ES457820A1 - Un procedimiento mejorado para la preparacion de esteres de oxalato de un alcohol. - Google Patents

Un procedimiento mejorado para la preparacion de esteres de oxalato de un alcohol.

Info

Publication number
ES457820A1
ES457820A1 ES457820A ES457820A ES457820A1 ES 457820 A1 ES457820 A1 ES 457820A1 ES 457820 A ES457820 A ES 457820A ES 457820 A ES457820 A ES 457820A ES 457820 A1 ES457820 A1 ES 457820A1
Authority
ES
Spain
Prior art keywords
preparation
oxalate esters
oxalate
esters
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES457820A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlantic Richfield Co
Original Assignee
Atlantic Richfield Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co
Publication of ES457820A1 publication Critical patent/ES457820A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/36—Oxalic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un procedimiento mejorado para la preparación de ésteres de oxalato de un alcohol que consiste hacer reaccionar, bajo condiciones esencialmente anhidras, un alcohol alifático, aliciclico o de aralquilo saturado monohídrico que contiene de 1 a 20 átomos de carbono con una mezcla de monóxido de carbono y oxígeno a una presión de entre aproximadamente 35,150 kilogramos por centímetro cuadrado manométrica y 210,900 kilogramos por centímetro cuadrado manométrica a una temperatura dentro de la escala de aproximadamente 40ºC a 150ºC en presencia de una cantidad efectiva de una mezcla catalítica.
ES457820A 1976-05-13 1977-04-14 Un procedimiento mejorado para la preparacion de esteres de oxalato de un alcohol. Expired ES457820A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US68583376A 1976-05-13 1976-05-13

Publications (1)

Publication Number Publication Date
ES457820A1 true ES457820A1 (es) 1978-03-01

Family

ID=24753858

Family Applications (1)

Application Number Title Priority Date Filing Date
ES457820A Expired ES457820A1 (es) 1976-05-13 1977-04-14 Un procedimiento mejorado para la preparacion de esteres de oxalato de un alcohol.

Country Status (12)

Country Link
US (1) US4076949A (es)
JP (1) JPS52139015A (es)
BE (1) BE854518A (es)
BR (1) BR7702387A (es)
DE (1) DE2721734C2 (es)
ES (1) ES457820A1 (es)
FR (1) FR2351085A1 (es)
GB (1) GB1570901A (es)
IE (1) IE45194B1 (es)
IT (1) IT1073243B (es)
MX (1) MX143512A (es)
NL (1) NL171698C (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX147442A (es) * 1977-05-09 1982-12-03 Atlantic Richfield Co Procedimiento mejorado para la preparacion de esteres de oxalato a partir de un alcohol
US4614832A (en) * 1979-12-17 1986-09-30 Chevron Research Company Dialkyl oxalates from carbon monoxide and an alcohol
US4281174A (en) * 1980-04-21 1981-07-28 Chevron Research Company Oxidative carbonylation of alcohols to produce dialkyl oxalates
JPS5867647A (ja) * 1981-10-15 1983-04-22 Ube Ind Ltd マロン酸ジエステルの製造法
US4463103A (en) * 1981-12-09 1984-07-31 E. I. Du Pont De Nemours And Company Toluic acid
US4431839A (en) * 1981-12-09 1984-02-14 E. I. Du Pont De Nemours And Company Toluic acid
US4523029A (en) * 1982-06-15 1985-06-11 Chevron Research Company Oxidative carbonylation of alcohols to produce dialkyl oxalates
US4468523A (en) * 1982-06-16 1984-08-28 Atlantic Richfield Company Synthesis of dialkyl oxalates by the heterogeneously catalyzed oxidative carbonylation of alcohols
US4454342A (en) * 1982-07-13 1984-06-12 Atlantic Richfield Company Preparation of dialkyl oxalates using a heterogeneous Pd-V-P catalyst for the oxidative carbonylation of alcohols
US4447638A (en) * 1982-08-02 1984-05-08 Atlantic Richfield Company Preparation of dialkyl oxalates by the oxidative carbonylation of alcohols with a heterogeneous Pd-V-P-Ti containing catalyst system
US4451666A (en) * 1982-08-06 1984-05-29 Atlantic Richfield Company Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst
US4447639A (en) * 1982-08-06 1984-05-08 Atlantic Richfield Company Oxidative carbonylation of alcohols to dialkyl oxalates using a heterogeneous iron promoted Pd-V-P catalyst
JPS5982233A (ja) * 1982-11-01 1984-05-12 Hitachi Ltd アンロ−ダの運転方法
CA1213607A (en) * 1982-12-15 1986-11-04 George E. Morris Process for the production of dihydrocarbyl oxalates
DE3342291A1 (de) * 1983-11-23 1985-05-30 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von oxalsaeurediestern
DE3513255A1 (de) * 1985-04-13 1986-10-23 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von oxalsaeurediestern
GB8521492D0 (en) * 1985-08-29 1985-10-02 Shell Int Research Preparation of diesters of alkanedioic acids
US5171874A (en) * 1989-08-22 1992-12-15 Quantum Chemical Corporation Process for making dihydrocarbyl carbonate
JP3058063B2 (ja) * 1995-10-18 2000-07-04 株式会社村田製作所 無電解めっきのための活性化触媒液および無電解めっき方法
CN103951559B (zh) * 2014-04-10 2015-08-12 中国科学院福建物质结构研究所 一种co气相氧化偶联生产草酸酯的安全装置和飞温控制方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3393136A (en) * 1965-09-28 1968-07-16 Union Oil Co Preparation of oxalates
US3994960A (en) * 1974-04-05 1976-11-30 Ube Industries, Ltd. Process for preparing dialkyl oxalates
US4005129A (en) * 1975-06-04 1977-01-25 Atlantic Richfield Company Process for the oxidative carbonylation of alcohols and method for the reoxidation of reduced copper salts produced by the oxidation carbonylation

Also Published As

Publication number Publication date
IE45194B1 (en) 1982-07-14
US4076949A (en) 1978-02-28
DE2721734C2 (de) 1982-07-01
BR7702387A (pt) 1978-05-09
IT1073243B (it) 1985-04-13
MX143512A (es) 1981-05-21
JPS5616139B2 (es) 1981-04-14
NL171698C (nl) 1983-05-02
FR2351085A1 (fr) 1977-12-09
NL171698B (nl) 1982-12-01
IE45194L (en) 1977-11-13
JPS52139015A (en) 1977-11-19
GB1570901A (en) 1980-07-09
BE854518A (fr) 1977-11-14
NL7701861A (nl) 1977-11-15
DE2721734A1 (de) 1977-12-01

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