EP3862452A1 - Austenitisches edelstahlblech und verfahren zur herstellung davon - Google Patents

Austenitisches edelstahlblech und verfahren zur herstellung davon Download PDF

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EP3862452A1
EP3862452A1 EP19868476.3A EP19868476A EP3862452A1 EP 3862452 A1 EP3862452 A1 EP 3862452A1 EP 19868476 A EP19868476 A EP 19868476A EP 3862452 A1 EP3862452 A1 EP 3862452A1
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steel sheet
stainless steel
austenitic stainless
case
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EP3862452A4 (de
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Natsuko Sugiura
Hiroshi Kamio
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Nippon Steel Corp
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Nippon Steel Corp
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26—Methods of annealing
    • C21D1/30—Stress-relieving
    • C—CHEMISTRY; METALLURGY
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    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
    • C—CHEMISTRY; METALLURGY
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    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
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    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
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    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
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    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
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    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite

Definitions

  • the present invention relates to an austenitic stainless steel sheet and a method for producing the austenitic stainless steel sheet.
  • a member having high surface glossiness is used for a housing of an electronic device which is a precisely worked component, and for example, a member formed of a stainless steel sheet is frequently used.
  • the member has been required to have higher polishability than before.
  • Patent Documents 1 to 4 an improvement in polishability of a stainless steel sheet is examined.
  • Patent Document 1 discloses a method for producing a mirror-finished stainless steel sheet for curved mirror, which has wrapping-finished surface gloss and excellent image clarity.
  • Patent Document 2 discloses an austenitic stainless steel for press forming, which has improved polishability for mirror finishing.
  • Patent Document 3 discloses a method for producing a stainless steel strip and a steel sheet having excellent polishability.
  • Patent Document 4 discloses a method for producing a steel strip having few micro surface defects in the production of strips of austenitic stainless steel, martensitic stainless steel, or ferrite + austenitic duplex stainless steel.
  • the precisely worked component is produced by a method in which stainless steel sheets are laminated and subjected to diffusion bonding at a high temperature.
  • a method in which precision processing by photoetching or laser is performed to form micropores or a pattern on a surface, and then the steel sheets are laminated and subjected to diffusion bonding is employed to produce the precisely worked component.
  • Demands for such precisely worked components and products are on the increase, and diffusion bonding is expected to be further applied and expanded.
  • a steel sheet which is used for the above purpose is required to have good bondability.
  • Patent Documents 5 to 9 an improvement in diffusion bondability is examined.
  • Patent Document 5 proposes a method for producing a diffusion-bonded product which can be processed without the application of special high-temperature heat or high surface pressure by using the growth of crystal grains accompanying the phase transformation during diffusion bonding.
  • Patent Document 6 discloses a stainless steel diffusion-bonded product which is excellent in reliability of a bonding portion and has a diffusion bonding structure in which there are many places where crystal grains on the steel side grow so as to invade the other side beyond the pre-bonding interface.
  • Patent Document 7 discloses a steel sheet in which diffusion bondability is increased by controlling austenite fraction during diffusion bonding.
  • Patent Document 8 discloses, as a stainless steel having excellent diffusion bondability, a stainless steel foil having fine crystal grains with an average crystal grain size of 0.001 to 5 ⁇ m in a foil thickness direction and an Al content of 0.5% to 8%.
  • Patent Document 9 describes that the etching surface is smoothened by grain refining and diffusion bondability is thus improved.
  • the inventors have conducted studies, and as a result, found that sufficient diffusion bondability may not be obtained by the related art and there is room for further improvement.
  • the invention is contrived to solve the above problems, and an object thereof is to provide an austenitic stainless steel sheet having good polishability.
  • the expression "having good polishability” means that smoothing can be easily achieved by mechanical polishing.
  • the austenitic stainless steel sheet has good polishability, and preferably further has good diffusion bondability.
  • an austenitic stainless steel sheet which has good diffusion bondability in addition to good polishability.
  • C is a potent solid solution strengthening element that increases the strength of a steel sheet at a low price.
  • the C content is 0.150% or less.
  • the C content is preferably 0.130% or less, and more preferably 0.120% or less.
  • the C content is less than 0.005%, this leads to only an increase in production cost, and a particularly effective effect is not obtained. Therefore, the C content is 0.005% or greater.
