EP3844329A1 - Fibres polymères bicomposants - Google Patents
Fibres polymères bicomposantsInfo
- Publication number
- EP3844329A1 EP3844329A1 EP19759265.2A EP19759265A EP3844329A1 EP 3844329 A1 EP3844329 A1 EP 3844329A1 EP 19759265 A EP19759265 A EP 19759265A EP 3844329 A1 EP3844329 A1 EP 3844329A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- propylene
- sheath
- core
- based elastomer
- derived units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 121
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 173
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 171
- 229920001971 elastomer Polymers 0.000 claims abstract description 139
- 239000000806 elastomer Substances 0.000 claims abstract description 139
- 239000000155 melt Substances 0.000 claims abstract description 48
- 229920001577 copolymer Polymers 0.000 claims abstract description 43
- 239000004711 α-olefin Substances 0.000 claims abstract description 23
- 230000004927 fusion Effects 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims description 69
- 229920000642 polymer Polymers 0.000 claims description 66
- 238000000034 method Methods 0.000 claims description 48
- 230000008569 process Effects 0.000 claims description 34
- 239000004745 nonwoven fabric Substances 0.000 claims description 33
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 29
- 239000005977 Ethylene Substances 0.000 claims description 28
- 229920005594 polymer fiber Polymers 0.000 claims description 4
- -1 polypropylene Polymers 0.000 description 79
- 229910052799 carbon Inorganic materials 0.000 description 34
- 239000004743 Polypropylene Substances 0.000 description 31
- 238000000113 differential scanning calorimetry Methods 0.000 description 31
- 229920001155 polypropylene Polymers 0.000 description 31
- 239000004744 fabric Substances 0.000 description 26
- 239000003054 catalyst Substances 0.000 description 25
- 239000000306 component Substances 0.000 description 21
- 239000012190 activator Substances 0.000 description 19
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- 239000000523 sample Substances 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000009987 spinning Methods 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 229920005629 polypropylene homopolymer Polymers 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 229910052723 transition metal Inorganic materials 0.000 description 6
- 150000003623 transition metal compounds Chemical class 0.000 description 6
- 150000003624 transition metals Chemical class 0.000 description 6
- 229910052727 yttrium Inorganic materials 0.000 description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 5
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000012018 catalyst precursor Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 239000012968 metallocene catalyst Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 206010021639 Incontinence Diseases 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229920000034 Plastomer Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 229920000553 poly(phenylenevinylene) Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000767 polyaniline Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 229920000417 polynaphthalene Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 229920000123 polythiophene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012748 slip agent Substances 0.000 description 2
- 229920006132 styrene block copolymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000002076 thermal analysis method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- ONUFSRWQCKNVSL-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(2,3,4,5,6-pentafluorophenyl)benzene Chemical group FC1=C(F)C(F)=C(F)C(F)=C1C1=C(F)C(F)=C(F)C(F)=C1F ONUFSRWQCKNVSL-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 1
- AVFZOVWCLRSYKC-UHFFFAOYSA-N 1-methylpyrrolidine Chemical compound CN1CCCC1 AVFZOVWCLRSYKC-UHFFFAOYSA-N 0.000 description 1
- NMXLXQGHBSPIDR-UHFFFAOYSA-N 2-(2-methylpropyl)oxaluminane Chemical compound CC(C)C[Al]1CCCCO1 NMXLXQGHBSPIDR-UHFFFAOYSA-N 0.000 description 1
- YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 description 1
- WEPNJTDVIIKRIK-UHFFFAOYSA-N 2-methylhept-2-ene Chemical compound CCCCC=C(C)C WEPNJTDVIIKRIK-UHFFFAOYSA-N 0.000 description 1
- BWEKDYGHDCHWEN-UHFFFAOYSA-N 2-methylhex-2-ene Chemical compound CCCC=C(C)C BWEKDYGHDCHWEN-UHFFFAOYSA-N 0.000 description 1
- UIIMVYYDGLHIAO-UHFFFAOYSA-N 2-methylnon-2-ene Chemical compound CCCCCCC=C(C)C UIIMVYYDGLHIAO-UHFFFAOYSA-N 0.000 description 1
- KNIRLWRQSSLZCZ-UHFFFAOYSA-N 3-ethyloct-3-ene Chemical compound CCCCC=C(CC)CC KNIRLWRQSSLZCZ-UHFFFAOYSA-N 0.000 description 1
- FHHSSXNRVNXTBG-UHFFFAOYSA-N 3-methylhex-3-ene Chemical compound CCC=C(C)CC FHHSSXNRVNXTBG-UHFFFAOYSA-N 0.000 description 1
- YCTDZYMMFQCTEO-UHFFFAOYSA-N 3-octene Chemical compound CCCCC=CCC YCTDZYMMFQCTEO-UHFFFAOYSA-N 0.000 description 1
- KLCNJIQZXOQYTE-UHFFFAOYSA-N 4,4-dimethylpent-1-ene Chemical compound CC(C)(C)CC=C KLCNJIQZXOQYTE-UHFFFAOYSA-N 0.000 description 1
- KZJIOVQKSAOPOP-UHFFFAOYSA-N 5,5-dimethylhex-1-ene Chemical compound CC(C)(C)CCC=C KZJIOVQKSAOPOP-UHFFFAOYSA-N 0.000 description 1
- BSJOLASGNWRVEH-UHFFFAOYSA-N 7,7-dimethyloct-1-ene Chemical compound CC(C)(C)CCCCC=C BSJOLASGNWRVEH-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- GOSUOOSEFYTBLI-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)[Zr+2](C1=C(CC=2C=C3C(=CC1=2)C(CCC3(C)C)(C)C)C)C1=C(CC=2C=C3C(=CC1=2)C(CCC3(C)C)(C)C)C Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)[Zr+2](C1=C(CC=2C=C3C(=CC1=2)C(CCC3(C)C)(C)C)C)C1=C(CC=2C=C3C(=CC1=2)C(CCC3(C)C)(C)C)C GOSUOOSEFYTBLI-UHFFFAOYSA-L 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000005418 aryl aryl group Chemical group 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- YKNMBTZOEVIJCM-UHFFFAOYSA-N dec-2-ene Chemical compound CCCCCCCC=CC YKNMBTZOEVIJCM-UHFFFAOYSA-N 0.000 description 1
- GVRWIAHBVAYKIZ-UHFFFAOYSA-N dec-3-ene Chemical compound CCCCCCC=CCC GVRWIAHBVAYKIZ-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 125000006492 halo alkyl aryl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 1
- WZHKDGJSXCTSCK-UHFFFAOYSA-N hept-3-ene Chemical compound CCCC=CCC WZHKDGJSXCTSCK-UHFFFAOYSA-N 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- RYPKRALMXUUNKS-UHFFFAOYSA-N hex-2-ene Chemical compound CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
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- 239000012535 impurity Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
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- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000006574 non-aromatic ring group Chemical group 0.000 description 1
- IRUCBBFNLDIMIK-UHFFFAOYSA-N oct-4-ene Chemical compound CCCC=CCCC IRUCBBFNLDIMIK-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000005062 perfluorophenyl group Chemical group FC1=C(C(=C(C(=C1F)F)F)F)* 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005630 polypropylene random copolymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000001370 static light scattering Methods 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 229920001576 syndiotactic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- ZNEOHLHCKGUAEB-UHFFFAOYSA-N trimethylphenylammonium Chemical compound C[N+](C)(C)C1=CC=CC=C1 ZNEOHLHCKGUAEB-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/30—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising olefins as the major constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
Definitions
- Embodiments of the present invention are directed toward bicomponent polymer fibers having a core and a sheath, wherein the sheath includes a propylene-based elastomer.
- Air-through bonded nonwovens are fabrics that are bonded through heat, typically hot air, using processes that are also referred to as air-through bonding. Air-through bonded nonwovens, which may also be referred to as air-through nonwovens, offer several advantages including bulkiness, softness, and good hand feel. These nonwoven fabrics are also advantageous because they lack chemical bonding agents. As a result, air-through nonwovens are useful in the manufacture of a wide range of articles, especially disposable hygiene goods such as diapers, sanitary napkins, training pants, and adult incontinence products.
- Air- through nonwovens are conventionally produced from multilayered fibers.
- these multilayered fibers include a core of a relatively high melt polymer encased within a polymer having a lower melt temperature (i.e. a sheath). Hot air is applied to at least partially melt the sheath and thereby bond or heat set the fibers.
- the nonwoven fabric to which the air-through bonding is applied can be formed by a variety of technologies including carding, spunbonding, airlaying, thermal bonding, wetlaying and spunlacing. Conventionally, many air-through bonded nonwoven fabrics are prepared from carded multilayer staple fiber webs or spunmelt nonwoven webs of multilayered fibers.
- Multilayered fibers which are also referred to as multicomponent fibers, are often prepared by using a spinning process in which separate polymer streams are fed to a single die or spinneret in order to form fibers having two (or more) polymer phases. While many structural variations of multicomponent fibers exist, sheath-core, or core- sheath, multicomponent fibers are often used in the manufacture of air-through nonwoven fabrics, especially those used in the manufacture of disposable hygiene products. In this regard, it is common to employ polypropylene or polyethylene terephthalate within the core, and polyethylene, which has a lower melt temperature, within the sheath. Polypropylene and polyethylene terephthalate have higher stiffness and melt temperatures, which ensure that the fiber bulkiness can be maintained during the air-through bonding process.
- One or more embodiments of the present invention provides a bicomponent fiber comprising a sheath, where the sheath includes a propylene-based elastomer, said propylene- based elastomer including propylene-derived units and from about 3.0 to about 15 wt% alpha- olefin-derived units other than propylene-derived units, based upon the entire weight of the copolymer, said propylene-based elastomer having a triad tacticity of greater than 75%, and a heat of fusion, as determined by DSC, of less than 75 J/g; and a core, where the melt temperature of the core, as determined by DSC, is at least 5% greater than the melt temperature of the sheath.
