ES2134548T3 - Emulsion con bajo contenido en compuestos organicos volatiles. - Google Patents
Emulsion con bajo contenido en compuestos organicos volatiles.Info
- Publication number
- ES2134548T3 ES2134548T3 ES96115707T ES96115707T ES2134548T3 ES 2134548 T3 ES2134548 T3 ES 2134548T3 ES 96115707 T ES96115707 T ES 96115707T ES 96115707 T ES96115707 T ES 96115707T ES 2134548 T3 ES2134548 T3 ES 2134548T3
- Authority
- ES
- Spain
- Prior art keywords
- emulsion
- ppm
- salts
- weight
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000839 emulsion Substances 0.000 title abstract 3
- 239000012855 volatile organic compound Substances 0.000 title 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 235000010323 ascorbic acid Nutrition 0.000 abstract 1
- 239000011668 ascorbic acid Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/006—Removal of residual monomers by chemical reaction, e.g. scavenging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/915—Redox catalyst
Abstract
PROCESO PARA REDUCIR EL CONTENIDO DE MONOMEROS RESIDUALES, EXPRESADO COMO VOC TOTAL INFERIOR A 600 PPM Y DERIVAR A PARTIR DE LOS MONOMEROS UTILIZADOS PARA OBTENER LA EMULSION INFERIOR A 100 PPM; TENER UNA CANTIDAD DE COAGULO HUMEDO INFERIOR O IGUAL A 500 PPM DESPUES DEL FILTRADO HUMEDO EN UN FILTRO DE 125 MICRAS DE LA EMULSION A LA SALIDA DESPUES DE LAS DIFERENTES FASES DE CAIDA, EN POLIMERIZACIONES Y COPOLIMERIZACIONES EN DISPERSION O EMULSION EN FASE ACUOSA BASADA EN MONOMEROS ACRILICOS, CARACTERIZADO EN QUE COMPRENDE COMO ACOPLADOR DE REDOX LA UTILIZACION DE UN AGENTE DE REDUCCION SELECCIONADO DE ACIDO ASCORBICO O UN ALDEHIDO QUE TIENE UN NUMERO DE ATOMOS DE CARBONO IGUAL O SUPERIOR A 4 Y QUE CONTIENE AL MENOS UN HIDROGENO SALIFICABLE, ORGANICO O INORGANICO, O SUS SALES Y EL HIDROGENO SALIFICABLE INORGANICO SIENDO AÑADIDO A UN GRUPO CARBOXILICO; EL AGENTE DE REDUCCION DE ALDEHIDO O SUS SALES SIENDO SOLUBLES EN AGUA AL MENOS EL 5% EN PESO, PREFERIBLEMENTE EL 10% EN PESO; Y DE UN AGENTE DEOXIDACION QUE CONSTA DE UN HIDROPEROXIDO ORGANICO EN SOLUCION ACUOSA, EXCLUYENDO LOS SOLUBLES EN H{SUB,2}O MAS DEL 10% EN PESO, O SUS SALES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT95MI002024A IT1276816B1 (it) | 1995-10-04 | 1995-10-04 | Emulsione a basso voc |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2134548T3 true ES2134548T3 (es) | 1999-10-01 |
Family
ID=11372308
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96115707T Expired - Lifetime ES2134548T3 (es) | 1995-10-04 | 1996-10-01 | Emulsion con bajo contenido en compuestos organicos volatiles. |
Country Status (8)
Country | Link |
---|---|
US (3) | US5721310A (es) |
EP (1) | EP0767180B1 (es) |
AT (1) | ATE180792T1 (es) |
DE (1) | DE69602700T2 (es) |
DK (1) | DK0767180T3 (es) |
ES (1) | ES2134548T3 (es) |
GR (1) | GR3030806T3 (es) |
IT (1) | IT1276816B1 (es) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1276816B1 (it) | 1995-10-04 | 1997-11-03 | Atochem Elf Italia | Emulsione a basso voc |
DE19741184A1 (de) | 1997-09-18 | 1999-03-25 | Basf Ag | Verfahren zur Verminderung von Restmonomeren in Flüssigsystemen unter Zugabe eines Redoxinitiatorsystems |
DE19839199A1 (de) * | 1998-08-28 | 2000-03-02 | Basf Ag | Verfahren zur Verminderung der Restmonomerenmenge in wässrigen Polymerdispersionen |
DE19840586A1 (de) | 1998-09-05 | 2000-03-09 | Basf Ag | Verfahren zur Verminderung der Restmonomerenmenge in wässrigen Polymerdispersionen |
US6277953B1 (en) | 1998-09-25 | 2001-08-21 | Mcwhorter Technologies, Inc. | Stable aqueous polymer dispersions and a process for their preparation |
US6225402B1 (en) | 1998-09-25 | 2001-05-01 | Mcwhorter Technologies, Inc. | Aqueous based dispersions for polyolefinic substrates |
