ES2140636T3 - Catalizador a base de alumina para el tratamiento de gases que contienen compuestos azufrados, utilizacion de estos catalizadores para el tratamiento y procedimientos de los indicados gases. - Google Patents

Catalizador a base de alumina para el tratamiento de gases que contienen compuestos azufrados, utilizacion de estos catalizadores para el tratamiento y procedimientos de los indicados gases.

Info

Publication number
ES2140636T3
ES2140636T3 ES95401677T ES95401677T ES2140636T3 ES 2140636 T3 ES2140636 T3 ES 2140636T3 ES 95401677 T ES95401677 T ES 95401677T ES 95401677 T ES95401677 T ES 95401677T ES 2140636 T3 ES2140636 T3 ES 2140636T3
Authority
ES
Spain
Prior art keywords
treatment
gases
gases containing
catalysts
procedures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95401677T
Other languages
English (en)
Inventor
Christophe Nedez
Olivier Legendre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2140636T3 publication Critical patent/ES2140636T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/16—Hydrogen sulfides
    • C01B17/165—Preparation from sulfides, oxysulfides or polysulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
    • C01B17/0434—Catalyst compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Glanulating (AREA)

Abstract

LA INVENCION SE REFIERE A UN CATALIZADOR PARA EL TRATAMIENTO DE GASES QUE CONTIENEN COMPUESTOS AZUFRADOS, POR LA REACCION DE CLAUS O POR HIDROLISIS, FORMADO POR PARTICULAS POROSAS A BASE DE ALUMINA, CARACTERIZADO EN QUE EL VOLUMEN ACUMULADO CREADO POR TODOS LOS POROS CUYO DIAMETRO ES SUPERIOR A 0,1 (MU)M, V{SUB,0,1}, ES SUPERIOR A 12 ML/100 G DE CATALIZADOR Y EN QUE EL VOLUMEN ACUMULADO CREADO POR TODOS LOS POROSOS CUYO DIAMETRO ES SUPERIOR A 1(MU)M, V1, ES TAL QUE LA RELACION V1/VO.1 ES SUPERIOR A 0,65. ESTE CATALIZADOR PUEDE UTILIZARSE PARA EL TRATAMIENTO DE GASES QUE CONTIENEN COMPUESTOS AZUFRADOS POR APLICACION DE LA REACCION DE CLAUS O DE GASES QUE CONTIENEN COMPUESTOS ORGANICOS DEL AZUFRE POR APLICACION DE UNA REACCION DE HIDROLISIS.
ES95401677T 1994-07-13 1995-07-12 Catalizador a base de alumina para el tratamiento de gases que contienen compuestos azufrados, utilizacion de estos catalizadores para el tratamiento y procedimientos de los indicados gases. Expired - Lifetime ES2140636T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9408745A FR2722429B1 (fr) 1994-07-13 1994-07-13 Catalyseur a base d'alumine pour le traitement de gaz contenant des composes soufres, utilisation deces catalyseurs pour le traitement et procedes de traitement desdits gaz

Publications (1)

Publication Number Publication Date
ES2140636T3 true ES2140636T3 (es) 2000-03-01

Family

ID=9465385

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95401677T Expired - Lifetime ES2140636T3 (es) 1994-07-13 1995-07-12 Catalizador a base de alumina para el tratamiento de gases que contienen compuestos azufrados, utilizacion de estos catalizadores para el tratamiento y procedimientos de los indicados gases.

Country Status (14)