- One or more embodiments of the present invention further provides a nonwoven fabric comprising a bicomponent fiber including a core and sheath, where the sheath includes a propylene-based elastomer that includes propylene-derived units and from about 3.0 to about 15 wt% alpha-olefin-derived units, based upon the entire weight of the copolymer, has a triad tacticity of greater than 75%, and a heat of fusion, as determined by DSC, of from about 30 to about 75 J/g.
- One or more embodiments of the present invention further provides a process for forming bicomponent polymer fibers, the process comprising extruding first and second polymeric compositions to thereby form a sheath-core structure, where the first polymeric composition forms the sheath and the second polymeric composition forms the core, where the first polymeric composition includes a propylene-based polymer and from about 3 to about 15 wt % alpha-olefin-derived units, has a triad tacticity greater than about 75%, and a heat of fusion less than about 75 J/g.
- One or more embodiments of the present invention further provides a process for forming an air-through nonwoven fabric, the process comprising (i) providing bicomponent fiber including a sheath, where the sheath includes a propylene-based elastomer, said propylene-based elastomer including propylene-derived units and from about 3.0 to about 15 wt% alpha-olefin- derived units other than propylene-derived units, based upon the entire weight of the copolymer, said propylene -based elastomer having a triad tacticity of greater than 75%, and a heat of fusion, as determined by DSC, of less than 75 J/g, and a core, where the melt temperature of the core, as determined by DSC, is at least 5% greater than the melt temperature of the sheath; (ii) forming fibers into a web of the fibers; and (iii) exposing the web to air having a temperature from 100 C° to 120 C°
- Embodiments of the invention are based, at least in part, on the discovery of bicomponent polymeric fibers having a core and sheath, where the sheath includes a propylene- based elastomer.
- the core includes a polymer having a higher flexural modulus and higher melt temperature than the propylene-based elastomer.
- bicomponent fibers have been produced using polyethylene in the sheath, it has now been discovered that polyethylene gives rise to several disadvantages including gelling during the spinning process, limited temperature windows in which the fabrics can be bonded, limited tensile strength of the bonded fabric, and the inability to recycle the fibers.
- the present invention employs propylene-based elastomer in the sheath, which advantageously provides for less gelling during the spinning process, lower-bonding temperature, higher tensile strength when bonded, and the ability to recycle the fabric.
- propylene-based elastomer in the sheath, which advantageously provides for less gelling during the spinning process, lower-bonding temperature, higher tensile strength when bonded, and the ability to recycle the fabric.
- the lower melt temperature of the propylene-based elastomer the higher tensile strength of the propylene-based elastomer, and the compatibility that exists between the propylene-based elastomer and useful core polymers, especially polypropylene.
- the propylene-based elastomer has been found to offer good hand feel to the finished product. Accordingly, embodiments of the invention are directed toward multicomponent fibers, such as bicomponent fibers, and methods for producing these fibers, where the sheath includes propylene-based elast
- the term “fiber,” which may be used interchangeably with the terms“filament” or“monofilament,” refers to a structure whose length is substantially greater than its diameter or breadth.
- the fibers of the present invention have an average diameter of from about 0.1 to about 250 pm, in other embodiments from about 0.3 to about 150 pm, in other embodiments from about 15 to about 30 pm, and in other embodiments from about 18 to about 30 pm .
- the fibers of the present invention have an aspect ratio of from about 0.5 to about 100 pm, and in other embodiments from about 1 to about 40 pm.
- a“bicomponent fiber” is a multicomponent fiber including two or more polymer domains.
- the bicomponent fibers of the present invention include a first polymer domain forming a sheath and a second polymer domain forming a core of the fiber (i.e. a sheath-core arrangement).
- the core-sheath arrangement of the fibers of the present invention is concentric, which refers to a sheath and core that share the same center, or it may be eccentric, which refers to a sheath and the core that have different centers, or it may be multi-lobal, which refers to a cross-sectional structure that includes three or more lobes with the core being encased by the sheath in each lobe.
- the sheath completely encases the core at cross-sections along the length of the fiber (e.g. the sheath forms a annulus around a circular core).
- the fibers of the present invention may be characterized by the ratio of the average cross-sectional area of the core to the average cross- sectional area of the sheath.
- the ratio of the average cross- sectional area of the core to the average cross-sectional area of the sheath is from about 1:9 to about 9:1, in other embodiments from about 1:5 to about 5:1, and in other embodiments from about 2:1 to about 1:2.
- the bicomponent fibers of the present invention may be characterized by the weight ratio of the sheath polymer to the core polymer.
- the ratio of the weight of the core to the weight of the sheath may be from about 5:95 to about 95:5, in other embodiments from about 10:90 to about 90:10, in other embodiments from about 20:80 to about 80:20, in other embodiments from about 30:70 to about 70:30, and in other embodiments from about 40:60 to about 60:40.
- the sheath and the core may be“mono-constituent,” which refers to the presence of a single polymeric species, or they may be“bi-constituent,” which refers to a blend of two or more distinct polymeric species.
- distinct polymeric species refers to polymers that are compositionally distinct (e.g. different type or amount of polymeric units) or that are structurally distinct (e.g. differ in molecular weight or molecular architecture).
- the fibers of the present invention may be characterized by fiber tenacity, which is the force/denier of a fiber bundle (72-fibers per bundle) and is reported in grams/denier.
- Fiber tenacity as described herein, is measured using a Textechno Statimat M S/N 23523, CRE loaded with a Textechno program FPAM0210E. These Textechno products are commercially available from Textechno Herbert Stein GmbH & Co. located in M5nchengladbach, Germany.
- a fiber bundle is threaded through ceramic guides on the Statimat M into a pneumatic clamp. The gage length for the fiber bundles being tested is 100 mm. Each fiber bundle is pulled at 1270 mm/min until it fails. The force to pull the fiber bundle and the strain of the fiber bundle are recorded until failure occurs.
- the fibers of the present invention have a fiber tenacity of greater than 1.70 g/den, in other embodiments greater than 1.90 g/den, in other embodiments greater than 2.00 g/den, in other embodiments greater than 2.15 g/den, in other embodiments greater than 2.30 g/den, in other embodiments greater than 2.50 g/den, in other embodiments greater than 2.55 g/den, and in other embodiments greater than 2.65 g/den.
- the fibers of the present invention have a fiber tenacity from about 1.70 g/den to about 5.00 g/den, in other embodiments about 2.15 g/den to about 4.50 g/den, and in other embodiments about 2.50 g/den to about 4.00 g/den.
- the sheath of the bicomponent fibers of the present invention is formed from a composition that includes a propylene-based elastomer.
- the sheath is bi-constituent.
- the sheath may include a blend of a propylene-based elastomer and a second polymer that is not a propylene- based elastomer.
- the sheath includes greater than 60 wt%, in other embodiments greater than 80 wt%, and in other embodiments greater than 95 wt% propylene- based elastomer, based upon the entire weight of the sheath.
- the sheath consists essentially of propylene-based elastomer whereby the sheath is devoid of other polymer that would have an appreciable impact on the sheath.
- the sheath consists of propylene-based elastomer.
- the sheath may include first and second propylene- based elastomers. These embodiments may be described with reference to the relative weight of each of the respective propylene-based elastomers. In one or more embodiments, the sheath includes greater than 65 wt%, in other embodiments greater than 70 wt%, and in other embodiments greater than 75 wt% of the first propylene-based copolymer, based upon the total weight of the propylene based elastomer (e.g. the first and second propylene-based elastomers) with the balance including distinct propylene -based elastomer (e.g. the second propylene-based elastomer).
- the sheath includes less than 100 wt%, in other embodiments less than 98 wt%, and in other embodiments less than 90 wt% of the first propylene-based copolymer, based upon the total weight of the propylene based elastomer (e.g. the first and second propylene-based elastomers) with the balance including distinct propylene- based elastomer (e.g. the second propylene -based elastomer).
- the propylene based elastomer e.g. the first and second propylene-based elastomers
- the sheath includes from about 65 to about 100 wt%, in other embodiments from about 70 to about 98 wt%, and in other embodiments from about 75 to about 90 wt% of the first propylene-based copolymer, based upon the total weight of the propylene based elastomer (e.g. the first and second propylene-based elastomers) with the balance including distinct propylene-based elastomer (e.g. the second propylene-based elastomer).
- the propylene based elastomer e.g. the first and second propylene-based elastomers
- the propylene-based elastomers are copolymers including propylene- derived units and alpha-olefin-derived units.
- the propylene -based elastomers are prepared from the polymerization of propylene and at least one alpha-olefin monomer other than propylene, which alpha-olefins include ethylene.
- alpha-olefin monomer other than propylene includes ethylene and C4 (i.e. butene) or higher alpha-olefin.
- the propylene-based elastomers are prepared from the polymerization of propylene and ethylene.
- first and second propylene-based elastomer within the sheath, unless otherwise stated, reference will be made to“first propylene-based elastomer” even for those embodiments that include only one propylene-based elastomer.
- Propylene-based elastomers can be characterized by comonomer content, which as described below, can be determined by 4D GPC analysis.
- the first propylene-based elastomer includes propylene-derived units and greater than 3.0 wt%, in other embodiments greater than 3.5 wt%, in other embodiments greater than 3.8 wt%, and in other embodiments greater than 4.0 wt% ethylene-derived units, based upon the entire weight of the copolymer (i.e. the total weight of the propylene-derived and ethylene-derived units).