DE19911170A1 (de) | 1999-03-12 | 2000-09-14 | Basf Ag | Verfahren zum Herstellen von W/O-Emulsionen |
DE19942776A1 (de) | 1999-09-08 | 2001-03-15 | Basf Ag | Verfahren zur Verminderung der Restmonomerenmenge in wäßrigen Polymerisatdispersionen |
US6696519B2 (en) | 2000-10-17 | 2004-02-24 | Rohm And Haas Company | Redox process for preparing emulsion polymer having low residual monomer content |
DE10206994A1 (de) * | 2001-11-12 | 2003-05-22 | Ercros Deutschland Gmbh | Kunststoffdispersion und Verfahren zu ihrer Herstellung |
DE10317434A1 (de) | 2003-04-15 | 2004-10-28 | Basf Ag | Verfahren zur Reduzierung der Restmonomerenmenge in wässrigen Polymerdispersionen |
DE10335958A1 (de) | 2003-08-04 | 2005-02-24 | Basf Ag | Verfahren zur Herstellung wässriger Polymerisatdispersionen |
US20070184732A1 (en) * | 2006-02-07 | 2007-08-09 | Lunsford David J | High strength polyvinyl acetate binders |
JP5449138B2 (ja) | 2007-05-04 | 2014-03-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 水性複合粒子分散液の製造方法 |
AU2008314734A1 (en) | 2007-10-24 | 2009-04-30 | Basf Se | Method for producing an aqueous composite-particle dispersion |
KR20140014366A (ko) | 2009-04-15 | 2014-02-06 | 바스프 에스이 | 수성 복합-입자 분산액의 제조 방법 |
WO2011058163A1 (en) | 2009-11-16 | 2011-05-19 | Dsm Ip Assets B.V. | Acrylic polymer |
KR101771758B1 (ko) * | 2009-12-09 | 2017-08-25 | 닛토덴코 가부시키가이샤 | 광학 필름용 점착제층, 점착형 광학 필름, 그 제조 방법 및 화상 표시 장치 |
US20110184088A1 (en) | 2010-01-27 | 2011-07-28 | Basf Se | Coating materials comprising composite particles |
BR112013012584A2 (pt) | 2010-12-02 | 2016-08-09 | Dsm Ip Assets Bv | polímero acrílico |
WO2014161817A1 (de) | 2013-04-03 | 2014-10-09 | Basf Se | Verfahren zur reduzierung der restmonomerenmenge in einer wässrigen polymerisatdispersion |
EP2965785A1 (en) | 2014-07-11 | 2016-01-13 | DSM IP Assets B.V. | Novel use |
WO2019125170A1 (en) | 2017-12-22 | 2019-06-27 | Dsm Ip Assets B.V. | Adhesive compositions and their use in 3d printing |
FR3100249B1 (fr) * | 2019-08-28 | 2021-10-29 | Arkema France | Procédé de traitement de dispersions polymères basé sur l’utilisation de peroxydes organiques spécifiques |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2834760A (en) * | 1954-12-14 | 1958-05-13 | Polymer Corp | Redox type polymerization |
GB795514A (en) * | 1955-01-13 | 1958-05-28 | Kellogg M W Co | Polymeric materials and the preparation thereof |
US3365409A (en) * | 1965-10-18 | 1968-01-23 | Shawinigan Chem Ltd | Vinyl acetate-acrylamide copolymer emulsions |
US3438941A (en) * | 1967-10-16 | 1969-04-15 | Nalco Chemical Co | Homopolymerization of acrolein in aqueous monomer emulsion via redox catalyst |
DE1745570C3 (de) * | 1968-02-20 | 1973-10-04 | Wacker-Chemie Gmbh, 8000 Muenchen | Verwendung von Aldehyden zur Herstellung von quallenfrei löslichen Copolymeren |
US3862096A (en) * | 1971-12-08 | 1975-01-21 | Kanegafuchi Chemical Ind | Method of polymerizing acrylic monomers |
IT959756B (it) * | 1972-05-23 | 1973-11-10 | Montedison Fibre Spa | Sistema catalitico adatto per poli merizzare in massa o in soluzione monomeri etilenicamente insaturi |
US3915941A (en) * | 1972-10-13 | 1975-10-28 | American Cyanamid Co | Acrylonitrile polymerization using sodium sulfoxylate formaldehyde |
US4054732A (en) * | 1974-07-05 | 1977-10-18 | American Can Company | Dry photopolymer imaging process |
JPS588410B2 (ja) * | 1975-11-04 | 1983-02-16 | 住友化学工業株式会社 | スイセイブンサンエキノ セイゾウホウホウ |
US4052547A (en) * | 1976-06-01 | 1977-10-04 | The Goodyear Tire & Rubber Company | Process for polymerizing diolefin copolymers employing a catalyst mixture of hydroperoxides |
GB1594863A (en) * | 1978-03-03 | 1981-08-05 | Int Synthetic Rubber | Emulsion polymerisation process |
DE2848967A1 (de) * | 1978-11-11 | 1980-05-22 | Basf Ag | Aromatische aldehydgruppen enthaltende polymerisate |
