ES2092428A1 - Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos. - Google Patents

Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.

Info

Publication number
ES2092428A1
ES2092428A1 ES09301327A ES9301327A ES2092428A1 ES 2092428 A1 ES2092428 A1 ES 2092428A1 ES 09301327 A ES09301327 A ES 09301327A ES 9301327 A ES9301327 A ES 9301327A ES 2092428 A1 ES2092428 A1 ES 2092428A1
Authority
ES
Spain
Prior art keywords
utilization
silicone
synthesis
selective oxidation
structure material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES09301327A
Other languages
English (en)
Other versions
ES2092428B1 (es
Inventor
Canos Avelino Corma
Villalba M Teresa Navarro
Pariente Joaquin Perez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Universitat de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Universitat de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8282204&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2092428(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia, Universitat de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES09301327A priority Critical patent/ES2092428B1/es
Priority to PCT/ES1994/000059 priority patent/WO1994029022A1/es
Priority to DK94917687T priority patent/DK0655278T3/da
Priority to DE69417518T priority patent/DE69417518T2/de
Priority to CA002142336A priority patent/CA2142336C/en
Priority to AT94917687T priority patent/ATE178224T1/de
Priority to EP94917687A priority patent/EP0655278B1/en
Priority to US08/413,867 priority patent/US5783167A/en
Publication of ES2092428A1 publication Critical patent/ES2092428A1/es
Publication of ES2092428B1 publication Critical patent/ES2092428B1/es
Application granted granted Critical
Priority to GR990401670T priority patent/GR3030587T3/el
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

MATERIAL DE ESTRUCTURA TIPO ZEOLITA DE POROS ULTRAGRANDES CON UNA RED CONSTITUIDA POR OXIDOS DE SILICIO Y TITANIO: SU SINTESIS Y UTILIZACION PARA LA OXIDACION SELECTIVA DE PRODUCTOS ORGANICOS. SE TRATA DE UN MATERIAL CONSTITUIDO POR SILICOTITANATOS DE ESTRUCTURA CRISTALINA SEMEJANTE A LAS ZEOLITAS TIPO MCM-41 CARACTERIZADO POR CONTENER EN SU RED ATOMOS DE TITANIO Y CANALES EN SU ESTRUCTURA POROSA CUYOS DIMENSIONES MEDIAS SUPERAN LOS 10 A LO QUE LE PERMITE CATALIZAR REACCIONES EN LAS QUE INTERVIENEN MOLECULAS ORGANICAS VOLUMINOSAS TALES COMO OXIDAR OLEFINAS A EPOXIDOS Y GLICOLES, ALCOHOLES A CETONAS, TIOETERES A SULFOXIDOS Y SULFONAS, Y FENOL A CATECOL E HIDROQUINONA Y SI SE INTRODUCE A1 EN LA ESTRUCTURA, ES POSIBLE PREPARAR CATALIZADORES BIFUNCIONALES OXIDANTE-ACIDO/BASE. PARA CONSEGUIR ESTE PRODUCTO SE PARTE DE UNA DISOLUCION ACUOSA QUE CONTIENE EL ION NR1R2R3R4+ Y OTRA QUE CONTIENE HIDROXIDO DE TETRAMETIL AMONIO Y UNA FUENTE DE SILICE (P.E. AEROSILCO). TRAS LA HOMOGENEIZACION SE AÑADE MASSILICE, Y LA FUENTE DE TI [P.E. TI(C2OH5)4]. EL GEL RESULTANTE SE CALIENTA EN UN AUTOCLAVE A UNA TEMPERATURA ENTRE 80 Y 200 C. EL GEL OBTENIDO SE ACTIVA POR CALCINACION ENTRE 350 Y 800 C. SE EMPLEA PARA LA OXIDACION CATALITICA.
ES09301327A 1993-06-15 1993-06-15 Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos. Expired - Fee Related ES2092428B1 (es)

Priority Applications (9)