- the first propylene-based elastomer includes propylene-derived units and less than 15 wt%, in other embodiments less than 10 wt%, in other embodiments less than 8 wt%, and in other embodiments less than 6 wt% ethylene-derived units, based upon the entire weight of the copolymer.
- the first propylene-based elastomer includes propylene-derived units and from about 3.0 to about 15 wt%, in other embodiments from about 3.5 to about 10 wt%, in other embodiments from about 3.8 to about 8 wt%, and in other embodiments from about 4.0 to about 6 wt% ethylene-derived units, based upon the entire weight of the copolymer.
- the amount of the alpha-olefin- derived units can be determined by GPC analysis as described herein.
- Propylene-based elastomers can be characterized by a melting point (Tm), which can be determined by differential scanning calorimetry (DSC), where the maximum of the highest temperature peak is considered to be the melting point of the polymer.
- Tm melting point
- DSC differential scanning calorimetry
- A“peak” in this context is defined as a change in the general slope of the DSC curve (heat flow versus temperature) from positive to negative, forming a maximum without a shift in the baseline where the DSC curve is plotted so that an endothermic reaction would be shown with a positive peak.
- the sample is heated at 10 °C/min to attain a final temperature of about 200 °C.
- the sample is kept at 200 °C for 5 minutes and a second cool-heat cycle is performed. Events from both cycles are recorded.
- the thermal output is recorded as the area under the melting peak of the sample, which typically occurs between about 0 and about 200 °C, is measured in Joules, and is a measure of the Hf of the polymer.
- the following procedure can be employed. About 0.5 grams of polymer is weighed out and pressed to a thickness of about 15-20 mils (about 381-508 microns) at about 140 °C -150 °C, using a“DSC mold” and MylarTM as a backing sheet.
- the pressed pad is allowed to cool to ambient temperature by hanging in air (the Mylar was not removed).
- the pressed pad is annealed at room temperature (about 23 °C - 25 °C) for about 8 days.
- room temperature about 23 °C - 25 °C
- an about 15-20 mg disc is removed from the pressed pad using a punch die and placed in a 10 microliter aluminum sample pan.
- the sample is placed in a differential scanning calorimeter (Perkin Elmer Pyris 1 Thermal Analysis System) and cooled to about -100 °C.
- the sample is heated at about 10 °C/min to attain a final temperature of about 165 °C.
- the thermal output recorded as the area under the melting peak of the sample, is a measure of the heat of fusion and can be expressed in Joules per gram (J/g) of polymer and automatically calculated by the Perkin Elmer System.
- J/g Joules per gram
- the melting profile shows two (2) maxima, the maxima at the highest temperature was taken as the melting point within the range of melting of the sample relative to a baseline measurement for the increasing heat capacity of the polymer as a function of temperature.
- the melt temperature (Tm) of the first propylene-based elastomer is less than 120 °C, in other embodiments less than 115 °C, in other embodiments less than 110 °C, and in other embodiments less than 105 °C. In one or more embodiments, the Tm of the first propylene-based elastomer is from about 85 to about 120 °C, in other embodiments from about 90 to about 115 °C, and in other embodiments from about 95 to about 110 °C.
- Propylene-based elastomers can be characterized by a heat of fusion (Hf), which can be determined by DSC.
- Hf heat of fusion
- the first propylene-based elastomer may be characterized by its heat of fusion (Hf), as determined by DSC of greater than 0.5 J/g, in other embodiments greater than 3.0 J/g, in other embodiments greater than 6.0 J/g, in other embodiments greater than 10 J/g, in other embodiments greater than 15 J/g, in other embodiments greater than 20 J/g, and in other embodiments greater than 30 J/g.
- Hf heat of fusion
- the first propylene-based elastomer may be characterized by an Hf of less than about 80 J/g, in other embodiments less than 75 J/g, in other embodiments less than 70 J/g, in other embodiments less than 65 J/g, and in other embodiments less than 60 J/g. In one or more embodiments, the first propylene-based elastomer has an Hf of from about 30 to about 75 J/g, in other embodiments from about 6 to about 70 J/g, and in other embodiments from about 10 to about 60 J/g.
- Propylene-based elastomers can be characterized by a triad tacticity of three propylene-derived units, as measured by 13 C NMR according to the methods described in U.S. Patent Application Publication No. 2004/0236042.
- the first propylene-based elastomer has a triad tacticity of greater than 75%, in other embodiments greater than 80%, in other embodiments greater than 85%, in other embodiments greater than 90%, in other embodiments greater than 92%, in other embodiments greater than 95%, and in other embodiments greater than 97%.
- the triad tacticity of the first propylene-based elastomer may range from about 75 to about 99%, in other embodiments from about 80 to about 99%, in other embodiments from about 85 to about 99%, in other embodiments from about 90 to about 99%, in other embodiments from about 90 to about 97%, and in other embodiments from about 80 to about 97%.
- Propylene-based elastomers can be characterized by a tacticity index (m/r), which is determined by 13 C nuclear magnetic resonance (“NMR”), where the tacticity index (m/r) is calculated as defined by H. N. Cheng in 17 MACROMOLECULES, pp. 1950-1955 (1984).
- the designation“m” or“r” describes the stereochemistry of pairs of contiguous propylene groups, where“m” refers to meso and“r” refers to racemic.
- an m/r ratio of 1.0 generally describes a syndiotactic polymer
- an m/r ratio of 2.0 generally describes an atactic material.
- An isotactic material theoretically may have a ratio approaching infinity, and many by-product atactic polymers have sufficient isotactic content to result in ratios of greater than 50.
- the first propylene-based elastomer may have a tacticity index (m/r) of greater than 4 or in other embodiments greater than 6. In these or other embodiments, the first propylene-based elastomer may have a tacticity index (m/r) of less than 12, in other embodiments less than 10, or in other embodiments less than 8.
- Propylene-based elastomers can be characterized by crystallinity, which may be determined by DSC procedures, where the Hf of a sample of the propylene-based elastomer is divided by the Hf of a 100% crystalline polymer, which is assumed to be 189 joules/gram for isotactic polypropylene or 350 joules/gram for polyethylene.
- the first propylene-based elastomer may have a crystallinity of from about 0.5% to about 40%, in other embodiments from about 1% to about 30%, and in other embodiments from about 5% to about 25%.
- Propylene-based elastomers can be characterized by density, which is measured at room temperature according to ASTM D-792.
- the first propylene-based elastomer may have a density of from about 0.85 g/cm 3 to about 0.92 g/cm 3 , in other embodiments from about 0.86 g/cm 3 to about 0.90 g/cm 3 , and in other embodiments from about 0.86 g/cm 3 to about 0.89 g/cm 3 .
- Propylene-based elastomers can be characterized by melt flow rate (MFR), which is measured according to ASTM D-1238, 2.16 kg weight @ 230 °C.
- the first propylene-based elastomer may have an MFR of greater than 6 g/lO min, in other embodiments greater than 8 g/lO min, in other embodiments greater than 10 g/lO min, in other embodiments greater than about 12 g/lO min, and in other embodiments greater than 15 g/lO min.
- the first propylene-based polymer may have an MFR of less than 55 g/lO min, in other embodiments less than about 50 g/lO min, in other embodiments less than about 45 g/lO min, in other embodiments less than about 35 g/lO min, and in other embodiments less than about 30 g/lO min.
- the first propylene-based polymer may have an MFR from about 6 to about 55 g/lO min, in other embodiments from about 8 to about 50 g/lO min, and other embodiments from about 10 to about 45 g/lO min.
- Propylene-based elastomers may be characterized by molecular weight moments and branching index (g').
- the distribution and the moments of molecular weight (Mp, Mw, Mn, Mz, Mw/Mn, etc.), the comonomer content (C2, C3, C6, etc.), and the branching index (g') are determined by using a high temperature Gel Permeation Chromatography (Polymer Char GPC-IR) equipped with a multiple-channel band-filter based Infrared detector IR5, an 18- angle light scattering detector and a viscometer (which may be referred to as 4D GPC analysis). Three Agilent PLgel l0-pm Mixed-B LS columns are used to provide polymer separation.
- TCB Aldrich reagent grade 1,2, 4-trichlorobenzene
- BHT butylated hydroxytoluene
- the TCB mixture is filtered through a 0.1- mih Teflon filter and degassed with an online degasser before entering the GPC instrument.
- the nominal flow rate is 1.0 ml/min and the nominal injection volume is 200 mH
- the whole system including transfer lines, columns, and detectors are contained in an oven maintained at 145 °C. Given amount of polymer sample is weighed and sealed in a standard vial with 80- pL flow marker (Heptane) added to it.
- polymer After loading the vial in the autosampler, polymer is automatically dissolved in the instrument with 8 ml added TCB solvent. The polymer is dissolved at 160 °C with continuous shaking for about 1 hour for most polyethylene samples or 2 hours for polypropylene samples.
- the TCB densities used in concentration calculation are 1.463 g/ml at room temperature and 1.284 g/ml at 145 °C.
- the sample solution concentration is from 0.2 to 2.0 mg/ml, with lower concentrations being used for higher molecular weight samples.
- the mass recovery is calculated from the ratio of the integrated area of the concentration chromatography over elution volume and the injection mass which is equal to the pre-determined concentration multiplied by injection loop volume.
- the conventional molecular weight (IR MW) is determined by combining universal calibration relationship with the column calibration which is performed with a series of monodispersed polystyrene (PS) standards ranging from 700 to 10M gm/mole.
- PS monodispersed polystyrene
- variables with subscript“PS” stand for polystyrene while those without a subscript are for the test samples.
