ES2064751T3 - Fenilciclohexanos y medio fluidocristalino. - Google Patents

Fenilciclohexanos y medio fluidocristalino.

Info

Publication number
ES2064751T3
ES2064751T3 ES90912038T ES90912038T ES2064751T3 ES 2064751 T3 ES2064751 T3 ES 2064751T3 ES 90912038 T ES90912038 T ES 90912038T ES 90912038 T ES90912038 T ES 90912038T ES 2064751 T3 ES2064751 T3 ES 2064751T3
Authority
ES
Spain
Prior art keywords
sup
sub
phenylcyclohexanes
fluid medium
crystalline fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90912038T
Other languages
English (en)
Inventor
Andreas Wachtler
Reinhard Hittich
Eike Poetsch
Herbert Plach
David Coates
Bernhard Wacore-Tamagaw Rieger
Joachim Krause
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27511321&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2064751(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Application granted granted Critical
Publication of ES2064751T3 publication Critical patent/ES2064751T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/26Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/02Monocyclic aromatic halogenated hydrocarbons
    • C07C25/13Monocyclic aromatic halogenated hydrocarbons containing fluorine
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C22/00Cyclic compounds containing halogen atoms bound to an acyclic carbon atom
    • C07C22/02Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings
    • C07C22/04Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings containing six-membered aromatic rings
    • C07C22/08Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings containing six-membered aromatic rings containing fluorine
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24Halogenated aromatic hydrocarbons with unsaturated side chains
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24Halogenated aromatic hydrocarbons with unsaturated side chains
    • C07C25/28Halogenated styrenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/50Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/20Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001Cyclohexane rings
    • C09K19/3003Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Crystal Substances (AREA)

Abstract

SE EXPONEN NUEVOS FENILCICLOHEXANOS DE LA FORMULA (I), EN LA CUAL N ES 0 A 7, Q ELEVADO A 1 Y Q (AL CUADRADO) REPRESENTAN H, O UNO DE ESTOS RESIDUOS PUEDE REPRESENTAR TAMBIEN CH SUB 3, R ES 0, 1, 2, 3, 4 O 5, A ES TRANS-1,4 -CICLOHEXILENO, 1,4-FENILENO, 3-FLUOR-1,4-FENILENO O UN ENLACE SIMPLE, X ES F, CL, -CF SUB 3, -CN, -OCF SUB 3 O -OCHF SUB 2, ASI COMO Y Y Z REPRESENTAN, INDEPENDIENTEMENTE EL UNO DEL OTRO, H O F, CON TAL QUE CUANDO A ES UN ENLACE SIMPLE, Q ELEVADO A 1 = Q (AL CUADRADO) = H Y AL MISMO TIEMPO X = CN, ASI COMO Y Y/O Z REPRESENTAN F.
ES90912038T 1989-08-16 1990-08-13 Fenilciclohexanos y medio fluidocristalino. Expired - Lifetime ES2064751T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE3926871 1989-08-16
DE4006313 1990-03-01
DE4013084 1990-04-25
DE4013467 1990-04-27
DE4021154 1990-07-03

Publications (1)

Publication Number Publication Date
ES2064751T3 true ES2064751T3 (es) 1995-02-01

Family

ID=27511321

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90912038T Expired - Lifetime ES2064751T3 (es) 1989-08-16 1990-08-13 Fenilciclohexanos y medio fluidocristalino.

Country Status (10)

