ES2166271A1 - Catalizador de oxido de silicio con contenido en titanio. - Google Patents

Catalizador de oxido de silicio con contenido en titanio.

Info

Publication number
ES2166271A1
ES2166271A1 ES9901743A ES9901743A ES2166271A1 ES 2166271 A1 ES2166271 A1 ES 2166271A1 ES 9901743 A ES9901743 A ES 9901743A ES 9901743 A ES9901743 A ES 9901743A ES 2166271 A1 ES2166271 A1 ES 2166271A1
Authority
ES
Spain
Prior art keywords
catalyst
titanium
silicon oxide
containing silicon
oxide catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES9901743A
Other languages
English (en)
Other versions
ES2166271B1 (es
Inventor
Jun Yamamoto
Junpei Tsuji
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP15639399A external-priority patent/JP3788107B2/ja
Priority claimed from JP15639599A external-priority patent/JP3731384B2/ja
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of ES2166271A1 publication Critical patent/ES2166271A1/es
Application granted granted Critical
Publication of ES2166271B1 publication Critical patent/ES2166271B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Catalizador de óxido de silicio con contenido en titanio. Un catalizador de óxido de silicio que contiene titanio que satisface todas las condiciones (1) a (4) que se exponen a continuación: (1) Tamaño de poro medio de 10 {angstron} o más, (2) Tamaño de poro de 90% o más del volumen de poro total de 5 a 200 {angstron}, (3) Volumen de poro específico de 0,2 cm{sup,3}/g o más, y (4) Uso de un ión de amonio cuaternario representado por la siguiente fórmula general (I) como plantilla eliminándose después dicha plantilla a través de una operación de extracción con disolvente; [NR{sup,1} R{sup,2} R{sup,3} R{sup,4}]{sup,+} (I) donde, R{sup,1} representa una cadena de hidrocarburos lineal o ramificada que tiene de 2 a 36 átomos de carbono y R{sup,2} a R{sup,4} representan un grupo alquilo que tiene de 1 a 6 átomos de carbono, un método para producir dicho catalizador y un método para producir óxido de propileno por reacción de propileno con un hidroperóxido, excepto hidroperóxido de etilbenceno, en presencia de dicho catalizador.
ES9901743A 1998-08-04 1999-07-30 Catalizador de oxido de silicio con contenido en titanio. Expired - Fee Related ES2166271B1 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP22066598 1998-08-04
JP15639399A JP3788107B2 (ja) 1998-08-04 1999-06-03 チタン含有珪素酸化物触媒、該触媒の製造方法及びプロピレンオキサイドの製造方法
JP15639599A JP3731384B2 (ja) 1998-08-04 1999-06-03 チタン含有珪素酸化物触媒、該触媒の製造方法及びプロピレンオキサイドの製造方法

Publications (2)

Publication Number Publication Date
ES2166271A1 true ES2166271A1 (es) 2002-04-01
ES2166271B1 ES2166271B1 (es) 2003-05-01

Family

ID=27320997

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9901743A Expired - Fee Related ES2166271B1 (es) 1998-08-04 1999-07-30 Catalizador de oxido de silicio con contenido en titanio.

Country Status (5)