  • C is effective for suppressing recrystallization and grain growth by combining with Nb and precipitating as a fine Nb compound. In obtaining the above effects, the C content is preferably 0.010% or greater.
  • the Si content is 1.0% or less.
  • the Si content is preferably 0.6% or less.
  • Si is an element that is used as a deoxidizing material during melting and also contributes to the strengthening of steel.
  • the Si content is preferably 0.1% or greater.
  • Mn is a potent austenite forming element. Therefore, in a case where the Mn content is excessive, the amount of strain-induced martensite formed during cold rolling is reduced, and thus the accumulation in the ⁇ 110 ⁇ plane orientation after final annealing is reduced. In addition, fine crystal grains cannot be obtained. Therefore, the Mn content is 1.5% or less. The Mn content is preferably 1.2% or less.
  • Mn is an element that contributes to the prevention of brittle fracture during hot working and the strengthening of steel.
  • the Mn content is preferably 0.1% or greater.
  • the P content is an impurity element.
  • the P content is limited to 0.10% or less. Since the P content is preferably low, it may be 0%. However, it is not preferable the P content is less than 0.005% in view of cost. Therefore, the lower limit of the P content may be 0.005%.
  • S is an impurity element.
  • the S content is greater than 0.010%, melt embrittlement is caused during hot working. Therefore, the S content is limited to 0.010% or less. Since the S content is preferably low, it may be 0%. However, it is not preferable the S content is less than 0.001% in view of cost. Therefore, the lower limit of the S content may be 0.001 %.
  • Al is an impurity element.
  • the Al content is greater than 0.10%, workability is reduced.
  • oxides are formed during bonding, and diffusion bondability is reduced. Therefore, the Al content is limited to 0.10% or less. Since the Al content is preferably low, it may be 0%. However, it is not preferable the Al content is less than 0.01% in view of cost. Therefore, the lower limit of the Al content may be 0.01%.
  • Cr is a basic element of a stainless steel, and is an element that acts to form an oxide layer on a surface of a steel and to increase corrosion resistance.
  • the Cr content is 15.0% or greater.
  • the Cr content is preferably 16.0% or greater.
  • Cr is a potent ferrite stabilizing element. Therefore, in a case where the Cr content is excessive, ⁇ ferrite is formed. The ⁇ ferrite deteriorates hot workability of the material. Therefore, the Cr content is 20.0% or less. The Cr content is preferably 19.0% or less.
  • Ni is an austenite forming element, and is an element that acts to stabilize austenite at room temperature. In order to obtain the above effects, the Ni content is 6.0% or greater. The Ni content is preferably 6.5% or greater.
  • the Ni content is excessive, the austenite is excessively stabilized, and thus strain-induced martensitic transformation during cold rolling does not occur. Whereby, the accumulation in the ⁇ 110 ⁇ plane orientation is reduced.
  • Ni is an expensive element. In a case where the Ni content is excessively increased, the cost is significantly increased. Therefore, the Ni content is 15.0% or less.
  • the Ni content is preferably 11.0% or less, and more preferably 9.0% or less.
  • N is a solid solution strengthening element, and is an element that contributes to an improvement in strength of a steel. It is not preferable that the N content is less than 0.005% in view of cost. Therefore, the N content is 0.005% or greater.
  • N is effective for suppressing recrystallization and grain growth by combining with Nb and precipitating as a fine Nb compound during hot rolling or annealing.
  • the N content is preferably 0.010% or greater.
  • N is also a potent austenite stabilizing element.
  • the N content is 0.150% or less.
  • the N content is preferably 0.130% or less, and more preferably 0.120% or less.
  • the austenitic stainless steel sheet according to this embodiment has a chemical composition containing the above elements and a remainder consisting of Fe and impurities.
  • one or more selected from the group consisting of Mo, Cu, Nb, V, Ti, and B may be contained in a range to be described later. Since these elements are not necessarily contained, the lower limit of the amount thereof is 0%.
  • the “impurities” include components mixed from raw materials such as ore and scrap in the industrial production of a steel, or components mixed due to various factors during the production process, and mean substances allowed within a range not affecting the austenitic stainless steel sheet according to this embodiment.
