Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
  • B01J20/3206—Organic carriers, supports or substrates
  • B01J20/3208—Polymeric carriers, supports or substrates
  • B01J20/321—Polymeric carriers, supports or substrates consisting of a polymer obtained by reactions involving only carbon to carbon unsaturated bonds
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F1/00—Treatment of water, waste water, or sewage
  • C02F1/28—Treatment of water, waste water, or sewage by sorption
  • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
  • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
  • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
  • B01J20/3204—Inorganic carriers, supports or substrates
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
  • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
  • B01J20/3268—Macromolecular compounds
  • B01J20/327—Polymers obtained by reactions involving only carbon to carbon unsaturated bonds
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
  • B01J20/30—Processes for preparing, regenerating, or reactivating
  • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
  • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
  • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
  • B01J20/3268—Macromolecular compounds
  • B01J20/328—Polymers on the carrier being further modified
  • B01J20/3282—Crosslinked polymers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
  • B01J41/04—Processes using organic exchangers
  • B01J41/07—Processes using organic exchangers in the weakly basic form
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
  • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
  • B01J41/12—Macromolecular compounds
  • B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J47/00—Ion-exchange processes in general; Apparatus therefor
  • B01J47/016—Modification or after-treatment of ion-exchangers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J2220/00—Aspects relating to sorbent materials
  • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
  • B01J2220/62—In a cartridge
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F2303/00—Specific treatment goals
  • C02F2303/04—Disinfection

Definitions

• the present invention relates to a method for producing antiviral particles and the particles themselves, which can be produced using the method according to the invention.
• the ones according to the invention are identical to the ones according to the invention.
• Particles are used to remove viruses from water, but also to
• the present invention also relates to a filter cartridge containing particles according to the invention.
• Membrane filtration only gives low yields, since a large part of the water is lost during the process.
• This hot water tank must always be above a certain level
• Heavy metal ions from drinking water is also important in this context.
• WO 2017/089523 and WO 2016/030021 disclose a sorbent for
• the object was achieved by a method for producing antiviral particles comprising the steps:
• Carrier material or the organic carrier material with the polyamine are Carrier material or the organic carrier material with the polyamine
• Steps (a) and (b) can be repeated at least once. This can be important when a high concentration of amino groups is required, for example a concentration of more than 600 ⁇ mol/g. Surprisingly, it was found that, on the one hand, this process enables a less complex production method for the
• Sorbent can be provided compared to the prior art. In addition, the sorbent thus prepared does not tend to
• biofilms shows a very high biocidal effect against bacteria and germs and, due to the protonation, also a very high effectiveness against viruses.
• the increased effectiveness against viruses due to the protonation was surprising.
• the effect against bacteria and germs could also be increased.
• the coating and the crosslinking preferably take place in a stirred reactor, for example a Lödige
• step (b) is increased in contrast to the coating from step (a).
• a temperature of less than or equal to 10° C. is preferably selected in step (a). It comes in step (b) almost predominantly to a crosslinking in the
• step (a) and consequently step (b) can be repeated in the same apparatus.
• Steps (a) and (b) can be repeated until the desired degree of coating and density of amino groups is achieved. Preference is given to coating only once. However, it is also possible to coat and crosslink at least twice, but it is also possible to coat and crosslink three times, four times or more. Most preferred is once.
• Step (c) Raise and hold the temperature to about 60°C for about 1 hour.
• the sorbent is post-crosslinked before step (c). This is preferably done with epichlorohydrin and
• step (c) there is a protonation of the amino groups of the
• the polyamine is used in the non-desalinated state.
• the polyvinylformamide which can be obtained by polymerization, with sodium hydroxide solution and the subsequent blunting with hydrochloric acid, common salt and
• the polymer solution is desalinated by
• Membrane filtration where the polymer is retained while the salts permeate through the membrane layer. The membrane filtration is continued until the salinity has been determined according to
• incineration residue corresponds to less than 1% of the weight (1% of the polymer content).
• step (a) forms directly in the pores of the
• the carrier slowly forms a hydrogel and the polymer is directly immobilized.
• the salts formed during hydrolysis can simply be washed out with water.
