EP3717615A1 - Composition solide comprimee pour usage non oral - Google Patents
Composition solide comprimee pour usage non oralInfo
- Publication number
- EP3717615A1 EP3717615A1 EP18808026.1A EP18808026A EP3717615A1 EP 3717615 A1 EP3717615 A1 EP 3717615A1 EP 18808026 A EP18808026 A EP 18808026A EP 3717615 A1 EP3717615 A1 EP 3717615A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- molasses
- solid composition
- compressed solid
- agents
- fermented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 235000013379 molasses Nutrition 0.000 claims abstract description 156
- 239000011230 binding agent Substances 0.000 claims abstract description 53
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
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- 241000335053 Beta vulgaris Species 0.000 claims description 24
- 239000008187 granular material Substances 0.000 claims description 23
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- 239000000654 additive Substances 0.000 claims description 14
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- 150000001875 compounds Chemical class 0.000 claims description 12
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- 238000005056 compaction Methods 0.000 claims description 8
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- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 239000008107 starch Substances 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 7
- 239000000314 lubricant Substances 0.000 claims description 7
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- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 4
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 4
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
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- 230000008901 benefit Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 239000003337 fertilizer Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000001033 granulometry Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical compound CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 3
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- 239000004117 Lignosulphonate Substances 0.000 description 3
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- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 229940024606 amino acid Drugs 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 239000012043 crude product Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000000194 fatty acid Chemical class 0.000 description 3
- 229930195729 fatty acid Chemical class 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 235000013922 glutamic acid Nutrition 0.000 description 3
- 239000004220 glutamic acid Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 235000019357 lignosulphonate Nutrition 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
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- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 2
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the present invention relates to a novel binding and / or disintegrating agent for obtaining a compressed solid composition for non-oral use, as well as a process for preparing said compressed solid composition.
- the compressed solid compositions may be in several forms generally conditioned by the intended use in order to obtain particular properties and to ensure optimal maintenance. For some applications, it is indeed important that a compressed solid composition has good integrity before use as well as the possibility of rapid disintegration during use, especially in contact with a liquid. These properties are generally provided by binding agents and / or disintegrants.
- binding agents makes it possible to increase the mechanical strength of the compressed solid compositions, also called agglomerates, to a level sufficient to avoid the problems of formation of fine particles during their handling or their implementation.
- the advantages of the use of a binding agent are generally noted for all known compression or agglomeration techniques, such as pressure-compaction, pelletisation, granulation, nodulisation, extrusion or the like. atomization.
- the disintegrating agents allow the compressed solid compositions which contain them to disintegrate in contact with a liquid, and in particular in contact with water.
- binders and disintegrants are termed binders and disintegrants because they make it possible to obtain in a dry medium a sufficient level of mechanical strength while also offering the possibility of disintegration during contact with a liquid.
- binders are known to those skilled in the art.
- Polyvinyl alcohols and their derivatives, celluloses and their derivatives, starches and starches modified physically and / or chemically, have good binder properties and allow to obtain agglomerates which meet the requirements of agglomeration techniques but do not meet not necessarily economic requirements. In fact, the necessary use doses do not generally make it possible to obtain compressed agglomerates or solid compositions under satisfactory economic conditions.
- Lignosulfonates have the disadvantage of being aggressive because of their pH and their composition vis-à-vis the means of agglomeration implemented.
- the lignosulfonates can cause the release of harmful vapors rich in sulfuric acid. It follows that lignosulphonates are a significant cause of air pollution and corrosion. In the context of developing greener products with reduced environmental impact, lignosulphonates should be avoided.
- Clays are low-cost products with binding properties but their field of application is restricted. In addition, it is often necessary to associate them with other binders. By way of example, mention may be made of amylaceous derivatives.
- alkali silicates As for the alkali silicates, they are of a delicate handling and their prolonged use requires frequent cleaning of the installations in which they are used.
- binding agents used in the compositions vary depending on the final application.
- the binders used are generally synthetic binders.
- the document EP 1 048 716 describes a laundry composition in the form of a tablet comprising in particular clay and a surfactant.
- the tablet is in the form of a compressed mass of particles held together by a binder having a dispersing effect on the clay less important than polyethylene glycol 6000 (PEG 6000).
