EP3814297A1 - Logement du type capsule, en particulier capsule pour la combustion d'un matériau pulvérulent de cathode pour des batteries lithium-ion, ainsi que mélange pour celui-ci - Google Patents

Logement du type capsule, en particulier capsule pour la combustion d'un matériau pulvérulent de cathode pour des batteries lithium-ion, ainsi que mélange pour celui-ci

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Publication number
EP3814297A1
EP3814297A1 EP19735279.2A EP19735279A EP3814297A1 EP 3814297 A1 EP3814297 A1 EP 3814297A1 EP 19735279 A EP19735279 A EP 19735279A EP 3814297 A1 EP3814297 A1 EP 3814297A1
Authority
EP
European Patent Office
Prior art keywords
weight
sic
range
capsule
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19735279.2A
Other languages
German (de)
English (en)
Inventor
Hans-Ulrich Dorst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain IndustrieKeramik Roedental GmbH
Original Assignee
Saint Gobain IndustrieKeramik Roedental GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain IndustrieKeramik Roedental GmbH filed Critical Saint Gobain IndustrieKeramik Roedental GmbH
Publication of EP3814297A1 publication Critical patent/EP3814297A1/fr
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • C04B35/575—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained by pressure sintering
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3817—Carbides
    • C04B2235/3826—Silicon carbides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/405—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5463—Particle size distributions
    • C04B2235/5472—Bimodal, multi-modal or multi-fraction
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts

Definitions

  • Silicon carbide with a grain size of 80/220 (mesh) in a proportion of 3.0-27.0% by weight is advantageous, silicon carbide with a grain size of 30/70 (mesh) in a proportion of 23.0-54 , 0 wt .-%, silicon carbide with a grain size of 16/24 (mesh) with a proportion of 7.0-25.0 wt .-% present, and preferably a maximum of 82 wt .-% SiC. But different grain sizes would also be suitable. The details are given in mesh.
  • a mix of powdery materials is preferably used, which is formed from an oxidically bound SiC mixture and an Al203 portion in the form of alumina and possibly also the addition of corundum and a powdery Si02 carrier or based on at least 90% SiO 2, preferably more than 95% SiO 2 with an average grain size preferably in the range of 40-150 ml, in particular 40-100 ml.
  • the residual content of the SiO 2 carrier is formed from conventional impurities, such as Fe203, A1203 and / or alkali or alkaline earth oxides and the like.
  • the proportion of SiO 2 carriers is preferably 5.0 to 15.0% by weight, preferably approximately 5.0 to 7.0% by weight. Unless otherwise stated, the percentages given herein relate to% by weight.
  • the silicon carbide is in powder form as an oxidically bonded SiC mixture, expediently with a grain size of SiC Mesh 80/220 in the range from 4 to 8%, SiC Mesh 30/70 in the range from 43 to 47% and SiC Mesh 16/24 in Range of 11 - 16%, with very fine powder with a size ⁇ 100mih up to 0.1%, in particular in the form of totanin powder.
  • Clay is in powder form, expediently in a grain size of 0-0.08 mm, whereby clay of various types is suitable, in particular clay of an average grain size of 3 ml to 5 ml is available.
  • Powdery, highly reactive clay is particularly suitable as the clay.
  • the silicon carbide is expediently present in an oxidically bonded SiC mixture, the following ranges being expedient, namely SiC Mesh 80/220 in the range from 3 to 6%, SiC Mesh 30/70 in the range from 23 to 29%, SiC Mesh 16 / 24 in the range of 7 - 11% and SiC fine grain ⁇ 100mih 0.5 - 2%, the percentages being given in percent by weight.
  • Suitable Si02 carriers are, in particular, materials available under the trade name Microsilica, in a suitable powder form.
  • the SiO 2 carrier is preferably added in the finest grain size, that is to say with a grain size preferably ⁇ 100 ml, in particular ⁇ 50 ml, expediently ⁇ 45 ml.
  • the Si02 carrier is preferably based on 90% Si02, the rest of the carrier component is quite desirable, such as usual impurities, such as oxides of iron, alkali and alkaline earth metal and the like.
  • the capsule or assembly material according to the invention avoids the disadvantages of the prior art by achieving a significantly higher strength and also increasing the resistance to temperature changes and reducing the risk of susceptibility to breakage.
  • the problem with conventional capsules has been that they often have to be replaced by new capsules due to contamination during the burning process of the cathode material, which causes a considerable amount of hazardous waste that can be eliminated through expensive recycling processes.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

