ES2056158T3 - Procedimiento de carbonilacion. - Google Patents
Procedimiento de carbonilacion.Info
- Publication number
- ES2056158T3 ES2056158T3 ES89114222T ES89114222T ES2056158T3 ES 2056158 T3 ES2056158 T3 ES 2056158T3 ES 89114222 T ES89114222 T ES 89114222T ES 89114222 T ES89114222 T ES 89114222T ES 2056158 T3 ES2056158 T3 ES 2056158T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- reaction
- carbonilation
- procedure
- alcohols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6527—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
UN PROCESO Y NUEVO CATALIZADOR PARA LA CARBONILACION DE UNO O MAS ALCOHOLES, ETERES Y ETER ALCOHOLES A ESTERES Y, OPCIONALMENTE, A ACIDOS CARBOXILICOS. LA REACCION SE EFECTUA EN ESTADO DE VAPOR SOBRE CATALIZADOR SOLIDO COMPRENDIENDO UN ANION DE POLIOXOMETALATO EN EL CUAL EL METAL TIENE AL MENOS UNO TOMADO DE LOS GRUPOS V Y VI DEL CUADRO PERIODICO DE ELEMENTOS ASOCIADO A UN CATION DE UN MIEMBRO DEL GRUPO VIIIA DEL CUADRO PERIODICO DE LOS ELEMENTOS. PREFERIBLEMENTE, EL CATALIZADOR ESTA DEPOSITADO SOBRE UN SOPORTE QUE ES INERTE A LA REACCION. EL SOPORTE PREFERIDO ES SILICE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/227,295 US5218140A (en) | 1988-08-02 | 1988-08-02 | Carbonylation reaction and catalyst therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2056158T3 true ES2056158T3 (es) | 1994-10-01 |
Family
ID=22852553
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94100031T Expired - Lifetime ES2108883T3 (es) | 1988-08-02 | 1989-08-01 | Catalizador de carbonilacion. |
ES89114222T Expired - Lifetime ES2056158T3 (es) | 1988-08-02 | 1989-08-01 | Procedimiento de carbonilacion. |
ES97101741T Expired - Lifetime ES2142109T3 (es) | 1988-08-02 | 1989-08-01 | Catalizador de carbonilacion. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94100031T Expired - Lifetime ES2108883T3 (es) | 1988-08-02 | 1989-08-01 | Catalizador de carbonilacion. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97101741T Expired - Lifetime ES2142109T3 (es) | 1988-08-02 | 1989-08-01 | Catalizador de carbonilacion. |
Country Status (6)
Country | Link |
---|---|
US (2) | US5218140A (es) |
EP (3) | EP0596859B1 (es) |
JP (1) | JPH0649661B2 (es) |
BR (1) | BR8903850A (es) |
DE (3) | DE68916718T2 (es) |
ES (3) | ES2108883T3 (es) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9223170D0 (en) * | 1992-11-05 | 1992-12-16 | British Petroleum Co Plc | Process for preparing carboxylic acids |
US5420243A (en) * | 1993-01-26 | 1995-05-30 | Celtrix Pharmaceuticals, Inc. | Biologically active TGF-β2 peptides |
AU697916B2 (en) * | 1993-01-26 | 1998-10-22 | Celtrix Pharmaceuticals, Inc. | Biologically active TGF-beta1 and TGF-beta2 peptides |
DE69406828T2 (de) * | 1993-03-26 | 1998-04-09 | Nippon Oil Co Ltd | Fester Säurenkatalysator für die Umwandlung von Paraffinen und Verfahren für die Paraffinumwandlung unter Verwendung derselben |
TW295579B (es) * | 1993-04-06 | 1997-01-11 | Showa Denko Kk | |
EP0623386A3 (en) * | 1993-05-06 | 1995-04-12 | Exxon Research Engineering Co | Catalytic compositions and their applications in isomerization. |
KR960006546B1 (ko) * | 1993-07-28 | 1996-05-17 | 한국과학기술연구원 | 초산에스테르의 제조 방법 |
GB9419387D0 (en) * | 1994-09-26 | 1994-11-09 | Bp Chem Int Ltd | Olefin hydration process |
US5618973A (en) * | 1994-11-10 | 1997-04-08 | Union Carbide Chemicals & Plastics Technology Corporation | Esterification process |
GB9503383D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
DE19530787A1 (de) * | 1995-08-22 | 1997-02-27 | Hoechst Ag | Mangan enthaltende Polyoxometallate, Synthese und Verwendung |
FR2749778B1 (fr) * | 1996-06-13 | 1998-08-14 | Elf Antar France | Procede de preparation de catalyseurs d'hydrotraitement |