  • Mo is an element that improves corrosion resistance of a material. Therefore, Mo may be optionally contained. In a case where the above effects are desired, the Mo content is preferably 0.1% or greater.
  • Mo is an extremely expensive element. In a case where the Mo content is excessively increased, the cost is significantly increased. Therefore, even in a case where Mo is contained, the Mo content is 2.0% or less.
  • the Mo content is preferably 1.0% or less.
  • Cu is an austenite forming element, and is an effective element for adjusting the stability of austenite. Therefore, Cu may be optionally contained. In a case where the above effects are desired, the Cu content is preferably 0.1% or greater.
  • the Cu content is excessive, Cu segregates at the grain boundaries during the production process. Since the segregation at the grain boundaries causes a significant deterioration in hot workability, there are difficulties in production in a case where Cu segregates at the grain boundaries. Therefore, even in a case where Cu is contained, the Cu content is 1.5% or less.
  • the Cu content is preferably 1.0% or less.
  • Nb is an element that forms fine carbides or nitrides during annealing. Since these fine carbides or nitrides suppress crystal grain growth by the pinning effect, Nb is an effective element for refining the crystal grains of the material. In addition, Nb is an element that is solid-solubilized or suppresses recrystallization during hot working as a carbonitride, thereby developing the deformation texture of austenite. Therefore, Nb may be contained.
  • the Nb content is preferably 0.010% or greater.
  • the Nb content is more preferably 0.030% or greater, and even more preferably 0.040% or greater.
  • Nb is an extremely expensive element. In a case where the Nb content is excessively increased, the cost is significantly increased.
  • the Nb content is 0.500% or less.
  • the Nb content is preferably 0.300% or less, and more preferably 0.200% or less.
  • V 0% to 0.150%
  • V and Ti are elements that are effective for suppressing recrystallization, strengthening a desired texture, and refining the crystal grains. Therefore, one or more selected from the group consisting of V and Ti may be optionally contained. In order to obtain the above effects, it is preferable to contain one or more selected from the group consisting of V: 0.010% or greater and Ti: 0.010% or greater.
  • the V content is 0.150% or less and the Ti content is 0.300% or less.
  • B is an element that strengthens the grain boundaries and contributes to an improvement in hot workability. Therefore, B may be optionally contained. In order to obtain the above effect, the B content is preferably 0.001% or greater.
  • the B content is excessive, workability deteriorates. Therefore, even in a case where B is contained, the B content is 0.010% or less.
  • the chemical composition of the austenitic stainless steel sheet according to this embodiment contains essential elements and a remainder consisting of Fe and impurities, or contains essential elements, one or more optional elements, and a remainder consisting of Fe and impurities.
  • the "impurities” include Ca, Mg, Zr, Sn, Pb, and W in addition to the above-described P, S, and Al.
  • the total amount of impurity elements such as Ca, Mg, Zr, Sn, Pb, and W excluding P, S, and Al is preferably 0.10% or less.
  • the Md30 value is an index indicating the stability of austenite in the austenitic stainless steel sheet according to this embodiment or the like, and is a value calculated from the chemical composition, that is thought to correspond to a temperature at which 50 vol% of strain-induced martensite is formed when rolling is performed with a reduction of 30%.
  • the austenite reverse-transformed during the heat treatment may transform into martensite again during the cooling or temper rolling.
  • the amount of austenite is reduced, and as a result, the area ratio of the grains having the ⁇ 110 ⁇ plane orientation is also reduced.
  • the Md30 value determined according to Expression (i) is 60°C or lower.
  • the Md30 value is preferably 55°C or lower, and more preferably 50°C or lower.
  • Md 30 Value ° C 497 ⁇ 462 ⁇ C + N ⁇ 9.2 ⁇ Si ⁇ 8.1 ⁇ Mn ⁇ 13.7 ⁇ Cr ⁇ 20 ⁇ Ni + Cu ⁇ 18.7 ⁇ Mo
  • element symbols represent amounts of respective elements in the steel by mass%, and 0 is substituted for the element in a case where the element is not contained.
  • fine crystal grains are obtained by utilizing the transformation from austenite to strain-induced martensite (martensite) during the cold rolling and the reverse transformation from strain-induced martensite to austenite in the subsequent heat treatment.
  • austenite to strain-induced martensite
  • austenite to austenite
  • martensite strain-induced martensite
  • the Md30 value is preferably 20°C to 60°C.
