ES2160058A1 - Sintesis de zeolitas. - Google Patents

Sintesis de zeolitas.

Info

Publication number
ES2160058A1
ES2160058A1 ES009901403A ES9901403A ES2160058A1 ES 2160058 A1 ES2160058 A1 ES 2160058A1 ES 009901403 A ES009901403 A ES 009901403A ES 9901403 A ES9901403 A ES 9901403A ES 2160058 A1 ES2160058 A1 ES 2160058A1
Authority
ES
Spain
Prior art keywords
synthesis
materials
zeolite
silica
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009901403A
Other languages
English (en)
Other versions
ES2160058B1 (es
Inventor
Canos Avelino Corma
Lopez Maria Lourdes Pena
Garcia Fernando Rey
Valencia Susana Valencia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES009901403A priority Critical patent/ES2160058B1/es
Priority to JP2001504852A priority patent/JP2003502267A/ja
Priority to EP00938828A priority patent/EP1229001A1/en
Priority to PCT/ES2000/000217 priority patent/WO2000078677A1/es
Publication of ES2160058A1 publication Critical patent/ES2160058A1/es
Priority to US10/023,211 priority patent/US20020090337A1/en
Application granted granted Critical
Publication of ES2160058B1 publication Critical patent/ES2160058B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/44—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C01B39/445—Ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/205—Faujasite type, e.g. type X or Y using at least one organic template directing agent; Hexagonal faujasite; Intergrowth products of cubic and hexagonal faujasite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent

Abstract

Sistemas de zeolitas. En la presente invención se describe un procedimiento general que, mediante el empleo de tensioactivos, permite acortar los tiempos de síntesis de materiales microporosos cristalinos basados en sílice con canales cuya apertura de poro está formada por 10 ó 12 tetraedros de sílice. Este procedimiento se basa en la adición a la mezcla de reacción en la cual se forma la zeolita, de un tensioactivo que puede ser catiónico, amónico o neutro. Además este nuevo método de síntesis aumenta el rendimiento de los reactivos empleados en la síntesis de zeolitas y la estabilidad de los materiales formados, permitiendo controlar el tamaño de cristal. Y en los casos en que existe competencia de crecimiento de distintos materiales microporosos, es posible mediante una adecuada selección del surfactante, favorecer la aparición de una fase respecto de la que compite con ella.
ES009901403A 1999-06-17 1999-06-17 Sintesis de zeolitas. Expired - Fee Related ES2160058B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES009901403A ES2160058B1 (es) 1999-06-17 1999-06-17 Sintesis de zeolitas.
JP2001504852A JP2003502267A (ja) 1999-06-17 2000-06-15 ゼオライトの合成
EP00938828A EP1229001A1 (en) 1999-06-17 2000-06-15 Synthesis of zeolites
PCT/ES2000/000217 WO2000078677A1 (es) 1999-06-17 2000-06-15 Sintesis de zeolitas
US10/023,211 US20020090337A1 (en) 1999-06-17 2001-12-17 Synthesis of zeolites

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009901403A ES2160058B1 (es) 1999-06-17 1999-06-17 Sintesis de zeolitas.

Publications (2)

Publication Number Publication Date
ES2160058A1 true ES2160058A1 (es) 2001-10-16
ES2160058B1 ES2160058B1 (es) 2002-06-16

Family

ID=8308959

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009901403A Expired - Fee Related ES2160058B1 (es) 1999-06-17 1999-06-17 Sintesis de zeolitas.

Country Status (5)

Country Link
US (1) US20020090337A1 (es)
EP (1) EP1229001A1 (es)
JP (1) JP2003502267A (es)
ES (1) ES2160058B1 (es)
WO (1) WO2000078677A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2241463A1 (es) * 2003-10-14 2005-10-16 Universidad Politecnica De Valencia Procedimiento de sintesis de la zeolita itq-13 en medio basico y en ausencia de iones fluoruro.