- the binder is a chemical binder selected from polyethylene glycols having a molecular weight of less than 1500, amine oxide and polyvinylpyrrolidone.
- WO 2005/068603 discloses tablets with improved breaking strength and a method for making them.
- the method comprises a step of providing a binder having a shear modulus value G of 10 to 100 GPa, a phase angle value d of at least 7 degrees, and a boiling point of at least 45 ° C at atmospheric pressure.
- the method then comprises a step of heating the binder beyond its boiling point followed by a step of applying said heated binder to a powder comprising a premix of detergent compounds to form a detergent composition.
- the last step of the process consists in transforming the detergent composition into a tablet.
- the binder used is chosen from the group consisting of anionic surfactants, non-anionic surfactants, polymeric materials, polyols, saccharic acids, sugar alcohols, sugar esters, fatty acids, acid esters and the like. fatty acids, fatty acid amines and mixtures thereof.
- binding agents for the manufacture of compressed solid compositions for non-oral use, said binding agents being able to replace the synthetic binding agents conventionally used and also making it possible to act as disintegrating agents in contact with a liquid, especially water.
- a first object of the invention relates to a compressed solid composition for non-oral use comprising fermented molasses as a binder and / or disintegrating agent.
- molasses is a substance known to those skilled in the art. It is a co-product of the production of sugar from sugar beet and sugar cane, or brown sugar from refineries. The process of manufacturing sugar, whether it is made from cane or beet, ends after the crystallization stage to obtain sugar on the one hand and molasses on the other hand. In general, it is generally accepted that sugar processes generate about 35 to 40 kg of molasses per ton of beet and 30 to 35 kg of molasses per tonne of cane. At the French national level alone, annual production amounts to several tens of thousands of tons.
- the dry matter content of molasses varies little and is commonly between 70% and 76%. Molasses have very low or no levels of raw celluloses and fat.
- molasses contain significant amounts of sugar.
- the total sugar content is essentially the same, regardless of the origin of the molasses, generally between 58% and 70% of the dry mass (DM), but has some variations according to the industrial process applied to beet molasses.
- SUBSTITUTE SHEET (RULE 26) cane molasses, sucrose represents only about 2/3 of the total sugars, ie 30% to 40% of the raw product.
- Molasses is a very viscous substance which represents a disadvantage for its transport and storage.
- this high viscosity is an advantage for animal feed and is generally used to feed ruminants and horses, mixed with straw or other cellulosic foods such as bran, or as a binder in rations. complete, see again to encourage the ingestion of unpalatable food.
- molasses is a food whose flavor and smell stimulate the appetite and promote the digestion of animals.
- molasses are also used by manufacturers for the production of so-called “noble” products via fermentation processes. Indeed, through the fermentation mechanisms available to certain microorganisms, molasses makes it possible to obtain baker's yeast, ethyl alcohol, citric and glutamic acids, lysine or antibiotics, and generates also liquid fermentation residues which correspond to fermented molasses.
- fermented molasses has been considered as a fermentation residue whose only interest is to be efficiently handledd in the field of agriculture and animal husbandry as fertilizer or animal feed. . Indeed, the chemical composition of fermented molasses, despite a depletion of the compounds due to fermentation, still gives them an attraction in feeding ruminants both for their energy intake and their nitrogen value.
- compressed solid composition is intended to mean any composition obtainable by the compression methods known to those skilled in the art, such as, for example, pressure-compaction, pelletisation, granulation, nodulisation, extrusion or atomization.
- the compressed solid composition according to the invention can therefore also be considered as an agglomerate.
- the compressed solid composition according to the invention may be in a multitude of compressed forms, said forms being conventionally adapted by those skilled in the art depending on the desired application.
- the compressed solid composition can occur
- SUBSTITUTE SHEET in the form of a single layer or multilayer tablet, a roller, a tablet, a granule, a pellet or a pellet.
- the compressed solid composition is in the form of a single-layer or multilayer tablet.
- the compressed solid composition is not intended to be ingested by an animal or a human and therefore can not in particular support its diet.
- Fermented molasses is a co-product of the molasses obtained after fermentation of the latter by bacteria, yeasts or fungi, said fermentation making it possible to obtain so-called "noble" products such as baker's yeast, ethyl alcohol or citric and glutamic acid.