  • the Md30 value is more preferably 25°C or higher, and even more preferably 30°C or higher.
  • the surface layer portion of the steel sheet means a region from the surface to a position at a depth of 1/10 of the sheet thickness in the sheet thickness direction.
  • Martensite is a hard structure. Therefore, in a case where the amount of martensite is excessive in the surface layer portion of the steel sheet in the producing stage before polishing, polishability deteriorates. In addition, in a case where the area ratio of martensite is increased, the area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation is relatively reduced. Therefore, the area ratio of martensite in the surface layer portion of the steel sheet is 5.0% or less. The area ratio is preferably 4.0% or less, and more preferably 3.0% or less.
  • the martensite in a case where the amount of martensite is large in the surface layer portion of the steel sheet, the martensite is transformed into austenite in a case where heat is applied by diffusion bonding or laser working, and the flatness of the steel sheet is reduced, resulting in reduced diffusion bondability.
  • the area ratio of austenite is reduced, and thus the fraction of the grains having the ⁇ 1101 ⁇ 112> orientation in the whole structure is also reduced. Therefore, from the viewpoint of diffusion bondability, the area ratio of martensite in the surface layer portion is preferably 5.0% or less.
  • the structure other than the martensite is substantially austenite.
  • the area ratio of martensite in the surface layer portion is determined by the following procedure.
  • a fcc structure and a bcc structure are selected as crystal structures, and the measurement is performed by EBSD. Then, a region that is not discriminated to have an fcc structure, that is, a region having a bcc crystal structure, or a region where the measurement is not possible due to high strain (a linear region such as a grain boundary is not included) is regarded as martensite, and the area ratio thereof is obtained.
  • the austenite of the surface layer may undergo strain-induced martensitic transformation. Therefore, it is necessary to produce a sample by electrolytic polishing or chemical polishing.
  • a polishing amount is limited to 1/10 of the sheet thickness.
  • the ⁇ 110 ⁇ plane orientation is a representative principal orientation of the rolled texture of austenite.
  • Good polishability is secured by setting the area ratio of austenite grains having the above plane orientation in the surface layer portion of the austenitic stainless steel sheet according to this embodiment to 50% or greater.
  • the area ratio of austenite grains having the above plane orientation is preferably 52% or greater, and more preferably 55% or greater.
  • the upper limit is not particularly set. However, since toughness is reduced in a case where the area ratio of austenite grains having the above plane orientation is greater than 85%, the upper limit is desirably 85%.
  • the area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation in the surface layer portion can be determined by the following method.
  • a region having an area of 500 ⁇ m ⁇ 500 ⁇ m or greater is subjected to EBSD measurement.
  • a region having a fcc crystal structure and surrounded by a grain boundary of 15° or greater is regarded as an austenite grain.
  • the total area of austenite grains having the ⁇ 110 ⁇ plane orientation is divided by the measurement area and multiplied by 100, and the resulting value is defined as the area ratio (%) of austenite grains having the ⁇ 110 ⁇ plane orientation.
  • the average grain size of the austenite grains in the surface layer portion is 5.0 ⁇ m or less, the number of crystal grains per unit area is increased, the existence frequency of grains having the ⁇ 110 ⁇ 112> orientation is averaged, and thus diffusion bondability is improved.
  • the average grain size of the austenite grains is 5.0 ⁇ m or less, when etching or the like is performed, a worked surface is smoothened.
  • the average grain size of the austenite grains in the surface layer portion is preferably 5.0 ⁇ m or less.
  • the average grain size of the austenite grains is calculated by the following procedure.
  • an area of 100 ⁇ m ⁇ 100 ⁇ m or greater is subjected to EBSD measurement.
  • regions discriminated to have an fcc structure a region surrounded by a boundary with an orientation difference of 15° or greater is regarded as one crystal grain, and an average area S per crystal grain is calculated from the number of crystal grains included in the predetermined area.
  • the ⁇ 110 ⁇ 112> orientation is a representative principal orientation of the rolled texture of austenite. High diffusion bondability is secured by setting the accumulation in the ⁇ 1101 ⁇ 112> orientation in the surface layer portion (bonding surface) of the steel sheet to 8.5 or greater. Therefore, in order to improve the diffusion bondability, the X-ray random intensity ratio of the ⁇ 110 ⁇ 112> orientation is preferably 8.5 or greater.