US4360632A (en) * | 1981-10-23 | 1982-11-23 | Air Products And Chemicals, Inc. | Ketone bisulfites as reducing agent for free radical polymerization |
US4445953A (en) * | 1982-02-25 | 1984-05-01 | Ppg Industries, Inc. | Method of forming shaped laminates |
US4594290A (en) * | 1982-12-06 | 1986-06-10 | Swedlow, Inc. | Impact resistant laminate |
JPS59157105A (ja) * | 1983-02-25 | 1984-09-06 | Sankyo Kasei Kogyo Kk | アクリルアミド系水溶性高分子物質の製法 |
DE3323810A1 (de) * | 1983-07-01 | 1985-01-03 | Wacker-Chemie GmbH, 8000 München | Verfahren zur herstellung waessriger polymerdispersionen und ihre verwendung |
DE3323851A1 (de) * | 1983-07-01 | 1985-01-03 | Wacker-Chemie GmbH, 8000 München | Verfahren zur herstellung waessriger polymerdispersionen und ihre verwendung |
DE3323804A1 (de) * | 1983-07-01 | 1985-01-03 | Wacker-Chemie GmbH, 8000 München | Verfahren zur herstellung waessriger polymerdispersionen und ihre verwendung |
US4617359A (en) * | 1984-09-12 | 1986-10-14 | The Goodyear Tire & Rubber Company | High molecular weight polyacrylamide synthesis |
DE3803450A1 (de) * | 1988-02-05 | 1989-08-17 | Hoechst Ag | Emissionsarme dispersionsfarben, anstrichmittel und kunststoffdispersionsputze sowie verfahren zu ihrer herstellung |
DE3834734A1 (de) * | 1988-10-12 | 1990-04-19 | Basf Ag | Verfahren zur herstellung von polymerisaten aus olefinisch ungesaettigten monomeren |
US5003016A (en) * | 1989-01-17 | 1991-03-26 | Minnesota Mining And Manufacturing Company | Surface activator for redox-initiated adhesives |
DE4026165A1 (de) * | 1990-08-15 | 1992-03-05 | Flachglas Solartechnik Gmbh | Bauplatte fuer laermschutzwand |
US5393607A (en) * | 1992-01-13 | 1995-02-28 | Mitsui Toatsu Chemiclas, Inc. | Laminated transparent plastic material and polymerizable monomer |
US5415926A (en) * | 1993-02-25 | 1995-05-16 | National Starch And Chemical Investment Holding Corporation | Process for reducing the free aldehyde content in N-alkylol amide monomers |
DE9305850U1 (es) | 1993-04-20 | 1993-06-09 | Roehm Gmbh, 6100 Darmstadt, De | |
DE4330874A1 (de) * | 1993-09-13 | 1995-03-16 | Czinki Laszlo | Lärmschutzwand mit Doppelglaselementen |
IT1276816B1 (it) * | 1995-10-04 | 1997-11-03 | Atochem Elf Italia | Emulsione a basso voc |
DE19545609A1 (de) * | 1995-12-07 | 1997-06-12 | Hoechst Ag | Redoxkatalysatorsystem zur Initiierung von Emulsionspolymerisationen |
-
1995
- 1995-10-04 IT IT95MI002024A patent/IT1276816B1/it active IP Right Grant
-
1996
- 1996-10-01 EP EP96115707A patent/EP0767180B1/en not_active Expired - Lifetime
- 1996-10-01 ES ES96115707T patent/ES2134548T3/es not_active Expired - Lifetime
- 1996-10-01 DK DK96115707T patent/DK0767180T3/da active
- 1996-10-01 DE DE69602700T patent/DE69602700T2/de not_active Expired - Fee Related
- 1996-10-01 AT AT96115707T patent/ATE180792T1/de not_active IP Right Cessation
- 1996-10-03 US US08/724,869 patent/US5721310A/en not_active Expired - Fee Related
-
1997
- 1997-10-09 US US08/948,237 patent/US6093675A/en not_active Expired - Fee Related
-
1999
- 1999-07-20 GR GR990401894T patent/GR3030806T3/el unknown
-
2000
- 2000-06-09 US US09/590,363 patent/US6274668B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69602700T2 (de) | 1999-09-30 |
IT1276816B1 (it) | 1997-11-03 |
EP0767180B1 (en) | 1999-06-02 |
US6274668B1 (en) | 2001-08-14 |
DK0767180T3 (da) | 1999-11-15 |
DE69602700D1 (de) | 1999-07-08 |
US5721310A (en) | 1998-02-24 |
ITMI952024A1 (it) | 1997-04-04 |
GR3030806T3 (en) | 1999-11-30 |
EP0767180A1 (en) | 1997-04-09 |
ITMI952024A0 (es) | 1995-10-04 |
US6093675A (en) | 2000-07-25 |
ATE180792T1 (de) | 1999-06-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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