- a is 0.695 and K is 0.000579*(l- 0.0087*w2b+0.0000l8*(w2b)
- a 2 for ethylene-butene copolymer where w2b is a bulk weight percent of butene comonomer
- a is 0.695 and K is 0.000579*(l-0.0075*w2b) for ethylene- hexene copolymer where w2b is a bulk weight percent of hexene comonomer
- a is 0.695 and K is 0.000579*(l-0.0077*w2b) for ethylene-octene copolymer where w2b is
- the comonomer composition is determined by the ratio of the IR5 detector intensity corresponding to CH 2 and CH 3 channel calibrated with a series of PE and PP homo/copolymer standards whose nominal value are predetermined by NMR or FTIR. In particular, this provides the methyls per 1000 total carbons (CH3/IOOOTC) as a function of molecular weight.
- the short- chain branch (SCB) content per 1000TC (SCB/1000TC) is then computed as a function of molecular weight by applying a chain-end correction to the CH3/IOOOTC function, assuming each chain to be linear and terminated by a methyl group at each end.
- the LS detector is the 18-angle Wyatt Technology High Temperature DAWN HELEOSII.
- the LS molecular weight (M) at each point in the chromatogram is determined by analyzing the LS output using the Zimm model for static light scattering ⁇ Light Scattering from Polymer Solutions ; Huglin, M. B., Ed.; Academic Press, 1972.):
- AR(9) is the measured excess Rayleigh scattering intensity at scattering angle Q
- c is the polymer concentration determined from the IR5 analysis
- A2 is the second virial coefficient
- R(q) is the form factor for a monodisperse random coil
- K Q is the optical constant for the system:
- (dn/dc) is the refractive index increment for the system.
- the g' index is defined as: where r
- i KW v “, K and a are measured values for linear polymers and should be obtained on the same instrument as the one used for the g' index measurement.
- the first propylene-based elastomer can have a weight average molecular weight (Mw) of from about 100,000 to about 500,000 g/mol, in other embodiments from about 125,000 to about 400,000 g/mol, in other embodiments from about
- the first propylene-based elastomer can have a number average molecular weight (Mn) of from about 50,000 to about 250,000 g/mol, in other embodiments from about 60,000 to about 200,000 g/mol, in other embodiments from about
- the first propylene-based elastomer hay have a molecular weight distribution (Mw/Mn) of from about 0.5 to about 5.0, in other embodiments from about 1.0 to about 4.0, in other embodiments from about 1.5 to about 3.5, and in other embodiments from about 2.0 to about 3.0.
- Mw/Mn molecular weight distribution
- the first propylene-based elastomer may have a g' index value of 0.95 or greater, or at least 0.97, or at least 0.99, wherein g' is measured at the Mw of the polymer using the intrinsic viscosity of isotactic polypropylene as the baseline.
- Propylene-based elastomers may be characterized by a flexural modulus, which may also be referred to as 1% secant modulus, which is determined according to ASTM D-790.
- the flexural modulus of the first propylene-based elastomer is less than 1,000 MPa, in other embodiments less than 800 MPa, in other embodiments less than 600 MPa, and in other embodiments less than 500 MPa. In these or other embodiments, the flexural modulus of the first propylene-based elastomer is greater than 100 MPa, in other embodiments greater than 200 MPa, and in other embodiments greater than 300 MPa. In one or more embodiments, the flexural modulus of the first propylene-based elastomer is from about 100 to 1,000 MPa, in other embodiments from about 200 to 800 MPa, and in other embodiments from about 300 to 600 MPa.
- the sheath includes a second propylene- based elastomer, which elastomer may also be referred to as flowability modifier.
- this second propylene-based elastomer is characterized by having a lower molecular weight, lower viscosity, and/or a higher melt flow rate than that first propylene-based elastomer, and as a result, the composition for forming the sheath has an overall lower melt temperature and thereby the extruding conditions relative to the sheath are less energy intensive.
- the second propylene-based elastomer can be characterized as set forth above with respect to the first propylene-based elastomer.
- the second propylene-based elastomer may have a melt flow rate (MFR), as measured according to ASTM D-1238, 2.16 kg weight @ 230 °C, of greater than 6 g/10 min, in other embodiments greater than 12 g/10 min, in other embodiments greater than 20 g/10 min, in other embodiments greater than 30 g/10 min, and in other embodiments greater than 35 g/10 min.
- MFR melt flow rate
- the second propylene-based polymer may have an MFR of less than 80 g/lO min, in other embodiments less than 70 g/lO min, in other embodiments less than 60 g/lO min, in other embodiments less than 50 g/lO min, and in other embodiments less than 40 g/lO min. In one or more embodiments, the second propylene-based polymer may have an MFR from about 6 to about 80 g/lO min, in other embodiments from about 12 to about 70 g/lO min, and other embodiments from about 20 to about 60 g/lO min.
- the second propylene-based copolymer can have a weight average molecular weight (Mw) of from about 10,000 to about 99,000 g/mol, in other embodiments from about 12,000 to about 80,000 g/mol, in other embodiments from about 15,000 to about 50,000 g/mol, and in other embodiments from about 20,000 to about 40,000 g/mol.
- Mw weight average molecular weight
- the second propylene-based copolymer can have a number average molecular weight (Mn) of from about 2,500 to about 49,000 g/mol, in other embodiments from about 5,000 to about 40,000 g/mol, in other embodiments from about 7,500 to about 25,000 g/mol, and in other embodiments from about 10,000 to about 20,000 g/mol.
- the second propylene-based elastomer hay have a molecular weight distribution (Mw/Mn) of from about 0.5 to about 5.0, in other embodiments from about 1.0 to about 4.0, in other embodiments from about 1.5 to about 3.5, and in other embodiments from about 2.0 to about 3.0.
- the second propylene-based elastomer may be characterized by its heat of fusion (Hf), as determined by DSC of greater than 0.5 J/g, in other embodiments greater than 1.0 J/g, in other embodiments greater than 1.5 J/g, in other embodiments greater than 3.0 J/g, in other embodiments greater than 4.0 J/g, in other embodiments greater than 6.0 J/g, and in other embodiments greater than 10 J/g.
- Hf heat of fusion
- the second propylene -based elastomer may be characterized by an Hf of less than 65 J/g, in other embodiments less than 60 J/g, in other embodiments less than 55 J/g, in other embodiments less than 50 J/g, in other embodiments less than 45 J/g, and in other embodiments less than 40 J/g.
- the second propylene -based elastomer has an Hf of from about 0.5 to about 65 J/g, in other embodiments from about 1.5 to about 55 J/g, and in other embodiments from about 3.0 to about 45 J/g.
- the Tm of the second propylene-based elastomer (as determined by DSC) is less than 120 °C, in other embodiments less than 115 °C, in other embodiments less than 110 °C, and in other embodiments less than 105 °C. In one or more embodiments, the Tm of the second propylene-based elastomer is from about 85 to about 120 °C, in other embodiments from about 90 to about 115 °C, and in other embodiments from about 95 to about 110 °C.
- the second propylene-based elastomer may be characterized by a flexural modulus, which may also be referred to as 1% secant modulus, which is determined according to ASTM D-790.
- the flexural modulus of the second propylene-based elastomer is less than 800 MPa, in other embodiments less than 600 MPa, in other embodiments less than 400 MPa, and in other embodiments less than 300 MPa.
- the flexural modulus of the second propylene-based elastomer is greater than 50 MPa, in other embodiments greater than 100 MPa, in other embodiments greater than 150 MPa, and in other embodiments greater than 200 MPa.
- the flexural modulus of the second propylene-based elastomer is from about 50 to 800 MPa, in other embodiments from about 100 to 600 MPa, and in other embodiments from about 150 to 400 MPa.
- Embodiments of the invention can be described with reference to the overall characteristics of the sheath composition, which as explained above may include a single polymeric species or multiple polymeric species.
- the sheath composition may be characterized by a flexural modulus, which may also be referred to as 1% secant modulus, which is determined according to ASTM D-790.
- the flexural modulus of the sheath composition is less than 1,000 MPa, in other embodiments less than 800 MPa, in other embodiments less than 600 MPa, and in other embodiments less than 500 MPa.
- the flexural modulus of the sheath composition is greater than 100 MPa, in other embodiments greater than 200 MPa, and in other embodiments greater than 300 MPa.
- the flexural modulus of the sheath composition is from about 100 to 1,000 MPa, in other embodiments from about 200 to 800 MPa, and in other embodiments from about 300 to 600 MPa.
- the sheath composition may be characterized by a melt temperature (Tm) as determined by DSC.
- Tm melt temperature
- the sheath composition may have a Tm of less than 120 °C, in other embodiments less than 115 °C, in other embodiments less than 110 °C, and in other embodiments less than 105 °C.
- the Tm of the sheath composition is from about 85 to about 120 °C, in other embodiments from about 90 to about 115 °C, and in other embodiments from about 95 to about 110 °C.
- the sheath composition may be characterized by melt flow rate (MFR).
- the sheath composition may have a melt flow rate (MFR), as measured according to ASTM D-1238, 2.16 kg weight @ 230 °C, of greater than 15 g/lO min, in other embodiments greater than 20 g/lO min, in other embodiments greater than 30 g/lO min, and in other embodiments greater than 35 g/lO min.
- MFR melt flow rate
- the sheath composition may have an MFR of less than 60 g/lO min, in other embodiments less than 50 g/lO min, in other embodiments less than 45 g/lO min, and in other embodiments less than 40 g/lO min.
- the sheath composition may have an MFR from about 15 to about 60 g/lO min, in other embodiments from about 20 to about 50 g/lO min, and other embodiments from about 30 to about 40 g/lO min.
- the sheath composition may be characterized by total ethylene-derived units (which may be included in one or more polymeric species), where the amount of ethylene-derived units is be determined by GPC analysis as described herein.
- the sheath composition includes greater than 3.0 wt%, in other embodiments greater than 3.5 wt%, in other embodiments greater than 3.8 wt%, and in other embodiments greater than 4.0 wt% ethylene- derived units, based upon the entire weight of the polymeric content of the sheath composition.