- the fermented molasses is obtained via the fermentation of molasses by yeasts.
- the fermented molasses can also be obtained from beet molasses, cane molasses, or a mixture of beet molasses and cane molasses.
- the mixture may contain up to 60% fermented beet molasses, up to 70% fermented beet molasses, up to 80% fermented beet molasses, up to 90% fermented beet molasses. or up to 95% fermented beet molasses.
- the fermented molasses is a mixture of fermented molasses of beet and cane, said mixture contains 90% of fermented molasses of beet.
- the fermented molasses contains more than 90% water but the latter is advantageously concentrated in order to reduce the quantity of water and to obtain higher solids content.
- the solids content of the fermented molasses, or the mixture of beet molasses and cane molasses according to the invention can be from 50% to 80%.
- the dry matter content of the fermented molasses is 55% to 75%, and more particularly 55% to 65%, for example about 60%.
- fermented molasses is also defined by its distribution in nitrogenous matter and by its aminogram.
- the fermented molasses according to the invention can thus have a distribution of nitrogenous materials as follows:
- betaine nitrogen 0% to 40% of total nitrogen
- Ammonia nitrogen 2% to 3% of the total nitrogen
- the average amino acid contents can be as presented hereinafter, the ranges of the contents being given in g / kg of dry matter:
- Threonine 0.5 - 3
- Lysine 0.5 - 2.5
- fermented molasses has a low sugar content.
- low sugar content is meant a fermented molasses comprising less than 5%, less than 4%, less than 3%, less than 2%, and more particularly less than 1% by weight of sugars per relative to the total mass of the dry extract.
- the fermented molasses according to the invention is free of sugars.
- the fermented molasses according to the invention may undergo one or more chemical or physicochemical treatments.
- fermented molasses may undergo de-packaging or demineralization.
- Such treatments can modify the nitrogenous composition of the fermented molasses.
- the de-assassification treatment consists, for example, of acidification of the crude fermented molasses with a solution of H 2 SO 4 , followed by neutralization with ammonia.
- a crude fermented molasses can have a raw ash content of 14% to 22% by weight relative to the raw product and a
- SUBSTITUTE SHEET (RULE 26) potassium from 5% to 18% by weight relative to the crude product.
- the raw ash content varies from 5% to 14% by weight relative to the crude product and the potassium content is generally less than 4% by weight relative to the crude product. .
- the raw fermented molasses Due to its high ash content, the raw fermented molasses has a density ranging from 1.10 to 1.50. Preferably, the density of the fermented molasses is from 1.20 to 1.40, and most preferably from 1.25 to 1.35.
- the fermented molasses according to the invention has a viscosity of 500 mPa.s at 5000 mPa.s, preferably 1000 mPa.s at 4000 mPa.s, and a slightly acidic pH of 5 to 6.
- the compressed solid composition according to the invention thus comprises crude fermented molasses or demineralized as a binding agent and / or disintegrating.
- Effective proportions are understood to mean those which are sufficient to obtain the desired effect, namely to obtain a compressed solid composition which can in particular be transported, handled and / or stored without substantial damage and which may disintegrate during contact. with a liquid such as water.
- the quantities used of fermented molasses raw or demineralized within the compressed solid composition according to the invention may be from 0.1% to 15% by weight, preferably from 0.5% to 5% by weight, and even more preferably from 0.5% to 1.5% by weight relative to the total weight of the compressed solid composition.
- the binding properties thus brought to light of the fermented molasses make it possible to obtain a compressed solid composition having sufficient mechanical strength in order to avoid the problems of formation of fine particles during their handling.
- the fermented molasses also acts as a disintegrating agent allowing the compressed solid composition to disintegrate in contact with a liquid, and in particular in contact with water.
- the inventors have thus identified a new way of valorization of fermented molasses but also an alternative to the use of synthetic or non-conventionally used binding agents for obtaining the compositions.
- solid By way of example, mention may be made in particular of polyethylene glycol, polyvinylpyrrolidone, ethoxylated fatty alcohols, starch, hydroxyethylcellulose, gelatin or even microcrystalline cellulose.