Application Number Priority Date Filing Date Title
ES09301327A ES2092428B1 (es) 1993-06-15 1993-06-15 Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
EP94917687A EP0655278B1 (en) 1993-06-15 1994-06-10 Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides; its synthesis and utilization for the selective oxidation of organic products
DK94917687T DK0655278T3 (da) 1993-06-15 1994-06-10 Strukturmateriale af zeolithtypen med ultrastore porer og et gitter sammensat af silicium- og titanoxider, dets syntese og
DE69417518T DE69417518T2 (de) 1993-06-15 1994-06-10 Strukturmaterial vom zeolithtypus mit ultragrossen poren und einem gitter aus silizium-und titaniumoxyden; dessen synthese und verwendung zur selektiven oxydation von organischen produkten
CA002142336A CA2142336C (en) 1993-06-15 1994-06-10 Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides, its synthesis and utilization for the selective oxidation of organic products
AT94917687T ATE178224T1 (de) 1993-06-15 1994-06-10 Strukturmaterial vom zeolithtypus mit ultragrossen poren und einem gitter aus silizium- und titaniumoxyden; dessen synthese und verwendung zur selektiven oxydation von organischen produkten
PCT/ES1994/000059 WO1994029022A1 (es) 1993-06-15 1994-06-10 Material de estructura tipo zeolita de poros ultragrandes con una red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos
US08/413,867 US5783167A (en) 1993-06-15 1995-02-15 Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides: its synthesis and utilization for the selective oxidation of organic products
GR990401670T GR3030587T3 (en) 1993-06-15 1999-06-23 Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides; its synthesis and utilization for the selective oxidation of organic products.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES09301327A ES2092428B1 (es) 1993-06-15 1993-06-15 Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.

Publications (2)

Publication Number Publication Date
ES2092428A1 true ES2092428A1 (es) 1996-11-16
ES2092428B1 ES2092428B1 (es) 1997-08-01

Family

ID=8282204

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09301327A Expired - Fee Related ES2092428B1 (es) 1993-06-15 1993-06-15 Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.

Country Status (9)

Country Link
US (1) US5783167A (es)
EP (1) EP0655278B1 (es)
AT (1) ATE178224T1 (es)
CA (1) CA2142336C (es)
DE (1) DE69417518T2 (es)
DK (1) DK0655278T3 (es)
ES (1) ES2092428B1 (es)
GR (1) GR3030587T3 (es)
WO (1) WO1994029022A1 (es)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2165771A1 (es) * 1999-07-20 2002-03-16 Sumitomo Chemical Co Catalizador de oxido de silicio que contiene titanio.
ES2165773A1 (es) * 1998-08-04 2002-03-16 Sumitomo Chemical Co Proceso para producir oxido de propileno.
ES2166271A1 (es) * 1998-08-04 2002-04-01 Sumitomo Chemical Co Catalizador de oxido de silicio con contenido en titanio.

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2092428B1 (es) * 1993-06-15 1997-08-01 Univ Valencia Politecnica Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
US5663384A (en) * 1996-03-06 1997-09-02 Arco Chemical Technology, L.P. Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide
US5718878A (en) * 1996-07-12 1998-02-17 Akzo Nobel N.V. Mesoporous titania and process for its preparation
US5688484A (en) * 1996-07-29 1997-11-18 Arco Chemical Technology, L.P. Non-hydrothermal method of making a titanium-containing zeolite
CA2215490A1 (fr) * 1996-10-11 1998-04-11 Elf Atochem S.A. Catalyseur a base de titano-silicalites et procede d'obtention d'hydroxylamine n,n-disubstituee
JPH10139419A (ja) * 1996-11-11 1998-05-26 Yukong Ltd 非結晶性中間細孔モレキュラーシーブの製造方法及びそのモレキュラーシーブ
US6042807A (en) * 1997-04-02 2000-03-28 Arco Chemical Technology, L.P. Tellurium-containing molecular sieves
JP3174829B2 (ja) * 1997-05-30 2001-06-11 経済産業省産業技術総合研究所長 多孔性チタノシリケート及びその製造方法
IT1296573B1 (it) * 1997-11-27 1999-07-14 Enichem Spa Procedimento per l'ossidazione di composti aromatici a idrossiaromatici
KR100639048B1 (ko) * 1998-08-04 2006-10-27 스미또모 가가꾸 가부시키가이샤 티탄-함유 산화규소 촉매, 이의 제조 방법 및 당해 촉매를 사용하는 프로필렌 옥사이드의 제조방법
ES2156506B1 (es) * 1998-10-14 2002-03-01 Sumitomo Chemical Co Metodo para la produccion de oxido de propileno.
ES2160044B1 (es) * 1999-03-16 2002-06-16 Univ Valencia Politecnica Oxidacion de *-pineno.
EP1252928B1 (en) 2000-02-02 2006-08-02 Sumitomo Chemical Company, Limited Molded catalyst, process for producing the molded catalyst, and process for producing oxirane compound
DE10047435A1 (de) 2000-09-26 2002-04-11 Degussa Verfahren zur Herstellung von Oximen
US6488741B2 (en) 2001-01-23 2002-12-03 The Trustess Of The University Of Pennsylvania Light hydrocarbon separation using 8-member ring zeolites
JP2002239381A (ja) 2001-02-22 2002-08-27 Sumitomo Chem Co Ltd チタン含有珪素酸化物触媒の製造方法及び触媒
ES2183710B1 (es) * 2001-04-12 2004-01-16 Univ Valencia Politecnica Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
US6417378B1 (en) * 2001-10-09 2002-07-09 Arco Chemical Technology, L.P. Direct epoxidation process using pre-treated titanium zeolite
US20030091504A1 (en) * 2001-11-15 2003-05-15 Gary Pasquale Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides
ES2192967B1 (es) * 2001-11-20 2004-09-16 Universidad Politecnica De Valencia. Proceso y catalizadores para la oxidacion de compuestos de azufre de las fracciones gasolina, queroseno y diesel.
JP4265212B2 (ja) * 2002-12-19 2009-05-20 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
CN100384733C (zh) * 2005-08-15 2008-04-30 中国石油化工股份有限公司 含钛mcm-41分子筛的制备方法
KR100727288B1 (ko) * 2005-10-14 2007-06-13 한국과학기술원 메조다공성 골격을 갖는 미세다공성 결정성 분자체의제조방법
ES2685497T3 (es) * 2006-09-25 2018-10-09 Chevron U.S.A. Inc. Preparación de tamices moleculares utilizando un agente director de estructura y un catión de amonio cuaternario de N,N,N-trialquil bencilo
US20080159950A1 (en) * 2006-12-27 2008-07-03 Miller Stephen J Preparation of molecular sieve ssz-13
US8057782B2 (en) * 2006-12-27 2011-11-15 Chevron U.S.A. Inc. Preparation of small pore molecular sieves
US10807961B2 (en) 2016-07-29 2020-10-20 Sumitomo Chemical Company, Limited Method for producing propylene oxide
CN107930610B (zh) 2017-11-29 2019-09-20 万华化学集团股份有限公司 一种烯烃环氧化催化剂的制备方法及由此制备的催化剂
JPWO2021060263A1 (es) 2019-09-25 2021-04-01
CN115244040A (zh) 2020-03-27 2022-10-25 住友化学株式会社 环氧丙烷的制造装置和环氧丙烷的制造方法

