ES2059008T3 - Bis(3-ciano-3,5,5-trimetil-ciclohexiliden)-azina, procedimiento para su preparacion y transformacion ulterior para dar 3-(aminometil)-3,5,5-trimetilciclohexilamina. - Google Patents

Bis(3-ciano-3,5,5-trimetil-ciclohexiliden)-azina, procedimiento para su preparacion y transformacion ulterior para dar 3-(aminometil)-3,5,5-trimetilciclohexilamina.

Info

Publication number
ES2059008T3
ES2059008T3 ES91115713T ES91115713T ES2059008T3 ES 2059008 T3 ES2059008 T3 ES 2059008T3 ES 91115713 T ES91115713 T ES 91115713T ES 91115713 T ES91115713 T ES 91115713T ES 2059008 T3 ES2059008 T3 ES 2059008T3
Authority
ES
Spain
Prior art keywords
ipn
azina
ciano
bis
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91115713T
Other languages
English (en)
Inventor
Klaus Dr Huthmacher
Hermann Schmitt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4033609A external-priority patent/DE4033609A1/de
Priority claimed from DE4119577A external-priority patent/DE4119577A1/de
Application filed by Degussa GmbH filed Critical Degussa GmbH
Application granted granted Critical
Publication of ES2059008T3 publication Critical patent/ES2059008T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/61—Carboxylic acid nitriles containing cyano groups and nitrogen atoms being part of imino groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

LA INVENCION SE REFIERE A UNA (IPN-AZINA), Y TRATA DE UN PROCEDIMIENTO PARA OBTENER LA MISMA QUE CONSISTE EN HACER REACCIONAR A (IPN) CON UNA FUENTE DE HIDRAZINA, EN PRESENCIA DE DISOLVENTES Y CON RELACIONES CELULARES (IPN)HIDRAZINA DE 2 A 1 SE REFIERE A UN PROCESO DE TRANSFORMACION POSTERIOR DE (IPN-AZINAS) A IPDA, QUE COMPRENDE HIDROGENAR LAS (IPN-AZINAS) CON HIDROGENO EN PRESENCIA DE DISOLVENTES ORGANICOS, AMONIACO Y UN SISTEMA CATALIZADOR (C) A UNA PRESION ENTRE 3 Y 30 MPC Y A UNA TEMPERATURA ENTRE 50 Y 150 C Y SE CARACTERIZA PORQUE EN LA OBTENCION DE IPDA A PARTIR DE IPN QUE SE REALIZA CON GRAN RENDIMIENTO Y PUREZA SE ELIMINA LA AMINACION REDUCTIVA DEL IPN. SIENDO IPN-AZINA EL ISOFORON-AZINA O EL BIS-(3-CIANO-3,5,5-TRIMETILCICLOHEXILIDENO) XO-CICLO HEXAMOCARBONITRILO E IPDA, EL ISOFORONDIAMINA O EL 3-(AMINOMETILO)-3,5,5-TRIMETILOHEXILAMINO. EL SISTEMA CATALIZADOR PERTENECE A LA SERIE DE UN CATALIZADOR RANEY QUE CONTIENE O NO, COBALTO Y UNOS CATALIZADORES DE LA SERIE DE ELEMENTOS: RU, RH, PD, IR, PT, O UNOS CATALIZADORES DE PT, PD O RU.
ES91115713T 1990-10-23 1991-09-17 Bis(3-ciano-3,5,5-trimetil-ciclohexiliden)-azina, procedimiento para su preparacion y transformacion ulterior para dar 3-(aminometil)-3,5,5-trimetilciclohexilamina. Expired - Lifetime ES2059008T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4033609A DE4033609A1 (de) 1990-10-23 1990-10-23 Bis(3-cyano-3,5,5-trimethyl-cyclohexyliden) -azin, verfahren zu seiner herstellung und weiterverarbeitung zu 3-(aminomethyl-3,5,5-trimethylcyclohexylamin)
DE4119577A DE4119577A1 (de) 1991-06-14 1991-06-14 Verfahren zur herstellung von 3-aminomethyl-3,5,5-trimethylcyclohexylamin (ipda) aus bis(3-cyano-3,5,5-trimethyl-cyclohexyliden)-azin (ipn-azin)

Publications (1)

Publication Number Publication Date
ES2059008T3 true ES2059008T3 (es) 1994-11-01

Family

ID=25897914

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91115713T Expired - Lifetime ES2059008T3 (es) 1990-10-23 1991-09-17 Bis(3-ciano-3,5,5-trimetil-ciclohexiliden)-azina, procedimiento para su preparacion y transformacion ulterior para dar 3-(aminometil)-3,5,5-trimetilciclohexilamina.