  • the X-ray random intensity ratio of the ⁇ 110 ⁇ 112> orientation is more preferably 9.0 or greater, and even more preferably 10.0 or greater.
  • the upper limit of the X-ray random intensity ratio of the ⁇ 110 ⁇ 112> orientation is not particularly set. However, in a case where the X-ray random intensity ratio is greater than 20.0, the orientation difference of 15° or greater between adjacent crystal grains cannot be satisfied, and the crystal grain boundary does not effectively act. Accordingly, the upper limit is desirably 20.0.
  • the X-ray random intensity ratio of the ⁇ 110 ⁇ 112> orientation may be obtained from a crystal orientation distribution function (orientation distribution function, called ODF) representing a three-dimensional texture, calculated by a series expansion method based on a plurality of pole figures among ⁇ 200 ⁇ , ⁇ 311 ⁇ , and ⁇ 220 ⁇ pole figures measured by X-ray diffraction.
  • ODF orientation distribution function
  • the X-ray random intensity ratio is a numerical value obtained by measuring X-ray intensities of a standard sample with no accumulation in a specific orientation and a test material by an X-ray diffraction method or the like under the same conditions, and by dividing the obtained X-ray intensity of the test material by the X-ray intensity of the standard sample.
  • the standard sample a sample with no specific accumulation in any plane measurement of ⁇ 200 ⁇ , ⁇ 311 ⁇ , and ⁇ 220 ⁇ is used.
  • the method for producing a standard sample is not specified, but usually, the standard sample is produced by compressing and sintering a powder of a metal having an fcc crystal structure at room temperature with a Fe group such as Fe-C, Fe-Ni, and Fe-Cr stably.
  • an orientation perpendicular to the sheet surface is usually represented by (hkl) or ⁇ hkl ⁇
  • an orientation parallel to the rolling direction is usually represented by [uvw] or ⁇ uvw>.
  • ⁇ hkl ⁇ and ⁇ uvw> are generic names for equivalent planes, and (hkl) and [uvw] refer to individual crystal planes. That is, in this embodiment, since the target structure is an fcc structure, for example, (111), (-111), (1-11), (11-1), (-1-11), (-11-1), (1-1-1), (-1-1-1) planes are equivalent and are not differentiated.
  • orientations thereof are collectively referred to as ⁇ 111 ⁇ .
  • ⁇ and ⁇ 2 are expressed in a range of 0° to 90°.
  • a sample for X-ray diffraction is produced as follows.
  • the X-ray random intensity ratio of the surface layer portion to be a bonding surface is important.
  • mechanical polishing, chemical polishing, and electrolytic polishing are required for a while or quite a while to obtain the flatness of the measurement plane or to remove strain. Therefore, the surface layer portion from the surface of the steel sheet to the position at a depth of 1/10 of the sheet thickness is adjusted so as to be the measurement plane.
  • the measurement may be performed a statistically sufficient number of times by an electron back scattering pattern (EBSD) method or an electron channeling pattern (ECP) method.
  • EBSD electron back scattering pattern
  • ECP electron channeling pattern
  • the sheet thickness of the austenitic stainless steel sheet according to this embodiment is not limited, and is, for example, 0.5 mm or less.
  • the austenitic stainless steel sheet can be produced by the following method.
  • the steel is melted and cast in the usual manner to obtain a steel piece to be hot-rolled.
  • the steel piece may be prepared by forging or rolling a steel ingot. From the viewpoint of productivity, the steel piece is preferably produced by continuous casting.
  • the steel piece may be produced using a thin slab caster or the like.
  • the austenitic stainless steel sheet according to this embodiment can be produced.
  • the steel piece is cooled after being cast, and reheated for hot rolling.
  • the heating temperature of the steel piece during hot rolling is 1,150°C or higher. This is because in a case where the heating temperature is lower than 1,150°C, coarse carbonitrides remain unmelted, which may be points where cracking starts during hot working, and promote randomization of the texture during hot rolling (suppress the formation of a desired texture).
  • the heating temperature is desirably 1,170°C or higher.
