ES2035464T3 - Procedimiento para la obtencion de esteres alquilicos del acido pentenoico. - Google Patents

Procedimiento para la obtencion de esteres alquilicos del acido pentenoico.

Info

Publication number
ES2035464T3
ES2035464T3 ES198989113381T ES89113381T ES2035464T3 ES 2035464 T3 ES2035464 T3 ES 2035464T3 ES 198989113381 T ES198989113381 T ES 198989113381T ES 89113381 T ES89113381 T ES 89113381T ES 2035464 T3 ES2035464 T3 ES 2035464T3
Authority
ES
Spain
Prior art keywords
catalyst
alkyl esters
hydrocarbons
butadiene
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198989113381T
Other languages
English (en)
Inventor
Robert Dr. Maerkl
Wolfgang Dr. Harder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2035464T3 publication Critical patent/ES2035464T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

EL PROCEDIMIENTO PARA PRODUCIR ESTERES ALQUILICOS DE ACIDOS PENTENICOS CONSISTE EN A) TRATAR BUTADIENO O MEZCLAS DE HIDROCARBUROS CONTENIENDO BUTADIENO CON MONOXIDO DE CARBONO Y ALCANOLES, EN PRESENCIA DE BASES NITROGENADAS HETEROCICLICAS AROMATICAS Y TERCIARIAS Y DE CATALIZADORES DE CARBOXILO Y COBALTO, A UNA TEMPERATURA ENTRE 80 Y 160 C Y A UNA PRESION ENTRE 100 Y 1000 BAR Y SE OBTIENE UNA MEZCLA DE REACCION CONTENIENDO ESTER ALQUILICO DE ACIDO PENTENICO, DIESTER CON SEIS CARBONOS, BASES NITROGENADAS TERCIARIAS, ALCANOLES, BUTADIENOS, HIDROCARBUROS Y PRODUCTO SECUNDARIO; B) DESTILAR LA MEZCLA DE REACCION OBTENIDA PARA SEPARAR ALCANOLES, BASES NITROGENADAS TERCIARIAS, HIDROCARBONOS Y ESTER ALQUILICOS DE ACIDOS PENTENICOS DE LA MEZCLA DE REACCION Y OBTENER UN RESIDUO CONTENIENDO EL CATALIZADOR DE CARBONO Y COBALTO; C) PONER EN CONTACTO EL RESIDUO CONTENIENDO EL CATALIZADOR DE CARBONILO Y COBALTO CON UNA MEZCLA DE MONOXIDO DE CARBONO E HIDROGENO, A ELEVADA TEMPERATURA Y PRESION Y D) EMPLEAR EL RESIDUO QUE CONTIENE EL CATALIZADOR ENRIQUECIDO EN LA ETAPA DE SINTESIS DEL ESTER ALQUILICO DE ACIDO PENTENICO.
ES198989113381T 1988-07-26 1989-07-21 Procedimiento para la obtencion de esteres alquilicos del acido pentenoico. Expired - Lifetime ES2035464T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3825296A DE3825296A1 (de) 1988-07-26 1988-07-26 Verfahren zur herstellung von pentensaeurealkylestern

Publications (1)

Publication Number Publication Date
ES2035464T3 true ES2035464T3 (es) 1993-04-16

Family

ID=6359537

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198989113381T Expired - Lifetime ES2035464T3 (es) 1988-07-26 1989-07-21 Procedimiento para la obtencion de esteres alquilicos del acido pentenoico.

Country Status (5)

Country Link
US (1) US4925972A (es)
EP (1) EP0352641B1 (es)
JP (1) JPH02104558A (es)
DE (2) DE3825296A1 (es)
ES (1) ES2035464T3 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0426653A (ja) * 1990-05-21 1992-01-29 Agency Of Ind Science & Technol ３―ペンテン酸エステルの製造方法
US5962680A (en) * 1997-04-15 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactams
US5886236A (en) * 1997-04-15 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing aldehyde acid salts
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
US5962732A (en) * 1998-12-17 1999-10-05 E. I. Du Pont De Nemours And Company Process for the preparation of 3-pentenoic acid from butadiene using a nickel catalyst

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3253018A (en) * 1962-12-31 1966-05-24 Exxon Research Engineering Co Decobalting aldehydic acid ester oxo reaction mixtures using oxalic acid at reflux temperatures and atmospheric pressure
JPS507579B1 (es) * 1971-06-18 1975-03-27
DE2630086C3 (de) * 1976-07-03 1981-07-23 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Pent-3-ensäure und deren Alkylestern
JPS5315309A (en) * 1976-07-28 1978-02-13 Agency Of Ind Science & Technol Continuous preparation of carboxylic acid esters
DE2837815A1 (de) * 1978-08-30 1980-03-13 Basf Ag Verfahren zur herstellung von butandicarbonsaeuredimethylestern
DE2951950A1 (de) * 1979-12-22 1981-07-09 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von formylvaleriansaeureestern
DE3023765C2 (de) * 1980-06-25 1983-05-05 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Fettsäureestern

Also Published As

Publication number Publication date
EP0352641B1 (de) 1992-09-16
US4925972A (en) 1990-05-15
DE58902282D1 (de) 1992-10-22
DE3825296A1 (de) 1990-02-01
EP0352641A1 (de) 1990-01-31
JPH02104558A (ja) 1990-04-17

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