ES2158332T3 - Procedimiento para estabilizar baños de blanqueo alcalinos que contienen peroxido para el blanqueo de celulosa y otras sustancias fibrosas. - Google Patents

Procedimiento para estabilizar baños de blanqueo alcalinos que contienen peroxido para el blanqueo de celulosa y otras sustancias fibrosas.

Info

Publication number
ES2158332T3
ES2158332T3 ES96926400T ES96926400T ES2158332T3 ES 2158332 T3 ES2158332 T3 ES 2158332T3 ES 96926400 T ES96926400 T ES 96926400T ES 96926400 T ES96926400 T ES 96926400T ES 2158332 T3 ES2158332 T3 ES 2158332T3
Authority
ES
Spain
Prior art keywords
bleach
whitening
peroxide
cellulose
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96926400T
Other languages
English (en)
Inventor
Thomas Jaschinski
Herbert Bachus
Othar Kordsachia
Jurgen Odermatt
Rudolf Patt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHT Germany GmbH
Original Assignee
CHT R Beitlich GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHT R Beitlich GmbH filed Critical CHT R Beitlich GmbH
Application granted granted Critical
Publication of ES2158332T3 publication Critical patent/ES2158332T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10Bleaching ; Apparatus therefor
    • D21C9/1026Other features in bleaching processes
    • D21C9/1042Use of chelating agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01Hydrogen peroxide
    • C01B15/037Stabilisation by additives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937Stabilising agents
    • C11D3/394Organic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10Bleaching ; Apparatus therefor
    • D21C9/16Bleaching ; Apparatus therefor with per compounds
    • D21C9/163Bleaching ; Apparatus therefor with per compounds with peroxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Paper (AREA)
  • Detergent Compositions (AREA)

Abstract

PARA BLANQUEAR CELULOSAS Y OTRAS SUSTANCIAS FIBROSAS EN LA FABRICACION DE PAPEL SE EMPLEA PEROXIDO DE HIDROGENO O COMPOSICIONES DISOCIADORAS DE PEROXIDO EN SOLUCIONES ALCALINAS. A CAUSA DE LOS IONES DE METALES DE TRANSICION, CONTENIDOS EN PEQUEÑAS CONCENTRACIONES EN LAS SUSTANCIAS FIBROSAS DE CELULOSA, LOS PEROXIDOS SE DESCOMPONEN HOMOLITICAMENTE, LO CUAL DESEMBOCA EN NOTABLES PERDIDAS DE PEROXIDO Y EN LA DISOCIACION DE LAS CADENAS DE HIDRATOS DE CARBONO DEBIDO A LA REACTIVIDAD DE LOS RADICALES DE OXIGENO. PARA ESTABILIZAR LAS SOLUCIONES DE BLANQUEO ALCALINAS QUE CONTIENEN OXIGENO, PEROXIDO DE HIDROGENO Y/O COMPOSICIONES DISOCIADORAS DE PEROXIDO, EL PROCEDIMIENTO CORRESPONDIENTE A LA INVENCION UTILIZA COMO ESTABILIZADOR, POR SEPARADO O COMO MEZCLA, UNA COMBINACION COMPUESTA POR UN FORMADOR DE COMPLEJO TIPO 1 FORMADO POR FOSFONATO Y/O POLI AL} ACIDO HIDROXIACRILICO Y/O AMINOPOLICARBOXILICO, JUNTO CON UN FORMADOR DE COMPLEJO TIPO 2 FORMADO POR COMPUESTOS OXI Y/O POLIOXI CON 2 A 7 ATOMOS DE CEN LA CADENA DEL CARBONO Y/O DERIVADOS PROTEINICOS. ESTE ESTABILIZADOR PUEDE SER UTILIZADO BAJO PRESION DEL OXIGENO, SIN PRESION O BAJO PRESION HIDROSTATICA PARA EL BLANQUEO DE SUSPENSIONES ACUOSAS DE SUSTANCIAS FIBROSAS EN LA FABRICACION DEL PAPEL O EN LA ELABORACION POSTERIOR DE FIBRAS (FIBRAS SINTETICAS) UTILIZADAS EN LA INDUSTRIA QUIMICA. GRACIAS A LA MEZCLA DE ESTABILIZACION PUEDEN OBTENERSE, CON UN USO CONSIDERABLEMENTE PEQUEÑO DE PEROXIDO DE HIDROGENO, UNOS EXCELENTES INDICES DE BLANQUEO, LAS FIBRAS SON BASTANTE MENOS DAÑADAS DURANTE SU BLANQUEO, PUDIENDO BIODEGRADARSE LA MEZCLA DE ESTABILIZACION MUCHO MEJOR QUE EL FORMADOR DE COMPLEJO TIPO 1.
ES96926400T 1995-08-04 1996-07-30 Procedimiento para estabilizar baños de blanqueo alcalinos que contienen peroxido para el blanqueo de celulosa y otras sustancias fibrosas. Expired - Lifetime ES2158332T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19528843A DE19528843A1 (de) 1995-08-04 1995-08-04 Verfahren zur Stabilisierung von alkalischen peroxidenthaltenden Bleichflotten für die Bleiche von Zellstoffen und anderen Faserstoffen