Country Link
US (2) US6323147B1 (es)
CN (1) CN1140335C (es)
ES (1) ES2166271B1 (es)
NL (1) NL1012749C2 (es)
SG (1) SG82626A1 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
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WO2001056693A1 (fr) * 2000-02-02 2001-08-09 Sumitomo Chemical Company, Limited Catalyseur moule et son procede de fabrication, et procede de fabrication de compose d'oxirane
JP4889865B2 (ja) * 2001-01-31 2012-03-07 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
JP2002239381A (ja) * 2001-02-22 2002-08-27 Sumitomo Chem Co Ltd チタン含有珪素酸化物触媒の製造方法及び触媒
US6872679B2 (en) * 2002-09-20 2005-03-29 Arco Chemical Technology, L.P. Heterogeneous catalyst regeneration
US6712398B1 (en) * 2002-09-20 2004-03-30 Fox Bindery, Inc. Removable insert assemblies and methods for making
EP1403358A1 (en) * 2002-09-27 2004-03-31 ENI S.p.A. Process and catalysts for deep desulphurization of fuels
JP4265212B2 (ja) * 2002-12-19 2009-05-20 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
US7270742B2 (en) * 2003-03-13 2007-09-18 Lyondell Chemical Technology, L.P. Organosulfur oxidation process
US7193093B2 (en) * 2003-06-30 2007-03-20 Shell Oil Company Process for producing alkylene oxide
US7144499B2 (en) * 2003-11-26 2006-12-05 Lyondell Chemical Technology, L.P. Desulfurization process
US7314545B2 (en) * 2004-01-09 2008-01-01 Lyondell Chemical Technology, L.P. Desulfurization process
CN102600820A (zh) * 2004-12-06 2012-07-25 住友化学株式会社 含钛氧化硅催化剂的制造方法、该催化剂、以及使用该催化剂的烯化氧化合物的制造方法
JP4834982B2 (ja) * 2004-12-06 2011-12-14 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法及び触媒
US7735998B2 (en) * 2006-10-25 2010-06-15 Volk Donald A Multi-layered multifocal lens with blended refractive index
JP4935604B2 (ja) * 2006-11-27 2012-05-23 住友化学株式会社 担持酸化ルテニウムの製造方法
CN102807538B (zh) * 2011-06-02 2014-08-06 中国石油化工股份有限公司 一种制备环氧丙烷的方法
CN102807537B (zh) * 2011-06-02 2014-08-06 中国石油化工股份有限公司 制备环氧丙烷的方法
CN102872847B (zh) * 2011-07-12 2014-11-26 中国石油化工股份有限公司 钛氧化硅材料的改性方法
CN103157450B (zh) * 2013-04-08 2014-09-10 南开大学 一种功能性介孔硅球制备方法
CN105315233B (zh) * 2014-07-03 2018-06-08 中国石油化工股份有限公司 环氧丁烷的生产方法
WO2017080962A1 (en) * 2015-11-09 2017-05-18 Shell Internationale Research Maatschappij B.V. Catalyst preparation
US10011575B2 (en) 2016-07-25 2018-07-03 Oriental Union Chemical Corp. Method for fabricating titanium-containing silicon oxide material and application of the same
US10493430B2 (en) 2016-11-28 2019-12-03 Oriental Union Chemical Corp. Method for fabricating a titanium-containing silicon oxide material with high thermal stability and applications of the same
CN107930610B (zh) 2017-11-29 2019-09-20 万华化学集团股份有限公司 一种烯烃环氧化催化剂的制备方法及由此制备的催化剂
JP7150476B2 (ja) * 2018-05-25 2022-10-11 三井化学株式会社 結晶性多孔質チタノシリケート触媒及びその製造方法、並びに該触媒を用いたｐ－ベンゾキノン類の製造方法
US10780431B1 (en) 2019-03-22 2020-09-22 Oriental Union Chemical Corp. Method of using biopolymer to synthesize titanium-containing silicon oxide material and applications thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2109867A5 (es) * 1970-10-01 1972-05-26 Shell Int Research
US4367342A (en) * 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
US5143879A (en) * 1991-07-18 1992-09-01 Mobil Oil Corporation Method to recover organic templates from freshly synthesized molecular sieves
EP0659685A1 (en) * 1993-12-23 1995-06-28 ARCO Chemical Technology, L.P. Epoxidation process and catalyst therefor
ES2092428A1 (es) * 1993-06-15 1996-11-16 Univ Valencia Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide

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US3829392A (en) 1970-10-01 1974-08-13 Shell Oil Co Heterogeneous catalysts for olefin epoxidation
US3923843A (en) 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
JPH07300312A (ja) * 1994-03-09 1995-11-14 Nippon Shokubai Co Ltd メソポアチタノシリケートおよびその合成方法
US5795555A (en) 1994-11-24 1998-08-18 Alive; Keshavaraja Micro-meso porous amorphous titanium silicates and a process for preparing the same
JP3658790B2 (ja) 1995-03-30 2005-06-08 住友化学株式会社 触媒及びオキシラン化合物の製造方法
US5622684A (en) * 1995-06-06 1997-04-22 Board Of Trustees Operating Michigan State University Porous inorganic oxide materials prepared by non-ionic surfactant templating route
US5688484A (en) 1996-07-29 1997-11-18 Arco Chemical Technology, L.P. Non-hydrothermal method of making a titanium-containing zeolite
DE19644348A1 (de) * 1996-10-25 1998-04-30 Degussa Verfahren zur Herstellung von titanhaltigen Molekularsieben
US6054112A (en) 1996-10-25 2000-04-25 Degussa-Huls Ag Process for the preparation of titanium containing molecular sieves
SG73663A1 (en) 1998-08-04 2000-06-20 Sumitomo Chemical Co A process for producing propylene oxide
ES2156506B1 (es) 1998-10-14 2002-03-01 Sumitomo Chemical Co Metodo para la produccion de oxido de propileno.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4367342A (en) * 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
FR2109867A5 (es) * 1970-10-01 1972-05-26 Shell Int Research
US5143879A (en) * 1991-07-18 1992-09-01 Mobil Oil Corporation Method to recover organic templates from freshly synthesized molecular sieves
ES2092428A1 (es) * 1993-06-15 1996-11-16 Univ Valencia Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
EP0659685A1 (en) * 1993-12-23 1995-06-28 ARCO Chemical Technology, L.P. Epoxidation process and catalyst therefor
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide

Also Published As

Publication number Publication date
NL1012749A1 (nl) 2000-02-08
CN1247101A (zh) 2000-03-15
ES2166271B1 (es) 2003-05-01
NL1012749C2 (nl) 2000-06-06
CN1140335C (zh) 2004-03-03
US6512128B2 (en) 2003-01-28
SG82626A1 (en) 2001-08-21
US6323147B1 (en) 2001-11-27
US20020037807A1 (en) 2002-03-28

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