EP3990287A1 - Procédé pour fabriquer au moins un matériau de support pourvu d'un décor imprimé - Google Patents

Procédé pour fabriquer au moins un matériau de support pourvu d'un décor imprimé

Info

Publication number
EP3990287A1
EP3990287A1 EP20735276.6A EP20735276A EP3990287A1 EP 3990287 A1 EP3990287 A1 EP 3990287A1 EP 20735276 A EP20735276 A EP 20735276A EP 3990287 A1 EP3990287 A1 EP 3990287A1
Authority
EP
European Patent Office
Prior art keywords
pigment
resin
layer
ink
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20735276.6A
Other languages
German (de)
English (en)
Inventor
Frank Oldorff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Flooring Technologies Ltd
Original Assignee
Flooring Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flooring Technologies Ltd filed Critical Flooring Technologies Ltd
Publication of EP3990287A1 publication Critical patent/EP3990287A1/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/322—Pigment inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/40—Ink-sets specially adapted for multi-colour inkjet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0023—Digital printing methods characterised by the inks used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock

Definitions

  • the present invention relates to a method for producing a carrier material provided with a printed decoration, in particular a printed paper or a printed material plate.
  • Carrier materials provided with a decoration e.g. Wood-based panels are typically used as flooring elements or to cover walls and ceilings.
  • the wood-based panels used as carrier materials were mostly coated with a decorative paper in the past, whereby there were no limits to the variety of decorative papers with different patterns.
  • the printing techniques mainly used here are gravure printing and digital printing.
  • the intaglio printing process is a printing technique in which the elements to be imaged are present as depressions in a printing form that is colored before printing.
  • the printing ink is primarily located in the depressions and is applied to the object to be printed on, such as e.g. transferred to a carrier material.
  • digital printing on the other hand, the print image is transferred directly from a computer to a printing machine such as transferred to a laser printer or an inkjet printer. There is no need to use a static printing form.
  • CMYK color model
  • CMYK subtractive color model
  • CMYK the three color components cyan, magenta, yellow (yellow) and the black component key as color depth.
  • CMYK the three color components cyan, magenta, yellow (yellow) and the black component key as color depth.
  • CMYK color space is a compromise, which means that certain colors either cannot be generated at all or that additional colors must then be used. This problem arises particularly when reproducing wood decors in the furniture or laminate flooring industry, where different shades of brown have to be produced.
  • the technical problem underlying the invention was therefore to provide a method for producing decorative prints on different carrier materials with the same quality or comparable quality perception while avoiding metamerism, whereby a good reproduction of warm-looking wood decors is guaranteed on all carrier materials.
  • a method for producing at least one carrier material provided with a printed decoration is provided, the printed decoration being digitally printed e.g. is applied to the at least one carrier material in an inkjet printing process.
  • the ink used for digital printing is a water-soluble CRYK ink which contains at least one cyan pigment, at least one red pigment from the group of quinacridone pigments, the yellow pigment PY181 and at least one black carbon pigment.
  • the present process accordingly uses an ink in which the magenta commonly used in inkjet inks has been replaced by a red color pigment.
  • this ink it is now possible to provide decorations on different carrier materials which are shifted in the color space in the direction of orange-red.
  • the use according to the invention of the color pigments PY181 and PR207 enables the color space to be shifted while increasing the orange-red color component.
  • a color space for gravure printing with PY181 and PR207 has been adapted for warmer wood decors in analogue printing and gravure printing. It should be noted that at least 5 basic colors are usually used in the analog printing process, while digital printing is limited to 4 basic colors. Surprisingly, with the present ink it was possible to transfer this larger color space from analog printing to digital printing without changes occurring that would have led to undesirable metamerism effects.
  • CRYK ink set avoids metameric effects for different carrier materials, in particular the same pigments can be used in the gravure printing process, so that both digital printing and gravure printing processes can be used while avoiding metamerism.
  • white primed wood-based panels and, on the other hand, white primed papers can be used as carrier materials. If the same decor with color sets with the pigments mentioned is printed on both carrier materials, metamerism is largely avoided.
  • Metamerism means that because of the use of different color pigments under different types of light, prints sometimes look the same in color, sometimes different in color. This results from the different reflection and transmission curves of the pigments.
  • the use of a CRYK ink set now avoids these effects for different carrier materials; in particular, the same pigments can be used in the gravure printing process, so that both digital printing and gravure printing processes can be used while avoiding metamerism.
  • EP 2 865 528 B1 the use of a CRYK ink is used for printing on a paper substrate. In addition to a cyan pigment and a carbon black pigment, this CRYK ink contains the red pigment PR 254 and the yellow pigment PY151.
  • the red pigment PR254 belongs to the class of the diketopyrrolopyrrole pigments and is described with a yellowish-red color. PR254 is preferred for use in automotive coatings.
  • the yellow pigment PY151 is a benzimidazolone pigment.
  • the red pigment used in the present process is based on a quinacridone pigment. These belong to a group of organic pigments that are derived from the basic structure of the quinacridone. They have very good weather resistance, high color strength and high chemical resistance.
  • the red pigment used is preferably selected from the group comprising 2,9-dimethylquinacridone (Pigment Red 122), 2,9-dichloroquinacridone (Pigment Red 202), mixed crystal of quinacridone and 4, 11-dichloroquinacridone (Pigment Red 207) and 3 , 10-dichloroquinacridone (Pigment red 209).
  • a mixed crystal is to be understood as a solid solution that differs from a purely physical mixture of the individual components. In a solid solution e.g. the molecules of one component are incorporated into the crystal lattice of the other component. PR207 is described with a yellowish-red color.