Publications (1)

Publication Number Publication Date
ES2158332T3 true ES2158332T3 (es) 2001-09-01

Family

ID=7768803

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96926400T Expired - Lifetime ES2158332T3 (es) 1995-08-04 1996-07-30 Procedimiento para estabilizar baños de blanqueo alcalinos que contienen peroxido para el blanqueo de celulosa y otras sustancias fibrosas.

Country Status (6)

Country Link
EP (1) EP0842321B1 (es)
AT (1) ATE200806T1 (es)
CA (1) CA2228636A1 (es)
DE (2) DE19528843A1 (es)
ES (1) ES2158332T3 (es)
WO (1) WO1997006303A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI115641B (fi) * 1996-02-19 2005-06-15 Kemira Oyj Korkeasaantomassojen valkaisumenetelmä
FI115470B (fi) * 1996-02-19 2005-05-13 Kemira Oyj Menetelmä kemiallisen selluloosamateriaalin käsittelemiseksi
DE19730650C2 (de) * 1997-07-17 1999-12-02 Henkel Kgaa Verfahren zur Vermeidung der Ablagerung von Schwermetallionen auf Textilfasern
DE19730648A1 (de) * 1997-07-17 1999-01-21 Henkel Kgaa Verwendung von Elektrolytgemischen als Sequestriermittel
DE19849379A1 (de) * 1998-10-27 2000-05-04 Cht R Beitlich Gmbh Wäßrige Lösungen von Phosphonsäuren
FI120202B (fi) 2003-01-10 2009-07-31 Kemira Oyj Polymeerikoostumus ja sen käyttö
FI117393B (fi) 2003-01-10 2006-09-29 Kemira Oyj Menetelmä selluloosakuitumateriaalin valkaisemiseksi
US7101832B2 (en) 2003-06-19 2006-09-05 Johnsondiversey, Inc. Cleaners containing peroxide bleaching agents for cleaning paper making equipment and method
US7351764B2 (en) 2004-03-31 2008-04-01 Nalco Company Methods to enhance brightness of pulp and optimize use of bleaching chemicals
US20100101743A1 (en) * 2007-02-21 2010-04-29 Solvay (Societe Anonyme) Process for the bleaching of paper pulp
EP2225175B1 (en) 2007-12-13 2012-12-12 Akzo Nobel N.V. Stabilized hydrogen peroxide solutions
EP2759518B1 (en) * 2013-01-24 2019-05-22 MKS-DEVO Kimyevi Mad. San. Tic. A.S. Bleaching compositions with improved performance and stability and their use
CN113942980B (zh) * 2021-11-11 2023-11-03 河南慧泽生物工程有限公司 一种过氧化氢稳定剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3338260C1 (de) * 1983-10-21 1985-07-25 Benckiser-Knapsack Gmbh, 6802 Ladenburg Verfahren und Mittel zum Bleichen von Holzschliff
JPS62197304A (ja) * 1986-02-20 1987-09-01 Nippon Peroxide Co Ltd 過酸化水素溶液の安定化方法
DE3720806C2 (de) * 1986-07-03 1997-08-21 Clariant Finance Bvi Ltd Verwendung eines Stabilisators in Peroxydbleichverfahren
DE3820160C2 (de) * 1987-06-26 1998-10-08 Clariant Finance Bvi Ltd Konzentriertes Präparat und dessen Verwendung als Stabilisator für alkalische peroxydhaltige Flotten
NZ274840A (en) * 1993-10-26 1997-05-26 Akzo Nobel Nv Bleaching pulp with hydrogen peroxide in the presence of at least one 1-aminoalkane-1,1-disphosphonate chelating agent; deinking of pulp using such a chelating agent

Also Published As

Publication number Publication date
ATE200806T1 (de) 2001-05-15
EP0842321A1 (de) 1998-05-20
CA2228636A1 (en) 1997-02-20
EP0842321B1 (de) 2001-04-25
DE19528843A1 (de) 1997-02-06
DE59606826D1 (de) 2001-05-31
WO1997006303A1 (de) 1997-02-20

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