US6025295A (en) * | 1996-12-23 | 2000-02-15 | Seton Hall University | Supported catalysts |
US5900505A (en) * | 1997-02-04 | 1999-05-04 | Eastman Chemical Company | Heterogeneous vapor phase carbonylation process |
FR2764211B1 (fr) * | 1997-06-09 | 1999-10-08 | Elf Antar France | Procede de preparation de catalyseurs d'hydrotraitement |
US6521783B1 (en) | 1998-01-29 | 2003-02-18 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates |
US6127432A (en) | 1998-01-29 | 2000-10-03 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates and catalysts therefor |
GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
US6137000A (en) * | 1999-02-16 | 2000-10-24 | Eastman Chemical Company | Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst |
US6160163A (en) * | 1999-02-16 | 2000-12-12 | Eastman Chemical Company | Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter |
US6159896A (en) * | 1999-02-16 | 2000-12-12 | Eastman Chemical Company | Iridium catalyst for carbonylation of lower aliphatic alcohols |
US6552220B1 (en) * | 1999-04-14 | 2003-04-22 | Showa Denko K.K. | Catalyst for production of acetic acid and ethyl acetate, process for its production and process for production of acetic acid and ethyl acetate using it |
US6160155A (en) * | 1999-04-29 | 2000-12-12 | General Electric Company | Method and catalyst system for producing aromatic carbonates |
WO2001007393A1 (en) * | 1999-07-23 | 2001-02-01 | Union Carbide Chemicals & Plastics | Processes for preparing oxygenates |
US6355595B1 (en) * | 1999-08-25 | 2002-03-12 | Eastman Chemical Company | Group 5 metal promoted iridium carbonylation catalyst |
US6353132B1 (en) * | 1999-08-25 | 2002-03-05 | Eastman Chemical Company | Vapor phase carbonylation process using group 5 metal promoted iridium catalyst |
US6355837B1 (en) | 1999-08-25 | 2002-03-12 | Eastman Chemical Company | Vapor phase carbonylation process using group 4 metal promoted iridium catalyst |
JP3920020B2 (ja) * | 1999-12-24 | 2007-05-30 | 株式会社日本触媒 | 含酸素有機化合物製造用触媒および含酸素有機化合物の製造方法 |
US6506933B1 (en) | 2000-05-22 | 2003-01-14 | Eastman Chemical Company | Vapor phase carbonylation process using gold catalysts |
US6177380B1 (en) | 2000-05-22 | 2001-01-23 | Eastman Chemical Company | Iridium-gold carbonylation co-catalysts |
US6509293B1 (en) | 2000-05-22 | 2003-01-21 | Eastman Chemical Company | Gold based heterogeneous carbonylation catalysts |
US6441222B1 (en) | 2000-05-22 | 2002-08-27 | Eastman Chemical Company | Vapor phase carbonylation process using iridium-gold co-catalysts |
US6903045B2 (en) | 2001-06-19 | 2005-06-07 | Eastman Chemical Company | Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols |
US6613938B2 (en) | 2001-06-19 | 2003-09-02 | Eastman Chemical Company | Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst |
US6537944B1 (en) | 2001-06-20 | 2003-03-25 | Eastman Chemical Company | Tungsten promoted catalyst for carbonylation of lower alkyl alcohols |
US6617471B2 (en) | 2001-06-20 | 2003-09-09 | Eastman Chemical Company | Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst |
US6548444B2 (en) | 2001-06-20 | 2003-04-15 | Eastman Chemical Company | Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols |
US6646154B2 (en) | 2001-06-20 | 2003-11-11 | Eastman Chemical Company | Method for carbonylation of lower alkyl alcohols using tungsten promoted group VIII catalyst |
US6596781B1 (en) | 2002-05-02 | 2003-07-22 | Chevron U.S.A. Inc. | Integrated process for preparing Fischer-Tropsch products and acetic acid from synthesis gas |
US7341847B2 (en) * | 2003-04-02 | 2008-03-11 | Agency For Science, Technology And Research | Promoter construct for gene expression in neuronal cells |