Country Status (5)

Country Link
US (1) US5166396A (es)
EP (1) EP0482347B1 (es)
JP (1) JP2598848B2 (es)
DE (1) DE59100144D1 (es)
ES (1) ES2059008T3 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0534449A3 (en) * 1991-09-25 1993-06-02 Mitsubishi Kasei Corporation Process for the preparation of 3-aminomethyl-3,5,5-trialkylcyclohexylamine
DE4211454C2 (de) * 1992-04-06 1995-11-02 Degussa Verfahren zum Verlängern der Topfzeit bei der Härtung von Epoxidharzen mit Isophorondiamin-Isomerengemischen
CA2115025A1 (en) * 1993-02-08 1994-08-09 Atsushi Furutani Process for producing amines
CA2115024A1 (en) * 1993-04-27 1994-10-28 Atsushi Furutani Process for producing amines
DE19747913C1 (de) * 1997-10-30 1999-02-11 Degussa Verfahren zur Herstellung primärer und/oder sekundärer Amine aus Iminen oder Nitrilen, insbesondere zur Herstellung von 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamin (Isophorondiamin) aus 3-Cyano-3,5,5-trimethylcyclohexanimin (Isophoronnitril-imin) durch Hydrierung in Gegenwart eines quaternären Ammoniumhydroxids
DE10056840A1 (de) * 2000-11-16 2002-05-23 Basf Ag Verfahren zur Hydrierung von Nitrilen an Raney-Katalysatoren
DE102007011483A1 (de) * 2007-03-07 2008-09-18 Evonik Degussa Gmbh Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin
CN102924291B (zh) * 2011-08-08 2014-08-06 万华化学集团股份有限公司 3-氨甲基-3,5,5-三甲基环己胺的制备方法
RU2616616C2 (ru) * 2012-12-07 2017-04-18 Ваньхуа Кемикал Груп Ко., Лтд. Способ получения 3-аминометил-3,5,5-триметилциклогексиламина

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2894028A (en) * 1956-10-12 1959-07-07 Grace W R & Co Cyclohexylideneimino compounds
DE1229078B (de) * 1961-10-18 1966-11-24 Hibernia Chemie Ges Mit Beschr Verfahren zur Herstellung von 3-(Aminomethyl)-3, 5, 5-trimethylcyclohexylderivaten
DE1643364A1 (de) * 1967-09-28 1971-10-28 Bayer Ag Azoacylverbindungen
FR2176244A5 (es) * 1972-03-16 1973-10-26 Pechiney Ugine Kuhlmann
FR2175614B1 (es) * 1972-03-16 1979-09-14 Ugine Kuhlmann
GB2027026A (en) * 1978-08-04 1980-02-13 American Liquid Xtal Chem Aromatic azines and nematic liquid crystal materials of positive dielectric anisotropy containing them
DE3011656A1 (de) * 1980-03-26 1981-10-01 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von 3-aminomethyl-3-5-5-trimethyl-cyclohexylamin
DE3021955A1 (de) * 1980-06-12 1981-12-24 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung primaerer mono- und diamine aus oxoverbindungen
GB8707304D0 (en) * 1987-03-26 1987-04-29 Bp Chem Int Ltd Chemical process
CN1047856A (zh) * 1989-04-25 1990-12-19 联合碳化化学品及塑料有限公司 羰基腈和类似化合物的还原胺化
AU5384890A (en) * 1989-04-25 1990-11-01 Union Carbide Chemicals And Plastics Company Inc. Reductive amination of carbonylnitriles and similar compounds
DE3942371A1 (de) * 1989-12-21 1991-06-27 Degussa Verfahren zur herstellung von 1,3,3-trimethyl-5-oxo-cyclohexan-carbonitril
DE4010227A1 (de) * 1990-03-30 1991-10-02 Basf Ag Verfahren zur herstellung von 3-aminomethyl-3,5,5-trimethyl-cyclohexylamin

Also Published As

Publication number Publication date
JP2598848B2 (ja) 1997-04-09
EP0482347A2 (de) 1992-04-29
EP0482347A3 (en) 1992-08-19
DE59100144D1 (de) 1993-07-15
JPH04264057A (ja) 1992-09-18
US5166396A (en) 1992-11-24
EP0482347B1 (de) 1993-06-09

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