  • the yellow pigment PY181 used in the present process is - like PY151 - a benzimidazolone azo pigment, but has different substituents.
  • PY181 contains an amidobenzene side chain as the R4 substituent, while PY151 only at the same position has a hydrogen.
  • PY181 has good acid and base stability as well as solvent stability and is easily dispersible.
  • the at least one cyan pigment is a copper phthalocyanine pigment, preferably C.I. Pigment Blue 15: 3 or C.I. Pigment Blue 15: 4, particularly preferably C.I. Pigment Blue is 15: 3.
  • the black carbon pigment is a soot pigment, in particular selected from the group of Regal TM 400R, Mogul TM, L, Elftex TM 320 from Cabot Co., or Carbon Black FW18, Special Black TM 250, Special Black TM 350, Special Black TM 550, Printex TM 25, Printex TM 35, Printex TM 55, Printex TM 90, Printex TM 150T from DEGUSSA Co., MA8 from MITSUBISHI CHEMICAL Co., and Cl Pigment Black 7 and C.I. Pigment Black 1 1.
  • the pigment concentration in the ink used in the present case, in particular with respect to the red and yellow pigment, is more than 2% by weight, preferably between 2.2 and 6% by weight, particularly preferably between 2.5 and 5% by weight, based on based on the total weight of the ink.
  • the ink used in the present case is an aqueous ink.
  • the water content in the ink is at least 50%, preferably more than 50%, particularly preferably at least 55%. e.g. at 51%, 52% or 53%.
  • the ink used in the present case also has a solvent content.
  • the ink contains at least one organic solvent with a proportion of less than 45%, preferably less than 43%; e.g. 41%, 42%.
  • the organic solvent holds the ink, especially in combination with other additives such as Dispersing aids, in a workable consistency.
  • Glycol or other alcohols such as ethanol can be used as organic solvent.
  • the ink used in the present case can contain further additives such as biocides, humectants, acids / bases to adjust the pH value, surfactants as surface-active substances.
  • humectants inter alia 2-pyrrolidone, glycerol and 1,2-hexanediol can be contained in an amount between 0.1 and 25% by weight, based on the total weight of the aqueous inkjet ink.
  • various carrier materials can be printed with the present method.
  • the at least one carrier material to be printed is at least one raw paper.
  • base papers are to be understood as those papers which were neither exposed to sizing in the mass nor to impregnation of the surface with a resin or glue.
  • Raw papers essentially consist of cellulose, pigments and fillers and common additives. Softwood pulp, hardwood pulp, or mixtures of both types of pulp can be used to produce base papers, such as decorative papers.
  • Inorganic color pigments such as metal oxides, metal hydroxides and metal oxide hydrates, metal sulfides, metal sulfates, metal chromates and metal molybdates as well as organic color pigments and / or dyes such as carbonyl colorants, cyanine colorants and others can be used to color the base papers.
  • the raw paper to be printed in the present case is at least one paper web without impregnation with at least one ink-receiving layer.
  • the ink-receiving layer is preferably a hydrophilic coating which contains water-soluble or water-dispersible polymers or binders as well as inorganic pigments.
  • Polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, starch, gelatin, carboxymethyl cellulose, ethylene / vinyl acetate, styrene / acrylic acid ester copolymers or mixtures thereof can be used as binders.
  • Inorganic white pigments such as silicates, kaolin, calcium carbonate, aluminum hydroxide, talc, titanium dioxide or colored pigments such as iron oxide, carbon black, or organic colored pigments can be contained in the ink-absorbing layer.
  • the ratio of pigment to binder in the ink-absorbing layer is between 1: 0.05-1: 1 based on the solids content.
  • the ink-receiving layer contains silicates, aluminum oxides, aluminum hydroxides or aluminum silicates and, as a water-soluble polymeric binder, polyvinyl alcohol.
  • the weight per unit area of the ink-absorbing layer can be between 0.5-20 g / m 2 .
  • the at least one carrier material to be printed is at least one pretreated, impregnated paper.
  • a pretreated paper or cellulose layer
  • the paper can be impregnated with a wide variety of resin solutions, for example melamine resins and urea resins, plastic-acrylate compounds or starch glue. It is also possible to impregnate the paper using resin powder. The use of resin powder is described in detail below.
  • an impregnated paper which is provided with the following process steps (see also EP 2 980 313 A1): a) complete impregnation of the cellulose layer with a hardenable resin, e.g. Melamine-formaldehyde resin), b) removing the excess resin that forms on the surface (e.g. by peeling off or doctoring), c) drying the soaked cellulose layer in such a way that after the water has evaporated from the resin, the cellulose fiber on the surface from which the Resin was removed, at least partially exposed.
  • a hardenable resin e.g. Melamine-formaldehyde resin
  • removing the excess resin that forms on the surface e.g. by peeling off or doctoring
  • drying the soaked cellulose layer in such a way that after the water has evaporated from the resin, the cellulose fiber on the surface from which the Resin was removed, at least partially exposed.
  • the resin remaining on the surface of the cellulose layer is sealed with the fiber tips by peeling or doctoring. During the drying process, the resin is drawn back into the fibers so that the fibers are soaked in the resin but not enclosed by the resin.
  • Such a surface is suitable for printing with aqueous digital printing inks.
  • the special device used for peeling or doctoring works similar to a spatula machine in which one or more rollers run backwards on the paper and absorb the excess resin.
  • the amount can be precisely controlled and repeatability guaranteed by the different speeds of the rollers.
  • the treated paper (base paper with or without an ink-absorbing layer, impregnated paper) can also be provided with a primer material.
