EP3836787A1 - Compositions biocides stables renfermant de la 1,2-benzisothiazolin-3-one et de la glycérine - Google Patents
Compositions biocides stables renfermant de la 1,2-benzisothiazolin-3-one et de la glycérineInfo
- Publication number
- EP3836787A1 EP3836787A1 EP19758604.3A EP19758604A EP3836787A1 EP 3836787 A1 EP3836787 A1 EP 3836787A1 EP 19758604 A EP19758604 A EP 19758604A EP 3836787 A1 EP3836787 A1 EP 3836787A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- benzisothiazolin
- biocide composition
- water
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 75
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 62
- 239000003139 biocide Substances 0.000 title claims abstract description 58
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims abstract description 16
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229960005323 phenoxyethanol Drugs 0.000 claims abstract description 15
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 14
- 239000011591 potassium Substances 0.000 claims abstract description 14
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 13
- -1 plasters Substances 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- 239000005068 cooling lubricant Substances 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 6
- 230000001070 adhesive effect Effects 0.000 claims abstract description 6
- 239000010426 asphalt Substances 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- 239000010985 leather Substances 0.000 claims abstract description 6
- 239000003973 paint Substances 0.000 claims abstract description 6
- 239000000123 paper Substances 0.000 claims abstract description 6
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 238000005498 polishing Methods 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 6
- 238000004513 sizing Methods 0.000 claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000009987 spinning Methods 0.000 claims abstract description 3
- 239000004753 textile Substances 0.000 claims abstract description 3
- 235000011187 glycerol Nutrition 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 9
- 244000005700 microbiome Species 0.000 claims description 7
- 239000008199 coating composition Substances 0.000 claims description 5
- 239000003599 detergent Substances 0.000 claims description 5
- 239000000565 sealant Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000002979 fabric softener Substances 0.000 claims description 3
- 230000006378 damage Effects 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 13
- 238000003860 storage Methods 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 230000003641 microbiacidal effect Effects 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000004321 preservation Methods 0.000 description 4
- 229910003002 lithium salt Inorganic materials 0.000 description 3
- 159000000002 lithium salts Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229960004063 propylene glycol Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Definitions
- the biocidal compositions according to the invention contain as component (d) ad. 100% water. This means that in addition to components (a), (b) and (c) and, if appropriate, further components, such as thickeners, defoamers and dispersants, water is present.
- the invention further comprises a process for the preparation of the biocide compositions according to the invention, in which the individual components are mixed with one another with stirring at a temperature of 20 to 60 ° C.
- the biocide composition contains the following components or consists of the following components:
- the biocide composition contains the following components or consists of the following components:
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
L'invention concerne des compositions biocides comprenant les composés : (a) entre 15 et 25 % en poids de 1,2-benzisothiazolin-3-one sous la forme de son sel de potassium et éventuellement son sel de sodium, cette invention étant caractérisée en ce que la fraction molaire du sel de potassium de 1,2-benzisothiazolin-3-one, par rapport à la totalité de sels de 1,2-benzisothiazolin-3-one est d'au moins 50 % molaire ; (b) entre 30 % en poids et 50 % en poids de phénoxyéthanol, (c) entre 10 % en poids et 30 % en poids de glycérine et (d) le reste étant constitué d'eau pour atteindre 100 % en poids. Cette invention concerne en outre l'utilisation de ces compositions biocides pour la conservation de produits à base d'eau de toute sorte, tels que des produits de nettoyage et des produits ménagers, des dispersions plastiques, des colorants, des nettoyants, des adhésifs, des agents d'étanchéité, des agents d'enduction de papier, des agents adoucissants textiles ou des agents d'encollage textiles, des matières premières pour détergents, des tensioactifs, des agents de polissage,, des bains de filage, des lubrifiants réfrigérants, des agents de traitement du cuir, et des émulsions de silicone et de bitume.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18000682 | 2018-08-16 | ||
| PCT/EP2019/000239 WO2020035165A1 (fr) | 2018-08-16 | 2019-08-06 | Compositions biocides stables renfermant de la 1,2-benzisothiazolin-3-one et de la glycérine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3836787A1 true EP3836787A1 (fr) | 2021-06-23 |
Family
ID=63311749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19758604.3A Withdrawn EP3836787A1 (fr) | 2018-08-16 | 2019-08-06 | Compositions biocides stables renfermant de la 1,2-benzisothiazolin-3-one et de la glycérine |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP3836787A1 (fr) |
| WO (1) | WO2020035165A1 (fr) |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4871A (en) | 1846-12-03 | Cooking-stove | ||
| GB1191253A (en) | 1968-02-21 | 1970-05-13 | Ici Ltd | New Compositions of Matter |
| ZA784934B (en) | 1977-09-30 | 1979-10-31 | Ici Ltd | Solutions of benzisothiazolinones |
| DE3600271A1 (de) | 1986-01-08 | 1987-07-09 | Cassella Ag | Waessrige zubereitung von 1,2-benzisothiazolin-3-on |
| GB9300936D0 (en) * | 1993-01-19 | 1993-03-10 | Zeneca Ltd | Stable liquid compositions and their use |
| US7468384B2 (en) * | 2004-11-16 | 2008-12-23 | Rohm And Haas Company | Microbicidal composition |
| DE102006045066B4 (de) * | 2006-09-21 | 2010-07-01 | Schülke & Mayr GmbH | Mikrobizide Zubereitung auf der Basis von 1,2-Benzisothiazolin-3-on mit einem Gehalt an aromatischem Alkohol |
| US20150126479A1 (en) * | 2011-05-13 | 2015-05-07 | Isp Investments Inc. | Aqueous solutions of 1,2-benzisothiazolin-3-one |
| JP6752882B2 (ja) * | 2015-09-09 | 2020-09-09 | トール ゲーエムベーハー | 貯蔵安定性のある殺生物剤組成物 |
-
2019
- 2019-08-06 EP EP19758604.3A patent/EP3836787A1/fr not_active Withdrawn
- 2019-08-06 WO PCT/EP2019/000239 patent/WO2020035165A1/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020035165A1 (fr) | 2020-02-20 |
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