ES2083375T3 - Resina de sulfuro de arileno con un alto peso molecular y procedimiento para su preparacion. - Google Patents

Resina de sulfuro de arileno con un alto peso molecular y procedimiento para su preparacion.

Info

Publication number
ES2083375T3
ES2083375T3 ES89123050T ES89123050T ES2083375T3 ES 2083375 T3 ES2083375 T3 ES 2083375T3 ES 89123050 T ES89123050 T ES 89123050T ES 89123050 T ES89123050 T ES 89123050T ES 2083375 T3 ES2083375 T3 ES 2083375T3
Authority
ES
Spain
Prior art keywords
polymerization process
alkali metal
arylene sulfide
mole
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89123050T
Other languages
English (en)
Inventor
Kenneth Charles Hoover
Lacey Eugene Scoggins
Earl Clark Jr
Afif Michael Nesheiwat
Roy Eugene Reger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2083375T3 publication Critical patent/ES2083375T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • C08G75/0204Polyarylenethioethers
    • C08G75/025Preparatory processes
    • C08G75/0259Preparatory processes metal hydrogensulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

EN UN PRIMER CASO, LAS RESINAS DE SULFURO ARILENO ESTAN PROVISTAS POR CONTACTAR, EN UNA MEZCLA DE POLIMERIZACION, DURANTE UN PROCESO DE POLIMERIZACION, REACTANTES COMPRENDIENDO: UN SULFURO DE METAL ALCALI, UN AMIDO ORGANICO, UN CARBOXILATO DE METAL ALCALI, AGUA Y UNA FUENTE DE MONOMERO QUE COMPRENDE AL MENOS UN COMPONENTE DIHALOAROMATICO. LA CANTIDAD DE CARBOXILATO DE METAL ALCALI PRESENTE DURANTE EL PROCESO DE POLIMERIZACION ES DEL RANGO DE SOBRE 0.002 A SOBRE 0.05 MOLES POR CADA MOL DE SULFURO PRESENTE EN LA RESINA DE SULFURO ARILENO RESULTANTE. LA CANTIDAD TOTAL DE AGUA PRESENTE DURANTE EL PROCESO DE POLIMERIZACION ES DEL RANGO DE SOBRE 1.02 A SOBRE 2.1 MOLES POR CADA MOL DE SULFURO PRESENTE EN LA RESINA DE SULFURO ARILENO RESULTANTE. EN UN SEGUNDO CASO, LAS RESINAS DE SULFURO ARILENO SON PROVISTAS POR CONTACTAR, EN UNA MEZCLA DE POLIMERIZACION, DURANTE UN PROCESO DE POLIMERIZACION, REACTANTES COMPRENDIENDO: UN SULFURO DE METAL ALCALI, UN AMIDO ORGANICO, UN CARBOXILATO DE METAL ALCALI, AGUA Y UNA FUENTE DE MONOMERO QUE COMPRENDE UNA MEZCLA DE AL MENOS UN COMPONENTE DIHALOAROMATICO Y AL MENOS UN COMPONENTE POLIHALOAROMATICO QUE TIENE MAS DE DOS SUSTITUYENTES POR MOLECULA. EL RANGO DE LA CANTIDAD DE CARBOXILATO DE METAL ALCALI PRESENTE DURANTE EL PROCESO DE POLIMERIZACION Y LA CANTIDAD TOTAL DE AGUA PRESENTE DURANTE EL PROCESO DE POLIMERIZACION SON IDENTICAS A ESAS CANTIDADES DESCUBIERTAS EN EL PRIMER CASO. LA CANTIDAD DEL COMPONENTE POLIHALOAROMATICO INICIALMENTE PRESENTE ES DEL RANGO DE SOBRE 0.0001 A SOBRE 0.01 MOLES POR CADA MOL DEL COMPONENTE DIHALOAROMETICO PRESENTE ANTERIOR A LA INICIACION DEL PROCESO DE POLIMERIZACION.
ES89123050T 1988-12-13 1989-12-13 Resina de sulfuro de arileno con un alto peso molecular y procedimiento para su preparacion. Expired - Lifetime ES2083375T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US28417088A 1988-12-13 1988-12-13

Publications (1)

Publication Number Publication Date
ES2083375T3 true ES2083375T3 (es) 1996-04-16

Family

ID=23089152

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89123050T Expired - Lifetime ES2083375T3 (es) 1988-12-13 1989-12-13 Resina de sulfuro de arileno con un alto peso molecular y procedimiento para su preparacion.