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7220350B2 (en) 2002-10-08 2007-05-22 Exxonmobil Research And Engineering Company Wax isomerate yield enhancement by oxygenate pretreatment of catalyst
US7597795B2 (en) 2003-11-10 2009-10-06 Exxonmobil Research And Engineering Company Process for making lube oil basestocks
ES2275422B1 (es) * 2005-07-25 2008-06-01 Universidad Politecnica De Valencia Separacion de gases utilizando la zeolita itq-32.
WO2008025002A2 (en) * 2006-08-24 2008-02-28 Intelligent Energy, Inc. Liquid phase desulfurization of fuels at mild operating conditions
JP5142123B2 (ja) * 2007-03-28 2013-02-13 義弘 杉 ベータ（β）−ゼオライトの合成方法
FR2914636B1 (fr) * 2007-04-05 2009-06-26 Inst Francais Du Petrole Procede de preparation d'une zeolithe beta
CN101514004B (zh) * 2008-02-20 2011-04-27 中国石油化工股份有限公司 共生分子筛及其合成方法
DE102010053054A1 (de) * 2010-12-01 2012-06-06 Süd-Chemie AG Mechanochemische Herstellung von Zeolithen
WO2012106675A2 (en) * 2011-02-03 2012-08-09 University Of Houston System Zeolite compositions and methods for tailoring zeolite crystal habits with growth modifiers
CN110167881B (zh) 2016-12-08 2023-01-03 巴斯夫公司 加速的铝硅酸盐沸石结晶
CN110038583B (zh) * 2018-01-16 2021-11-09 中国石油化工股份有限公司 一种加氢精制催化剂的制备方法
CN110038580B (zh) * 2018-01-16 2021-11-09 中国石油化工股份有限公司 加氢精制催化剂的制法
CN110038624B (zh) * 2018-01-16 2022-01-04 中国石油化工股份有限公司 加氢裂化催化剂的制法
EP3844248A1 (en) 2018-08-27 2021-07-07 ExxonMobil Research and Engineering Company Dewaxing using a molecular sieve catalyst
CA3109390A1 (en) 2018-08-27 2020-03-05 Exxonmobil Research And Engineering Company A process for making molecular sieves
JP2021536414A (ja) 2018-08-27 2021-12-27 エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company モレキュラーシーブ及びモレキュラーシーブの製造方法
WO2020046640A1 (en) 2018-08-27 2020-03-05 Exxonmobil Research And Engineering Company Molecular sieves and a process for making molecular sieves
KR101994765B1 (ko) * 2018-09-21 2019-07-01 에스케이이노베이션 주식회사 계층화된 제올라이트 및 이의 제조방법
US20220073360A1 (en) * 2018-12-13 2022-03-10 The University Of Tokyo Zeolite and Manufacturing Method Thereof
CN113307284A (zh) * 2021-07-09 2021-08-27 山东亮剑环保新材料有限公司 一种纳米尺度复合分子筛的制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0137289A2 (en) * 1983-08-31 1985-04-17 E.I. Du Pont De Nemours And Company Process for the preparation of silica polymorphs from silicon
CN1208718A (zh) * 1998-07-01 1999-02-24 复旦大学 复合中微孔分子筛及其合成方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1083399C (zh) * 1998-03-30 2002-04-24 中国石油化工总公司 合成高硅丝光沸石的方法
CN1093086C (zh) * 1999-09-08 2002-10-23 复旦大学 表面活性剂作辅助剂的emt沸石的合成方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0137289A2 (en) * 1983-08-31 1985-04-17 E.I. Du Pont De Nemours And Company Process for the preparation of silica polymorphs from silicon
CN1208718A (zh) * 1998-07-01 1999-02-24 复旦大学 复合中微孔分子筛及其合成方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KOYANO, K.A. et al. Synthesis of titanium-containing mesoporous molecular sieves with a cubic structure. Stud. Surf. Sci. Catal., 1997, Vol. 105 (Progress in Zeolite and Microporous Materials, pt. A), paginas 93-100, ISSN: 0167-2991 *
MOREY, M. et al. A new step toward transition metal incorporation in cubic mesoporous materials; preparation and characterization of Ti-MCM-48. Microporous Mater., 1996, Vol. 6, no 2, paginas 99-104, ISSN: 0927-6513 *
ZHANG, W. et al. Transition metal substituted derivatives of cubic MCM-48 mesoporous molecular sieves. Catal. Lett., 1996, Vol. 38, no 3,4, paginas 261-265, ISSN: 1011-372X *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2241463A1 (es) * 2003-10-14 2005-10-16 Universidad Politecnica De Valencia Procedimiento de sintesis de la zeolita itq-13 en medio basico y en ausencia de iones fluoruro.

Also Published As

Publication number Publication date
ES2160058B1 (es) 2002-06-16
JP2003502267A (ja) 2003-01-21
EP1229001A1 (en) 2002-08-07
US20020090337A1 (en) 2002-07-11
WO2000078677A1 (es) 2000-12-28

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