ES2112873T3 - Sistema catalizador aislable, soportado, para la polimerizacion de alq-1-enos de 2 a 10 atomos de carbono. - Google Patents
Sistema catalizador aislable, soportado, para la polimerizacion de alq-1-enos de 2 a 10 atomos de carbono.Info
- Publication number
- ES2112873T3 ES2112873T3 ES92108558T ES92108558T ES2112873T3 ES 2112873 T3 ES2112873 T3 ES 2112873T3 ES 92108558 T ES92108558 T ES 92108558T ES 92108558 T ES92108558 T ES 92108558T ES 2112873 T3 ES2112873 T3 ES 2112873T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- catalyst system
- enos
- alq
- supported
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 230000000737 periodic effect Effects 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4119343A DE4119343A1 (de) | 1991-06-12 | 1991-06-12 | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2112873T3 true ES2112873T3 (es) | 1998-04-16 |
Family
ID=6433761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92108558T Expired - Lifetime ES2112873T3 (es) | 1991-06-12 | 1992-05-21 | Sistema catalizador aislable, soportado, para la polimerizacion de alq-1-enos de 2 a 10 atomos de carbono. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6152543A (enExample) |
| EP (1) | EP0518092B1 (enExample) |
| JP (1) | JP3963489B2 (enExample) |
| DE (2) | DE4119343A1 (enExample) |
| ES (1) | ES2112873T3 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW309523B (enExample) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| DE4242486A1 (de) * | 1992-12-16 | 1994-06-23 | Basf Ag | Propylen-Homopolymere |
| WO1994028034A1 (en) * | 1993-05-25 | 1994-12-08 | Exxon Chemical Patents Inc. | Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof |
| IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| FR2717816B1 (fr) * | 1994-03-23 | 1996-04-26 | Atochem Elf Sa | Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique. |
| US5468440B1 (en) * | 1994-05-06 | 1997-04-08 | Exxon Chemical Patents Inc | Process of making oriented film or structure |
| EP0760744A1 (en) * | 1994-05-24 | 1997-03-12 | Exxon Chemical Patents Inc. | Fibers and fabrics incorporating lower melting propylene polymers |
| US5571619A (en) * | 1994-05-24 | 1996-11-05 | Exxon Chemical Patents, Inc. | Fibers and oriented films of polypropylene higher α-olefin copolymers |
| US5468702A (en) * | 1994-07-07 | 1995-11-21 | Exxon Chemical Patents Inc. | Method for making a catalyst system |
| ATE200496T1 (de) * | 1995-05-09 | 2001-04-15 | Fina Research | Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators |
| DE19548288A1 (de) * | 1995-12-22 | 1997-06-26 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| WO1997032906A1 (en) * | 1996-03-04 | 1997-09-12 | Exxon Chemical Patents Inc. | Stable metallocene catalyst systems |
| EP0928297A1 (en) * | 1996-09-24 | 1999-07-14 | Exxon Chemical Patents Inc. | Improved method for preparing supported metallocene catalyst systems |
| US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| KR20060002837A (ko) | 2003-03-21 | 2006-01-09 | 다우 글로벌 테크놀로지스 인크. | 형태 제어된 올레핀 중합 방법 |
| DE602005020688D1 (de) | 2004-12-17 | 2010-05-27 | Dow Global Technologies Inc | Rheologiemodifizierte polyethylenzusammensetzungen |
| EP1803747A1 (en) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films |
| WO2007130553A2 (en) * | 2006-05-02 | 2007-11-15 | Dow Global Technologies Inc. | High-density polyethylene compositions, method of making the same, wire and cable jackets made therefrom, and method of making such wire and cable jackets |
| US7456244B2 (en) | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
| BRPI0713185B1 (pt) | 2007-05-02 | 2018-08-28 | Dow Global Technologies Inc | composição de polietileno de alta densidade, método para produzir uma composição de polietileno de alta densidade, tampa de garrafa, método para produzir uma tampa de garrafa e composição de polietileno de alta densidade |
| US7981517B2 (en) | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