- the sheath composition includes less than 30 wt%, in other embodiments less than 25 wt%, in other embodiments less than 20 wt%, in other embodiments less than 15 wt%, in other embodiments less than 12 wt%, in other embodiments less than 10 wt%, and in other embodiments less than 8 wt% ethylene-derived units, based upon the entire weight of the polymeric content of the sheath composition.
- the sheath composition includes from about 3.0 to about 30 wt%, in other embodiments from about 3.5 to about 25 wt%, in other embodiments from about 3.8 to about 20 wt%, and in other embodiments from about 4.0 to about 15 wt% ethylene-derived units, based upon the entire weight of the polymeric content of the sheath composition.
- the propylene-based elastomer employed in this invention can be prepared by reacting monomers in the presence of a catalyst system described herein at a temperature of from 0 °C to 200 °C for a time of from 1 second to 10 hours.
- homogeneous conditions are used, such as a continuous solution process or a bulk polymerization process with excess monomer used as diluent.
- the continuous process may use some form of agitation to reduce concentration differences in the reactor and maintain steady state polymerization conditions.
- the heat of the polymerization reaction can be removed by cooling of the polymerization feed and allowing the polymerization to heat up to the polymerization, although internal cooling systems may be used.
- Further description of exemplary methods suitable for preparation of the propylene-based elastomer described herein may be found in U.S. Pat. No. 6,881,800, which is incorporated by reference herein for purposes of U.S. practice.
- the triad tacticity and tacticity index of the propylene-based copolymer may be controlled by the catalyst, which influences the stereoregularity of propylene placement, the polymerization temperature, according to which stereoregularity can be reduced by increasing the temperature, and by the type and amount of a comonomer, which tends to reduce the level of longer propylene derived sequences.
- the catalyst may also control the stereoregularity in combination with the comonomer and the polymerization temperature.
- the propylene-based elastomers described herein are prepared using one or more catalyst systems.
- a“catalyst system” includes at least a transition metal compound, also referred to as catalyst precursor, and an activator. Contacting the transition metal compound (catalyst precursor) and the activator in solution upstream of the polymerization reactor or in the polymerization reactor of the disclosed processes yields the catalytically active component (catalyst) of the catalyst system.
- Catalyst systems may include at least one transition metal compound and at least one activator. However, catalyst systems may also comprise more than one transition metal compound in combination with one or more activators. These catalyst systems may optionally include impurity scavengers. Each of these components is described in further detail below.
- the catalyst systems used for producing propylene- based elastomers includes a metallocene compound.
- the metallocene compound is a bridged bisindenyl metallocene having the general formula (In 1 )Y(In 2 )MX 2 , where In 1 and In 2 are identical substituted or unsubstituted indenyl groups bound to M and bridged by Y, Y is a bridging group in which the number of atoms in the direct chain connecting In 1 with In 2 is from 1 to 8 and the direct chain comprises C or Si, and M is a Group 3, 4, 5, or 6 transition metal. In 1 and In 2 may be substituted or unsubstituted.
- the substituents are selected from the group consisting of a halogen atom, Ci to Cio alkyl, Cs to Cis aryl, C 6 to Cisalkylaryl, and N- or P-containing alkyl or aryl.
- exemplary metallocene compounds of this type include, but are not limited to, m- dimethylsilylbis(indenyl)hafniumdimethyl and p-dimethylsilylbis(indenyl)zirconiumdimethyl.
- the metallocene compound may be a bridged bisindenyl metallocene having the general formula (In 1 )Y(In 2 )MX 2 , where In 1 and In 2 are identical 2,4- substituted indenyl groups bound to M and bridged by Y, Y is a bridging group in which the number of atoms in the direct chain connecting In 1 with In 2 is from 1 to 8 and the direct chain comprises C or Si, and M is a Group 3, 4, 5, or 6 transition metal.
- In 1 and In 2 are substituted in the 2 position by a methyl group and in the 4 position by a substituent selected from the group consisting of Cs to Cis aryl, C 6 to C 2 s alkylaryl, and N- or P-containing alkyl or aryl.
- Exemplary metallocene compounds of this type include, but are not limited to, (p-dimethylsilyl)bis(2- methyl-4-(3,'5'-di-tert-butylphenyl)indenyl)zirconiumdimethyl, (p-dimethylsilyl)bis (2-methyl-4- (3,'5'-di-tert-butylphenyl)indenyl)hafniumdimethyl, (p-dimethylsilyl)bis(2-methyl-4- naphthylindenyl)zirconiumdimethyl, (p-dimethylsilyl)bis(2-methyl-4- naphthylindenyl)hafniumdimethyl, (p-dimethylsilyl)bis(2-methyl-4-(N- carbazyl)indenyl)zirconiumdimethyl, and (p-dimethylsilyl)bis(2-methyl-4-(N- carbazyl)indenyl)hafniumdi
- the metallocene compound may correspond to one or more of the formulas disclosed in U.S. Pat. No. 7,601,666.
- These metallocene compounds include, but are not limited to, dimethylsilyl bis(2-(methyl)-5, 5,8,8- tetramethyl-5,6,7,8-tetrahydrobenz(f)indenyl)hafnium dimethyl, diphenylsilyl bis(2-(methyl)- 5,5,8,8-tetramethyl-5,6,7,8-tetrahydrobenz(f)indenyl)hafnium dimethyl, diphenylsilyl bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydrobenz(f)indenyl)hafnium dimethyl, diphenylsilyl bis(2- (methyl)-5,5,8,8-tetramethyl-5,6,7,8-tetrahydrobenz(f)indenyl)zirconium
- the activators of the catalyst systems used to produce propylene-based elastomers comprise a cationic component.
- the cationic component has the formula [R 1 R 2 R 3 AH] + , where A is nitrogen, R 1 and R 2 are together a— (CH 2 ) a— group, where a is 3, 4, 5 or 6 and form, together with the nitrogen atom, a 4-, 5-, 6- or 7-membered non-aromatic ring to which, via adjacent ring carbon atoms, optionally one or more aromatic or heteroaromatic rings may be fused, and R 3 is Ci, C 2 , C 3 , C 4 or C 5 alkyl, or N-methylpyrrolidinium or N-methylpiperidinium.
- the cationic component has the formula [R n AH] + , where A is nitrogen, n is 2 or 3, and all R are identical and are Ci to C 3 alkyl groups, such as for example trimethylammonium, trimethylanilinium, triethylammonium, dimethylanilinium, or dimethylammonium.
- the activators of the catalyst systems used to produce the propylene-based elastomers comprise an anionic component, [Y]-.
- the anionic component is a non-coordinating anion (NCA), having the formula [B(R 4 ) 4 ] _ , where R 4 is an aryl group or a substituted aryl group, of which the one or more substituents are identical or different and are selected from the group consisting of alkyl, aryl, a halogen atom, halogenated aryl, and haloalkylaryl groups.
- NCA non-coordinating anion
- the substituents are perhalogenated aryl groups, or perfluorinated aryl groups, including but not limited to perfluorophenyl, perfluoronaphthyl and perfluorobiphenyl.
- the activator may be N,N- dimethylanilinium-tetra(perfluorophenyl)borate, N,N-dimethylanilinium- tetra(perfluoronaphthyl)borate, N,N-dimethylanilinium-tetrakis(perfluorobiphenyl)borate, N,N- dimethylanilinium-tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, triphenylcarbenium- tetra(perfluorophenyl)borate, triphenylcarbenium-tetra(perfluoronaphthyl)borate, triphenylcarbenium-tetrakis(perfluorobiphenyl)borate, or triphenylcarbenium-tetrakis(3,5- bis(trifluor
- Any catalyst system resulting from any combination of a metallocene compound, a cationic activator component, and an anionic activator component mentioned in the preceding paragraphs shall be considered to be explicitly disclosed herein and may be used in accordance with the present invention in the polymerization of one or more olefin monomers. Also, combinations of two different activators can be used with the same or different metallocene(s).
- Suitable activators also include alominoxanes (or alumoxanes) and aluminum alkyls.
- alumoxane is typically believed to be an oligomeric aluminum compound represented by the general formula (R x — Al— 0) n , which is a cyclic compound, or R x (R x — Al— 0) n AlR x 2 , which is a linear compound.
- R x (R x — Al— 0) n AlR x 2 which is a linear compound.
- alumoxane is believed to be a mixture of the cyclic and linear compounds.
- R x is independently a C1-C20 alkyl radical, for example, methyl, ethyl, propyl, butyl, pentyl, isomers thereof, and the like, and n is an integer from 1-50. In one or more embodiments, R x is methyl and n is at least 4.
- MAO Methyl alumoxane
- modified MAO containing some higher alkyl groups to improve solubility ethyl alumoxane, iso-butyl alumoxane, and the like are useful for the processes disclosed herein.
- catalyst systems may contain, in addition to the transition metal compound and the activator described above, additional activators (co-activators) and/or scavengers.
- a co activator is a compound capable of reacting with the transition metal complex, such that when used in combination with an activator, an active catalyst is formed.
- Co-activators include alumoxanes and aluminum alkyls.
- scavengers may be used to “clean” the reaction of any poisons that would otherwise react with the catalyst and deactivate it.
- Typical aluminum or boron alkyl components useful as scavengers are represented by the general formula R x JZ 2 where J is aluminum or boron, R x is a C1-C20 alkyl radical, for example, methyl, ethyl, propyl, butyl, pentyl, and isomers thereof, and each Z is independently R x or a different univalent anionic ligand such as halogen (Cl, Br, I), alkoxide (OR x ) and the like.
