ES2063860T3 - Composiciones de resina de polipropileno de alta sindiotacticidad y proceso de preparacion de las mismas. - Google Patents

Composiciones de resina de polipropileno de alta sindiotacticidad y proceso de preparacion de las mismas.

Info

Publication number
ES2063860T3
ES2063860T3 ES90110807T ES90110807T ES2063860T3 ES 2063860 T3 ES2063860 T3 ES 2063860T3 ES 90110807 T ES90110807 T ES 90110807T ES 90110807 T ES90110807 T ES 90110807T ES 2063860 T3 ES2063860 T3 ES 2063860T3
Authority
ES
Spain
Prior art keywords
polypropylene resin
same
preparation process
resin compositions
high syndiotacticity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90110807T
Other languages
English (en)
Inventor
Tadashi Asanuma
Tetsunosuke Shiomura
Nobutaka Uchikawa
Tutomu Iwatani
Katsumi Takeuchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Toatsu Chemicals Inc
Original Assignee
Mitsui Toatsu Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc
Application granted granted Critical
Publication of ES2063860T3 publication Critical patent/ES2063860T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/10—Peculiar tacticity
    • C08L2207/12—Syndiotactic polypropylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

SE PRESENTA UN COMPUESTO DE RESINA DE POLIPROPILENO DE UNA ALTA SINDIOTACTICIDAD QUE COMPRENDE UN HOMOPOLIMERO SUSTANCIAL DE PROPILENO, EN EL CUAL LA RELACION DE INTENSIDAD DEL PICO ATRIBUIBLE A LOS ENLACES SINDIOTACTICOS PENDIENTES CON RELACION A LA SUMA DE LAS INTENSIDADES DE TODOS LOS PICOS ATRIBUIBLES A LOS GRUPOS DE METIL EN EL ESPECTRO DE LOS GRUPOS DE METIL MEDIDAS MEDIANTE 13C-NMR ES 0.7 O MAYOR, TAMBIEN SE PRESENTA UN COPOLIMERO DE ETILENO Y PROPILENO, Y UN PROCESO PARA LA PREPARACION DE LOS MISMOS
ES90110807T 1989-06-12 1990-06-07 Composiciones de resina de polipropileno de alta sindiotacticidad y proceso de preparacion de las mismas. Expired - Lifetime ES2063860T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1146738A JP2818199B2 (ja) 1989-06-12 1989-06-12 シンジオタクチックポリプロピレン樹脂組成物およびその製造方法

Publications (1)

Publication Number Publication Date
ES2063860T3 true ES2063860T3 (es) 1995-01-16

Family

ID=15414479

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90110807T Expired - Lifetime ES2063860T3 (es) 1989-06-12 1990-06-07 Composiciones de resina de polipropileno de alta sindiotacticidad y proceso de preparacion de las mismas.

Country Status (13)