L'invention concerne un logement du type capsule pour la combustion de matériaux pulvérulents de cathode, en particulier pour la fabrication de batteries lithium-ion, formé d'une coque en particulier rectangulaire pourvu de quatre parois latérales et d'un fond, le logement étant fabriqué par un processus de combustion à partir de matériaux résistants aux hautes températures, lesquels résistent à des températures en particulier supérieures à 900 °C, le matériau de la capsule étant fabriqué à base d'un constituant SiC pulvérulent lié de façon oxydique présentant une proportion de SiC dans la plage de 40,0 – 80,0 % en poids, une proportion de Al2O3 pulvérulent dans la plage de 19,0 – 43,0 % en poids, et un support de SiO2 également pulvérulent à base d'au moins 90 % de SiO2, un mélange adapté étant utilisé.
EP19735279.2A 2018-06-29 2019-06-27 Logement du type capsule, en particulier capsule pour la combustion d'un matériau pulvérulent de cathode pour des batteries lithium-ion, ainsi que mélange pour celui-ci Pending EP3814297A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102018115771.1A DE102018115771A1 (de) 2018-06-29 2018-06-29 Kapselartige Aufnahme, insbesondere Kapsel zum Brennen von pulverförmigem Kathoden-Material für Lithium-Ionen-Akkus sowie Mischung hierfür
PCT/EP2019/067254 WO2020002557A1 (fr) 2018-06-29 2019-06-27 Logement du type capsule, en particulier capsule pour la combustion d'un matériau pulvérulent de cathode pour des batteries lithium-ion, ainsi que mélange pour celui-ci

Publications (1)

Publication Number Publication Date
EP3814297A1 true EP3814297A1 (fr) 2021-05-05

Family

ID=67139732

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19735279.2A Pending EP3814297A1 (fr) 2018-06-29 2019-06-27 Logement du type capsule, en particulier capsule pour la combustion d'un matériau pulvérulent de cathode pour des batteries lithium-ion, ainsi que mélange pour celui-ci

Country Status (7)

Country Link
US (1) US20220144707A9 (fr)
EP (1) EP3814297A1 (fr)
JP (1) JP2021529148A (fr)
KR (1) KR20210013609A (fr)
CN (1) CN112292365A (fr)
DE (1) DE102018115771A1 (fr)
WO (1) WO2020002557A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3131295B1 (fr) 2021-12-23 2023-12-29 Saint Gobain Centre De Rech Et Detudes Europeen support de cuisson de poudre alcaline avec revêtement de porosité contrôlée

Family Cites Families (16)

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BE635375A (fr) * 1962-07-24
DD299465A7 (de) * 1978-11-15 1992-04-23 Ve Inst Der Feuerfest Ind Verfahren zur herstellung sic-haltiger erzeugnisse
WO1994003410A1 (fr) * 1992-07-31 1994-02-17 Lonza A.G. Corps moules refractaires en carbure de silicium avec liaison de mullite, leur procede de fabrication, matiere a mouler a utiliser comme produit intermediaire et utilisation desdits corps moules comme materiel d'enfournement
DE4242610A1 (en) * 1992-12-14 1993-07-22 Siegfried Dipl Ing Mueller Mixt. for high value silicon carbide prods. - comprises silicon carbide, dextrin soln., alumina, corundum, amorphous silicic acid and refractory binding clay
CN1093073A (zh) * 1993-04-01 1994-10-05 山东省硅酸盐研究设计院 稀土复合碳化硅材料及其用途
CN1099017A (zh) * 1993-08-14 1995-02-22 湖南省新化县电子材料厂 粘土结合碳化硅耐火材料
US7247588B2 (en) * 2002-11-22 2007-07-24 Saint-Gobain Ceramics & Plastics, Inc. Zirconia toughened alumina ESD safe ceramic composition, component, and methods for making same
BRPI0318224B1 (pt) * 2003-03-26 2018-09-11 Saint-Gobain Ceramics & Plastics, Inc. componentes cerâmicos de carboneto de silício com camada de óxido, métodos para produzir os referidos componentes e de processamento de peças de cerâmica
FR2902423B1 (fr) * 2006-06-19 2008-09-12 Saint Gobain Ct Recherches Ciment de jointoiement pour filtre a particules.
DE202009013354U1 (de) * 2009-10-14 2010-03-25 Imerys Magyarország Tüzállóanyaggyártó KFT Feuerfeste Ofenausstattungselemente
KR101129756B1 (ko) * 2010-03-10 2012-03-23 김영근 조립성이 우수한 탄화규소 내화갑 및 그 제조방법
JP2013149398A (ja) * 2012-01-17 2013-08-01 Toyota Motor Corp 非水電解質二次電池
CN103204686B (zh) * 2013-03-28 2014-10-15 安徽马钢耐火材料有限公司 一种滑板砖埋碳烧成用的匣钵砖及砌筑用火泥
JP6230945B2 (ja) * 2014-03-28 2017-11-15 Ｊｘｔｇエネルギー株式会社 二段加熱方式縦型黒鉛化炉および黒鉛の製造方法
CN105384450B (zh) * 2015-11-10 2018-01-16 安吉科灵磁性材料有限公司 硅铝溶胶增强碳化硅窑具的生产方法
CN108046816A (zh) * 2017-12-25 2018-05-18 江苏三恒高技术窑具有限公司 一种高抗热震性匣钵及其制备方法

Also Published As

Publication number Publication date
US20220144707A9 (en) 2022-05-12
WO2020002557A1 (fr) 2020-01-02
KR20210013609A (ko) 2021-02-04
CN112292365A (zh) 2021-01-29
US20210269365A1 (en) 2021-09-02
DE102018115771A1 (de) 2020-01-02
JP2021529148A (ja) 2021-10-28

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