- Exemplary aluminum alkyls include triethylaluminum, diethylaluminum chloride, ethylaluminium dichloride, tri-iso- butylaluminum, tri-n-octylaluminum, tri-n-hexylaluminum, trimethylaluminum and combinations thereof.
- Exemplary boron alkyls include triethylboron. Scavenging compounds may also be alumoxanes and modified alumoxanes including methylalumoxane and modified methylalumoxane.
- the catalyst system used to produce the propylene-based elastomers include a transition metal component which is a bridged bisindenyl metallocene having the general formula (In 1 )Y(In 2 )MX 2 , where In 1 and In 2 are identical substituted or unsubstituted indenyl groups bound to M and bridged by Y, Y is a bridging group in which the number of atoms in the direct chain connecting In 1 with In 2 is from 1 to 8 and the direct chain comprises C or Si, and M is a Group 3, 4, 5, or 6 transition metal. In 1 and In 2 may be substituted or unsubstituted.
- the substituents are selected from the group consisting of a halogen atom, Ci to Cio alkyl, Cs to C 15 aryl, C 6 to C 25 alkylaryl, and N- or P-containing alkyl or aryl.
- the transition metal component used to produce the propylene -based polymers is m- dimethylsilylbis(indenyl)hafniumdimethyl.
- the core includes one or more polymers (i.e. core polymer) that provide the core composition with a higher melt temperature and higher flexural modulus as compared to the sheath composition.
- polymers i.e. core polymer
- the core composition is characterized by having a flexural modulus, as defined by ASTM D-790, that is at least 5%, in other embodiments at least 10%, in other embodiments at least 15%, in other embodiments at least 20%, in other embodiments at least 30%, and in other embodiments at least 40% greater than the flexural modulus of the sheath composition.
- the core composition is characterized by having a flexural modulus, as defined by ASTM D-790, that is at least 100 MPa, in other embodiments at least 250 MPa, in other embodiments at least 500 MPa, in other embodiments at least 750 MPa, in other embodiments at least 850 MPa, and in other embodiments at least 950 MPa greater than the flexural modulus of the sheath composition.
- the core composition is characterized by having a melt temperature (Tm as determined by DSC) that is at least 5%, in other embodiments at least 10%, in other embodiments at least 15%, in other embodiments at least 20%, in other embodiments at least 30%, and in other embodiments at least 40%, greater than the melt temperature of the sheath composition.
- Tm melt temperature
- the core composition is characterized by having a melt temperature (Tm as determined by DSC) that is at least 15 °C, in other embodiments at least 20 °C, in other embodiments at least 25 °C, in other embodiments at least 30 °C, in other embodiments at least 35 °C, in other embodiments at least 45 °C, in other embodiments at least 55 °C greater than the melt temperature of the sheath composition.
- Tm melt temperature
- the core composition may be characterized by a flexural modulus, which may also be referred to as 1% secant modulus, which is determined according to ASTM D-790.
- the flexural modulus of the core composition is greater than 1,000 MPa, in other embodiments greater than 1,200 MPa, and in other embodiments greater than 1,300 MPa.
- the flexural modulus of the core composition is from about 1,000 to 2,000 MPa, in other embodiments from about 1,200 to 1,800 MPa, and in other embodiments from about 1,300 to 1,500 MPa.
- the melt temperature (Tm) of the core composition is greater than 125 °C, in other embodiments greater than 140 °C, and in other embodiments greater than 150 °C. In one or more embodiments, the Tm of the core composition is from about 125 to about 330 °C, in other embodiments from about 140 to about 280 °C, and in other embodiments from about 150 to about 260 °C.
- the core composition can include or consist of polymers, such as, but not limited to, propylene-based polymers (e.g., homopolymers, impact copolymers, copolymers), ethylene-based polymers (e.g., LDPE, LLDPE, HDPE (copolymers and block copolymers)), functionalized polyolefins (e.g., ExxelorTM. maleic anhydride functionalized elastomeric ethylene copolymers), plastomers (e.g., ethylene-. alpha.
- polymers such as, but not limited to, propylene-based polymers (e.g., homopolymers, impact copolymers, copolymers), ethylene-based polymers (e.g., LDPE, LLDPE, HDPE (copolymers and block copolymers)), functionalized polyolefins (e.g., ExxelorTM. maleic anhydride functionalized elastomeric ethylene copolymers), plast
- polyesters such as polyethylene terephthalate, polylactic acid, polyvinyl chloride, polytetrafluoroethylene, styrenic block copolymers, ethylene vinyl acetate copolymers, polyamide, polycarbonate, cellulosics (e.g., RayonTM, LyocellTM., TencilTM), an elastomer, poly(acetylene), poly (thiophene), poly (aniline), poly(fluorene), poly(pyrrole), poly(3- alkylhiophene), poly(phenylene sulphide), polynaphthalenes, poly(phenylene vinylene), poly(vinylidene fluoride), and blends of any two or more of these materials.
- polyesters such as polyethylene terephthalate, polylactic acid, polyvinyl chloride, polytetrafluoroethylene, styrenic block copolymers, ethylene vinyl acetate copolymers, polyamide, polycarbonate
- Useful polymers also include plastomers (e.g., ethylene-. alpha. -olefin copolymers and block copolymers), polyurethane, polyesters such as polyethylene terephthalate, polylactic acid, polyvinyl chloride, polytetrafluoroethylene, styrenic block copolymers, ethylene vinyl acetate copolymers, polyamide, polycarbonate, cellulosics (e.g., RayonTM, LyocellTM, TencilTM), an elastomer, poly(acetylene), poly (thiophene), poly(aniline), poly(fluorene), poly(pyrrole), poly(3- alky thiophene), poly(phenylene sulphide), polynaphthalenes, poly(phenylene vinylene), poly(vinylidene fluoride), and blends of any two or more of these materials.
- plastomers e.g., ethylene-. alpha.
- polyesters are used in the core of the bicomponent fibers of the present invention.
- exemplary polyesters include polyolefin-terephthalates and polyalkylene terephthalates, such as poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), and poly(cyclohexane dimethylene terephthalate) (PCT).
- PET poly(ethylene terephthalate)
- PBT poly(butylene terephthalate)
- PCT poly(cyclohexane dimethylene terephthalate)
- polypropylene-based thermoplastic are used in the core of the bicomponent fibers of the present invention.
- the polypropylene-based thermoplastics may include propylene homopolymer, or a copolymer of propylene, or some mixture of propylene homopolymers and copolymers.
- the polypropylene described herein is predominately crystalline, thus the polypropylene may have a melting point (Tm) greater than 110 °C or 115 °C or 130 °C.
- Tm melting point
- crystalline characterizes those polymers which possess high degrees of inter-and intra-molecular order.
- the polypropylene has a heat of fusion (Hf) greater than 60 J/g or 70 J/g or 80 J/g, as determined by Differential Scanning Calorimetry (DSC) analysis.
- Hf is dependent on the composition of the polypropylene; the thermal energy for the highest order of polypropylene is estimated at 189 J/g that is, 100% crystallinity is equal to a Hf of 189 J/g.
- a polypropylene homopolymer will have a higher H Hf than a copolymer or blend of homopolymer and copolymer.
- the polypropylene(s) can be isotactic. Isotacticity of the propylene sequences in the polypropylenes can be achieved by polymerization with the choice of a desirable catalyst composition. The isotacticity of the polypropylenes as measured by 13 C NMR, and expressed as a meso diad content is greater than 90% (meso diads [m]>0.90) or 95 % or 97 % or 98 % in certain embodiments, determined as in U.S. Pat. No. 4,950,720 by 13 C NMR. Expressed another way, the isotacticity of the polypropylenes as measured by 13 C NMR, and expressed as a pentad content, is greater than 93 % or 95 % or 97 % in certain embodiments.
- the polypropylene can vary widely in composition.
- substantially isotactic polypropylene homopolymer or in other embodiments propylene copolymer containing equal to or less than 10 wt% of other monomer, that is, at least 90 wt% propylene can be used.
- the polypropylene can be present in the form of a graft or block copolymer, in which the blocks of polypropylene have substantially the same stereoregularity as the propylene-based elastomer described herein so long as the graft or block copolymer has a sharp melting point above 110 °C or 115 °C or 130 °C, characteristic of the stereoregular propylene sequences.
- the polypropylene can be a combination of homopolypropylene, and/or random, and/or block copolymers.
- the percentage of the a-olefin derived units in the copolymer is, in general, up to 5 wt% of the polypropylene, 0.5 wt% to 5 wt% in another embodiment, and 1 wt% to 4 wt% in yet another embodiment.
- One, two or more comonomers can be copolymerized with propylene.
- Exemplary a-olefins may be selected from the group consisting of: ethylene; l-butene; l-pentene-2-methyl-l-pentene-3-methyl-l-butene; l-hexene- 3 -methyl- 1- pentene-4-methyl-l-pentene-3, 3-dimethyl- l-butene; l-heptene; l-hexene; 1 -methyl- 1 -hexene; dimethyl- l-pentene; trimethyl- l-butene; ethyl- l-pentene; l-octene; methyl- l-pentene; dimethyl- 1 -hexene; trimethyl- l-pentene; ethyl- l-hexene; l-methylethyl- l-pentene; 1 -diethyl- l-butene; propyl- l-pentene; l
- the weight average molecular weight (Mw) of the polypropylene can be between 50,000 g/mol to 3,000,000 g/mol, or from 90,000 g/mol to 500,000 g/mol in another embodiment, with a molecular weight distribution (MWD, Mw/Mn) within the range from 1.5 to 2.5; or 3.0 to 4.0; or 5.0 to 20.0.
- the polypropylene can have an MFR (2.16 kg/230 °C) ranging of from 10 dg/min to 15 dg/min; or 18 dg/min to 30 dg/min; or 35 dg/min to 45 dg/min; or 40 dg/min to 50 dg/min.