• Consequence of the pre-crosslinking during the coating for example or preferably with epichlorohydrin and diaminoethylene, in aqueous
• epichlorohydrin also has the advantage that unreacted epichlorohydrin is simply hydrolyzed with the sodium hydroxide solution and thus rendered harmless or converted into harmless substances (glycerol).
• the organic carrier material is preferably a polystyrene, a sulfonated polystyrene, a polymethacrylate or a strong or weak ion exchanger.
• Carrier polymer a strong or a weak cation exchanger coated with the polymer only on its outer surface.
• a strong cation exchanger such organic
• Cation exchangers are polymers that have carboxylic acid groups.
• silica gel particles (as template) with non-desalinated polymer and subsequent dissolution of the inorganic support and its antibacterial activity.
• Polystyrenes usually tend to form a pronounced biofilm and in no way remove viruses or bacteria. Furthermore, unlike the carriers used up to now, polystyrene is markedly lipophilic, and thus has completely different properties than the carriers used up to now.
• Polystyrene-based resins is achieved by dispensing with the desalination of the polymer hydrolyzate and other process changes, in particular the addition and drying of the
• the polymer content is now calculated by the approach at the
• Polyvinylamine polymer solution that does not contain salts.
• the salts contained are then partially dissolved out during the preparation of the suspension for post-crosslinking. After the silica gel of
• BacCap® T or MetCap® T material has the same Properties as the absorber resins made by the desalted PVA polymer process. This is the first
• the second method involves coating commercial strong or weak ion exchangers with an antiviral as well as antibacterial PVA polymer shell.
• Cation exchangers usually have acid groups that are covalently bonded to the polymer carrier (e.g. polystyrene, acrylates, etc.).
• the acid groups are carboxylic acids or carboxylates in the case of weak ion exchangers or sulfonic acids or sulfonates in the case of strong ion exchangers.
• Capacity-bearing acid groups is to modify.
• non-desalinated polymer of the appropriate size can also be used for this, but this is not a mandatory requirement.
• Coating with desalted polymer is also possible, as is the use of non-desalted polymer.
• the polymer After hydrolysis of the amide groups, the polymer contains
• the polymer content of the aqueous solution corresponds to 9-13% by weight.
• the salts were removed by reverse osmosis, which was a laborious process, and the polymer used had a salt content of less than 2.5% by weight.
• the new process allows this time-consuming and expensive desalination step to be dispensed with. It is therefore preferred with the new method, the polymer partially desalinated with a
• the inorganic support material in particulate form is a macroporous, meso-porous or non-porous support material, preferably a mesoporous or macroporous support material.
• the mean pore size of the porous support material is preferably in the range of 6 nm to 400 nm, more preferably in the range of 8 to 300 nm and most preferably in the range of 10 to 150 nm. For industrial applications there is also a
• Particle size range from 100 to 3000 nm preferred. Furthermore, it is preferred that the porous support material has a pore volume in Range from 30% to 90% by volume, more preferably from 40 to 80%
• Carrier material can be determined using the pore-filling method with mercury in accordance with DIN 66133.
• Carrier material is not porous, which means its pore size is in the
• the porous inorganic material is preferably one that is soluble in aqueous alkaline conditions at pH greater than 10, more preferably pH greater than 11, and most preferably pH greater than 12.
• the preferably porous inorganic carrier material is dissolved out at a pH>10. This enables the creation of a porous hydrogel, which
• Carrier material preferably takes place before step (c), the protonation.
• the step of dissolving out the inorganic support material takes place in the aqueous-alkaline ones mentioned, with the porous particles being obtained from a crosslinked polymer
• the porous inorganic material is preferably one based on or consists of silicon dioxide or silica gel.
• the step of dissolving the inorganic carrier material to obtain the porous particles from a crosslinked polymer is preferably carried out in an aqueous alkaline solution with a pH greater than 10, more preferably pH greater than 11, even more preferably pH greater than 12 Base preferably an alkali hydroxide, more preferred
• step (c) of the process according to the invention the particles obtained from step (b) are treated with the corresponding aqueous alkaline solution for several
• Polymer for example, as a binding material for metals, which consists only of organic material and is therefore subject to whereabouts or
• Recovery of the metals can be burned completely or residue-free.