- the compressed solid composition comprising the fermented molasses according to the invention may be free of polyethylene glycol and / or polyvinylpyrrolidone and / or ethoxylated fatty alcohols and / or starch and / or hydroxyethylcellulose and / or gelatin and / or microcrystalline cellulose.
- the fermented molasses can be adjuvanted in particular to present particular physical properties.
- the molasses may be adjuvanted with a compound selected from the group comprising cellulose derivatives such as carboxymethylcellulose, hemicelluloses, lignins, ethyl cellulose, methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, derivatives thereof.
- sugar derivatives like glucose, fructose, lactos
- the fermented molasses is adjuvanted with carboxymethylcellulose.
- the amounts of compounds for adjuvanting the fermented molasses can range from 0.1% to 2%, preferably from 0.1% to 1%, more preferably from 0.1% to 0.5%. The percentages being expressed by dry weight relative to the total dry weight of the fermented molasses adjuvanted.
- the compressed solid composition may also include one or more additives.
- the additives may be selected from the additives known to those skilled in the art such as, for example, effervescent agents, detergents, sequestering agents, pelletizing additives, bleaching agents, polymers, surfactants, flow agents stabilizing agents, anti-foaming agents, coloring agents or lubricating agents.
- stabilizing agents examples include parahydroxybenzoic acid esters such as methylparaben and propylparaben, alcohols such as chlorobutanol, benzyl alcohol and phenylethyl alcohol, phenols such as phenol and cresol, sulphite salts such as sodium bisulfite and sodium sulphite, edetic acid salts such as sodium edetate and tetrasodium edetate, and hydrogenated oils, sesame, chondroitin-sodium sulphate, dibutylhydroxytoluene, adipic acid,
- parahydroxybenzoic acid esters such as methylparaben and propylparaben
- alcohols such as chlorobutanol, benzyl alcohol and phenylethyl alcohol
- phenols such as phenol and cresol
- sulphite salts such as sodium bisulfite and sodium sulphite
- edetic acid salts such as sodium ede
- SUBSTITUTE SHEET (RULE 26) ascorbic acid, L-ascorbate stearic acid esters, sodium L-ascorbate, L-aspartic acid, sodium L-aspartate, acetyltryptophan sodium, acetanilide, aprotinin solution, aminoethylsulfonic acid, aminoacetic acid, DL-alanine, L-alanine, benzalkonium chloride, sorbic acid.
- stearic acids such as stearic acid, calcium stearate and magnesium stearate
- waxes such as white beeswax and carnauba wax
- sulphates such as sodium sulphate
- silicic acid compounds such as magnesium silicate and light silicic anhydride
- lauryl sulphates such as sodium lauryl sulphate, cocoa butter, carmellose calcium, carmellose sodium, callopeptide, hydrated silicon dioxide, hydrated amorphous silicon oxide, dry aluminum hydroxide gel, glycerin, light liquid paraffin, hydrogenated oil, synthetic aluminum silicate, sesame, wheat starch, talc, macrogols, phosphoric acid.
- a detergent agent By way of example of a detergent agent, mention may be made of polyacrylates, acrylic / maleic copolymers, monomeric polycarbonates such as citrates, gluconates, oxydisuccinate, mono- and tri-succinates glycerols, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates and hydroxyethyliminodiacetates.
- the compressed solid composition may also comprise at least one active ingredient, at least one filler and optionally at least one additive that may be chosen from effervescent agents, detergent agents, sequestering agents and pelletizing additives. bleaching agents, polymers, surfactants, flow agents, stabilizing agents, anti-foaming agents, coloring agents or lubricating agents.
- the compressed solid composition may be in tablet form and finds application in the field of washing and / or household cleaning, agricultural and industrial. As an example of washing and / or household cleaning we can mention the washing machine such as washing in particular in a dishwasher.
- the compressed solid composition for non-oral use according to the invention has a friability of between 5% and 15%, preferably of between 5% and 11%, and especially of between 6% and 8%. .
- the compressed solid composition for non-oral use according to the invention has a hardness of between 50 N and 90 N, preferably between 60 N and 80 N, and especially between 70 N and 75 N .
- the compressed solid composition for non-oral use according to the invention has a dust content (dust area) of less than 3, preferably less than 2.5, and most preferably less than 2.
