ES2135119T3 - Un procedimiento para preparar aductos esfericos, discretos y pequeños de dihaluro de magnesio/alcohol. - Google Patents

Un procedimiento para preparar aductos esfericos, discretos y pequeños de dihaluro de magnesio/alcohol.

Info

Publication number
ES2135119T3
ES2135119T3 ES96101934T ES96101934T ES2135119T3 ES 2135119 T3 ES2135119 T3 ES 2135119T3 ES 96101934 T ES96101934 T ES 96101934T ES 96101934 T ES96101934 T ES 96101934T ES 2135119 T3 ES2135119 T3 ES 2135119T3
Authority
ES
Spain
Prior art keywords
alcohol
dihalide
magnesium
discreet
spherical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96101934T
Other languages
English (en)
Inventor
Joel L Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2135119T3 publication Critical patent/ES2135119T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Lubricants (AREA)
  • Polymerization Catalysts (AREA)

Abstract

SE PRESENTA UN PROCEDIMIENTO PARA HACER UNA ADUCCION DE DIHALURO DE MAGNESIO/ALCOHOL, ESFERICA, DISCRETA, PEQUEÑA. ESTE PROCEDIMIENTO COMPRENDE: LA PUESTA EN CONTACTO DE UN DIHALURO DE MAGNESIO Y UN ALCOHOL EN UN LIQUIDO DE ALTA VISCOSIDAD QUE CONSTE DE HIDROCARBUROS, PARA OBTENER UNA DISPERSION; EL CALENTAMIENTO Y AGITACION DE LA DISPERSION PARA OBTENER UNA DISPERSION FUNDIDA; EL ENFRIAMIENTO DE LA DISPERSION FUNDIDA PARA FORMAR LAS ADUCCIONES DE DIHALURO DE MAGNESIO/ALCOHOL ESFERICAS, DISCRETAS, PEQUEÑAS.
ES96101934T 1995-02-09 1996-02-09 Un procedimiento para preparar aductos esfericos, discretos y pequeños de dihaluro de magnesio/alcohol. Expired - Lifetime ES2135119T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/385,619 US5500396A (en) 1995-02-09 1995-02-09 Process to make small, discrete, spherical adducts

Publications (1)

Publication Number Publication Date
ES2135119T3 true ES2135119T3 (es) 1999-10-16

Family

ID=23522179

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96101934T Expired - Lifetime ES2135119T3 (es) 1995-02-09 1996-02-09 Un procedimiento para preparar aductos esfericos, discretos y pequeños de dihaluro de magnesio/alcohol.

Country Status (11)

Country Link
US (1) US5500396A (es)
EP (1) EP0726278B1 (es)
JP (1) JPH08301912A (es)
KR (1) KR960031488A (es)
CN (1) CN1051562C (es)
CA (1) CA2164743C (es)
DE (1) DE69603631T2 (es)
ES (1) ES2135119T3 (es)
HU (1) HU220445B1 (es)
NO (1) NO305482B1 (es)
RU (1) RU2156259C2 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19962129A1 (de) * 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
WO2002051544A1 (en) * 2000-12-22 2002-07-04 Basell Poliolefine Italia S.P.A. Process for the preparation of a spherical support comprising a mg dihalide
US7087688B2 (en) * 2002-09-17 2006-08-08 Basell Poliolefine Italia S.P.A. Magnesium dichloride-ethanol adduct and catalyst components obtained therefrom
CN1267508C (zh) * 2003-08-08 2006-08-02 中国石油化工股份有限公司 一种卤化镁/醇加合物及其制备方法和应用
US7135531B2 (en) * 2004-01-28 2006-11-14 Basf Catalysts Llc Spherical catalyst for olefin polymerization
US6962889B2 (en) * 2004-01-28 2005-11-08 Engelhard Corporation Spherical catalyst for olefin polymerization
CN1289542C (zh) * 2004-07-05 2006-12-13 中国石油化工股份有限公司 用于烯烃聚合反应的球形催化剂组分及其催化剂
JP4841845B2 (ja) * 2005-01-19 2011-12-21 三井化学株式会社 オレフィン重合触媒用の担体分離方法
US8003559B2 (en) * 2008-05-13 2011-08-23 Basf Corporation Internal donor for olefin polymerization catalysts
US7638585B2 (en) 2008-05-13 2009-12-29 Basf Catalysts, Llc Catalyst flow
US8003558B2 (en) * 2008-07-29 2011-08-23 Basf Corporation Internal donor for olefin polymerization catalysts
US11833479B2 (en) * 2020-03-26 2023-12-05 Chevron Phillips Chemical Company Lp Catalyst slurry mixing process and system

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2635041A (en) * 1950-06-23 1953-04-14 Du Pont Alkali metal dispersions
US2642345A (en) * 1950-07-15 1953-06-16 Du Pont Alkali metal dispersions and their use as diesel fuel additives
US2642344A (en) * 1950-07-15 1953-06-16 Du Pont Alkali metal dispersions
US2777887A (en) * 1953-11-24 1957-01-15 Du Pont Process for preparing cyclopentadienylsodium
CA920299A (en) * 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
US4042374A (en) * 1975-03-20 1977-08-16 Wisconsin Alumni Research Foundation Micron sized spherical droplets of metals and method
IT1096661B (it) * 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS6037804B2 (ja) * 1979-04-11 1985-08-28 三井化学株式会社 オレフイン重合触媒用担体の製法
IT1136627B (it) * 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
IT1186747B (it) * 1985-07-01 1987-12-16 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene
IT1203330B (it) * 1987-02-06 1989-02-15 Enichem Base Spa Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
FI83331C (fi) * 1988-12-30 1991-06-25 Neste Oy Framstaellning och anvaendning av en ny ziegler-natta-katalysatorkomponent.
IT1231768B (it) * 1989-08-02 1991-12-21 Himont Inc Composizioni polipropileniche adatte alla modifica di bitumi.
JP2879347B2 (ja) * 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
JPH03140308A (ja) * 1989-10-27 1991-06-14 Chisso Corp ポリオレフィン用重合触媒の製法
US5212246A (en) * 1990-09-28 1993-05-18 Himont Incorporated Olefin polymer films
IT1255523B (it) * 1992-09-24 1995-11-09 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
JP3471099B2 (ja) * 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法

Also Published As

Publication number Publication date
RU2156259C2 (ru) 2000-09-20
NO305482B1 (no) 1999-06-07
US5500396A (en) 1996-03-19
DE69603631D1 (de) 1999-09-16
JPH08301912A (ja) 1996-11-19
NO960510L (no) 1996-08-12
CN1136044A (zh) 1996-11-20
HU9600282D0 (en) 1996-04-29
HUP9600282A1 (en) 1996-12-30
HU220445B1 (hu) 2002-02-28
CA2164743C (en) 1998-12-29
CN1051562C (zh) 2000-04-19
EP0726278B1 (en) 1999-08-11
DE69603631T2 (de) 1999-12-16
EP0726278A3 (en) 1997-05-28
CA2164743A1 (en) 1996-08-10
EP0726278A2 (en) 1996-08-14
KR960031488A (ko) 1996-09-17
NO960510D0 (no) 1996-02-08

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