| ES2408589T3 (es) | 2008-12-18 | 2013-06-21 | Univation Technologies, Llc | Método para tratamiento de un lecho de siembra para una reacción de polimerización |
| WO2010088265A1 (en) | 2009-01-30 | 2010-08-05 | Dow Global Technologies Inc. | High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices |
| WO2014105614A1 (en) | 2012-12-28 | 2014-07-03 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
| KR102135226B1 (ko) | 2013-01-14 | 2020-07-20 | 유니베이션 테크놀로지즈, 엘엘씨 | 증가된 생산성을 갖는 촉매 시스템의 제조 방법 |
| WO2016182920A1 (en) | 2015-05-08 | 2016-11-17 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063767A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063764A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063765A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2019118073A1 (en) | 2017-12-13 | 2019-06-20 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization process |
| WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
| EP3788082A1 (en) | 2018-05-02 | 2021-03-10 | ExxonMobil Chemical Patents Inc. | Methods for scale-up from a pilot plant to a larger production facility |
| EP3788081B1 (en) | 2018-05-02 | 2025-07-02 | ExxonMobil Chemical Patents Inc. | Methods for scale-up from a pilot plant to a larger production facility |
| EP3814390A2 (en) | 2018-06-28 | 2021-05-05 | ExxonMobil Chemical Patents Inc. | Polyethylene compositions, wires and cables, and methods for making the same |
| WO2020014138A1 (en) | 2018-07-09 | 2020-01-16 | Exxonmobil Chemical Patents Inc. | Polyethylene cast films and methods for making the same |
| CN112469556B (zh) | 2018-07-26 | 2023-05-02 | 埃克森美孚化学专利公司 | 多层泡沫膜及其制造方法 |
| WO2020102385A1 (en) | 2018-11-13 | 2020-05-22 | Exxonmobil Chemical Patents Inc. | Polyethylene films |
| CN113207293B (zh) | 2018-11-13 | 2023-08-04 | 埃克森美孚化学专利公司 | 聚乙烯共混物和膜 |
| WO2020163079A1 (en) | 2019-02-06 | 2020-08-13 | Exxonmobil Chemical Patents Inc. | Films and backsheets for hygiene articles |
| US20230018505A1 (en) | 2019-12-17 | 2023-01-19 | Exxonmobil Chemical Patents Inc. | Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties |
| WO2021183337A1 (en) | 2020-03-12 | 2021-09-16 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved bending stiffness and high md tear resistance |
| EP4330294A1 (en) | 2021-04-30 | 2024-03-06 | ExxonMobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4098979A (en) * | 1970-12-29 | 1978-07-04 | Sumitomo Chemical Company, Limited | Method for preparing easily processable polyolefin granule |
| DE3007725A1 (de) * | 1980-02-29 | 1981-09-17 | Hansjörg Prof. Dr. 2000 Hamburg Sinn | Verfahren zur herstellung von polyethylen, polypropylen und copolymeren |
| US4897455A (en) * | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
| JPS6392621A (ja) * | 1986-10-08 | 1988-04-23 | Mitsubishi Petrochem Co Ltd | エチレン共重合体の製造法 |
| EP0295312B1 (en) * | 1986-12-30 | 1994-04-20 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and process for its preparation |
| DE3904468A1 (de) * | 1989-02-15 | 1990-08-16 | Hoechst Ag | Polypropylenwachs und verfahren zu seiner herstellung |
| US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
-
1991
- 1991-06-12 DE DE4119343A patent/DE4119343A1/de not_active Withdrawn
-
1992
- 1992-05-21 ES ES92108558T patent/ES2112873T3/es not_active Expired - Lifetime
- 1992-05-21 EP EP92108558A patent/EP0518092B1/de not_active Expired - Lifetime
- 1992-05-21 DE DE59209223T patent/DE59209223D1/de not_active Expired - Fee Related
- 1992-05-22 JP JP13057392A patent/JP3963489B2/ja not_active Expired - Fee Related
- 1992-06-04 US US07/894,128 patent/US6152543A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE4119343A1 (de) | 1992-12-17 |
| JPH05140226A (ja) | 1993-06-08 |
| JP3963489B2 (ja) | 2007-08-22 |
| US6152543A (en) | 2000-11-28 |
| EP0518092A3 (enExample) | 1995-05-10 |
| EP0518092A2 (de) | 1992-12-16 |
| EP0518092B1 (de) | 1998-03-11 |
| DE59209223D1 (de) | 1998-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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