- the compressed solid composition for non-oral use in accordance with the invention can be packaged in bags in order to keep it free from moisture and to provide additional protection for the handling and / or transport and / or storage.
- the bag is a biodegradable bag and / or water soluble.
- the compressed solid composition comprising fermented molasses as a binding agent and / or disintegrant is in the form of an effervescent cleaning roller for toilets, dishwasher tablets, tablets calcium hypochlorite for pool, granulated fertilizer.
- compressed solid composition that may be in the form of a multilayer tablet, and especially a multilayer dishwasher tablet, mention may be made of the composition given in the table below:
- Another object of the invention is the use of fermented molasses as a binding and / or disintegrating agent for the manufacture of a compressed solid composition for non-oral use.
- the fermented molasses is as defined above.
- the use of fermented molasses as a binding and / or disintegrating agent in a compressed solid composition is doubly advantageous.
- the use according to the invention makes it possible to propose a new recovery route for molasses which until now was solely intended for spreading or for animal feed.
- the use according to the invention allows the substitution of synthetic binders conventionally used and thus obtain compressed solid compositions that are more respectful of the environment.
- the amounts used of fermented molasses within the compressed solid composition may be from 0.1% to 15% by weight, preferably from 0.5% to 5% by weight, and still more preferably from 0.5% to 1.5% by weight relative to the total weight of the compressed solid composition.
- the compressed solid composition may be as defined above and may be in the form of a single-layer or multilayer tablet, a roller, a tablet, a granule, a pellet or a pellet.
- the compressed solid composition is in the form of a single-layer or multilayer tablet.
- Another subject of the invention relates to a binder and / or disintegrating composition comprising at least fermented molasses as binding agent.
- the fermented molasses according to the invention can also be used as such in a binder and / or disintegrating composition containing one or more other constituents of any kind, including binding or suitable, for example, to increase the mechanical strength of the final product, in particular an agglomerate, or to minimize the phenomena of erosion that may be experienced by said agglomerate during its handling or storage.
- the fermented molasses is as defined above.
- the binder composition according to the invention may also comprise a curing agent, that is to say able to further improve the binding power.
- the fermented molasses can be adjuvanted in particular to present particular physical properties.
- the molasses may be adjuvanted with a compound chosen from the group comprising cellulose derivatives such as carboxymethylcellulose, lignins, hemicelluloses, ethyl cellulose, methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, derivatives thereof.
- starch products such as starch from wheat, maize, cassava, tapioca, potato, rice, dextrins and other modified starches, dextrans, sugar derivatives such as glucose, fructose, lactose, sucrose, sucrose, sorbitol, glycerol, natural gums such as diutan, gelan, xanthan, carrageenan, pectins, alginates, chitosan, gum arabic, tragacanth, locust bean, acacia, agar agar, guar, production derivatives such as beet pulp, chicory pulp, dried or uncooked apple pomace, sugarcane bagasse, citrus pulp, fruit juice waste, gum production waste, the dec starch hoes, mineral drifts, smectites, bentonites and other silica-derived clays, lime, magnesia and the like from the same family as well as mixtures of several of these compounds.
- sugar derivatives such as glucose, fruct
- Another subject of the invention relates to a method of manufacturing a compressed solid composition for non-oral use comprising the following steps:
- the first step of the process therefore consists in providing an active material, a filler and optionally at least one additive chosen from effervescent agents, detergent agents, sequestering agents, pelletizing additives, bleaching agents, polymers, surfactants, flow agents, stabilizing agents, anti-foaming agents, coloring agents or lubricating agents.
- the active ingredient and the filler are selected by those skilled in the art depending on the desired application for the compressed solid composition.
- the fermented molasses is then incorporated in a second step to the compounds provided according to the first step of the process so as to obtain a mixture.
- Fermented molasses is
- SUBSTITUTE SHEET (RULE 26) as defined above, namely in particular the coproduct obtained by fermentation of molasses.
- the amounts of molasses to be incorporated according to this step may be from 0.1% to 15% by weight, preferably from 0.5% to 5% by weight, and still more preferably from 0.5% to 1.5% by weight. weight relative to the total weight of the mixture.
- the incorporation step may be performed by techniques known to those skilled in the art which result in obtaining a mixture.
- the incorporation step may for example be obtained by spray age.