- RCP random polypropylene
- alpha olefin comonomer a single phase copolymer of propylene having up to 9 wt%, or 2 wt% to 8 wt% of an alpha olefin comonomer.
- exemplary alpha olefin comonomers have 2 carbon atoms, or from 4 to 12 carbon atoms.
- the alpha olefin comonomer is ethylene.
- the propylene impact copolymers (“ICP”) is heterogeneous and can include a first phase of 70 to 95 wt% homopolypropylene and a second phase of from 5 wt% to 30 wt% ethylene-propylene rubber, based on the total weight of the impact copolymer.
- the propylene impact copolymer can include 78 wt% to 95 wt% homopolypropylene and from 5 wt% to 22 wt% ethylene-propylene rubber, based on the total weight of the impact copolymer.
- the impact copolymer can include from 90 wt% to 95 wt% homopolypropylene and from 5 wt% to 10 wt% ethylene-propylene rubber, based on the total weight of the impact copolymer.
- the polymer is a propylene homopolymer obtained by homopolymerization of propylene in a single stage or multiple stage reactor.
- Copolymers may be obtained by copolymerizing propylene and ethylene or an a-olefin having from 4 to 20 carbon atoms in a single stage or multiple stage reactor.
- Polymerization methods include, but are not limited to, high pressure, slurry, gas, bulk, or solution phase, or a combination thereof, using any suitable catalyst such as traditional Ziegler-Natta catalyst or a single-site, metallocene catalyst system, or combinations thereof including bimetallic (i.e., Ziegler-Natta and metallocene) supported catalyst systems.
- any suitable catalyst such as traditional Ziegler-Natta catalyst or a single-site, metallocene catalyst system, or combinations thereof including bimetallic (i.e., Ziegler-Natta and metallocene) supported catalyst systems.
- Exemplary commercial polypropylenes include the family of AchieveTM polymers (ExxonMobil Chemical Company, Baytown, Tex.).
- the Achieve polymers are produced using metallocene catalyst systems.
- the metallocene catalyst system produces a narrow molecular weight distribution polymer.
- the MWD is typically in the range of 1.5 to 2.5.
- a broader MWD polymer may be produced in a process with multiple reactors. Different MW polymers can be produced in each reactor to broaden the MWD.
- Achieve polymer such as Achieve 3854, a homopolymer having an MFR of 24 dg/min can be used as a blend component described herein.
- an Achieve polymer such as Achieve 6936G1, a 1550 dg/min MFR homopolymer, can be used as a blend component described herein.
- Other polypropylene random copolymer and impact copolymer may also be used.
- the choice of polypropylene MFR can be used as means of adjusting the final MFR of the blend, especially the facing layer composition. Any of the polypropylenes described herein can be modified by controlled rheology to improve spinning performance as is known in the art.
- one or more additives may be incorporated into the sheath, the core, or both the core and the sheath.
- additives may include, but are not limited to, stabilizers, antioxidants, fillers, colorants, nucleating agents, dispersing agents, mold release agents, slip agents, fire retardants, plasticizers, pigments, vulcanizing or curative agents, vulcanizing or curative accelerators, cure retarders, processing aids, tackifying resins, and the like.
- Other additives may include fillers and/or reinforcing materials, such as carbon black, clay, talc, calcium carbonate, mica, silica, silicate, combinations thereof, and the like.
- the antioxidants may include primary and secondary antioxidants such as, for example, hindered phenols, hindered amines, and phosphates.
- Nucleating agents may include, for example, sodium benzoate and talc. Also, to improve crystallization rates, other nucleating agents may also be employed such as Ziegler-Natta olefin products or other highly crystalline polymers. Other additives such as dispersing agents, for example, Acrowax C, can also be included.
- Slip agents include, for example, oleamide and erucamide. Catalyst deactivators are also commonly used, for example, calcium stearate, hydrotalcite, and calcium oxide, and/or other acid neutralizers known in the art.
- the bicomponent fibers of the present invention may be prepared in a melt-spun process (i.e. meltspinning), which is a process that extrudes polymeric melts or solutions through spinnerets to form filaments, which may also be referred to as monofilaments.
- meltspinning a process that extrudes polymeric melts or solutions through spinnerets to form filaments, which may also be referred to as monofilaments.
- the monofilaments may be formed into a fabric through various techniques including, but not limited to, spunbonding, meltblowing, flash spinning, coforming.
- the fibers may be stable fibers that are carded.
- the sheath-core fibers of the present invention are prepared by a melt- spun process where two polymer liquids are separately supplied to spinneret orifices and then extruded to form the sheath-core structure.
- the orifice supplying the core polymer is in the center of the spinning orifice outlet and flow conditions of core polymer fluid are strictly controlled to maintain the concentricity of both components when spinning.
- Eccentric fiber production can include eccentric positioning of the inner polymer channel and controlling of the supply rates of the two component polymers.
- a varying element can be introduced near the supply of the sheath component melt.
- a stream of single component can be merged with a concentric sheath-core component just before emerging from the orifice.
- spun concentric fiber can be deformed by passing over a hot edge.
- the melt-spun process for preparing the bicomponent fibers of the present invention includes formation of a fabric by a spunbonding process. Following extrusion through a spinneret (i.e. meltspinning), the filaments can be quenched with air at a low temperature, drawn, usually pneumatically, and deposited on a moving mat, belt or “forming wire” to form the nonwoven fabric. See, for example, in U.S. Pat. Nos. 4,340,563; 3,692,618; 3,802,817; 3,338,992; 3,341,394; 3,502,763; and 3,542,615. The skilled person understands that process conditions can be altered to tailor fiber and fabric properties. For example, increasing the polymer molecular weight or decreasing the processing temperature results in larger diameter fibers. Changes in the quench air temperature and pneumatic draw pressure also have an affect on fiber diameter.
- the melt-spun process for preparing the bicomponent fibers of the present invention includes formation of a fabric by a co-forming process. Following extrusion through a spinneret (i.e. meltspinning), other materials are added to the fabric either within the die or at or near the exit of the die. These other materials may include, but are not limited to, pulp, superab sorbent particles, cellulose or staple fibers. Co-forming processes are described in U.S. Pat. No. 4,818,464 and U.S. Pat. No. 4,100,324.
- the use of the propylene-based elastomer to form the sheath as described herein provides for a process characterized by advantageous meltspinning speed, which is also referred to as spinning speed, which is measured in distance per unit of time (e.g. meters per minute“m/min’) at a given throughput, which is conventionally measured in grams per hole per minute (“ghm”).
- the fibers of the present invention can be meltspun, at a throughput of 0.6 ghm, at a maximum speed that is greater than 2800 m/min, in other embodiments greater than 3000 m/min, and in other embodiments greater than 3200 m/min.
- the fibers of the present invention can be meltspun, at a throughput of 0.4 ghm, at a maximum speed that is greater than 2800 m/min, in other embodiments greater than 3000 m/min, and in other embodiments greater than 3200 m/min.
- fiber production can take place by employing a pack pressure that is less than 600 psi, in other embodiments less than 550 psi, and in other embodiments less than 500 psi at 0.6 ghm.
- the bicomponent fiber may be used to prepare an air-through nonwoven fabric (i.e. a bonded fabric).
- a nonwoven web of bicomponent fibers prepared according to this invention are subjected to an air-through bonding process to thereby thermally bond or set the fibers.
- the nonwoven fabrics prepared according to the present invention may be characterized by their initial sealing temperature, which may be determined according to ASTM F-2029. The skilled person understands that the sealing temperature impacts the temperature that must be employed to bond the fibers in the preparation of bonded fabrics.
- the nonwoven fabrics (and/or the fibers) of the present invention have an initial sealing temperature that is less than 140 °C, in other embodiments less than 125 °C, and in other embodiments less than 110 °C.
- the nonwoven fabrics (and/or the fibers) have an initial sealing temperature that is greater than 70 °C, in other embodiments greater than 80 °C, and in other embodiments greater than 90 °C.
- the nonwoven fabrics (and/or the fibers) have an initial sealing temperature that is from about 70 °C to about 140 °C, in other embodiments from about 80 °C to about 125 °C, and in other embodiments from about 95 °C to about 105 °C.
- the unbonded fabrics are subjected to air-bonding techniques where the temperature of the air is equivalent to the foregoing sealing temperatures.
- the nonwoven fabrics prepared using the bicomponent fiber may be characterized by their basis weight, which can be measured according to WSP (Worldwide Strategic Partners) 130.1 (05).
- the nonwoven fabrics of the present invention may have a basis weight less than 120 g/m 3 , in other embodiments less than 50 g/m 3 , and in other embodiments less than 20 g/m 3 .
- the nonwoven fabric may have a basis weight greater than 6 g/m 3 , in other embodiments greater than 10 g/m 3 , and in other embodiments greater than 15 g/m 3 .
- the nonwoven fabric may have a basis weight from about 6 g/m 3 to about 120 g/m 3 , in other embodiments from about 10 g/m 3 to about 50 g/m 3 , and in other embodiments from about 15 g/m 3 to about 20 g/m 3 .
- the fibers produced according to the process described here are formed into a nonwoven web of the fibers.
- This nonwoven web is then bonded by employing air-through bonding techniques to thereby form a bonded nonwoven.
- the air-through bonding techniques include exposing the web to air having a temperature of less than 130 C°, in other embodiments less than 120 C°, in other embodiments less than 115 C°, and in other embodiments less than 110 C°.
- the nonwoven web is exposed to air at temperatures of from about 90 to about 130 C°, in other embodiments from about 100 to about 120 C°, and in other embodiments from about 105 to about 115 C°.
- Fabrics formed from the bicomponent fibers described herein may be a single layer, or may be multilayer laminates.