  • a water-based synthetic resin or acrylate resin dispersion which is completely miscible with water or partially soluble in water can be used as the primer material.
  • the primer material should have a low solvent content of less than 3%.
  • the printed decoration is applied to the carrier material in direct printing by means of a digital printing process using the CRYK ink described above. With digital printing, the print image is transferred directly from a computer to a printing machine, such as an inkjet printer.
  • the decor data is translated into machine data by software (e.g. RIP software from the manufacturer Colorgate).
  • the printed papers can be provided with a resin layer as a protective layer after printing.
  • This protective layer can consist of a resin that has not yet fully cured, preferably a formaldehyde-containing resin, particularly preferably melamine-formaldehyde resin, urea-formaldehyde resin and / or melamine-urea-formaldehyde resin, or a radiation-curable acrylate, preferably polyester acrylate, Polyether acrylates, urethane acrylate, hexanediol diacrylate or mixtures thereof exist.
  • This protective layer serves to protect the printed decorations and enables temporary storage.
  • the applied protective layer should not yet be fully cured, which is controlled in particular by the drying process.
  • the resins used for the impregnation of paper layers go through various polymerization and crosslinking states in these processes.
  • these melamine-formaldehyde monomers are subject to polycondensation, with the monomers being linked via ether and methylene groups and the formation of higher molecular weight precondensates and polycondensates (see scheme II).
  • Precondensates and polycondensates differ in terms of their molar mass and their solubility.
  • the low molecular weight precondensates can still have a limited solubility in water, while the higher molecular weight polycondensates are insoluble.
  • the limited water solubility of the precondensates is due, among other things, to the methylol groups that are still free and the low degree of crosslinking of the mostly still linear oligomers.
  • the precondensates are thus an intermediate polymerisation product. When the polycondensates harden completely, there is strong crosslinking with elimination of the methylol groups still present, with closely crosslinked plastics being formed via methylene groups (see scheme III).
  • A-state easily soluble in solvent, meltable, curable
  • impregnated paper layers for finishing wood-based panels, e.g. For floor panels of higher quality, it is desirable that the impregnation resin is not yet fully cured, but is preferably still in the partially crosslinked B-state. This enables flowing / filming in combination with further cross-linking of the synthetic resins during further processing in the press. Accordingly, the presently impregnated and printed papers are preferably dried to condition B.
  • the printed and, if necessary, coated or impregnated paper can then be pressed with a material plate, at least one protective paper (overlay) and, if necessary, a backing paper.
  • the at least one carrier material to be printed is at least one material board, in particular a wood-based board, such as MDF and HDF boards made of wood fibers, chipboard made of chips, OSB made of wood strands, the wood fibers, wood chips and wood strands each being mixed with suitable adhesives hot-pressed), WPC panels, plastic panels, e.g. SPC (stone plastic composite) or a cement fiber panel.
  • suitable for direct printing are, for example, carrier materials such as Wood-based materials, wood-based material-plastic mixtures, WPC, plastics or mixtures of different plastics, for example PE, PP, PVC, PU, all also with fillers such as chalk, talc or fibers.
  • the surface of the material plate can be pretreated before printing to improve the adhesion of the subsequent layers. This can be cleaning with brushes, a bevel that also removes unevenness from the surface, and / or a plasma or corona treatment.
  • an unsanded wood-based panel in particular MDF or HDF, can also be used, which is also provided with a pressed skin (rotting layer) on the upper side.
  • Aqueous melamine resin is applied to the top to fill the pressed skin.
  • the melamine resin is later melted in the short-cycle press and thus has a compensatory effect in the area of this layer; i.e. it counteracts delamination.
  • At least one primer is applied in a next step to increase the covering power.
  • the primer preferably comprises casein, corn starch or soy protein and can contain inorganic color pigments and thus serve as a primer layer for the decorative layer to be subsequently printed on.
  • White pigments such as titanium dioxide T1O2 can again be used as color pigments.
  • Further color pigments can be calcium carbonate, barium sulfate or barium carbonate, but also iron oxide pigments (for a brownish primer).
  • the primer can also contain water as a solvent.
  • the amount of liquid primer applied can be between 10 and 50 g / m 2 , preferably between 15 and 30 g / m 2 , particularly preferably between 20 and 25 g / m 2 .
  • the primer consists of at least one, preferably of at least two or more successively applied layers or orders (for example up to five orders), the amount applied between the layers or orders is the same or different, ie the application amount of each individual layer can vary.
  • the primer can be applied to the material carrier plate using a roller with subsequent drying. It is also possible to apply the primer to the material plate using digital printing. In this case, water-based inks enriched with white color pigments are preferably used, which are suitable for the digital printing inks used below. An order using digital printing is advantageous, as the printing system is significantly shorter than a roller device and thus saves space, energy and costs.
  • a primer layer is applied to the primer, preferably as a single application with subsequent drying.
  • the amount of the applied liquid primer is between 10 and 30 g / m 2 , preferably between 15 and 20 g / m 2 .
  • Polyurethane-based compounds are preferably used as primers.
  • the decorative layer can also be provided with a protective layer (as already described above for the papers).
  • This protective layer can be a formaldehyde-containing resin (in the B state, see above), in particular a melamine-formaldehyde resin, urea-formaldehyde resin or melamine-urea-formaldehyde resin and glass spheres (size 50-150 ⁇ m) as Spacers included for optional intermediate storage of the panels.
  • This protective layer is used to temporarily protect the decorative layer for storage before further finishing.
