ES2122563T3 - Sintesis de complejos de coordinacion de ciclopentadienil-metal a partir de hidroxicarbiloxidos-metal. - Google Patents

Sintesis de complejos de coordinacion de ciclopentadienil-metal a partir de hidroxicarbiloxidos-metal.

Info

Publication number
ES2122563T3
ES2122563T3 ES95910875T ES95910875T ES2122563T3 ES 2122563 T3 ES2122563 T3 ES 2122563T3 ES 95910875 T ES95910875 T ES 95910875T ES 95910875 T ES95910875 T ES 95910875T ES 2122563 T3 ES2122563 T3 ES 2122563T3
Authority
ES
Spain
Prior art keywords
metal
coordination complexes
cyclopentadienyl
bis
contacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95910875T
Other languages
English (en)
Inventor
Robert K Rosen
Brian W S Kolthammer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2122563T3 publication Critical patent/ES2122563T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

UN PROCESO PARA PREPARAR COMPLEJOS DE COORDINACION DE DIHIDROCARBILOXI METALICA MONO- Y BIS(CICLOPENDADIENILO) PUENTEADA (I) AL PONERSE EN CONTACTO EN PRESENCIA DE UN DILUYENTE ORGANICO APROTICO, UN COMPUESTO METALICO DE LA FORMULA M(OR){SUB,4} CON UN COMPUESTO DE SAL DIANIONICA. UN PROCESO PARA PREPARAR COMPLEJOS DE COORDINACION DE METALES DE DIHIDROCARBILO MONO- Y BIS(CICLO-PENTADIENIL)PUENTEADOS (II) AL PONERSE EN CONTACTO UN COMPLEJO (I) CON UN AGENTE DE HIDROCARBILACION. UN PROCESO PARA PREPARAR COMPLEJOS DE COORDINACION DE DIHALURO METALICO MONO- Y BIS(CICLOPENTADIENILO)PUENTEADO (III) AL PONER EN CONTACTO UN COMPLEJO (I) CON UN AGENTE DE HALOGENACION.
ES95910875T 1994-01-25 1995-01-23 Sintesis de complejos de coordinacion de ciclopentadienil-metal a partir de hidroxicarbiloxidos-metal. Expired - Lifetime ES2122563T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/186,402 US5504223A (en) 1994-01-25 1994-01-25 Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Publications (1)

Publication Number Publication Date
ES2122563T3 true ES2122563T3 (es) 1998-12-16

Family

ID=22684809

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95910875T Expired - Lifetime ES2122563T3 (es) 1994-01-25 1995-01-23 Sintesis de complejos de coordinacion de ciclopentadienil-metal a partir de hidroxicarbiloxidos-metal.

Country Status (8)

Country Link
US (2) US5504223A (es)
EP (1) EP0741739B1 (es)
JP (1) JPH09509149A (es)
CA (1) CA2181268A1 (es)
DE (1) DE69505642T2 (es)
ES (1) ES2122563T3 (es)
FI (1) FI962959A (es)
WO (1) WO1995019984A2 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1272923B (it) * 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
JPH1112289A (ja) * 1997-06-19 1999-01-19 Sumitomo Chem Co Ltd 架橋型遷移金属錯体の製造方法
EP1098934A1 (en) 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
EP0970964B1 (en) * 1998-07-09 2004-04-21 Sumitomo Chemical Company, Limited Method for producing a titanium complex
US6087290A (en) * 1999-01-19 2000-07-11 Hughes Electronics Corporation Si-N-Si-bridged metallocenes, their production and use
JP2003501436A (ja) * 1999-06-04 2003-01-14 バセル テクノロジー カンパニー ビー．ブイ． チタン錯体の製造法
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
MXPA02011762A (es) * 2000-05-31 2004-05-17 Basell Polyolefine Gmbh Proceso para la preparacion de compuestos metales de transicion y su empleo para la polimerizacion de olefinas.
EP1390417B1 (en) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Process for polymerizing propylene and ethylene in solution
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6943215B2 (en) * 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
SG147306A1 (en) 2001-11-06 2008-11-28 Dow Global Technologies Inc Isotactic propylene copolymers, their preparation and use
US6906160B2 (en) * 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6590114B2 (en) * 2001-11-09 2003-07-08 Boulder Scientific Company Conversion of cyclopentadienyl silyl amines to organometallic complexes comprising titanium bisalkoxy moiety or titanium dichloride moiety
US6452031B1 (en) * 2001-11-21 2002-09-17 Boulder Scientific Company Preparation of titanium organometallic complexes comprising a titanium bisalkoxide or dihalide moiety
US7169489B2 (en) * 2002-03-15 2007-01-30 Fuelsell Technologies, Inc. Hydrogen storage, distribution, and recovery system
DE60304595T3 (de) 2002-10-02 2012-01-12 Dow Global Technologies Inc. Flüssige und gelartige niedermolekulare ethylenpolymere
US20040065171A1 (en) * 2002-10-02 2004-04-08 Hearley Andrew K. Soild-state hydrogen storage systems
DE60322410D1 (de) * 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
US7459500B2 (en) 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7579407B2 (en) 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
EP1620448B1 (en) * 2003-05-08 2010-06-16 Basell Polyolefine GmbH Process for the production of halide metallocene compounds
US7531601B2 (en) 2003-08-19 2009-05-12 Dow Global Technologies, Inc. Interpolymers suitable for use in hot melt adhesives and processes to prepare same
US8093341B2 (en) 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5158920A (en) * 1988-07-15 1992-10-27 Fina Technology, Inc. Process for producing stereospecific polymers
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
ATE147761T1 (de) * 1990-06-22 1997-02-15 Exxon Chemical Patents Inc Aluminiumfreie monocyclopentadienyl- metallocenkatalysatoren für olefinpolymerisation
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
JP2931642B2 (ja) * 1990-07-12 1999-08-09 出光興産株式会社 スチレン系重合体の製造方法とその触媒
SE466246B (sv) * 1990-12-14 1992-01-20 Volvo Ab Anordning foer oeverfoering av arbetsstycken fraan en maskin till en annan, foeretraedesvis pressar
JP3275211B2 (ja) * 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
NL9101502A (nl) * 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.

Also Published As

Publication number Publication date
FI962959A0 (fi) 1996-07-24
DE69505642D1 (de) 1998-12-03
CA2181268A1 (en) 1995-07-27
WO1995019984A3 (en) 1995-12-28
FI962959A (fi) 1996-07-24
US5703257A (en) 1997-12-30
WO1995019984A2 (en) 1995-07-27
JPH09509149A (ja) 1997-09-16
EP0741739A1 (en) 1996-11-13
MX9602890A (es) 1997-12-31
EP0741739B1 (en) 1998-10-28
US5504223A (en) 1996-04-02
DE69505642T2 (de) 1999-06-17

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