ES2038404T3 - Preparacion de ligandos bidentados. - Google Patents
Preparacion de ligandos bidentados.Info
- Publication number
- ES2038404T3 ES2038404T3 ES198989300485T ES89300485T ES2038404T3 ES 2038404 T3 ES2038404 T3 ES 2038404T3 ES 198989300485 T ES198989300485 T ES 198989300485T ES 89300485 T ES89300485 T ES 89300485T ES 2038404 T3 ES2038404 T3 ES 2038404T3
- Authority
- ES
- Spain
- Prior art keywords
- independently selected
- chem
- cycloaliphatic
- aryl
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000003118 aryl group Chemical group 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- -1 e.g. Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000001624 naphthyl group Chemical group 0.000 abstract 2
- 125000005561 phenanthryl group Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 125000003435 aroyl group Chemical group 0.000 abstract 1
- 125000005333 aroyloxy group Chemical group 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 125000005160 aryl oxy alkyl group Chemical group 0.000 abstract 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000005841 biaryl group Chemical group 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- 125000001589 carboacyl group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 150000003460 sulfonic acids Chemical class 0.000 abstract 1
- BZWKPZBXAMTXNQ-UHFFFAOYSA-N sulfurocyanidic acid Chemical compound OS(=O)(=O)C#N BZWKPZBXAMTXNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/505—Preparation; Separation; Purification; Stabilisation
- C07F9/509—Preparation; Separation; Purification; Stabilisation by reduction of pentavalent phosphorus derivatives, e.g. -P=X with X = O, S, Se or -P-Hal2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
- C07C1/326—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being a magnesium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/505—Preparation; Separation; Purification; Stabilisation
- C07F9/5063—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Peptides Or Proteins (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
PROCESO DE PREPARACION DE LIGANDOS BIDENTADOS DE FORMULA(I) DE LA QUE SE INDICA LA SIGNIFICACION DE LOS DIFERENTES SUSTITUYENTES, QUE COMPRENDE: 1) PONER EN CONTACTO UN COMPUESTO DE BIARILO DE FORMULA(II) CON UN AGENTE SEPARADOR DE PROTONES EN CONDICIONES ADECUADAS PARA FORMAR UN DANION DE BIARILO; Y 2) PONER EN CONTACTO EL DIANION BARILICO OBTENIDO EN LA ETAPA 1) CON UN COMPUESTO DEL GRUPO V, DE FORMULA (III) O (IV) EN LAS QUE X'' ES HALOGENO O UN GRUPO SEPARABLE ADECUADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/148,241 US5026886A (en) | 1988-01-25 | 1988-01-25 | Preparation of bidentate ligands |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2038404T3 true ES2038404T3 (es) | 1993-07-16 |
Family
ID=22524898
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198989300485T Expired - Lifetime ES2038404T3 (es) | 1988-01-25 | 1989-01-19 | Preparacion de ligandos bidentados. |
Country Status (10)
Country | Link |
---|---|
US (1) | US5026886A (es) |
EP (2) | EP0419485B1 (es) |
JP (1) | JP2968545B2 (es) |
KR (1) | KR970011166B1 (es) |
CN (1) | CN1023315C (es) |
AT (1) | ATE84790T1 (es) |
CA (1) | CA1334204C (es) |
DE (1) | DE68904558T2 (es) |
ES (1) | ES2038404T3 (es) |
WO (1) | WO1989006653A1 (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1244008B (it) * | 1990-11-02 | 1994-06-28 | Ausimont Spa | Processo per la produzione di sali di articoli fluorurati. |
DE4338826A1 (de) * | 1993-11-13 | 1995-05-18 | Hoechst Ag | Verfahren zur Herstellung von 1,1`-Binaphthylen |
US5399771A (en) * | 1994-06-01 | 1995-03-21 | Merck & Co., Inc. | Process of synthesizing binaphthyl derivatives |
DE4434844A1 (de) | 1994-09-29 | 1996-04-04 | Hoechst Ag | Diphosphane und Verfahren zu ihrer Herstellung |
US6333435B1 (en) | 1995-05-18 | 2001-12-25 | Merck & Co., Inc. | Process of synthesizing binaphthyl derivatives |
US5767276A (en) * | 1995-10-13 | 1998-06-16 | The Penn State Research Foundation | Asymmetric synthesis catalyzed by transition metal complexes with new chiral ligands |
US5777087A (en) * | 1996-04-18 | 1998-07-07 | Celanese International Corporation | Aryl diphosphines and catalysts containing the same |
JP3441605B2 (ja) * | 1996-10-30 | 2003-09-02 | 高砂香料工業株式会社 | 新規光学活性ジホスフィン及び該化合物より得られる遷移金属錯体及び該錯体の存在下にて光学活性体を得る方法 |