- the third step of the process according to the invention consists of a compaction step that can be carried out according to the techniques known to those skilled in the art resulting in the compression or agglomeration of the mixture prepared in the previous step.
- the compacting step may for example be carried out by pressure-compaction on a rotary press, by pelletizing, by granulation, by nodulation, by extrusion or by atomization.
- the compression-compaction compaction step can be implemented via a rotary press.
- the compacting step thus makes it possible to obtain a compressed solid composition that can be in several forms, for example a single-layer or multilayer tablet, a roller, a tablet, a granule, a pellet or a pellet.
- the method according to the invention may also comprise a drying step after the incorporation and / or compaction step.
- Friability test This test consists of measuring the loss of mass of the compressed solid composition after rotations in a drum at 25 rotations / min for 2 minutes. This test is implemented via the FT2 machine distributed by SOTAX. The friability is determined according to the formula below:
- ml corresponds to the mass of the composition before the rotations, and m2 to the mass of the composition after rotations.
- Disintegration This test consists in measuring the disintegration time of the compressed solid composition in a liquid medium. Fe test is implemented by an apparatus performing
- the first to-and-fro corresponds to T 0 and when there is no more solid composition residue compressed in the basket, the time elapsed since T 0 corresponds to the disintegration time.
- the value of the disintegration time is given in minutes, and corresponds to the average of 5 measurements.
- Hardness The hardness is calculated using a Synergie 100 traction machine (MTS) and Test works 4 software and corresponds to the force required to break the compressed solid composition. The hardness is expressed in Newton (N) and corresponds to the average of 5 measurements.
- Dust rate The measurement is carried out via the DustMon L machine and DustMon L software according to the manufacturer's recommendations. The measurement consists of evaluating the concentration of dust of a mass of compressed solid composition during its fall at the time of its passage in front of a laser beam. The value is given in dust area.
- EXAMPLE 1 Preparation of a compressed solid composition for non-oral use comprising fermented molasses as a binder and / or disintegrant.
- the compressed solid composition is in the form of a multilayer tablet composed of a first layer, an intermediate layer and a third layer.
- a mixture of fermented molasses of beet and cane is used.
- the mixture contains about 90% fermented beet molasses and about 10% fermented cane molasses.
- Fermented molasses has a dry matter content of 60%. This fermented molasses is then adjuvanted with carboxymethylcellulose in an amount (dry / dry) of 0.2%.
- the adjuvanted fermented molasses is mixed in an amount (dry / dry) with other compounds to obtain the first and third layer of the tablet.
- the compositions of all the layers of the tablet are listed below:
- Each composition is then compacted one on the other by means of a rotary press so as to obtain a compressed solid composition in the form of a multilayer tablet.
- SUBSTITUTE SHEET (RULE 26)
- the compressed solid composition according to the invention has good mechanical properties and can thus be easily handled and transported without breaking or generating significant amounts of fines. It also has a disintegration time compatible with applications in the cleaning field for which disintegration times of less than 12 min (based on the protocol described above) are generally sought.
- COMPARATIVE EXAMPLE 1 Preparation of a compressed solid composition for non-oral use comprising polyethylene glycol (PEG) as a binding and / or disintegrating agent.
- PEG polyethylene glycol
- Polyethylene glycol is mixed in an amount (dry / dry) with other compounds to obtain the first and third layer of the tablet.
- the compositions of all the layers of the tablet are listed below:
- Each composition is then compacted according to the same protocol as Example 1 by means of a rotary press so as to obtain a solid composition compressed in the form of a multilayer tablet.
- fermented molasses according to the invention as a binder and / or disintegrant is also a good alternative to the chemical binders conventionally used while allowing a new product recovery route. until then only intended for spreading or animal feeding.
- the purpose of this example is to demonstrate the good binding properties of fermented molasses according to the invention.
- Binder solution 1 fermented cane molasses with a solids content of 60%.
- Binder solution 2 a mixture containing 90% fermented beet molasses, 10% fermented cane molasses and having a solids content of 60%.
- Binder solution 3 control: Bretax C (lignosulfonate, Burgo Company). Bretax C is a known binder of the market.
- Each of the binder solutions is used to be sprayed onto the carbon black and allow it to granulate.