  • the upper limit of the heating temperature is not particularly specified. However, in a case where the heating is performed at a temperature higher than 1,400°C, this may lead to a reduction in productivity and growth in an orientation that does not develop in usual rolling. Therefore, the upper limit is desirably 1,400°C.
  • a process such as continuous casting-direct rolling (CC-DR) in which hot rolling is performed (without reheating) before the temperature drops below 1,150°C may be employed.
  • CC-DR continuous casting-direct rolling
  • hot rolling is performed on the heated steel piece.
  • the hot rolling is ended in a temperature range of 880°C to 1,000°C.
  • the temperature at which the hot rolling is ended is lower than 880°C, deformation resistance increases.
  • the end temperature is desirably 900°C or higher.
  • the temperature at which the hot rolling is ended is higher than 1,000°C, recrystallization occurs in all rolling passes, and thus the development degree of the texture of the hot-rolled steel sheet is reduced (the structure is randomized). Moreover, the area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation in the surface layer portion is reduced. In addition, the X-ray random intensity ratio of the ⁇ 110 ⁇ 112> orientation in the surface layer portion is also reduced. Therefore, the temperature at which the hot rolling is ended is 1,000°C or lower. The end temperature is desirably 980°C or lower, and more desirably 950°C or lower.
  • a shape ratio L determined according to Expression (ii) is 4.5 or less in final two passes respectively.
  • a layer called a shear layer having a different crystal orientation from that of the central layer in the sheet thickness direction is formed in the surface layer portion of the hot-rolled sheet due to the friction between the steel sheet and the rolling roll.
  • the shear layer does not include the ⁇ 110 ⁇ plane orientation. Accordingly, in a case where the shear layer develops at the stage of hot rolling, the area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation is also reduced.
  • the shape ratio L is desirably 4.2 or less, and more desirably less than 4.0.
  • the lower limit of the shape ratio L is not particularly set. However, in a case where the lower limit is less than 2.5, the sheet thickness of the hot-rolled sheet is increased, and the load of cold rolling increases. Therefore, the shape ratio is desirably 2.5 or greater in final two passes respectively.
  • the steel sheet (hot-rolled sheet) hot-rolled under the above conditions is coiled in a temperature range of 900°C or lower.
  • the coiling temperature is higher than 900°C, recrystallization proceeds during the coiling, and the desired texture is weakened.
  • the coiling temperature is desirably 880°C or lower, and more desirably 850°C or lower.
  • the lower limit of the coiling temperature is not particularly specified. However, even in a case where the coiling temperature is lower than 550°C, no special effects can be obtained, and there are difficulties in uncoiling due to the increased coil strength. Therefore, the coiling temperature is desirably 550°C or higher.
  • cold rolling and annealing are repeated once or multiple times in the usual manner to produce a steel sheet.
  • the temperature in the steps other than the final step is not particularly limited, and the temperature of the annealing (intermediate annealing) other than the final step is generally 900°C to 1,100°C.
  • the rolling reduction of the final cold rolling is 40% or greater.
  • the rolling reduction is desirably 45% or greater, and more desirably 50% or greater.
  • the rolling reduction is greater than 90%, an orientation different from that developed by usual rolling, and the area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation is reduced. In addition, the load on the device is extremely increased. Therefore, the rolling reduction is 90% or less.
  • the rolling reduction is desirably 85% or less, and more desirably 80% or less.
  • the roll diameter of the rolling roll in the final cold rolling step is 80 mm or greater.
  • the roll diameter is desirably 90 mm or greater, and more desirably 100 mm or greater.
  • the end-point temperature of the final annealing is lower than 600°C
  • the worked ⁇ -structure remains, and the ratio of austenite grains having the ⁇ 110 ⁇ plane orientation is reduced. Therefore, polishability cannot be secured.
  • the end-point temperature of the final annealing is lower than 600°C
  • reverse transformation does not occur, and austenite grains have an average grain size greater than 5.0 ⁇ m. Therefore, the end-point temperature of the final annealing is 600°C or higher.
  • the end-point temperature of the final annealing is desirably 650°C or higher, and more desirably 700° C or higher.
  • the end-point temperature of the final annealing is 1,000°C or lower.
  • the end-point temperature of the final annealing is desirably 980°C or lower, and more desirably 970° C or lower.