- the fabric may include a laminate (or“composite”) from meltblown fabric (“M”) and spunbond fabric (“S”), which combines the advantages of strength from spunbonded fabric and greater barrier properties of the meltblown fabric.
- M meltblown fabric
- S spunbond fabric
- a typical laminate or composite has three or more layers, a meltblown layer(s) sandwiched between two or more spunbonded layers, or“SMS” fabric composites. Examples of other combinations are SSMMSS, SMMS, and SMMSS composites.
- Composites can also be made of the meltblown fabrics of the invention with other materials, either synthetic or natural, to produce useful articles.
- the bicomponent fibers may be used to make fabrics that have a variety of uses including, but not limited to, diapers, feminine care products, and adult incontinence products including components thereof such as the top sheet, back sheet, leg cuffs, elastic waistband, and transfer layers.
- the fabrics of this invention can be used as nonwoven structures in absorbent cores in wet wipes.
- the fabrics of this invention can be used in spun-laced nonwoven products like medical disposable textiles and filtration products.
- Paragraph A A bicomponent fiber comprising a sheath, where the sheath includes a propylene-based elastomer, said propylene-based elastomer including propylene-derived units and from about 3.0 to about 15 wt% alpha-olefin-derived units other than propylene-derived units, based upon the entire weight of the copolymer, said propylene-based elastomer having a triad tacticity of greater than 75%, and a heat of fusion, as determined by DSC, of less than 75 J/g; and a core, where the melt temperature of the core, as determined by DSC, is at least 5% greater than the melt temperature of the sheath.
- Paragraph B The bicomponent fiber of Paragraph A, where the melt temperature of the core, as determined by DSC, that is greater than 125 °C and the flexural modulus of the core, as determined by ASTM D-790, is greater than 1,000 MPa.
- Paragraph C The bicomponent fibers of Paragraphs A-B, where the melt temperature of the core is at least 20% greater than the melt temperature of the sheath.
- Paragraph D The bicomponent fibers of Paragraphs A-C, where the melt temperature of the core is at least 15 °C greater than the melt temperature of the sheath.
- Paragraph E The bicomponent fibers of Paragraphs A-D, where the melt temperature of the core is at least 30 °C greater than the melt temperature of the sheath.
- Paragraph F The bicomponent fibers of Paragraphs A-E, where the flexural modulus of the core is at least 1,000 MPa greater than the flexural modulus of the sheath.
- Paragraph G The bicomponent fibers of Paragraphs A-F, where the flexural modulus of the core is at least 1,300 MPa greater than the flexural modulus of the sheath.
- Paragraph H The bicomponent fibers of Paragraphs A-G, where the total ethylene- derived units within the sheath is less than 30 wt% based upon the entire weight of the polymeric content of the sheath.
- Paragraph I The bicomponent fibers of Paragraphs A-H, where the alpha-olefin- derived units are ethylene-derived units, and where the propylene-based elastomer includes less than 8 wt% ethylene-derived units.
- Paragraph J The bicomponent fibers of Paragraphs A-I, where the propylene-based elastomer includes less than 6 wt% ethylene-derived units.
- Paragraph K The bicomponent fibers of Paragraphs A-J, where the sheath has a flexural modulus, according to ASTM D-790, of from about 100 to about 1,000 MPa.
- Paragraph L The bicomponent fibers of Paragraphs A-K, where the sheath has a melt temperature, as determined by DSC, of from about 85 to about 120 °C.
- Paragraph M The bicomponent fibers of Paragraphs A-L, where the sheath includes a first propylene-based elastomer and a second propylene -based elastomer, where the first propylene-based elastomer has an MFR, according to ASTM D-1238, 2.16 kg weight @ 230 °C, of from about 6 to about 55 g/lO min, and where the second propylene-based elastomer has an MFR, according to ASTM D-1238, 2.16 kg weight @ 230 °C, of from about 6 to about 80 g/lO min.
- Paragraph N A nonwoven fabric comprising a bicomponent fiber including a core and sheath, where the sheath includes a propylene-based elastomer that includes propylene- derived units and from about 3.0 to about 15 wt% alpha-olefin-derived units, based upon the entire weight of the copolymer, has a triad tacticity of greater than 75%, and a heat of fusion, as determined by DSC, of from about 30 to about 75 J/g.
- Paragraph O The nonwoven fabric of Paragraph N, where the alpha-olefin-derived units are ethylene-derived units, and where the propylene-based elastomer includes less than 8 wt% ethylene-derived units.
- Paragraph P The nonwoven fabrics of Paragraphs N-O, where the melt temperature of the core, as determined by DSC, is at least 5% greater than the melt temperature of the sheath.
- Paragraph Q The nonwoven fabrics of Paragraphs N-P, where the melt temperature of the core, as determined by DSC, that is greater than 125 °C and the flexural modulus of the core, as determined by ASTM D-790, is greater than 1,000 MPa.
- Paragraph R The nonwoven fabrics of Paragraphs N-Q, where the sheath has a melt temperature, as determined by DSC, of from about 85 to about 120 °C.
- Paragraph S A process for forming bicomponent polymer fibers, the process comprising extruding first and second polymeric compositions to thereby form a sheath-core structure, where the first polymeric composition forms the sheath and the second polymeric composition forms the core, where the first polymeric composition includes a propylene-based polymer and from about 3 to about 15 wt % alpha-olefin-derived units, has a triad tacticity greater than about 75%, and a heat of fusion less than about 75 J/g.
- Paragraph T The process of Paragraph S, further comprising the step of forming a web of the fibers.
- Paragraph U A process for forming an air-through nonwoven fabric, the process comprising (i) providing bicomponent fiber including a sheath, where the sheath includes a propylene-based elastomer, said propylene-based elastomer including propylene-derived units and from about 3.0 to about 15 wt% alpha-olefin-derived units other than propylene-derived units, based upon the entire weight of the copolymer, said propylene-based elastomer having a triad tacticity of greater than 75%, and a heat of fusion, as determined by DSC, of less than 75 J/g, and a core, where the melt temperature of the core, as determined by DSC, is at least 5% greater than the melt temperature of the sheath; (ii) forming fibers into a web of the fibers; and (i
- Paragraph V The process of Paragraph U, wherein a pack pressure is less than 600 psi at 0.6 ghm.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Multicomponent Fibers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US201862724994P | 2018-08-30 | 2018-08-30 | |
EP18204558 | 2018-11-06 | ||
PCT/US2019/046448 WO2020046581A1 (fr) | 2018-08-30 | 2019-08-14 | Fibres polymères bicomposants |
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EP3844329A1 true EP3844329A1 (fr) | 2021-07-07 |
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EP19759265.2A Pending EP3844329A1 (fr) | 2018-08-30 | 2019-08-14 | Fibres polymères bicomposants |
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EP (1) | EP3844329A1 (fr) |
CN (1) | CN112805418B (fr) |
WO (1) | WO2020046581A1 (fr) |
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CN116529431A (zh) * | 2020-11-19 | 2023-08-01 | 埃克森美孚化学专利公司 | 具有改进的触感和机械性能的无纺布 |
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US3542615A (en) | 1967-06-16 | 1970-11-24 | Monsanto Co | Process for producing a nylon non-woven fabric |
DE2048006B2 (de) | 1969-10-01 | 1980-10-30 | Asahi Kasei Kogyo K.K., Osaka (Japan) | Verfahren und Vorrichtung zur Herstellung einer breiten Vliesbahn |
DE1950669C3 (de) | 1969-10-08 | 1982-05-13 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Vliesherstellung |
US4100324A (en) | 1974-03-26 | 1978-07-11 | Kimberly-Clark Corporation | Nonwoven fabric and method of producing same |
US4340563A (en) | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
US4818464A (en) | 1984-08-30 | 1989-04-04 | Kimberly-Clark Corporation | Extrusion process using a central air jet |
US4950720A (en) | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
US5382400A (en) * | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
US6525157B2 (en) | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
JP4058247B2 (ja) * | 2000-05-09 | 2008-03-05 | 大和紡績株式会社 | 熱接着性複合繊維およびその製造方法、ならびにこれを用いた不織布および合繊紙 |
EP1339756B1 (fr) | 2000-10-25 | 2006-08-23 | Exxonmobil Chemical Patents Inc. | Procedes et appareil de polymerisation en solution en continu |
CN100577898C (zh) * | 2004-04-30 | 2010-01-06 | 陶氏环球技术公司 | 改进的无纺织物和纤维 |
CN101010705B (zh) | 2004-07-08 | 2011-03-23 | 埃克森美孚化学专利公司 | 在超临界条件下生产聚合物 |
EP1871931B1 (fr) * | 2005-03-17 | 2011-04-27 | Dow Global Technologies LLC | Fibres de copolymeres de propylene/alpha-olefines |
BRPI0711223A2 (pt) * | 2006-05-25 | 2011-08-23 | Dow Global Technologies Inc | pano não-tecido spudbond e método para melhorar a maciez de panos não- tecidos spunbond |
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CN103201416B (zh) * | 2010-11-09 | 2016-07-06 | 埃克森美孚化学专利公司 | 双组分纤维及其制造方法 |
US10059081B2 (en) * | 2011-12-22 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | Fibers and nonwoven materials prepared therefrom |
JP6142085B2 (ja) * | 2013-06-18 | 2017-06-07 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 繊維及びこれから調製された不織材料 |
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- 2019-08-14 WO PCT/US2019/046448 patent/WO2020046581A1/fr unknown
- 2019-08-14 CN CN201980062342.7A patent/CN112805418B/zh active Active
- 2019-08-14 EP EP19759265.2A patent/EP3844329A1/fr active Pending
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CN112805418B (zh) | 2023-06-27 |
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