• the porous inorganic carrier material is preferably a particulate material with an average particle size in
• the shape of the particles can be spherical
• the proportion of polyamine used in step (a) is one
• Carrier material without polyamine without polyamine
• the polyamine can be applied to the support material in particle form in step (a) of the process according to the invention by various processes, such as impregnation processes or by the pore-filling method, with the pore-filling method being preferred.
• the pore filling method brings compared to conventional Impregnation process has the advantage that a larger total
• Amount of dissolved polymer can be applied to the porous inorganic support material in one step, whereby the
• the polymer In all conceivable methods in step (a), the polymer must be dissolved in a solvent.
• the solvent used for the polymer applied in step (a) is preferably one in which the polymer is soluble.
• the concentration of the polymer for application to the porous inorganic support material is preferably in the range from 5 g/L to 200 g/L, more preferably in the range from 10 g/L to 180 g/L, most preferably in the range from 30 to 160g/L.
• Carrier material are determined. Likewise, the relative dimensions of the Carrier material are determined. Likewise, the relative dimensions of the Carrier material are determined. Likewise, the relative amounts of the relative materials.
• pore volume [% by volume] can be determined. This is the volume of the freely accessible pores of the
• Solvent absorption capacity can be determined.
• Solvent absorption capacity indicates the volume of a
• Solvent is required to completely fill the pore space of one gram of dry sorbent (preferably stationary phase). Both pure water or aqueous media and organic solvents with a high
• CTE is an accurately weighed quantity of the porous inorganic
• Carrier material moistened with an excess of well-wetting solvent and excess solvent from the Interstitial volume removed in a centrifuge by rotation.
• Solvent remains within the pores of the sorbent due to the
• Solvent is determined by weighing and the density of the
• step (b) the solvent is removed by drying the material at temperatures in the range 40°C to 100°C, more preferably in the range 50°C to 90°C and most preferably in the range 50°C removed up to 75°C.
• drying is carried out in particular at a pressure in the range from 0.01 to 1 bar, more preferably at a pressure in the range from 0.01 to 0.5 bar.
• Step (b) of the process according to the invention is preferably carried out in such a way that the degree of crosslinking of the polyamine is at least 10%, based on the total number of crosslinkable groups of the polyamine.
• the degree of crosslinking can be adjusted according to the desired amount
• crosslinking agent 100 mole percent of the crosslinking agent reacts and forms crosslinks.
• Crosslinking agent are verified in relation to the amount of polymer used. This method is preferable in the present invention. However, the degree of cross-linking can also be
• Spectroscopy related to e.g. C-O-C or OH vibrations can be determined using a calibration curve.
• the maximum degree of crosslinking is preferably at
• the degree of crosslinking is above the specified upper limit, the polyamine coating is not sufficiently flexible. If the degree of crosslinking is below the specified lower limit, the resulting porous particles of the crosslinked polyamine are not rigid enough, for example as particles of a to be used in the chromatographic phase or in a water purification cartridge, in which sometimes higher pressures are applied. If the resulting porous particles of the crosslinked polyamine are used directly as a material for an antibacterial or antiviral absorbent resin, the
• Degree of crosslinking of the polyamine preferably at least 20%.
• the crosslinking agent used for the crosslinking preferably has two, three or more functional groups, the crosslinking being effected by their binding to the polyamine.
• Crosslinking agent used to crosslink the polyamine applied in step (b) is preferably selected from
• Group selected consisting of dicarboxylic acids, tricarboxylic acids,
• Halogen epoxides with dicarboxylic acids, bis-epoxides and
• Halogen epoxides are preferred, such as terephthalic acid,
• Biphenyldicarboxylic acid ethylene glycol diglycidyl ether (EGDGE), 1,12-bis(5-norbornene-2,3-dicarboximido)decanedioic acid and
• the crosslinking agent is in a
• Embodiment of the present invention preferably a linear, molecule with a length between 3 and 20 atoms.
• the polyamine used in step (a) preferably has a
• Repeat unit means the smallest unit of a
• Polyamines are preferably polymers that have primary and/or secondary amino groups. It can a
• polyamines examples are the following: Polyamines, such as any
• Polyalkylamines eg polyvinylamine, polyalkylamine, polyethyleneimine and polylysine, etc.
• polyalkylamines eg polyvinylamine, polyalkylamine, polyethyleneimine and polylysine, etc.