- the carbon black is disposed in the tank (5L) of the pilot shear mixer in which the stirring member is rotated.
- a mass quantity of 5% by weight relative to the weight of the carbon black is sprayed inside the vessel by means of a bi-fluid nozzle so as to allow the granulation of the carbon black.
- the parameters of the pilot mixer are as follows:
- Pulsed pressure 0, 1 bar.
- the obtained carbon black granules were analyzed by laser granulometry to analyze the effect of each binder solution.
- Fermented molasses is used in this example to granulate a fermented cane molasses powder.
- the products implemented are listed below:
- Fermented molasses 1 fermented cane molasses with a solids content of 60%.
- Fermented molasses 2 mixture of fermented molasses of beet and cane. The mixture contains about 90% fermented beet molasses and about 10% fermented cane molasses. Fermented molasses has a dry matter content of 60%. This fermented molasses is then adjuvanted with carboxymethylcellulose in an amount (dry / dry) of 0.2%.
- Fermented molasses 1 and 2 are used as a binder and / or disintegrating composition on fermented cane molasses powder.
- the fermented molasses are used to granulate the powder and thus obtain compressed solid compositions.
- the granules obtained were then analyzed.
- the granulation is carried out on a wet granulator (model VG-25, GLATT Company) and according to the conditions below:
- 1501.4 g of molasses powder fermented cane is disposed within the granulator.
- the granulation is then carried out with 10% by weight of a liquid solution of molasses 1 relative to the weight of powder.
- the amount of solution sprayed is 150 g and the rate of liquid molasses solution 1 spray / fermented raw cane molasses powder is 10%.
- the granulator is the same as that of test 1 and the operating conditions are the same except for the setting of the mixer which is set at 600 U / min.
- SUBSTITUTE SHEET (RULE 26) The duration here expresses the time required for the different samples to arrive at the passage of the air / water interface.
- the results show that the granules obtained have a significant decrease in wettability.
- the fermented molasses according to the invention makes it possible to improve this parameter and thus to demonstrate the good binding properties.
- the disintegration test is carried out on the granules obtained in test 1 and 2 above in order to highlight the disintegrating effect of fermented molasses.
- the test is carried out according to the following protocol:
- this example thus demonstrates the binding and disintegrating properties of the fermented molasses according to the invention. Indeed, its implementation allows to obtain compressed solid compositions in the form of granules, said granules can then disintegrate under the action of water.
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Abstract
Description
Claims
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FR1761555A FR3074500B1 (fr) | 2017-12-01 | 2017-12-01 | Composition solide comprimee pour usage non oral |
PCT/EP2018/083232 WO2019106190A1 (fr) | 2017-12-01 | 2018-11-30 | Composition solide comprimee pour usage non oral |
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JP (2) | JP2021504535A (fr) |
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DK (1) | DK3717615T3 (fr) |
ES (1) | ES2941537T3 (fr) |
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---|---|---|---|---|
FR1211066A (fr) * | 1958-10-01 | 1960-03-14 | Melle Usines Sa | Procédé d'extraction de l'acide eitrique de ses solutions aqueuses |
