ES2072992T3 - Proceso para la preparacion de un catalizador del tipo ziegler-natta. - Google Patents

Proceso para la preparacion de un catalizador del tipo ziegler-natta.

Info

Publication number
ES2072992T3
ES2072992T3 ES90313568T ES90313568T ES2072992T3 ES 2072992 T3 ES2072992 T3 ES 2072992T3 ES 90313568 T ES90313568 T ES 90313568T ES 90313568 T ES90313568 T ES 90313568T ES 2072992 T3 ES2072992 T3 ES 2072992T3
Authority
ES
Spain
Prior art keywords
liquid hydrocarbon
vanadium
contacting
ziegler
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90313568T
Other languages
English (en)
Inventor
Jean-Claude Bailly
Patrick Behue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2072992T3 publication Critical patent/ES2072992T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/68—Vanadium, niobium, tantalum or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Beans For Foods Or Fodder (AREA)

Abstract

ESTA INVENCION SE REFIERE A UN PROCESO PARA PREPARAR UN CATALIZADOR TIPO ZIEGLER-NATTA BASADO EN UN COMPUESTO DE VANADIO. EL PROCESO COMPRENDE EL PONER EN CONTACTO SECUENCIALMENTE DENTRO DE UN HIDROCARBON LIQUIDO UN SOPORTE ESFEROIDAL, COMPRENDIENDO (I) MGCL SUB 2 LIBRE DE CUALQUIER ENLACE MG-C Y (II) UN ELECTRON-DONANTE DI LIBRE DE HIDROGENO LABIL, UN ELECTRON-DONADOR D2 CONTENIENDO HIDROGENO LABIL Y UN COMPUESTO ORGANO METALICO CAPAZ DE REDUCIR UN COMPUESTO DE VANADIO, (2) LAVANDO EL PRODUCTO SOLIDO CON UN HIDROCARBONO LIQUIDO DEL CONTACTO, Y (3) PONIENDO EN CONTACTO EL PRODUCTO SOLIDO LAVADO CON UNO O MAS COMPUESTOS DE VANADIO SOLUBLES EN EL HIDROCARBONO LIQUIDO, COMPRENDIENDO ATOMOS HALOGENOS Y UN RADICAL ALCOXI, ESTANDO AMBOS ENLAZADOS A LOS MISMOS O DIFERENTES ATOMOS DE VANADIO. EL CATALIZADOR QUE CONSISTE EN PARTICULAS ESFEROIDES SIN FINAS , ES MUY ACTIVO EN LA POLIMERIZACION OLEFINA Y ES PARTICULARMENTE ADAPTABLE PARA PRODUCIR COPOLIMEROS ELASOMETRICOS DE PROPILENO.
ES90313568T 1990-01-03 1990-12-13 Proceso para la preparacion de un catalizador del tipo ziegler-natta. Expired - Lifetime ES2072992T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9000136A FR2656614B1 (fr) 1990-01-03 1990-01-03 Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium, supporte sur un chlorure de magnesium.

Publications (1)

Publication Number Publication Date
ES2072992T3 true ES2072992T3 (es) 1995-08-01

Family

ID=9392579

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90313568T Expired - Lifetime ES2072992T3 (es) 1990-01-03 1990-12-13 Proceso para la preparacion de un catalizador del tipo ziegler-natta.

Country Status (20)

Country Link
US (1) US5098875A (es)
EP (1) EP0436325B1 (es)
JP (1) JP2912027B2 (es)
KR (1) KR0184600B1 (es)
CN (2) CN1026237C (es)
AT (1) ATE123784T1 (es)
AU (1) AU637856B2 (es)
BR (1) BR9100010A (es)
CA (1) CA2033029A1 (es)
CS (1) CS491A2 (es)
DE (1) DE69020124T2 (es)
ES (1) ES2072992T3 (es)
FI (1) FI99208C (es)
FR (1) FR2656614B1 (es)
HU (1) HUT58353A (es)
MY (1) MY105846A (es)
NO (1) NO177720C (es)
NZ (1) NZ236668A (es)
PL (1) PL288599A1 (es)
PT (1) PT96406B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1252129B (it) * 1991-11-22 1995-06-05 Himont Inc Componenti a catalizzatori sferici per la polimerizzazione di olefine
IT1254474B (it) * 1992-02-28 1995-09-25 Montecatini Tecnologie Srl Processo per la preparazione di copolimeri elastomerici dell'etilene
IT1256403B (it) * 1992-08-18 1995-12-05 Montecatini Tecnologie Srl Componenti e catalizzatori a base di vanadio per la polimerizzazione di olefine,e processi di polimerizzazione impieganti gli stessi
US6831032B2 (en) 2002-08-19 2004-12-14 Novolen Technology Holdings C.V. Ziegler-Natta catalyst and methods of making and using same
US6767857B1 (en) 2003-05-29 2004-07-27 Fina Technology, Inc. Process for forming a Ziegler-Natta catalyst system having a controlled morphology
CN105732699B (zh) * 2014-12-10 2018-07-13 中国石油天然气股份有限公司 烷氧基钒化合物及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4363746A (en) * 1979-05-29 1982-12-14 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
US4481301A (en) * 1981-12-04 1984-11-06 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
FR2560200B1 (fr) * 1984-02-23 1986-06-27 Bp Chimie Sa Procede de preparation de catalyseurs supportes a base de composes de vanadium pour la polymerisation et la copolymerisation de l'ethylene
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation
GB8916952D0 (en) * 1989-07-25 1989-09-13 Cozens Raymond D Container for cards or the like flat objects
FR2650827B1 (fr) * 1989-08-08 1993-03-05 Bp Chem Int Ltd Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium
FR2656615B1 (fr) * 1990-01-04 1993-05-07 Bp Chemicals Snc Procede de preparation d'un catalyseur de type ziegler-watta a base de vanadium et de titane, supporte sur un chlorure de magnesium.

Also Published As

Publication number Publication date
FI99208C (fi) 1997-10-27
FR2656614B1 (fr) 1993-05-07
NO905633D0 (no) 1990-12-28
DE69020124D1 (de) 1995-07-20
FI99208B (fi) 1997-07-15
EP0436325B1 (en) 1995-06-14
PL288599A1 (en) 1991-09-09
AU6835690A (en) 1991-07-04
DE69020124T2 (de) 1995-09-21
US5098875A (en) 1992-03-24
NO177720B (no) 1995-07-31
HUT58353A (en) 1992-02-28
NO177720C (no) 1995-11-08
CN1053242A (zh) 1991-07-24
NO905633L (no) 1991-07-04
JPH0439308A (ja) 1992-02-10
CA2033029A1 (en) 1991-07-04
EP0436325A1 (en) 1991-07-10
CN1033091C (zh) 1996-10-23
PT96406A (pt) 1991-10-15
JP2912027B2 (ja) 1999-06-28
FI910019A (fi) 1991-07-04
CN1090855A (zh) 1994-08-17
AU637856B2 (en) 1993-06-10
BR9100010A (pt) 1991-10-22
FR2656614A1 (fr) 1991-07-05
FI910019A0 (fi) 1991-01-02
PT96406B (pt) 1998-06-30
CN1026237C (zh) 1994-10-19
KR0184600B1 (ko) 1999-05-15
KR910014406A (ko) 1991-08-31
ATE123784T1 (de) 1995-06-15
CS491A2 (en) 1991-09-15
HU910008D0 (en) 1991-08-28
MY105846A (en) 1995-01-30
NZ236668A (en) 1992-02-25

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