Country Status (7)

Country Link
EP (1) EP0374719B1 (es)
JP (1) JP2674713B2 (es)
AT (1) ATE133694T1 (es)
CA (1) CA2004259A1 (es)
DE (1) DE68925576T2 (es)
ES (1) ES2083375T3 (es)
GR (1) GR3019540T3 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5053486A (en) * 1989-11-06 1991-10-01 Phillips Petroleum Company Process for preparing poly(arylene sulfide sulfone) with controlled ratio of alkali metal carboxylate to sulfur source
US5239050A (en) * 1991-05-13 1993-08-24 Phillips Petroleum Company Process for preparing arylene sulfide polymer with addition of aqueous alkali metal carboxylate prior to termination of polymerization
BE1006187A3 (fr) * 1992-09-25 1994-06-07 Solvay Procede pour la fabrication de poly(sulfure d'arylene).
JP4820486B2 (ja) * 2000-12-18 2011-11-24 ディーアイシー・イーピー株式会社 ポリアリーレンスルフィド樹脂の製造方法
US7312300B2 (en) * 2005-02-22 2007-12-25 Chevron Phillips Chemical Company Lp Inferred water analysis in polyphenylene sulfide production
JP4994997B2 (ja) * 2007-08-09 2012-08-08 株式会社クレハ ポリアリーレンスルフィドの製造方法
JP4953020B2 (ja) * 2008-02-05 2012-06-13 Dic株式会社 ポリアリ−レンスルフィド樹脂の製造方法
JP5125993B2 (ja) * 2008-10-31 2013-01-23 東レ株式会社 ポリアリーレンスルフィド樹脂の製造方法
CN111533910A (zh) * 2020-05-11 2020-08-14 山东滨化滨阳燃化有限公司 一种注塑级聚苯硫醚树脂的工业化生产工艺及装置
CN111471177A (zh) * 2020-05-11 2020-07-31 山东滨化滨阳燃化有限公司 一种纤维级聚苯硫醚树脂的工业化生产工艺及装置

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4116947A (en) * 1977-04-29 1978-09-26 Phillips Petroleum Company Branched arylene sulfide polymer production
US4350810A (en) * 1979-08-14 1982-09-21 Phillips Petroleum Company Preparation of branched chain arylene sulfide polymer
US4282347A (en) * 1979-08-14 1981-08-04 Phillips Petroleum Company Preparation of branched polymers of arylene sulfide
US4371671A (en) * 1981-09-01 1983-02-01 Phillips Petroleum Company Controlled, elevated pressure dehydration of poly(arylene sulfide) prepolymerization mixture
JPH0768350B2 (ja) * 1986-12-24 1995-07-26 東ソー株式会社 ポリアリ−レンスルフイドの製造方法
JPH0618877B2 (ja) * 1987-06-30 1994-03-16 出光石油化学株式会社 ポリアリ−レンスルフィドの製造方法
JP2575430B2 (ja) * 1987-12-18 1997-01-22 東ソー株式会社 ポリ(p−フェニレンスルフィド)の製造方法

Also Published As

Publication number Publication date
DE68925576D1 (de) 1996-03-14
JPH02258837A (ja) 1990-10-19
JP2674713B2 (ja) 1997-11-12
DE68925576T2 (de) 1996-06-05
EP0374719A2 (en) 1990-06-27
ATE133694T1 (de) 1996-02-15
GR3019540T3 (en) 1996-07-31
EP0374719A3 (en) 1991-01-30
EP0374719B1 (en) 1996-01-31
CA2004259A1 (en) 1990-06-13

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