Country Link
US (8) US5891360A (es)
EP (1) EP0438563B1 (es)
JP (2) JP2935744B2 (es)
KR (2) KR0152483B1 (es)
AT (1) ATE115109T1 (es)
DE (2) DE4025550B4 (es)
DK (1) DK0438563T3 (es)
ES (1) ES2064751T3 (es)
SG (1) SG26368G (es)
WO (1) WO1991002709A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5482653A (en) * 1989-05-30 1996-01-09 Merck Patent Gesellschaft Mit Beschrankter Haftung Fluoro-chloro-benzene derivatives
DE4025550B4 (de) * 1989-08-16 2007-05-03 Merck Patent Gmbh Phenylcyclohexane und flüssigkristallines Medium
ATE119871T1 (de) * 1989-09-06 1995-04-15 Merck Patent Gmbh Fluorbenzolderivate und flüssigkristallines medium.
KR920701386A (ko) * 1990-04-03 1992-08-11 위르겐 호이만, 라인하르트 슈틀러 액정 매질
DE59104951D1 (de) * 1990-04-13 1995-04-20 Merck Patent Gmbh Flüssigkristallines medium.
KR0171590B1 (ko) * 1990-04-13 1999-03-20 위르겐 호이만, 라인하르트 슈틀러 액정 매질
DE59107572D1 (de) * 1990-04-13 1996-04-25 Merck Patent Gmbh Flüssigkristallines medium
JP3073233B2 (ja) * 1990-04-13 2000-08-07 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 液晶媒体
EP0458176B1 (de) * 1990-05-21 1995-08-02 F. Hoffmann-La Roche Ag Bicyclohexylderivate
US5292452A (en) * 1990-09-14 1994-03-08 Hoffmann-La Roche Inc. Alkenylcyclohexane liquid crystalline compounds
DE4107167B4 (de) * 1991-03-06 2008-05-08 Merck Patent Gmbh Flüssigkristallmischung
DE4123539A1 (de) * 1991-07-16 1993-01-21 Merck Patent Gmbh Fluessigkristallines medium
DE69324586T2 (de) * 1993-10-08 1999-09-16 Chisso Corp Cyclohexanderivat
US6830787B1 (en) * 1994-03-17 2004-12-14 Hitachi, Ltd. Active matrix liquid crystal display apparatus
DE19515504A1 (de) * 1995-04-27 1996-10-31 Merck Patent Gmbh Fluorierte Biphenylcyclohexane und flüssigkristallines Medium
JPH08325173A (ja) * 1995-05-25 1996-12-10 Chisso Corp エキソメチレン部位を持つ液晶性化合物およびそれを含む液晶組成物
US5888423A (en) * 1995-07-17 1999-03-30 Rolic Ag Fluorobenzyl ether derivatives
US5807499A (en) * 1995-08-23 1998-09-15 Chisso Corporation Liquid crystal composition and a liquid crystal display device containing the same
JP3856188B2 (ja) 1999-10-28 2006-12-13 大日本インキ化学工業株式会社 液晶組成物
US8232564B2 (en) * 2007-01-22 2012-07-31 Cree, Inc. Wafer level phosphor coating technique for warm light emitting diodes
US8167674B2 (en) * 2007-12-14 2012-05-01 Cree, Inc. Phosphor distribution in LED lamps using centrifugal force
US10546846B2 (en) 2010-07-23 2020-01-28 Cree, Inc. Light transmission control for masking appearance of solid state light sources
TWI456031B (zh) 2010-12-23 2014-10-11 Ind Tech Res Inst 液晶化合物、液晶組合物及包括該化合物或組合物之液晶顯示器及光電裝置
EP3183330B1 (en) 2014-08-20 2019-07-17 Bedoukian Research, Inc. Perfume compositions containing isomeric alkadienals