GB0404793D0 (en) * | 2004-03-03 | 2004-04-07 | Bp Chem Int Ltd | Process |
GB0427021D0 (en) * | 2004-12-09 | 2005-01-12 | Bp Chem Int Ltd | Process |
GB0427821D0 (en) * | 2004-12-17 | 2005-01-19 | Bp Chem Int Ltd | Catalyst and process |
US7465822B2 (en) | 2005-05-05 | 2008-12-16 | Bp Chemicals Ltd. | Process for carbonylation of alkyl ethers |
US20060252959A1 (en) * | 2005-05-05 | 2006-11-09 | The Regents Of The University Of California | Process for carbonylation of alkyl ethers |
GB0601863D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
TWI311498B (en) * | 2006-07-19 | 2009-07-01 | Lg Chemical Ltd | Catalyst for partial oxidation of methylbenzenes, method for preparing the same, and method for producing aromatic aldehydes using the same |
US7507855B2 (en) | 2006-12-15 | 2009-03-24 | The Regents Of The University Of California | Process for carbonylation of aliphatic alcohols and/or ester derivatives thereof |
EP1985608A1 (en) * | 2007-04-26 | 2008-10-29 | BP Chemicals Limited | Process for the carbonylation of dimethyl ether |
US8080493B2 (en) | 2008-02-26 | 2011-12-20 | Exxonmobil Chemical Patents Inc. | Heteropolyanions with late transition metal addenda atoms and process for their preparation |
DE102010040921A1 (de) | 2010-09-16 | 2012-03-22 | Basf Se | Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure |
EP2559680A1 (en) | 2011-08-16 | 2013-02-20 | BP Chemicals Limited | Carbonylation of methanol |
US9421522B2 (en) | 2011-12-28 | 2016-08-23 | Eastman Chemical Company | Iridium catalysts for carbonylation |
US20140121403A1 (en) | 2012-10-31 | 2014-05-01 | Celanese International Corporation | Integrated Process for the Production of Acrylic Acids and Acrylates |
CN103012062B (zh) * | 2012-12-20 | 2015-04-22 | 上海戊正工程技术有限公司 | 一种合成气间接生产乙醇的工艺及其应用 |
US9120743B2 (en) | 2013-06-27 | 2015-09-01 | Celanese International Corporation | Integrated process for the production of acrylic acids and acrylates |
CN106365994B (zh) * | 2015-07-20 | 2019-01-01 | 中国科学院大连化学物理研究所 | 一种低级脂肪羧酸烷基酯的生产方法 |
CN111111774A (zh) * | 2018-11-01 | 2020-05-08 | 中国科学院大连化学物理研究所 | 有机含膦聚合物载体负载铑和杂多酸催化剂及制备和应用 |
CN114534724A (zh) * | 2020-11-24 | 2022-05-27 | 中国科学院大连化学物理研究所 | 一种甲醇无卤素气相羰基化制备醋酸及醋酸酯的方法 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2608534A (en) * | 1949-04-18 | 1952-08-26 | Union Oil Co | Heteropoly acids or salts thereof as catalysts |
DE1083801B (de) * | 1958-08-22 | 1960-06-23 | Basf Ag | Verfahren zur Herstellung von Essigsaeure oder deren Gemischen mit Methylacetat |
IT667228A (es) * | 1961-04-18 | |||
US3409701A (en) * | 1964-01-06 | 1968-11-05 | Dow Chemical Co | Catalyst and method for dehydrogenating and cracking alkanes and olefins |
US3769329A (en) * | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
FR2218379B1 (es) * | 1973-02-16 | 1981-05-08 | Chevron Res | |
US5138093A (en) * | 1975-03-10 | 1992-08-11 | Eastman Kodak Company | Process for preparing ethylidene diacetate |
US4083771A (en) * | 1976-09-01 | 1978-04-11 | Uop Inc. | Hydrorefining of petroleum fraction utilizing a catalyst prepared with an anion complex of a group VI-B and a group VIII metal component |
JPS5452025A (en) * | 1977-09-28 | 1979-04-24 | Tokuyama Soda Co Ltd | Preparation of ester |
FR2455021A1 (fr) * | 1979-04-25 | 1980-11-21 | Rhone Poulenc Ind | Procede de preparation d'acides carboxyliques par carbonylation |
US4210597A (en) * | 1979-05-14 | 1980-07-01 | Ethyl Corporation | Preparation of oxygenates from carbon monoxide and hydrogen |
JPS56104839A (en) * | 1980-01-23 | 1981-08-20 | Kuraray Co Ltd | Preparation of acetic acid and/or methyl acetate |
JPS56104838A (en) * | 1980-01-23 | 1981-08-20 | Kuraray Co Ltd | Preparation of acetic acid and/or methyl acetate |