Country Link
US (2) US5212247A (es)
EP (1) EP0405201B1 (es)
JP (1) JP2818199B2 (es)
KR (1) KR920008526B1 (es)
CN (1) CN1040444C (es)
AU (1) AU613834B2 (es)
BR (1) BR9002744A (es)
CA (1) CA2018666C (es)
DE (1) DE69013991T2 (es)
ES (1) ES2063860T3 (es)
FI (1) FI902918A0 (es)
NO (1) NO902573L (es)
PT (1) PT94316A (es)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9007281A (pt) * 1989-04-11 1992-03-03 Mitsui Toatsu Chemicals Artigos moldados de polipropileno sindiotatico,e metodo para a sua preparacao
JP2818199B2 (ja) * 1989-06-12 1998-10-30 三井化学株式会社 シンジオタクチックポリプロピレン樹脂組成物およびその製造方法
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
DE3942363A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
DE3942365A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
EP0729985A3 (en) * 1990-12-26 1997-05-07 Shell Oil Co Ethylene propylene copolymer compositions
DE69223823T2 (de) * 1991-02-15 1998-05-20 Mitsui Toatsu Chemicals Durchsichtige schlagzähe Formkörper
US6153703A (en) * 1991-12-20 2000-11-28 Exxon Research And Engineering Company Semicrystalline polymer blend compositions with enhanced interspherulitic and interlamellar strength
US6245870B1 (en) * 1992-03-20 2001-06-12 Fina Technology, Inc. Process for producing syndiotactic/isotactic block polyolefins
JP3328360B2 (ja) * 1993-03-31 2002-09-24 三井化学株式会社 熱可塑性エラストマー
JP3275223B2 (ja) * 1994-09-22 2002-04-15 科学技術振興事業団 ポリプロピレン−ｂ−ポリ（エチレン−ｃｏ−プロピレン）とその製造方法
US5516848A (en) * 1995-01-31 1996-05-14 Exxon Chemical Patents Inc. Process to produce thermoplastic elastomers
US5539056A (en) * 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
CN1187404C (zh) * 1999-04-13 2005-02-02 三井化学株式会社 软质间同立构聚丙烯组合物含它的层压片和成型产品
JP4514856B2 (ja) * 1999-08-20 2010-07-28 三井化学株式会社 軟質シンジオタクティックポリプロピレン系組成物
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
KR100712631B1 (ko) * 2003-02-14 2007-05-02 미쓰이 가가쿠 가부시키가이샤 신디오택틱 프로필렌계 중합체 조성물
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
SG178810A1 (en) 2005-05-18 2012-03-29 Mitsui Chemicals Inc Catalyst for olefin polymerization, method for producing olefin polymer, method for producing propylene copolymer, propylene polymer, propylene polymer composition, and use of those
JP5374606B2 (ja) * 2006-01-20 2013-12-25 三井化学株式会社 プロピレン系重合体組成物およびその用途
JP5068038B2 (ja) * 2006-01-20 2012-11-07 三井化学株式会社 プロピレン系重合体組成物の製造方法
JP4979987B2 (ja) * 2006-06-02 2012-07-18 三井化学株式会社 プロピレン系重合体組成物、および該組成物を用いてなる成形体
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
WO2017121756A1 (en) * 2016-01-13 2017-07-20 Total Research & Technology Feluy Pipes comprising syndiotactic polypropylene
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3305538A (en) * 1961-11-22 1967-02-21 Montedison Spa Polymerization process
GB1099853A (en) * 1964-02-20 1968-01-17 Mitsubishi Petrochemical Co Process for producing modified propylene polymer
JPS5661415A (en) * 1979-10-24 1981-05-26 Mitsubishi Chem Ind Ltd Preparation of propylene-ethylene block copolymer
US4491652A (en) * 1981-05-13 1985-01-01 Uniroyal, Inc. Sequentially prepared thermoplastic elastomer and method of preparing same
DE3331877A1 (de) * 1983-09-03 1985-03-21 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung einer polypropylen-formmasse
JPS60212443A (ja) * 1984-04-09 1985-10-24 Toa Nenryo Kogyo Kk ポリプロピレン組成物
JPH07100751B2 (ja) * 1987-11-11 1995-11-01 出光石油化学株式会社 プロピレン重合体組成物
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
JP2818199B2 (ja) * 1989-06-12 1998-10-30 三井化学株式会社 シンジオタクチックポリプロピレン樹脂組成物およびその製造方法
DE3942365A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse

Also Published As

Publication number Publication date
FI902918A0 (fi) 1990-06-11
AU613834B2 (en) 1991-08-08
DE69013991D1 (de) 1994-12-15
EP0405201A2 (en) 1991-01-02
AU5681390A (en) 1990-12-13
KR920008526B1 (ko) 1992-10-01
CN1040444C (zh) 1998-10-28
US5314956A (en) 1994-05-24
NO902573D0 (no) 1990-06-11
NO902573L (no) 1990-12-13
KR910000906A (ko) 1991-01-30
CA2018666C (en) 1995-08-29
PT94316A (pt) 1991-02-08
EP0405201A3 (en) 1992-06-03
US5212247A (en) 1993-05-18
CN1048718A (zh) 1991-01-23
EP0405201B1 (en) 1994-11-09
JPH0312439A (ja) 1991-01-21
CA2018666A1 (en) 1990-12-12
DE69013991T2 (de) 1995-06-14
BR9002744A (pt) 1991-08-20
JP2818199B2 (ja) 1998-10-30

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