US8513468B2 (en) | 2010-12-30 | 2013-08-20 | Eastman Chemical Company | Process for removing degradation acids from hydroformylation reactions |
US10436506B2 (en) | 2015-12-22 | 2019-10-08 | Eastman Chemical Company | Supersonic separation of hydrocarbons |
EP3393622A4 (en) | 2015-12-22 | 2019-12-25 | Eastman Chemical Company | SUPERSONIC TREATMENT OF STEAM FLOW FOR SEPARATION AND DRYING OF HYDROCARBON GASES |
EP4430218A1 (en) | 2021-11-11 | 2024-09-18 | Dow Technology Investments LLC | Processes for recovering rhodium from hydroformylation processes |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1044813C2 (de) * | 1957-04-26 | 1959-05-14 | Hoechst Ag | Verfahren zur Herstellung von organischen Phosphinsäuren |
US3048638A (en) * | 1958-09-04 | 1962-08-07 | Union Carbide Corp | Vinyl phosphines |
GB877592A (en) * | 1959-03-26 | 1961-09-13 | Ici Ltd | Preparation of diphosphines |
US3239566A (en) * | 1960-07-22 | 1966-03-08 | Shell Oil Co | Hydroformylation of olefins |
US3539622A (en) * | 1966-12-23 | 1970-11-10 | Hercules Inc | Process for producing diaryl compounds |
US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
US3748350A (en) * | 1969-12-29 | 1973-07-24 | Hercules Inc | Coupling with a palladium salt |
US3636168A (en) * | 1969-12-29 | 1972-01-18 | Hercules Inc | Preparation of polynuclear aromatic compounds |
US4193943A (en) * | 1976-01-19 | 1980-03-18 | Celanese Corporation | Hydroformylation catalysts |
US4138420A (en) * | 1976-01-19 | 1979-02-06 | Celanese Corporation | Hydroformylation catalysts |
US4026957A (en) * | 1976-04-30 | 1977-05-31 | Iowa State University Research Foundation, Inc. | Symmetrical conjugated diene and polyene synthesis via vinylmercuric salts |
US4139565A (en) * | 1977-03-31 | 1979-02-13 | Celanese Corporation | Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands |
US4152344A (en) * | 1977-08-08 | 1979-05-01 | Celanese Corporation | Phosphino-ferrocene ligands |
US4169861A (en) * | 1977-08-19 | 1979-10-02 | Celanese Corporation | Hydroformylation process |
US4201728A (en) * | 1977-08-19 | 1980-05-06 | Celanese Corporation | Hydroformylation catalyst and process |
JPS54119407A (en) * | 1978-03-09 | 1979-09-17 | Agency Of Ind Science & Technol | Preparation of aldehydes |
JPS54128551A (en) * | 1978-03-25 | 1979-10-05 | Ihara Chem Ind Co Ltd | Preparation of triphenylphosphine |
US4263466A (en) * | 1978-10-30 | 1981-04-21 | Union Carbide Corporation | Coupling of aryl and heteroaryl mono chlorides |
US4221744A (en) * | 1978-12-01 | 1980-09-09 | Celanese Corporation | Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents |
US4326989A (en) * | 1979-09-11 | 1982-04-27 | Union Carbide Corporation | Catalyst of nickel compound and ligand in presence of a reducing metal |
JPS5699494A (en) * | 1980-01-10 | 1981-08-10 | Ihara Chem Ind Co Ltd | Preparation of triarylphosphine |
DK350383A (da) * | 1982-08-27 | 1984-02-28 | Hoffmann La Roche | Phosphorforbindelser |
-
1988
- 1988-01-25 US US07/148,241 patent/US5026886A/en not_active Expired - Lifetime
-
1989
- 1989-01-19 CA CA000588600A patent/CA1334204C/en not_active Expired - Lifetime
- 1989-01-19 WO PCT/US1989/000253 patent/WO1989006653A1/en active IP Right Grant
- 1989-01-19 AT AT89902144T patent/ATE84790T1/de active
- 1989-01-19 EP EP89902144A patent/EP0419485B1/en not_active Expired - Lifetime
- 1989-01-19 DE DE8989902144T patent/DE68904558T2/de not_active Expired - Lifetime
- 1989-01-19 JP JP1501996A patent/JP2968545B2/ja not_active Expired - Lifetime
- 1989-01-19 ES ES198989300485T patent/ES2038404T3/es not_active Expired - Lifetime
- 1989-01-19 KR KR1019890701753A patent/KR970011166B1/ko not_active IP Right Cessation
- 1989-01-19 EP EP89300485A patent/EP0326286B1/en not_active Expired - Lifetime
- 1989-01-25 CN CN89101417A patent/CN1023315C/zh not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0326286B1 (en) | 1993-02-10 |
EP0419485B1 (en) | 1993-01-20 |
US5026886A (en) | 1991-06-25 |
CA1334204C (en) | 1995-01-31 |
KR970011166B1 (ko) | 1997-07-08 |
JP2968545B2 (ja) | 1999-10-25 |
CN1023315C (zh) | 1993-12-29 |
DE68904558D1 (de) | 1993-03-04 |
WO1989006653A1 (en) | 1989-07-27 |
JPH03502450A (ja) | 1991-06-06 |
EP0326286A1 (en) | 1989-08-02 |
KR900700491A (ko) | 1990-08-13 |
EP0419485A1 (en) | 1991-04-03 |
DE68904558T2 (de) | 1993-08-12 |
ATE84790T1 (de) | 1993-02-15 |
CN1039239A (zh) | 1990-01-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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