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3022818C2 (de) 1980-06-19 1986-11-27 Merck Patent Gmbh, 6100 Darmstadt Flüssigkristall-Anzeigeelement
US4405488A (en) 1980-10-09 1983-09-20 Chisso Corporation Liquid-crystalline halogenobenzene derivatives
US4565425A (en) * 1983-03-16 1986-01-21 Hoffmann-La Roche Inc. Liquid crystals
EP0122389B1 (de) * 1983-03-16 1987-08-05 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft Flüssigkristallkomponenten mit einer Alkenylseitenkette
DE3575158D1 (de) * 1984-07-12 1990-02-08 Hoffmann La Roche Fluessigkristalline gemische enthaltend komponenten mit einer 4-alkenyl- oder 2z-alkenyl-seitenkette.
DE3447359A1 (de) 1984-12-24 1986-07-03 Merck Patent Gmbh, 6100 Darmstadt Fluessigkristalline phase
DE3500897A1 (de) 1985-01-12 1986-07-17 Merck Patent Gmbh, 6100 Darmstadt Fluessigkristalline phase
DE3504866A1 (de) 1985-02-13 1986-08-14 Merck Patent Gmbh, 6100 Darmstadt Fluorbenzolderivate
DE3667170D1 (de) * 1985-03-26 1990-01-04 Hoffmann La Roche Alkenylsubstituierte phenylisothiocyanate und benzonitrile.
DE3614778A1 (de) * 1986-05-02 1987-11-05 Merck Patent Gmbh Smektische fluessigkristalline phasen
US5318721A (en) 1986-05-02 1994-06-07 Merck Patent Gesellschaft Mit Beschrankter Haftung Nematic liquid-crystalline phases
GB2193536A (en) 1986-08-04 1988-02-10 Ford Motor Co I.c. engine fuel metering and distribution system
KR950014738B1 (ko) * 1986-09-08 1995-12-14 메르크 파텐트 게젤샤프트 미트 베슈랭크터 하트퉁 액정상
DE3732284A1 (de) * 1987-09-25 1989-04-13 Merck Patent Gmbh Substituierte phenyltrifluormethylether
DE3732384A1 (de) 1987-09-25 1989-04-06 Bayer Ag Bisazolyl-hydroxyalkyl-derivate enthaltende antimykotische mittel
US5013477A (en) 1987-11-06 1991-05-07 Hoffmann-La Roche Inc. Alkenylbicyclohexane liquid crystals
DE3887084D1 (de) * 1987-11-06 1994-02-24 Hoffmann La Roche Halogenierte Benzolderivate.
JP2504491B2 (ja) 1987-11-11 1996-06-05 チッソ株式会社 液晶組成物
DE3835803A1 (de) * 1988-03-10 1990-04-26 Merck Patent Gmbh Supertwist-fluessigkristallanzeigeelement und fluessigkristallmischung
US5286410A (en) 1988-03-10 1994-02-15 Merck Patent Gesellschaft Mit Beschrankter Haftung Supertwist liquid-crystal display
DE3807958B4 (de) * 1988-03-10 2004-03-18 Merck Patent Gmbh Supertwist-Flüssigkristallanzeigeelement
DE3906040A1 (de) * 1988-03-10 1989-09-21 Merck Patent Gmbh Cyclohexenderivate
EP0365962B1 (de) * 1988-10-20 1994-09-21 MERCK PATENT GmbH Matrix-Flüssigkristallanzeige
JP2696557B2 (ja) * 1989-03-07 1998-01-14 チッソ株式会社 トリフルオロベンゼン誘導体
WO1991002710A2 (de) * 1989-08-12 1991-03-07 MERCK Patent Gesellschaft mit beschränkter Haftung Benzolderivate und flüssigkristallines medium
DE4025550B4 (de) * 1989-08-16 2007-05-03 Merck Patent Gmbh Phenylcyclohexane und flüssigkristallines Medium
US5171469A (en) * 1989-08-22 1992-12-15 Merck Patent Gesellschaft Mit Beschraenkter Haftung Liquid-crystal matrix display
DE4002609A1 (de) * 1989-09-07 1991-03-21 Merck Patent Gmbh Difluorbenzonitrile und fluessigkristallines medium
US5389289A (en) * 1990-03-09 1995-02-14 Merck Patent Gesellschaft Mit Beschrankter Haftung Liquid-crystalline medium
US5185098A (en) * 1990-04-05 1993-02-09 Hoffmann-La Roche Inc. Liquid crystalline mixtures containing 3,4-difluorophenyl-substituted bicyclohexyls
DE59107572D1 (de) * 1990-04-13 1996-04-25 Merck Patent Gmbh Flüssigkristallines medium
WO1991016398A1 (de) * 1990-04-13 1991-10-31 MERCK Patent Gesellschaft mit beschränkter Haftung Flüssigkristallines medium
KR0171590B1 (ko) * 1990-04-13 1999-03-20 위르겐 호이만, 라인하르트 슈틀러 액정 매질
WO1991016291A1 (de) * 1990-04-21 1991-10-31 MERCK Patent Gesellschaft mit beschränkter Haftung Phenylcyclohexane und flüssigkristallines medium
EP0458176B1 (de) * 1990-05-21 1995-08-02 F. Hoffmann-La Roche Ag Bicyclohexylderivate
US5292452A (en) * 1990-09-14 1994-03-08 Hoffmann-La Roche Inc. Alkenylcyclohexane liquid crystalline compounds
EP0503021B1 (en) * 1990-10-02 1996-06-12 MERCK PATENT GmbH Liquid crystalline medium
KR100275841B1 (ko) * 1992-10-07 2000-12-15 고토 기치 사이클로헥산 유도체 및 이를 함유하는 액정 조성물
DE19515504A1 (de) * 1995-04-27 1996-10-31 Merck Patent Gmbh Fluorierte Biphenylcyclohexane und flüssigkristallines Medium

Also Published As

Publication number Publication date
JP3122426B2 (ja) 2001-01-09
US20040089845A1 (en) 2004-05-13
KR0153476B1 (ko) 1998-12-01
US6677002B2 (en) 2004-01-13
US7250199B2 (en) 2007-07-31
DE4025550B4 (de) 2007-05-03
US20020043646A1 (en) 2002-04-18
DK0438563T3 (da) 1995-02-13
US20050133763A1 (en) 2005-06-23
WO1991002709A1 (de) 1991-03-07
KR0152483B1 (ko) 1998-10-15
DE59007937D1 (de) 1995-01-19
EP0438563B1 (de) 1994-12-07
US20010015422A1 (en) 2001-08-23
JPH11315040A (ja) 1999-11-16
US5458805A (en) 1995-10-17
US6284154B1 (en) 2001-09-04
JPH04501270A (ja) 1992-03-05
KR960701583A (ko) 1996-02-24
EP0438563A1 (de) 1991-07-31
KR920701095A (ko) 1992-08-11
US5891360A (en) 1999-04-06
US20040169159A9 (en) 2004-09-02
JP2935744B2 (ja) 1999-08-16
US6955837B2 (en) 2005-10-18
DE4025550A1 (de) 1991-02-21
ATE115109T1 (de) 1994-12-15
US20080173844A1 (en) 2008-07-24
SG26368G (en) 1995-09-18

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