  • the protective layer on the decorative layer has not yet fully cured, but has a certain residual moisture content of approx. 10%, preferably approx. 6%, and can be further crosslinked. In the case of temporary storage, the resin remains in state B (not yet fully cured and crosslinked), whereby the decoration is protected.
  • the glass balls can be added to the resin or sprinkled on it and act as spacers.
  • Such protective layers are e.g. described in WO 2010/1 12125 A1 or EP 2 774 770 B1.
  • At least one wear protection layer is applied to the printed material plate (with or without a protective layer).
  • This wear protection layer can consist of one or more layers, e.g. consist of three, four, five or six layers.
  • a wear protection layer is applied with the following steps:
  • the first resin layer having a solids content between 60 and 80% by weight, preferably 65 and 70% by weight, particularly preferably between 65 and 67% by weight;
  • the first resin layer provided with the abrasion-resistant particles on the top of the material plate may not be dried after application,
  • the second resin layer having a solids content between 60 and 80% by weight, preferably 65 and 70% by weight, particularly preferably between 65 and 67% by weight;
  • the third resin layer having a solids content between 60 and 80% by weight, preferably 65 and 70% by weight, particularly preferably between 65 and 67% by weight, and containing glass spheres;
  • the fourth resin layer having a solids content between 50 and 70% by weight, preferably 55 and 65% by weight, particularly preferably between 58 and 62% by weight, and containing glass spheres;
  • the fifth resin layer having a solids content between 50 and 70% by weight, preferably 55 and 65% by weight, particularly preferably between 58 and 62% by weight, and containing glass spheres;
  • the sixth resin layer having a solids content between 50 and 70% by weight, preferably 55 and 65% by weight, particularly preferably between 58 and 62% by weight, and containing no glass spheres;
  • the resin layers used for the wear protection layer are preferably based on aqueous formaldehyde-containing resins, in particular melamine-formaldehyde resin, urea-formaldehyde resin or melamine-urea-formaldehyde resin.
  • the resins used preferably each contain additives such as hardeners, wetting agents (surfactants or mixtures thereof), defoamers, release agents and / or other components.
  • the wetting agent is used in the resin layers in an amount of 0.1-1% by weight.
  • Release agents and smoothing agents are preferably added to the fifth and sixth resin layer in amounts between 0.5-1.5% by weight.
  • a latent hardener is preferably used as hardener, such as alkanolamine salts of acids, for example an alkanolamine salt of a sulfonic acid (see DeuroCure from the manufacturer Deurowood).
  • the latent hardener is preferably added to the resin immediately before the application unit, to avoid premature hardening of the resin and thus losses. Accordingly, there is preferably no central admixing of the hardener, but rather an admixing of the variable amount of hardener at the corresponding application units. This has the advantage that if the system fails, the resin can remain in the lines longer without the hardener. Only the application units with resin hardener have to be specifically adjusted to the pot life of the system. In this way, losses caused by pumping out resin hardener in the event of a standstill / malfunction can be significantly reduced.
  • the proportion of hardener in the individual resin layers varies and can be between 0.5 to 1.5% by weight, preferably 0.7 to 1.3% by weight. It is particularly preferred that the proportion of hardener per resin application decreases in the production direction; i.e. In the lower resin layers, the proportion of hardener is greater than in the upper resin layers. By reducing the amount of hardener from the lower to the upper resin layers, the individual resin layers can be hardened evenly in the KT press.
  • the first resin layer is applied in an amount between 10-100 g / m 2 , preferably 40-80 g / m 2 , particularly preferably 45-60 g / m 2 .
  • the first resin layer is applied, for example, with a grooved application roller in a first application unit.
  • the first resin layer can contain cellulose fibers or wood fibers, preferably cellulose fibers. By adding cellulose fibers, the viscosity of the resin to be applied can be adjusted and the application of the first cover layer to the wood-based panel can be increased.
  • the amount of cellulose fibers that is applied with the first resin layer can be between 0.1 and 1% by weight, preferably between 0.5 and 0.8% by weight (based on the amount of resin to be applied) or between 0.1-0, 5 g / m 2 , preferably 0.2-0.4 g / m 2 , particularly preferably 0.25 g / m 2 .
  • the cellulose fibers used with preference are white in color and are in the form of a fine or granular, slightly hygroscopic powder.
  • the abrasion-resistant particles used are corundum particles (aluminum oxides), boron carbides, silicon dioxides, silicon carbides. Corundum particles are particularly preferred. In this case, it is preferably a matter of high-grade corundum (white) with a high level of transparency, so that the visual effect of the underlying decoration is adversely affected as little as possible. Corundum has an uneven spatial shape.
  • the amount of abrasion-resistant particles scattered on is 10 to 50 g / m 2 , preferably 10 to 30 g / m 2 , particularly preferably 15 to 25 g / m 2 .
  • the amount of abrasion-resistant particles scattered on depends on the abrasion class to be achieved and the grain size.
  • the amount of abrasion-resistant particles in the case of abrasion class AC3 is in the range between 10 to 15 g / m 2
  • in abrasion class AC4 between 15 to 20 g / m 2
  • in abrasion class AC5 between 20 to 25 g / m 2 when used the grit F200.
  • the finished panels preferably have abrasion class AC4.
  • Abrasion-resistant particles with grain sizes in classes F180 to F240, preferably F200, are used.
  • the grain size of class F180 covers a range from 53 - 90 gm, F220 from 45-75 gm, F230 34-82 gm, F240 28-70 gm (FEPA standard).
  • white aluminum oxide F180 to F240 preferably in a main grain range of 53-90 ⁇ m, are used as abrasion-resistant particles.