US4522934A (en) * | 1981-04-27 | 1985-06-11 | Atlantic Richfield Company | Vanadotungstomolybdophosphoric acid oxidation catalyst |
JPS58119343A (ja) * | 1982-01-11 | 1983-07-15 | Mitsui Mining & Smelting Co Ltd | 排ガス浄化用触媒の製造方法 |
DE3208572A1 (de) * | 1982-03-10 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Verfahren und katalysator zur herstellung von methacrylsaeure |
ZA833177B (en) * | 1982-05-15 | 1984-12-24 | British Petroleum Co Plc | Process for the production of hydrocarbyl formates |
CA1212689A (en) * | 1982-06-30 | 1986-10-14 | Steven P. Current | Alcohol carbonylation process using a nickel catalyst |
JPS59139330A (ja) * | 1983-01-31 | 1984-08-10 | Toyo Eng Corp | 酢酸メチル又は酢酸の合成方法 |
JPS59172436A (ja) * | 1983-03-22 | 1984-09-29 | Hiroo Tominaga | ジメチルエ−テルのカルボニル化方法 |
US4454244A (en) * | 1983-03-28 | 1984-06-12 | Ashland Oil, Inc. | New compositions |
US4625050A (en) * | 1983-06-23 | 1986-11-25 | Chevron Research Company | Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst |
DE3323654A1 (de) * | 1983-07-01 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von essigsaeure und methylacetat |
JPS60109584A (ja) * | 1983-11-17 | 1985-06-15 | Asahi Chem Ind Co Ltd | ポリオキシテトラメチレングリコ−ルの解重合方法 |
US4757044A (en) * | 1985-04-17 | 1988-07-12 | The Standard Oil Company | Lanthanide metal salts of heteropolyanions as catalysts for alcohol conversion |
CA1291983C (en) * | 1986-09-29 | 1991-11-12 | Keisuke Kinomura | Glycosidation catalyst and process for preparing glycoside derivatives |
CA1305467C (en) * | 1986-12-12 | 1992-07-21 | Nobumitsu Ohtake | Additive for the hydroconversion of a heavy hydrocarbon oil |
FR2625598B1 (fr) * | 1987-12-30 | 1990-05-04 | Commissariat Energie Atomique | Polymeres conducteurs electroniques dopes par des heteropolyanions, leur procede de preparation et leur utilisation en catalyse chimique et electrochimique |
-
1988
- 1988-08-02 US US07/227,295 patent/US5218140A/en not_active Expired - Fee Related
-
1989
- 1989-08-01 ES ES94100031T patent/ES2108883T3/es not_active Expired - Lifetime
- 1989-08-01 ES ES89114222T patent/ES2056158T3/es not_active Expired - Lifetime
- 1989-08-01 BR BR898903850A patent/BR8903850A/pt not_active Application Discontinuation
- 1989-08-01 ES ES97101741T patent/ES2142109T3/es not_active Expired - Lifetime
- 1989-08-01 DE DE68916718T patent/DE68916718T2/de not_active Expired - Fee Related
- 1989-08-01 DE DE68928417T patent/DE68928417T2/de not_active Expired - Fee Related
- 1989-08-01 DE DE68929159T patent/DE68929159T2/de not_active Expired - Fee Related
- 1989-08-01 EP EP94100031A patent/EP0596859B1/en not_active Expired - Lifetime
- 1989-08-01 EP EP97101741A patent/EP0782979B1/en not_active Expired - Lifetime
- 1989-08-01 JP JP1198116A patent/JPH0649661B2/ja not_active Expired - Lifetime
- 1989-08-01 EP EP89114222A patent/EP0353722B1/en not_active Expired - Lifetime
-
1993
- 1993-03-17 US US08/032,509 patent/US5330955A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE68916718T2 (de) | 1995-01-26 |
EP0596859A2 (en) | 1994-05-11 |
DE68928417D1 (de) | 1997-12-04 |
ES2142109T3 (es) | 2000-04-01 |
DE68928417T2 (de) | 1998-02-26 |
ES2108883T3 (es) | 1998-01-01 |
DE68916718D1 (de) | 1994-08-18 |
EP0782979A1 (en) | 1997-07-09 |
EP0353722A2 (en) | 1990-02-07 |
EP0596859B1 (en) | 1997-10-29 |
US5330955A (en) | 1994-07-19 |
EP0353722B1 (en) | 1994-07-13 |
EP0596859A3 (en) | 1994-06-15 |
DE68929159D1 (de) | 2000-03-23 |
DE68929159T2 (de) | 2000-09-28 |
BR8903850A (pt) | 1990-03-20 |
US5218140A (en) | 1993-06-08 |
EP0353722A3 (en) | 1991-07-31 |
JPH0649661B2 (ja) | 1994-06-29 |
EP0782979B1 (en) | 2000-02-16 |
JPH02152937A (ja) | 1990-06-12 |
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