• polyalkylamines more preferably polyvinylamine and polyallylamine, wherein
• Polyvinylamine is particularly preferred.
• the preferred molecular weight of the polyamine used in step (a) of the process according to the invention is preferably in the range from 5,000 to 50,000 g/mol, which applies in particular to the polyvinylamine specified.
• an organic radical is preferably bound to the polymer.
• This radical can be any conceivable radical, such as an aliphatic and aromatic group, which can also have heteroatoms. These groups can also be substituted with anionic or cationic radicals or radicals that can be protonated or deprotonated.
• the group with which the side groups of the polymer are derivatized is one
• organic radical which has the property of a Lewis base is understood to mean, in particular, radicals which enter into a complex bond with the metal to be bonded.
• Organic radicals which have a Lewis base are, for example, those which have free heteroatoms
• Electron pairs such as N, O, P, As or S have.
• Preferred organic residues for the derivatization of the polymer are the ligands shown below:
• ligands PVA i.e. the amino group of the PVA, EtSr, NTA, EtSH, MeSH, EDTA and iNic or combinations of the above.
• PVA i.e. the amino group of the PVA, EtSr, NTA, EtSH, MeSH, EDTA and iNic or combinations of the above.
• EtSr, NTA or EtSH i.e. the amino group of the PVA, EtSr, NTA, EtSH, MeSH, EDTA and iNic or combinations of the above.
• Polyvinylamine itself represent Lewis bases and also by their
• the present invention also relates to crosslinked polymer antiviral particles obtainable or produced by the above process of the invention. It is preferred that the particles produced by the process according to the invention have a maximum swelling factor in water of 300
• the particles according to the invention can increase by a maximum of three times in water
• a further subject of the present application are also antiviral particles made from a crosslinked polyamine, these
• Particles have a maximum swelling factor of 300%, assuming that the percentage of dry particles is 100%.
• Process produced antiviral particles or the antiviral particles according to the invention have a maximum swelling factor in water of 250%, even more preferably 200% and most preferably less than 150%, since otherwise the
• (antiviral and antibacterial) particles are preferably made of a crosslinked polyamine.
• the polyamine or the porous particles consisting of it preferably have a concentration of the amino groups, determined by titration, of at least 300 ⁇ mol/mL, more preferably at least 600 ⁇ mol/mL, and even more preferably of at least 1000 ⁇ mol/mL. under the through
• the particles produced according to the invention preferably have a dry bulk density in the range from 0.25 g/mL to 0.8 g/mL, even more preferably from 0.3 g/mL to 0.7 g/mL.
• the porous particles are extremely light particles overall, which is ensured by the high porosity obtained.
• the average pore size of the particles produced according to the invention or according to the invention, determined by inverse size exclusion chromatography, is preferably in the range from 1 nm to 100 nm, more preferably 2 nm to 80 nm.
• the antiviral particles produced according to the invention are preferably particles which have a shape similar to that of the dissolved porous inorganic
• Carrier material had, but with the proviso that the particles according to the invention essentially with their material
• Step (b) of the method according to the invention the inverse pore image of the porous inorganic support material used.
• the porous particles according to the invention are preferably in an im
• Substantially spherical shape is preferably in the range from 5 ⁇ m to 1000 ⁇ m, more preferably in the range from 100 to 500 ⁇ m.
• the particles according to the invention are made of the crosslinked
• Polymer according to one embodiment characterized in that they consist essentially of the crosslinked polymer. "In the
• Residues of, for example, inorganic carrier material which may still contain porous particles, but the proportion of which is preferably below 2000 ppm, even more preferably 1000 ppm and most preferably 500 ppm.
• the porous particles of the crosslinked polymer of the present invention are substantially free of an inorganic Material, such as the material of the inorganic
• Carrier material are. This is also meant above in connection with step (c) of the method according to the invention, when it is said that the inorganic carrier material in
• the particles according to the invention or the particles produced according to the invention are preferably
• the material according to the invention can, for example, be used in a simple manner in a stirred tank or in a "fluidized bed” application, in which the material is simply added to a biologically contaminated and metal-containing solution and stirred for a certain time.
• the present invention also relates to a filter cartridge, for example for the treatment of drinking water, which contains particles according to the invention.
