成分を含むオレフィン重合用触媒および該触媒を用いるオレフィンの重合方法 |
FR2725993B1 (fr) * | 1994-10-21 | 1996-11-29 | Atochem Elf Sa | Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence |
JPH08259617A (ja) * | 1995-03-28 | 1996-10-08 | Maruzen Petrochem Co Ltd | 重合用触媒成分及びそれを用いるエチレン系重合体の製造方法 |
US5885924A (en) * | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
US5610115A (en) * | 1995-07-20 | 1997-03-11 | Samsung General Chemicals Co., Ltd. | Organic carrier supported metallocene catalyst for olefin polymerization |
-
1997
- 1997-06-30 FR FR9708204A patent/FR2765225B1/fr not_active Expired - Fee Related
-
1998
- 1998-06-08 EP EP98110432A patent/EP0889065B1/fr not_active Expired - Lifetime
- 1998-06-08 ES ES98110432T patent/ES2162372T3/es not_active Expired - Lifetime
- 1998-06-08 AT AT98110432T patent/ATE204586T1/de not_active IP Right Cessation
- 1998-06-08 DE DE69801403T patent/DE69801403T2/de not_active Expired - Lifetime
- 1998-06-23 NO NO982923A patent/NO982923L/no not_active Application Discontinuation
- 1998-06-26 US US09/104,983 patent/US6057258A/en not_active Expired - Lifetime
- 1998-06-29 CA CA002241352A patent/CA2241352A1/fr not_active Abandoned
- 1998-06-30 CN CNB981156150A patent/CN1227271C/zh not_active Expired - Fee Related
- 1998-06-30 KR KR10-1998-0025574A patent/KR100502758B1/ko not_active IP Right Cessation
- 1998-06-30 JP JP10183185A patent/JPH11228613A/ja not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CA2241352A1 (fr) | 1998-12-30 |
CN1203924A (zh) | 1999-01-06 |
EP0889065B1 (fr) | 2001-08-22 |
KR19990007483A (ko) | 1999-01-25 |
NO982923L (no) | 1999-01-04 |
DE69801403D1 (de) | 2001-09-27 |
JPH11228613A (ja) | 1999-08-24 |
FR2765225A1 (fr) | 1998-12-31 |
NO982923D0 (no) | 1998-06-23 |
EP0889065A1 (fr) | 1999-01-07 |
US6057258A (en) | 2000-05-02 |
CN1227271C (zh) | 2005-11-16 |
ATE204586T1 (de) | 2001-09-15 |
FR2765225B1 (fr) | 2000-01-14 |
DE69801403T2 (de) | 2002-06-20 |
KR100502758B1 (ko) | 2005-09-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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