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JPS5562877A (en) * | 1978-11-02 | 1980-05-12 | Nisshin Oil Mills Ltd | Solid fertilizer |
JPS5849796A (ja) * | 1981-09-19 | 1983-03-24 | Nippon Oil & Fats Co Ltd | 石炭−水スラリ−用添加剤 |
DE3821950A1 (de) * | 1988-06-29 | 1990-01-04 | Bp Benzin Und Petroleum Ag | Verfahren zur herstellung von wasserfesten kohleformlingen |
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JP3476188B2 (ja) * | 2000-07-31 | 2003-12-10 | ト部産業株式会社 | カキ殻を含んだ肥料 |
ATE371716T1 (de) | 2004-01-12 | 2007-09-15 | Procter & Gamble | Tabletten mit verbessertem bruchswiderstand |
JP4482631B2 (ja) * | 2004-02-20 | 2010-06-16 | 株式会社Em研究機構 | 発酵技術を応用した洗浄剤及びその製造方法 |
US20050271739A1 (en) * | 2004-06-08 | 2005-12-08 | Wang Xiang H | Methods and compositions for accelerating alcohol metabolism |
US20060201877A1 (en) * | 2005-03-10 | 2006-09-14 | Baldridge John W | Septic system cleaning |
JP5586143B2 (ja) * | 2008-11-20 | 2014-09-10 | 株式会社古田産業 | パームアッシュカリ肥料 |
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CN103183530A (zh) * | 2013-03-12 | 2013-07-03 | 南宁市英德肥业有限责任公司 | 利用糖蜜发酵液制作甘蔗专用复混肥的方法 |
KR101343133B1 (ko) * | 2013-08-14 | 2013-12-17 | 주식회사 이엠에코 | 미강과 한방생약성분이 함유된 미용비누 조성물 및 이를 이용한 비누 제조방법 |
KR101565506B1 (ko) | 2013-12-26 | 2015-11-03 | 주식회사 포스코 | 성형탄용 바인더의 제조 방법 및 이를 포함하는 성형탄의 제조 방법 |
CN104030768A (zh) * | 2014-07-01 | 2014-09-10 | 广西力源宝科技有限公司 | 一种糖蜜酒精发酵液用于肥料造粒的方法 |
CN105732226A (zh) * | 2016-03-02 | 2016-07-06 | 福建珠山复合肥有限公司 | 一种悬浮型起苗液体复合肥及其制备方法 |
CN106212911A (zh) * | 2016-07-22 | 2016-12-14 | 青岛农业大学 | 一种能同时降低奶牛氮、磷和甲烷排放量的精饲料 |
CN106380359A (zh) * | 2016-08-26 | 2017-02-08 | 靖西县卉美花卉种植专业合作社 | 非洲菊的种植用基肥及其制作方法 |
CN107056478A (zh) * | 2017-05-18 | 2017-08-18 | 福建省农业科学院茶叶研究所 | 一种含硒肥料的配方 |
-
2017
- 2017-12-01 FR FR1761555A patent/FR3074500B1/fr active Active
-
2018
- 2018-11-30 FI FIEP18808026.1T patent/FI3717615T3/en active
- 2018-11-30 RU RU2020121589A patent/RU2768832C2/ru active
- 2018-11-30 US US16/768,808 patent/US11760961B2/en active Active
- 2018-11-30 EP EP18808026.1A patent/EP3717615B1/fr active Active
- 2018-11-30 JP JP2020529252A patent/JP2021504535A/ja active Pending
- 2018-11-30 ES ES18808026T patent/ES2941537T3/es active Active
- 2018-11-30 CN CN201880003752.XA patent/CN110114451B/zh active Active
- 2018-11-30 DK DK18808026.1T patent/DK3717615T3/da active
- 2018-11-30 WO PCT/EP2018/083232 patent/WO2019106190A1/fr unknown
- 2018-11-30 PL PL18808026.1T patent/PL3717615T3/pl unknown
- 2018-11-30 HU HUE18808026A patent/HUE061352T2/hu unknown
- 2018-11-30 PT PT188080261T patent/PT3717615T/pt unknown
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2023
- 2023-07-07 JP JP2023112505A patent/JP2023134594A/ja active Pending
- 2023-08-01 US US18/363,141 patent/US20230374421A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
FR3074500B1 (fr) | 2020-06-12 |
RU2768832C2 (ru) | 2022-03-24 |
WO2019106190A1 (fr) | 2019-06-06 |
PL3717615T3 (pl) | 2023-06-19 |
FI3717615T3 (en) | 2023-03-30 |
ES2941537T3 (es) | 2023-05-23 |
US11760961B2 (en) | 2023-09-19 |
HUE061352T2 (hu) | 2023-06-28 |
FR3074500A1 (fr) | 2019-06-07 |
RU2020121589A3 (fr) | 2022-01-12 |
JP2023134594A (ja) | 2023-09-27 |
CN110114451A (zh) | 2019-08-09 |
EP3717615B1 (fr) | 2023-01-18 |
CN110114451B (zh) | 2022-04-01 |
DK3717615T3 (da) | 2023-03-27 |
US20230374421A1 (en) | 2023-11-23 |
RU2020121589A (ru) | 2022-01-12 |
PT3717615T (pt) | 2023-04-04 |
US20210171879A1 (en) | 2021-06-10 |
JP2021504535A (ja) | 2021-02-15 |
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