  • the holding time at the annealing temperature is 60 seconds or shorter. Holding for longer than 60 seconds causes randomization of the texture and coarsening of the grain size. From the above viewpoint, the holding time is preferably 30 seconds or shorter, and more preferably 10 seconds or shorter.
  • the hot-rolled sheet may be annealed (intermediate annealing) before cold rolling.
  • the annealing temperature before cold rolling is desirably 600°C to 1,000°C. The reasons for this are as follows: in a case where the temperature is lower than 600°C, the hot-rolled sheet is not sufficiently softened, and the working load during the cold rolling increases, and in a case where the temperature is higher than 1,000°C, the grain size is coarsened, and static recrystallization proceeds so that the structure is randomized.
  • thermo rolling for adjusting the mechanical characteristics of the steel sheet, and a subsequent heat treatment for reducing residual stress (strain relief) that causes a change in the shape of the sheet and for reverse transformation to the ⁇ -primary phase may be performed.
  • strain relief residual stress
  • the rolling reduction is desirably 50% or less. This is because in a case where the rolling reduction is 50% or less, adjustment to the required mechanical properties specified in JIS standards (G4305) and the like is possible.
  • the heat treatment temperature is desirably 600°C to 900°C, and more desirably 650°C to 850°C. This is because in a case where the heat treatment temperature is lower than 600°C, the effect of strain relief cannot be obtained, and reverse transformation does not occur.
  • the heat treatment temperature is higher than 900°C, the performance adjustment effect in the cold rolling disappears.
  • Steel pieces were produced by melting steels each having a chemical composition shown in Table 1. The steel pieces were heated and roughly hot-rolled, and then subjected to finish rolling under conditions shown in Tables 2-1 and 2-2.
  • SRT °C
  • L1 represents a shape ratio in a pass immediately before a final pass
  • L2 represents a shape ratio in the final pass
  • FT °C
  • CT represents a coiling temperature.
  • an area ratio of martensite ( ⁇ '), an average grain size of austenite grains ( ⁇ ), an area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation, and an X-ray random intensity ratio of the ⁇ 110 ⁇ 112> orientation were measured.
  • the average grain size of the austenite grains and the area ratio of the martensite in the surface layer portion were measured by the following methods. First, a plane which was parallel to a steel sheet surface at a position at a depth of 1/10 of the sheet thickness in the sheet thickness direction from the steel sheet surface and had an area of 500 ⁇ m ⁇ 500 ⁇ m was subjected to EBSD measurement. Among regions discriminated to have an fcc structure, a region surrounded by a boundary with an orientation difference of 15° or greater was regarded as one crystal grain, and an average area S per crystal grain was calculated from the number of crystal grains contained in the predetermined area. From the average area, an average grain size D of the austenite grains was calculated by Expression (iii).
  • a region that was not discriminated to have an fcc structure that is, a region having a bcc crystal structure, or a region where the measurement was not possible due to high strain (a linear region such as a grain boundary was excluded) was regarded as martensite, and the area ratio thereof was obtained.
  • the area ratio of the martensite ( ⁇ '-area ratio) and the average grain size of the austenite grains ( ⁇ -grain size) each are represented by an average value after final annealing.
  • the area ratio ( ⁇ -area ratio of ⁇ 110 ⁇ plane) of austenite grains having the ⁇ 110 ⁇ plane orientation in the surface layer portion was measured as follows.
  • a region having an area of 500 ⁇ m ⁇ 500 ⁇ m in a plane which was parallel to a steel sheet surface as with the above was subjected to EBSD measurement.
  • a region having a fcc crystal structure and surrounded by a grain boundary of 15° or greater was regarded as an austenite grain, and among the grains, grains having a crystal orientation in which the ⁇ 110> axis had an angle difference of 0° to 15° with respect to a vector perpendicular to the surface of the steel sheet were defined as austenite grains having the ⁇ 110 ⁇ plane orientation.
  • the total area of the grains having the ⁇ 110 ⁇ plane orientation was divided by the measurement area and multiplied by 100, and the resulting value was defined as the area ratio of austenite grains having the ⁇ 110 ⁇ plane orientation.
  • the X-ray random intensity ratio ( ⁇ 110 ⁇ 112> X-ray random intensity ratio) of the ⁇ 110 ⁇ 112> orientation in the surface layer portion of the steel sheet was measured as follows.