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WO1991018833A1 (en) * 1990-05-28 1991-12-12 Engelhard Corporation Large-pored molecular sieves containing at least one octahedral site and tetrahedral sites of at least one type
US5160717A (en) * 1984-04-26 1992-11-03 Uop Titanium-aluminum-silicon-oxide molecular sieve compositions
WO1993002013A1 (en) * 1991-07-24 1993-02-04 Mobil Oil Corporation Synthetic porous crystalline material, its synthesis and use

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JP2573511B2 (ja) * 1988-04-06 1997-01-22 久俊 浅岡 チタニウム、アルミニウム、ケイ素及びホウ素の各四面体酸化物の組合せによる組成物及びその製造方法
US5174888A (en) * 1990-01-25 1992-12-29 Mobil Oil Corp. Catalytic conversion
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US5160717A (en) * 1984-04-26 1992-11-03 Uop Titanium-aluminum-silicon-oxide molecular sieve compositions
WO1991018833A1 (en) * 1990-05-28 1991-12-12 Engelhard Corporation Large-pored molecular sieves containing at least one octahedral site and tetrahedral sites of at least one type
WO1993002013A1 (en) * 1991-07-24 1993-02-04 Mobil Oil Corporation Synthetic porous crystalline material, its synthesis and use

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2165773A1 (es) * 1998-08-04 2002-03-16 Sumitomo Chemical Co Proceso para producir oxido de propileno.
ES2166271A1 (es) * 1998-08-04 2002-04-01 Sumitomo Chemical Co Catalizador de oxido de silicio con contenido en titanio.
ES2165771A1 (es) * 1999-07-20 2002-03-16 Sumitomo Chemical Co Catalizador de oxido de silicio que contiene titanio.

Also Published As

Publication number Publication date
EP0655278B1 (en) 1999-03-31
GR3030587T3 (en) 1999-10-29
US5783167A (en) 1998-07-21
ATE178224T1 (de) 1999-04-15
WO1994029022A1 (es) 1994-12-22
CA2142336A1 (en) 1994-12-16
DK0655278T3 (da) 1999-10-11
ES2092428B1 (es) 1997-08-01
EP0655278A1 (en) 1995-05-31
CA2142336C (en) 2004-12-07
DE69417518D1 (de) 1999-05-06
DE69417518T2 (de) 1999-10-21

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