  • corundum particles of class F200 are used, F200 being a mixture between F180 and F220 and having a diameter between 53 and 75 ⁇ m.
  • the abrasion-resistant particles must not be too fine-grained (risk of dust formation), but also not too coarse-grained. The size of the abrasion-resistant particles is therefore a compromise.
  • silanized corundum particles can be used.
  • Typical silanizing agents are aminosilanes.
  • the second resin layer to be applied to the upper side of the material plate is applied in an amount between 10-50 g / m 2 , preferably 20-30 g / m 2 , particularly preferably 20-25 g / m 2 . Overall, the amount of the second resin layer is less than the amount of the first resin layer. In a preferred embodiment, the second resin layer to be applied to the top of the material panel does not contain any glass spheres.
  • the total amount of first and second resin layer is between 50-100 g / m 2 , preferably 60-80 g / m 2 , particularly preferably 70 g / m 2 . In one variant, the amount of the first resin layer is 50 g / m 2 and the amount of the second resin layer is 25 g / m 2 .
  • the abrasion-resistant particles accumulate in the second resin layer due to the entrainment of loose particles by the second applicator. So can turn into the second Resin layer to be applied resin set a content of abrasion-resistant particles of 5 to 15 wt%, preferably 10 wt%.
  • the amount of the third resin layer applied to the top of the wood-based panel can be between 10-50 g / m 2 , preferably 20-30 g / m 2 , particularly preferably 25 g / m 2 .
  • the third resin layer contains glass spheres that act as spacers.
  • the glass spheres that are preferably used have a diameter of 90-150 ⁇ m.
  • the glass spheres can be applied together with the third resin layer or separately sprinkled onto the third resin layer.
  • the amount of glass spheres is 10 to 50 g / m 2 , preferably 10 to 30 g / m 2 , particularly preferably 15 to 25 g / m 2 .
  • the approach preferably consists of approx. 40 kg of liquid resin plus glass balls and auxiliary materials.
  • the glass beads can also be present in silanized form. The silanization of the glass beads improves the embedding of the glass beads in the resin matrix.
  • the amount of the fourth resin layer applied to the top of the wood-based panel can be between 10-40 g / m 2 , preferably 15-30 g / m 2 , particularly preferably 20 g / m 2 .
  • the solids content of the fourth resin layer (as well as the fifth and sixth resin layers) is lower compared to the first to third resin layers.
  • the varying solids content of the resin layers to be applied enables, on the one hand, a higher total layer thickness due to the increased solids content in the first to third layers; on the other hand, the reduced solids content in the fourth to sixth resin layers ensures that the drying and pressing time is sufficient for the overall structure.
  • the amount of the fifth resin layer applied to the top of the wood-based panel can be between 10-40 g / m 2 , preferably 15-30 g / m 2 .
  • the fifth resin layer also contains glass spheres.
  • the glass spheres can be applied together with the third resin layer or separately sprinkled onto the third resin layer.
  • the glass balls are applied in an amount of 8 to 10 kg per application unit.
  • the sixth resin layer to be applied to the fifth resin layer after drying does not contain any glass spheres. The omission of glass spheres in the sixth resin layer ensures that the underlying resin layers, which have already dried, are not destroyed and the surface of the resin structure does not appear torn.
  • the total thickness of the resin layers applied to the wood-based panel can be between 60 and 200 ⁇ m, preferably between 90 and 150 ⁇ m, particularly preferably between 100 and 120 ⁇ m.
  • the total layer thickness is thus well above the previous methods, with which layer thicknesses of up to 50 ⁇ m are typically achieved.
  • a resin layer is applied to the underside of the material plate together with the second, third, fourth, fifth and sixth resin layer to be applied to the upper side of the material plate.
  • a resin layer is also applied to the underside of the material plate parallel to the second resin layer on the upper side of the material plate.
  • the amount of the resin layer applied to the underside of the material plate can be between 50-100 g / m 2 , preferably 60-80 g / m 2 , particularly preferably 60 g / m 2 .
  • the lower resin layer is preferably colored (eg brownish) in order to simulate a counter-pull.
  • the second resin layer is preferably applied in parallel or simultaneously to the top and bottom of the material plate in at least one double application device (roller application unit). After the second resin layer has been applied, the structure of the first and second resin layers is dried (air-dried) in a first drying device.
  • a third, fourth, fifth and sixth resin layer are applied to the underside parallel to the upper side in double applicators on the carrier plate and each dried after the application.
  • the resin layer (s) applied to the underside act as a counterweight. By applying the resin layers to the top and bottom of the material panels in approximately the same amounts, it is ensured that the tensile forces on the material panel that arise during the pressing process cancel each other out.
  • the layer structure and the respective layer thickness of the backing applied to the underside approximately correspond to the layer sequence applied to the upper side, but without the addition of glass spheres.
  • the resin layers are dried at dryer temperatures between 150 and 220 ° C., preferably between 180 and 210 ° C., in particular in a convection dryer.
  • the temperature is adapted to the respective resin layers and can vary in the individual convection dryers;
  • the temperature in the second, third and fourth convection dryers can be 205 ° C and in the fifth and sixth convection dryers 198 ° C each.
  • convection dryers instead of convection dryers, however, other dryers can also be used.
  • the layer structure is pressed under the influence of pressure and temperature in a short-cycle press at temperatures between 150 and 250 ° C, preferably between 180 and 230 ° C, particularly preferably at 200 ° C and a pressure between 30 and 60 kg / cm 2 , particularly preferably between 40 and 50 kg / cm 2 .
  • the pressing time is between 5 and 15 seconds, preferably between 7 and 10 seconds.