  • the polishability of the austenitic stainless steel sheet was evaluated.
  • the polishability was evaluated as follows.
  • a test piece having a length of 100 mm, a width of 150 mm, and a thickness of 0.2 mm was collected from the austenitic stainless steel sheet, and then the collected test piece was polished under conditions of a contact pressure of 8.0 N/cm 2 , #400 alumina abrasive grains, a rotation speed of 300 rpm, and a polishing time of 10 seconds. Then, roughness Ra after polishing was measured according to JIS B 0601: 2013. In this example, the austenitic stainless steel sheet was judged to have good polishability in a case where the roughness Ra after polishing was 0.050 ⁇ m or less.
  • the diffusion bondability of the austenitic stainless steel sheet was evaluated as follows.
  • the diffusion bonding portion was evaluated by a transmission method. A position where the transmission pulse height was 25% or greater was judged as a diffusion bonding portion, and a position where the transmission pulse height was less than 25% was judged as a cavity portion to calculate the area ratio of the diffusion bonding portion.
  • the austenitic stainless steel sheet was judged to have good diffusion bondability in a case where the area ratio of the diffusion bonding portion was 70% or greater.
  • the transmission method is a method of grasping a size and a degree of a defect inside a measurement target from the degree to which ultrasonic waves are attenuated due to the scattering occurring by the defect in the measurement target in the process in which the ultrasonic waves transmitted from a probe for transmission pass through the measurement target and are received by a probe for reception.
  • the height of the transmitted pulse received after passing through the measurement target is measured as compared to that of the pulse of the transmitted ultrasonic waves. It is evaluated that the closer the height of the transmitted pulse received is to 100%, the fewer defects are in the measurement target and the better the diffusion bonding is achieved, and the lower the height of the transmitted pulse received is, the poorer the bonding is.
  • tap water was used as a contact medium.
  • a 0.4 mm thick austenitic stainless steel sheet desirably an austenitic stainless steel sheet having a chemical composition range according to the invention was used as a test piece for calibration, and the transmitted pulse was measured at a pitch of 0.2 mm for each of the vertical and horizontal directions of the measurement target after adjustment of the oscillator diameter of the ultrasonic probe to 0.5 mm.
  • test Nos. 18 to 21, 41, and 43 are comparative examples using a steel whose chemical composition is outside the specified range of the invention.
  • Test No. 18 since the C content was too large, the texture was randomized, and the ⁇ 110 ⁇ plane orientation did not sufficiently develop.
  • Test No. 19 since the Cr content was too large, cracks occurred during hot rolling, and the test was stopped.
  • Test Nos. 20, 21, and 43 since the Md30 value was too high and the amount of martensite was excessive, the polishability was reduced.
  • Test Nos. 4, 6, 8, 10, 12, 14, 16, 23, 25, 27, 29, 30, 32, 34, 36, and 38 are all comparative examples in which although their chemical compositions satisfy the provisions of the invention, the production conditions are outside the preferable range of the invention, and as a result, the desired texture was not obtained.
  • Steel pieces were produced by melting steels each having a chemical composition (A, I, F2, I2) shown in Table 1.
  • the steel pieces were heated and roughly hot-rolled, and then subjected to finish rolling under conditions shown in Table 3.
  • pickling was performed.
  • Intermediate cold rolling was performed with a reduction of 55%, and intermediate annealing was performed to hold the resulting sheets at 1,120°C for 20 minutes.
  • final cold rolling was performed thereon.
  • annealing was performed to increase the temperature to an end-point temperature represented by AT (°C).
  • temper rolling was performed with a rolling reduction shown in Table 3, and stress relief annealing was performed. [Table 3] Test No.
  • an austenitic stainless steel sheet according to the invention is suitable as a material for a member such as a housing of an electronic device which requires high surface glossiness.

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JP2018189321A (ja) 2017-05-09 2018-11-29 トヨタホーム株式会社 ヒートポンプシステム

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EP4361305A4 (de) * 2021-08-18 2024-10-09 Posco Co Ltd Austenitischer edelstahl und verfahren zur herstellung davon
WO2024135988A1 (ko) * 2022-12-20 2024-06-27 주식회사 포스코 오스테나이트계 스테인리스강 및 그 제조방법

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EP3862452A4 (de) 2022-06-29
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