Country Link
US (1) US6080379A (es)
EP (1) EP0692305B1 (es)
JP (1) JP2992536B2 (es)
KR (1) KR0156811B1 (es)
CN (1) CN1072975C (es)
AT (1) ATE185706T1 (es)
CA (1) CA2153748C (es)
DE (1) DE69512843T2 (es)
DK (1) DK0692305T3 (es)
ES (1) ES2140636T3 (es)
FR (1) FR2722429B1 (es)
GR (1) GR3032190T3 (es)
RU (1) RU2112595C1 (es)
TW (1) TW332155B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2722429B1 (fr) * 1994-07-13 1996-10-04 Rhone Poulenc Chimie Catalyseur a base d'alumine pour le traitement de gaz contenant des composes soufres, utilisation deces catalyseurs pour le traitement et procedes de traitement desdits gaz
CN1102420C (zh) * 2000-07-11 2003-03-05 中国科学院山西煤炭化学研究所 一种羰基硫水解催化剂及其制备方法和用途
FR2840295B1 (fr) * 2002-06-03 2005-02-04 Inst Francais Du Petrole Prodede d'elimination du soufre d'une charge contenant de l'hydrogene sulfure et du benzene, toluene et/ou xylenes
US7704486B2 (en) * 2005-02-16 2010-04-27 Basf Corporation Precious metal water-gas shift catalyst with oxide support modified with rare earth elements
US8142748B2 (en) * 2007-09-17 2012-03-27 Shell Oil Company Catalyst composition useful in the catalytic reduction of sulfur compound contained in a gas stream and a method of making and using such composition
US9480970B2 (en) * 2009-12-30 2016-11-01 Korea Aerospace Research Institute Catalyst carrier for a spacecraft thruster and method for preparing same
RU2527259C2 (ru) * 2012-12-19 2014-08-27 Общество с ограниченной ответственностью "Новомичуринский катализаторный завод" Катализатор получения элементной серы по процессу клауса, способ его приготовления и способ проведения процесса клауса
BR112018069469B1 (pt) 2016-03-23 2023-01-10 Shell Internationale Research Maatschappij B.V. Composição catalítica útil na redução catalítica de compostos de enxofre contidos em uma corrente de gás, método de preparação da mesma e processo de hidrólise
WO2018138200A1 (en) * 2017-01-25 2018-08-02 Haldor Topsøe A/S A process for treating the off gas from a carbon black plant to recover sulphur
RU2711605C1 (ru) * 2019-07-03 2020-01-17 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Способ получения алюмооксидных катализаторов процесса Клауса и применение их на установках получения серы
CN111151240A (zh) * 2020-01-07 2020-05-15 中国石油大学(华东) 一种用于克劳斯尾气中硫化氢转化催化剂的制备方法
CN114146699B (zh) * 2020-08-17 2023-09-26 中国石油天然气股份有限公司 一种用于有机硫水解的催化剂及其制备方法
CN114425315B (zh) * 2020-09-28 2023-10-31 中国石油化工股份有限公司 一种常温cs2水解剂及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1108011A (fr) 1954-06-28 1956-01-09 Pechiney Procédé de préparation d'alumine activée
FR1178168A (fr) * 1956-07-05 1959-05-05 Metallgesellschaft Ag Procédé pour la transformation catalytique de combinaisons sulfureuses gazeuses
GB888772A (en) 1957-05-17 1962-02-07 American Cyanamid Co Method of producing alumina
FR1400365A (fr) * 1963-05-07 1965-05-28 Perfectionnements à la fabrication du verre plat
GB1076450A (en) 1963-12-06 1967-07-19 Grace W R & Co Improvements relating to the production of alumina gels
US3630670A (en) 1970-05-25 1971-12-28 Kaiser Aluminium Chem Corp Pseudoboehmitic alumina and process for making same
FR2190517B1 (es) * 1972-06-29 1975-08-29 Rhone Progil
FR2221405B1 (es) 1973-03-14 1984-02-24 Rhone Poulenc Spec Chim
FR2449650A1 (fr) 1979-02-26 1980-09-19 Rhone Poulenc Ind Procede de preparation d'alumine au moins partiellement sous forme de boehmite ultra-fine
US4364858A (en) * 1980-07-21 1982-12-21 Aluminum Company Of America Method of producing an activated alumina Claus catalyst
US4608363A (en) * 1980-07-21 1986-08-26 Aluminum Company Of America Activated alumina Claus catalyst having increased sodium oxide content
FR2540006B1 (fr) * 1983-01-31 1988-04-01 Rhone Poulenc Spec Chim Catalyseur d'oxydation de l'hydrogene sulfure
US4990481A (en) * 1988-05-20 1991-02-05 Toyo Engineering Corporation Catalyst for steam reforming
NL8901893A (nl) * 1989-07-21 1991-02-18 Veg Gasinstituut Nv Katalysator voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel, werkwijze voor de bereiding van een dergelijke katalysator en werkwijze voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel.
CA2107090A1 (en) * 1992-02-21 1993-08-22 Yukihiro Sakoda Process for hydrogenating treatment of heavy hydrocarbon oil
FR2722429B1 (fr) * 1994-07-13 1996-10-04 Rhone Poulenc Chimie Catalyseur a base d'alumine pour le traitement de gaz contenant des composes soufres, utilisation deces catalyseurs pour le traitement et procedes de traitement desdits gaz

Also Published As

Publication number Publication date
EP0692305A1 (fr) 1996-01-17
JPH08192046A (ja) 1996-07-30
CA2153748A1 (en) 1996-01-14
CA2153748C (en) 1999-05-25
FR2722429B1 (fr) 1996-10-04
KR0156811B1 (ko) 1998-12-15
US6080379A (en) 2000-06-27
KR960003797A (ko) 1996-02-23
TW332155B (en) 1998-05-21
JP2992536B2 (ja) 1999-12-20
CN1072975C (zh) 2001-10-17
GR3032190T3 (en) 2000-04-27
DK0692305T3 (da) 2000-04-25
RU95113198A (ru) 1997-06-27
DE69512843T2 (de) 2000-08-10
FR2722429A1 (fr) 1996-01-19
CN1123713A (zh) 1996-06-05
EP0692305B1 (fr) 1999-10-20
ATE185706T1 (de) 1999-11-15
DE69512843D1 (de) 1999-11-25
RU2112595C1 (ru) 1998-06-10

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