  • a pressure of 50-60 kg / cm 2 is applied for 16 seconds.
  • the coated material panel is preferably aligned in the short-cycle press with a structured press plate located in the short-cycle press using markings on the wood-based panel so that congruence between the decor on the wood-based panel and the structure of the press panel to be embossed is produced. This enables the creation of a decor-synchronous structure.
  • the melamine resin layers melt and a laminate is formed by a condensation reaction including the components corundum / glass / fibers.
  • the material panel is processed with the following method steps: a) applying at least one first layer of at least one powdery resin to at least one side of a wood-based panel and melting the at least one applied layer made of a powdery resin; a1) optional application of at least one primer layer which can contain color pigments, in particular white color pigments; a2) optional application of at least one primer layer; b) applying at least one printed decoration or decorative layer by means of digital printing using the CRYK ink described above; and c) applying at least one further (second) layer of at least one powdery resin to the at least one printed decorative layer and melting the at least one layer of powdery resin scattered onto the decorative layer.
  • the powdered resin is applied to the wood-based panel in an amount of 10 to 50 g / m 2 , preferably 15 to 30 g / m 2 , particularly preferably 20 to 25 g / m 2 .
  • This application amount of resin powder essentially applies to all resin powder layers to be applied, whereby these can be adapted in each case.
  • the scattering density is chosen so that covering layers are generated in every case.
  • the particle size of the powdery resin is between 20 and 100 gm, preferably between 40 and 89 gm.
  • the powdery resin to be applied is a formaldehyde resin, preferably a urea resin, a melamine resin or a phenolic resin, particularly preferably a melamine-formaldehyde resin. It is preferable if a melamine resin or a urea resin is used for the first resin layer. Only melamine resin is preferably used in the upper layers.
  • “Melting” or “gelling” in the context of the present application means that the resin layer is not yet completely polymerized, but rather the polymerization is stopped at an intermediate stage in which further crosslinking or polymerization is still possible at a later processing time.
  • the sense of "gelling” is therefore usually based on the fact that at a later point in time further functional layers are to be applied to the protective layer that has already been applied or the product would only be finished in further processing steps.
  • salting-out, thickening, settling, curing-influencing effects, etc. substances that are poorly compatible with liquid melamine resin can be used. These can be salts to increase the Conductivity, organic or inorganic flame retardants, cellulose derivatives, radical scavengers, pigments, UV absorbers, etc.
  • the powdery resin used can contain additives such as pigments, conductive substances and cellulose.
  • the layer of the melted resin powder can simultaneously serve as a white primer layer for the decorative layer to be subsequently printed.
  • White pigments such as titanium dioxide T1O2 can be used as color pigments.
  • Further color pigments can be calcium carbonate, barium sulfate or barium carbonate. The proportion of color pigments can be up to 50% by weight of the total amount of powder.
  • the addition of color pigments to the first layer of resin powder increases the covering power, so that it can be used as the (sole) base or primer for the subsequent decorative layer.
  • the resin powder is applied by means of electrostatic charging.
  • the application can also be carried out by means of powder coating using the tribo method.
  • the powder to be applied is charged by friction.
  • the applied layer of powdery resin can be melted using an IR radiator, or microwave systems or the like.
  • IR radiators is particularly preferred.
  • the further powder resin layer applied and fused in step c) of the present method preferably comprises powder based on formaldehyde resin, particularly preferably melamine-formaldehyde resin.
  • the amount of resin powder applied in this step is between 10 and 50 g / m 2 , preferably between 20 and 40 g / m 2 .
  • abrasion-resistant particles are uniformly sprinkled onto the decorative layer or the resin powder layer applied in step c) (step d).
  • At least one third layer of at least one powdery resin (step e), in particular on the layer of abrasion-resistant particles, is applied.
  • This layer serves as a separating layer to block off the abrasion-resistant particles.
  • the powder resin layer applied and fused in this step e) preferably comprises powder based on formaldehyde resin, particularly preferably melamine-formaldehyde resin.
  • the amount of resin powder applied in this step is between 10 and 50 g / m 2 , preferably between 20 and 40 g / m 2 .
  • glass spheres are sprinkled on, in particular on the at least one third melted resin powder layer (step f).
  • the glass spheres act as spacers between abrasion-resistant particles and the subsequent press plate. The sheet metal wear can thus be at least partially reduced.
  • At least one fourth layer of at least one powdery resin, in particular on the layer of glass spheres, is applied (step g). This layer serves to block the glass balls and as a finishing layer.
  • the fourth powder resin layer applied and fused in this step g) preferably comprises powder based on formaldehyde resin, particularly preferably melamine-formaldehyde resin.
  • the amount of resin powder applied in this step is between 10 and 50 g / m 2 , preferably between 20 and 40 g / m 2 .
  • the layer structure is pressed in a short-cycle press (KT press) (step h).
  • the pressing step takes place under the influence of pressure and temperature at temperatures between 180 and 250 ° C., preferably between 200 and 230 ° C., particularly preferably at 200 ° C. and a pressure between 30 and 60 kg / cm 2 , particularly preferably between 40 and 50 kg / cm 2 .
  • the pressing time is between 8 and 30 seconds, preferably between 10 and 25 seconds.
  • Embodiment 1a printing of raw paper
  • a base paper (paper weight: 80 g / m 2 ) is unrolled by an unwinding device.
  • the printing inks are applied in an amount between 5 and 10 g / m 2 .
  • the printed paper can be provided with a melamine-formaldehyde resin layer as a protective layer.
  • This protective layer serves to protect the printed decorations and enables temporary storage.
