ES2065468T3 - Procedimiento para la preparacion de tetralinas e indanos alquil-sustituidos. - Google Patents
Procedimiento para la preparacion de tetralinas e indanos alquil-sustituidos.Info
- Publication number
- ES2065468T3 ES2065468T3 ES90200817T ES90200817T ES2065468T3 ES 2065468 T3 ES2065468 T3 ES 2065468T3 ES 90200817 T ES90200817 T ES 90200817T ES 90200817 T ES90200817 T ES 90200817T ES 2065468 T3 ES2065468 T3 ES 2065468T3
- Authority
- ES
- Spain
- Prior art keywords
- ene
- carbon atoms
- preferred
- preparation
- dimethylbut
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 235000019445 benzyl alcohol Nutrition 0.000 abstract 2
- 125000005329 tetralinyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 abstract 2
- OWWIWYDDISJUMY-UHFFFAOYSA-N 2,3-dimethylbut-1-ene Chemical compound CC(C)C(C)=C OWWIWYDDISJUMY-UHFFFAOYSA-N 0.000 abstract 1
- PKXHXOTZMFCXSH-UHFFFAOYSA-N 3,3-dimethylbut-1-ene Chemical compound CC(C)(C)C=C PKXHXOTZMFCXSH-UHFFFAOYSA-N 0.000 abstract 1
- 241000402754 Erythranthe moschata Species 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 1
- 150000003938 benzyl alcohols Chemical class 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 abstract 1
- 125000003392 indanyl group Chemical class C1(CCC2=CC=CC=C12)* 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 239000011968 lewis acid catalyst Substances 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
- C07C2527/126—Aluminium chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/135—Compounds comprising a halogen and titanum, zirconium, hafnium, germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA INVENCION PROVEE UN PROCESO PARA LA PREPARACION DE INDANOS Y TETRALINDANOS ALQUILO SUSTITUIDOS EN DONDE UN BENCILO ALCOHOL QUE TIENE LA FORMULA: EN DONDE R1-R4 REPRESENTA ATOMOS DE HIDROGENO O GRUPOS ALQUILO QUE TIENEN DE 1 A 3 ATOMOS DE CARBONO Y R5 Y R6 SON GRUPOS ALQUILO QUE TIENEN DE 1 A 3 ATOMOS DE CARBONO, REACCIONA CON UN ALCANO QUE TIENE DE 4 A 7 ATOMOS DE CARBONO BAJO LA INFLUENCIA DE UN CATALIZADOR ACIDO DE LEWIS. LOS BENCILO ALCOHOLES PREFERIDOS SON AQUELLOS EN DONDE R1,R3 Y R4 SON ATOMOS DE HIDROGENO Y R2 ES UN ATOMO DE HIDROGENO O UN GRUPO METILO. LOS ALCANOS PREFERIDOS SON 2,3-DIMETILOBUTIL-1-ENO, 3,3-DIMETILOBUTIL-1-ENO, Y 2 METILOBUTIL-2-ENO. LOS ACIDOS DE LEWIS PREFERIDOS SON ALCL3, FECL3B Y TICL4. LOS INDANOS Y TETRALINDANOS PRODUCIDOS SE USAN COMO PRODUCTOS INTERMEDIOS PARA LA PRODUCCION E FRAGANCIAS DE ALMIZCLE BIEN CONOCIDAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP89200943 | 1989-04-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2065468T3 true ES2065468T3 (es) | 1995-02-16 |
Family
ID=8202364
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90200817T Expired - Lifetime ES2065468T3 (es) | 1989-04-14 | 1990-04-05 | Procedimiento para la preparacion de tetralinas e indanos alquil-sustituidos. |
Country Status (6)
Country | Link |
---|---|
US (1) | US5079386A (es) |
EP (1) | EP0393742B1 (es) |
JP (1) | JPH0639420B2 (es) |
AT (1) | ATE114622T1 (es) |
DE (1) | DE69014386T2 (es) |
ES (1) | ES2065468T3 (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3055245B2 (ja) * | 1991-09-30 | 2000-06-26 | 住友化学工業株式会社 | 1,1,3,4,4,6−ヘキサメチルテトラリンの精製方法 |
EP0561447B1 (en) * | 1992-03-16 | 1997-01-02 | Quest International B.V. | Method of acylating 1,2,3,4-tetrahydro-1,1,2,4,4,7-hexamethylnaphthalene (HMT) and compositions comprising acylated HMT |
US5292719A (en) * | 1993-06-18 | 1994-03-08 | Union Camp Corporation | Tetralin formate ester aroma chemicals |
US5401720A (en) * | 1993-06-18 | 1995-03-28 | Union Camp Corporation | Alkyl tetralin aldehyde compounds |
US5403823A (en) * | 1993-06-18 | 1995-04-04 | Union Camp Corporation | Alkyl indane aldehyde compounds |
US5457239A (en) * | 1994-05-25 | 1995-10-10 | Union Camp Corporation | Process for formylation of aromatic compounds |
KR100621823B1 (ko) | 2004-07-21 | 2006-09-14 | 재단법인서울대학교산학협력재단 | 2,6-디알킬테트랄린의 제조 방법 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2587577A (en) * | 1948-03-27 | 1952-03-04 | Universal Oil Prod Co | Production of arylindanes |
US2519576A (en) * | 1948-06-30 | 1950-08-22 | Universal Oil Prod Co | Production of arylindans |
US2752404A (en) * | 1953-10-09 | 1956-06-26 | Polak Frutal Works | Process of producing indanes from para-cymene |
US2857433A (en) * | 1956-06-20 | 1958-10-21 | Olin Mathieson | Aromatic ketones and process of their production |
US3210433A (en) * | 1962-12-31 | 1965-10-05 | Socony Mobil Oil Co Inc | Preparation of substituted indenes |
NL123427C (es) * | 1963-06-10 | |||
US3379782A (en) * | 1965-08-27 | 1968-04-23 | Universal Oil Prod Co | Process for preparing polyalkyltetrahydronaphthalenes |
GB1566538A (en) * | 1977-02-25 | 1980-04-30 | Naarden Internationale Nv | Acyl polyalkyo indan compounds their preparation and their use in perfumery |
DE3626227A1 (de) * | 1986-08-02 | 1988-02-04 | Basf Ag | Verfahren zur herstellung von indanen |
-
1990
- 1990-04-05 AT AT90200817T patent/ATE114622T1/de not_active IP Right Cessation
- 1990-04-05 DE DE69014386T patent/DE69014386T2/de not_active Expired - Fee Related
- 1990-04-05 ES ES90200817T patent/ES2065468T3/es not_active Expired - Lifetime
- 1990-04-05 EP EP90200817A patent/EP0393742B1/en not_active Expired - Lifetime
- 1990-04-13 JP JP2099149A patent/JPH0639420B2/ja not_active Expired - Lifetime
- 1990-10-19 US US07/598,886 patent/US5079386A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0393742B1 (en) | 1994-11-30 |
DE69014386T2 (de) | 1995-04-20 |
EP0393742A1 (en) | 1990-10-24 |
JPH0639420B2 (ja) | 1994-05-25 |
ATE114622T1 (de) | 1994-12-15 |
JPH04182438A (ja) | 1992-06-30 |
DE69014386D1 (de) | 1995-01-12 |
US5079386A (en) | 1992-01-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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