• the filter cartridge is preferably shaped in such a way that the drinking water to be treated can pass through the cartridge and comes into contact with the particles according to the invention in its interior, with biological
• the filter cartridge can have an additional material for removing
• micropollutants Activated carbon is preferably used for this.
• Zones can be arranged within the filter cartridge, or in one
• the filter cartridge can also contain several different materials (with and without derivatization) which have been produced using the method according to the invention.
• the filter cartridge can be designed in all conceivable sizes.
• the filter cartridge can be designed in a size that is suitable for daily drinking water needs in one
• the filter cartridge can also be of a size that allows the drinking water requirement for several people
• the filter cartridge can, for example, have the shape of a cylinder with linear flow or the shape of a radial flow
• the ion exchanger is then dried at 80° C. for 60 minutes.
• the dried ion exchanger is weighed
• Product temperature in the dryer is set to 10°C.
• the ion exchanger is at a
• Vacuum Paddle Dryer VT 5 filled.
• the jacket temperature is set to 4
• Polyvinylamine solution (polymer content 10%) Solder: PC 18007 and 227 g of deionized water are weighed out in a vessel. 9.20 g of ethylene glycol diglycidyl ether (EGDGE) [2224-15-9] as crosslinking agent are weighed out in another vessel. The crosslinker becomes the
• the mixture is pumped into the Lödige mixer within 5 minutes using a peristaltic pump.
• the speed of the mixer is set to 240 rpm and the jacket temperature is left at 4°C.
• Product temperature in the dryer is set to 10 °C.
• Polymer adsorbate 750 g carrier material silica gel (AGC Si-Tech Co. M.S
• Product temperature is set to 10°C.
• the mixer comes with
• Ethylene glycol diglycidyl ether (EGDGE) CAS no. [2224-15-9] offset. The mixture is added to the mixer within 10 minutes and mixed for 1 hour at 10°C. Then it will be Ethylene glycol diglycidyl ether (EGDGE) CAS no. [2224-15-9] offset. The mixture is added to the mixer within 10 minutes and mixed for 1 hour at 10°C. Then it will be Ethylene glycol diglycidyl ether (EGDGE) CAS no. [2224-15-9] offset. The mixture is added to the mixer within 10 minutes and mixed for 1 hour at 10°C. Then it will
• Ethylene glycol diglycidyl ether (EGDGE) CAS no. [2224-15-9] offset.
• the polymer solution was within 5 min in the
• the polymer adsorbate was mixed for 30 min at 10°C. The temperature in the Lödige mixer was then increased again to 65° C. for 1 hour. The polymer adsorbate was mixed with 3 L VE
• This suspension is used for crosslinking.
• the coated silica gel suspended in water is placed in a 101
• Template particles are then transferred to a suitable suction filter and washed with the following solvents: 3 BV 0.1 M NaOH, 3 BV
• the product is obtained as a wet filter cake.
• FIG. 1 There are no viruses in the effluent over the entire investigation area verifiable. That means that the viruses in drinking water are relevant
• Resins from Example 6 is filled, passed and filtered. After
• Viruses are no longer detectable after passing through the resin bed.
• the use of the antiviral particles according to the invention thus allows the removal of viruses from drinking water by a simple

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Analytical Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Water Supply & Treatment (AREA)
• Environmental & Geological Engineering (AREA)
• Engineering & Computer Science (AREA)
• Hydrology & Water Resources (AREA)
• Life Sciences & Earth Sciences (AREA)
• Solid-Sorbent Or Filter-Aiding Compositions (AREA)
• Filtering Materials (AREA)
• Medicines Containing Material From Animals Or Micro-Organisms (AREA)

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• 2021
  • 2021-08-05 DE DE102021120424.0A patent/DE102021120424A1/de active Pending
• 2022
  • 2022-08-04 CA CA3226266A patent/CA3226266A1/en active Pending
  • 2022-08-04 KR KR1020247006015A patent/KR20240034247A/ko unknown
  • 2022-08-04 AU AU2022321810A patent/AU2022321810A1/en active Pending
  • 2022-08-04 WO PCT/EP2022/071890 patent/WO2023012251A1/de active Application Filing
  • 2022-08-04 CN CN202280060178.8A patent/CN117916013A/zh active Pending
  • 2022-08-04 EP EP22761979.8A patent/EP4380725A1/de active Pending

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