  • the paper is then dried in a convection dryer or by NIR (near infrared) to a moisture content of approx. 6% by weight, so that the resin layer is in the B-state.
  • NIR near infrared
  • Embodiment 1b Printing of base paper with an ink-receiving layer
  • a base paper (paper weight: 80 g / m 2 ) is unrolled by an unwinding device. Then a pigmented (T1O2) ink-receiving layer (synthetic silicate with polyvinyl alcohol as binder) (layer thickness 40 ⁇ m; after drying at 125 ° C dry weight per unit area 4 g / m 2 ) and a primer layer are applied and the layer structure is dried.
  • T1O2 pigmented ink-receiving layer
  • a decorative layer is applied to the paper obtained in this way (paper weight: 80 g / m 2 ) in the digital printing process using a CRYK ink with the above composition.
  • the printing inks are applied in an amount between 5 and 10 g / m 2 .
  • the printed paper can be provided with a melamine-formaldehyde resin layer as a protective layer.
  • This protective layer serves to protect the printed decorations and enables temporary storage.
  • the paper is then dried in a convection dryer or by NIR (near infrared) to a moisture content of approx. 6% by weight, so that the resin layer is in the B-state.
  • NIR near infrared
  • Embodiment 2a Printing a first impregnate with an ink-receiving layer
  • the paper to be printed is impregnated with a liquid melamine resin on the front and back in an impregnation device.
  • About 50 g of melamine resin / m 2 with a solids content of about 50% are applied.
  • a pigmented (T1O2) ink-receiving layer synthetic silicate with polyvinyl alcohol as binder
  • layer thickness 40 gm after drying at 125 ° C dry basis weight 4 g / m 2
  • primer layer a primer layer
  • a decorative layer is applied to the impregnate obtained in this way (paper weight: 80 g / m 2 ) in a digital printing process using a CRYK ink with the above composition.
  • the printing inks are applied in an amount between 5 and 10 g / m 2 .
  • the printed paper can be provided with a melamine-formaldehyde resin layer as a protective layer.
  • the paper is then dried in a convection dryer or by NIR (near infrared) to a moisture content of approx. 6% by weight, so that the resin layer is in the B-state.
  • NIR near infrared
  • Embodiment 2b Printing a second impregnate with an ink-receiving layer
  • the paper to be printed is coated in an application device with melamine resin powder in an amount of 25 g / m 2 with the aid of tribo guns.
  • the melamine resin powder contained the usual auxiliaries such as hardeners, release agents, etc. The powder is then melted using infrared radiation.
  • a pigmented (T1O2) ink-receiving layer synthetic silicate with polyvinyl alcohol as binder
  • layer thickness 40 gm after drying at 125 ° C dry basis weight 4 g / m 2
  • primer layer a primer layer
  • a decorative layer is applied to the impregnate obtained in this way (paper weight: 80 g / m 2 ) in a digital printing process using a CRYK ink with the above Composition applied.
  • the printing inks are applied in an amount between 5 and 10 g / m 2 .
  • the printed paper can be provided with a melamine-formaldehyde resin layer as a protective layer.
  • the paper is then dried in a convection dryer or by NIR (near infrared) to a moisture content of approx. 6% by weight, so that the resin layer is in the B-state.
  • NIR near infrared
  • Exemplary embodiment 2c printing a third impregnate
  • the paper to be printed is impregnated with a melamine resin on the front and back in an impregnation device. About 50 g of melamine resin / m 2 with a solids content of about 50% are applied.
  • the resin on the side of the impregnate to be printed is drawn off with a special device (e.g. a knife squeegee) so that fibers remain free to absorb the printer ink.
  • a special device e.g. a knife squeegee
  • a decorative layer is applied to the impregnate obtained in this way (paper weight: 80 g / m 2 ) in a digital printing process using a CRYK ink with the above composition.
  • the printing inks are applied in an amount between 5 and 10 g / m 2 .
  • the printed impregnate does not need to be dried any further, as the digital printing ink brings only little moisture.
  • Embodiment 3 Printing a plate with a liquid overlay
  • An HDF board (fiber board with increased bulk density) is first pre-coated with an aqueous synthetic resin (melamine-formaldehyde resin).
  • the application rate is 20-50 g resin liquid / m 2 (solids content: approx. 55%).
  • the resin contains the usual auxiliaries such as wetting agents, hardeners, release agents and defoamers.
  • the applied resin is then dried in a convection dryer or a near-infrared oven to a moisture content of approx. 20%.
  • several coats of a water-based, pigmented one Primer applied (5 - 8 times). After each application the primer is dried with the help of a convection dryer or a near-infrared dryer.
  • the primed plate is printed with a motif using a digital printer. Approx. 6 - 8 g / m 2 of the water-based CRYK digital printing ink are used.
  • melamine resin fluid solids content: 55% by weight
  • auxiliaries hardener, wetting agent, etc.
  • a melamine resin is also applied to the underside of the plate with the first roller application unit (application quantity: 60 g resin area / m 2 , solids content: approx. 55% by weight).
  • a melamine resin which also contains glass beads, is then applied to the panel surface. These have a diameter of 60 - 80 pm. The amount of resin applied is approx. 20 g melamine resin liquid / m 2 (solids content: 61.5% by weight). In addition to the hardener and the wetting agent, the recipe also contains a release agent. The amount of glass spheres applied is approx. 3 g / m 2 .
  • a melamine resin is also applied to the underside of the plate using a roller application unit (application quantity: 40 g resin fluid / m 2 , solids content: approx. 55% by weight). The plate is again dried in a circulating air dryer and then coated again with a melamine resin containing glass beads.
