ES462298A1 - Un procedimiento para la preparacion de esteres oxalicos. - Google Patents
Un procedimiento para la preparacion de esteres oxalicos.Info
- Publication number
- ES462298A1 ES462298A1 ES462298A ES462298A ES462298A1 ES 462298 A1 ES462298 A1 ES 462298A1 ES 462298 A ES462298 A ES 462298A ES 462298 A ES462298 A ES 462298A ES 462298 A1 ES462298 A1 ES 462298A1
- Authority
- ES
- Spain
- Prior art keywords
- alkoxycycloalkene
- preparation
- carbon monoxide
- oxalate esters
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 title abstract 2
- 150000003891 oxalate salts Chemical class 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- -1 amine salt compound Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000005832 oxidative carbonylation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
- C07C69/36—Oxalic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento para la preparación de ésteres oxálicos que consiste en hacer reaccionar, en condiciones sustancialmente anhidras, un alcoxicicloalqueno de fórmula: ***(ver fórmula) donde R es un grupo alquilo o aralquilo, R' es hidrógeno o un grupo alquilo lineal o ramificado y x es un número entero de 3 a 6, con monóxido de carbono, un alcohol monohídrico alifático, alicíclico o aralquílico de fórmula ROH.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/734,799 US4069388A (en) | 1976-10-22 | 1976-10-22 | Preparation of oxalate esters from carbon monoxide and an alkoxycycloalkene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES462298A1 true ES462298A1 (es) | 1978-05-16 |
Family
ID=24953118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES462298A Expired ES462298A1 (es) | 1976-10-22 | 1977-09-12 | Un procedimiento para la preparacion de esteres oxalicos. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4069388A (es) |
| JP (1) | JPS5353612A (es) |
| BE (1) | BE859919A (es) |
| CA (1) | CA1091692A (es) |
| DE (1) | DE2747363C2 (es) |
| ES (1) | ES462298A1 (es) |
| FR (1) | FR2368461A1 (es) |
| GB (1) | GB1572145A (es) |
| IT (1) | IT1091133B (es) |
| NL (1) | NL7709193A (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4379939A (en) * | 1980-04-04 | 1983-04-12 | Tennessee Valley Authority | Preparation of nitrogen fertilizers from oxalate esters prepared by the oxidative carbonylation of alcohols over noble metal catalysts utilizing regenerable 2,5-cyclohexadiene-1,4-dione oxidants |
| US4571435A (en) * | 1980-06-30 | 1986-02-18 | Tennessee Valley Authority | Preparation of nitrogen fertilizers from oxalate esters prepared by the oxidative carbonylation of alcohols over noble metal catalysts utilizing regenerable 2,5-cyclohexadiene-1,4-dione oxidants |
| FR2517298A1 (fr) * | 1981-12-01 | 1983-06-03 | Rhone Poulenc Chim Base | Procede de preparation de diesters satures lineaires |
| JPS6043308U (ja) * | 1983-09-01 | 1985-03-27 | 株式会社 中西歯科器械製作所 | バッテリ−内蔵型歯科用ハンドピ−スの接続構造 |
| JPS60138670U (ja) * | 1984-02-24 | 1985-09-13 | 有限会社 ワイテイ医科器械研究所 | 医療用ドライバ− |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3393136A (en) * | 1965-09-28 | 1968-07-16 | Union Oil Co | Preparation of oxalates |
| DE2213435A1 (de) * | 1972-03-20 | 1973-10-11 | Roehm Gmbh | Verfahren zur herstellung von oxalsaeure und estern dieser saeure |
| US3994960A (en) * | 1974-04-05 | 1976-11-30 | Ube Industries, Ltd. | Process for preparing dialkyl oxalates |
-
1976
- 1976-10-22 US US05/734,799 patent/US4069388A/en not_active Expired - Lifetime
-
1977
- 1977-08-09 CA CA284,359A patent/CA1091692A/en not_active Expired
- 1977-08-19 NL NL7709193A patent/NL7709193A/xx not_active Application Discontinuation
- 1977-09-09 JP JP10868877A patent/JPS5353612A/ja active Granted
- 1977-09-09 IT IT50939/77A patent/IT1091133B/it active
- 1977-09-12 ES ES462298A patent/ES462298A1/es not_active Expired
- 1977-10-19 FR FR7731436A patent/FR2368461A1/fr active Pending
- 1977-10-19 BE BE181901A patent/BE859919A/xx unknown
- 1977-10-21 DE DE2747363A patent/DE2747363C2/de not_active Expired
- 1977-10-21 GB GB43963/77A patent/GB1572145A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2368461A1 (fr) | 1978-05-19 |
| US4069388A (en) | 1978-01-17 |
| JPS5353612A (en) | 1978-05-16 |
| GB1572145A (en) | 1980-07-23 |
| DE2747363C2 (de) | 1982-09-23 |
| IT1091133B (it) | 1985-06-26 |
| CA1091692A (en) | 1980-12-16 |
| BE859919A (fr) | 1978-04-19 |
| JPS575209B2 (es) | 1982-01-29 |
| DE2747363A1 (de) | 1978-04-27 |
| NL7709193A (nl) | 1978-04-25 |
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