  • melamine resin fluid / m 2 solids content: 61.6% by weight
  • the recipes also contain a release agent.
  • a melamine resin is also applied to the underside of the plate using a roller application unit (application amount: 30 g resin fluid / m 2 , solids content: approx. 55% by weight).
  • the resin is again dried in a circulating air dryer and then the plate is placed in a short-cycle press at 200 ° C. and a pressure of 400 N / cm 2 pressed. The pressing time was 10 seconds.
  • a pressed sheet with a wooden structure was used as a structure generator.
  • Embodiment 4 Printing a plate with a powder overlay
  • 8 mm HDF are separated, freed from dust with the help of brushes and then transported onwards via roller transports.
  • melamine resin powder In an application device, they are then coated with melamine resin powder in an amount of 25 g / m 2 with the aid of tribo guns.
  • the melamine resin powder contained the usual auxiliaries such as hardeners, release agents, etc. The powder is then melted using infrared radiation.
  • the primed board is coated in multiple applications with a colored primer with subsequent intermediate drying (circulating air).
  • the color primer is a mixture of casein and pigment (titanium dioxide).
  • the amount applied per order is approx. 5 g b / m 2 .
  • the job is repeated at least five times.
  • a primer is then applied (application quantity: 10-20 g fl./m 2 ) with circulating air drying.
  • the plate is printed with a digital printer using the aqueous CRYK ink.
  • the application quantities of paint are 3 to 15 g fl. / M 2 .
  • the paint is dried over IR radiation or circulating air.
  • Corundum is sprinkled onto the print using a scattering device (application rate: 20 g corundum / m 2 , F 180).
  • melamine resin powder is again applied with a tribo gun (application rate: 80 g / m 2 ).
  • This melamine resin powder is gelled again with the help of an IR radiator.
  • the melamine resin powder contained the usual auxiliaries such as hardeners, release agents, etc.
  • the board is pressed together with a counter-tension impregnate in a KT press.
  • the pressed plate was then inspected visually, and no abnormalities were found.
  • the surface tests subsequently carried out in accordance with DIN EN 15468 - August 2018 also showed no abnormalities. All requirements of exposure class 32 were met.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

La présente invention concerne un procédé pour fabriquer au moins un matériau de support pourvu d'un décor imprimé, le décor imprimé étant appliqué sur le ou les matériaux de support au moyen d'une impression numérique, l'encre utilisée pour l'impression numérique étant une encre hydrosoluble CMJN qui contient au moins un pigment cyan, au moins un pigment rouge du groupe des pigments de quinacridone, le pigment jaune PY181 et au moins un pigment noir de carbone.
EP20735276.6A 2019-06-25 2020-06-12 Procédé pour fabriquer au moins un matériau de support pourvu d'un décor imprimé Pending EP3990287A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP19182230.3A EP3757178B1 (fr) 2019-06-25 2019-06-25 Procédé de fabrication d'au moins un matériau porteur pourvu d'un decor imprimé
PCT/EP2020/066390 WO2020260044A1 (fr) 2019-06-25 2020-06-12 Procédé pour fabriquer au moins un matériau de support pourvu d'un décor imprimé

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EP3990287A1 true EP3990287A1 (fr) 2022-05-04

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EP20735276.6A Pending EP3990287A1 (fr) 2019-06-25 2020-06-12 Procédé pour fabriquer au moins un matériau de support pourvu d'un décor imprimé

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US (1) US20220363930A1 (fr)
EP (2) EP3757178B1 (fr)
CN (1) CN114080433B (fr)
ES (1) ES2899460T3 (fr)
PL (1) PL3757178T3 (fr)
PT (1) PT3757178T (fr)
WO (1) WO2020260044A1 (fr)

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EP4086081A1 (fr) * 2021-05-07 2022-11-09 Swiss Krono TEC AG Procédé d'impression numérique
EP4279284A1 (fr) * 2022-05-17 2023-11-22 SWISS KRONO Tec AG Procédé et dispositif d'impression d'un papier
EP4279285A1 (fr) * 2022-05-17 2023-11-22 SWISS KRONO Tec AG Procédé et dispositif permettant d'imprimer un objet
CN117661813A (zh) * 2022-08-24 2024-03-08 赵培东 一种耐磨耐刮板材及其制备方法

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GB2367299B (en) * 2000-09-29 2003-12-10 Ilford Imaging Uk Ltd Pigment ink set
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JP2005002186A (ja) * 2003-06-11 2005-01-06 Toray Ind Inc インクジェット用インク組成物
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JP4934977B2 (ja) * 2005-03-28 2012-05-23 セイコーエプソン株式会社 インクセット及びこれを用いた記録方法、記録物
ES2334256T3 (es) * 2006-12-21 2010-03-08 Agfa Graphics N.V. Metodo de impresion por inyeccion de tinta y conjuntos de tinta de inyeccion.
WO2008110563A1 (fr) * 2007-03-15 2008-09-18 Akzo Nobel Coatings International B.V. Peinture à couleur non constante
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PL2774770T3 (pl) 2013-03-08 2015-10-30 Flooring Technologies Ltd Sposób drukowania płyt z tworzywa drzewnego z warstwą dekoracyjną
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CN114080433A (zh) 2022-02-22
ES2899460T3 (es) 2022-03-11
EP3757178A1 (fr) 2020-12-30
PL3757178T3 (pl) 2022-01-24
US20220363930A1 (en) 2022-11-17
PT3757178T (pt) 2021-11-19
EP3757178B1 (fr) 2021-09-08
CN114080433B (zh) 2023-05-23
WO2020260044A1 (fr) 2020-12-30

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