EP3623509B1 - Fabric made of twisted yarns - Google Patents

Fabric made of twisted yarns Download PDF

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Publication number
EP3623509B1
EP3623509B1 EP18194179.0A EP18194179A EP3623509B1 EP 3623509 B1 EP3623509 B1 EP 3623509B1 EP 18194179 A EP18194179 A EP 18194179A EP 3623509 B1 EP3623509 B1 EP 3623509B1
Authority
EP
European Patent Office
Prior art keywords
fabric
weight
staple fibres
yarns
cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP18194179.0A
Other languages
German (de)
French (fr)
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EP3623509A1 (en
Inventor
Friedrich Suchomel
Dieter Eichinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lenzing AG
Original Assignee
Lenzing AG
Chemiefaser Lenzing AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP18194179.0A priority Critical patent/EP3623509B1/en
Application filed by Lenzing AG, Chemiefaser Lenzing AG filed Critical Lenzing AG
Priority to ES18194179T priority patent/ES2879348T3/en
Priority to PT181941790T priority patent/PT3623509T/en
Priority to PCT/EP2019/073786 priority patent/WO2020053080A1/en
Priority to US17/275,239 priority patent/US11713523B2/en
Priority to CN201980059820.9A priority patent/CN112654739B/en
Priority to KR1020217008974A priority patent/KR102589588B1/en
Priority to JP2021513772A priority patent/JP2022500567A/en
Publication of EP3623509A1 publication Critical patent/EP3623509A1/en
Application granted granted Critical
Publication of EP3623509B1 publication Critical patent/EP3623509B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • D03D1/0041Cut or abrasion resistant
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/41Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific twist
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/54Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads coloured
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00Industrial
    • D10B2505/12Vehicles

Definitions

  • the present invention relates to a fabric made from interwoven threads which is suitable for use in automobile applications, in particular as a fabric cover in automobile seats.
  • the invention relates to fabrics for use in automobile seats (in particular for the surfaces which come into contact with the vehicle occupants) and to automobile seats which contain the fabrics according to the invention.
  • fabrics are subject to strong mechanical stress over many years of use, but may show as little wear as possible. Wear is caused in particular by chafing and pilling.
  • the seating comfort can be noticeably increased through the use of fibers with good moisture absorption capacity.
  • Cellulosic fibers and wool would be particularly suitable for this, but these usually have a significantly reduced rub resistance and increased pilling compared to synthetic fibers.
  • Car seat fabrics currently consist mainly of synthetic fibers and mainly 100% polyester fibers (yarn dyed / spun-dyed) or a mixture with wool.
  • polyester fibers polyester fibers
  • inexpensive filament yarn is predominantly used, with a high-priced worsted yarn being used in a mixture with wool.
  • High demands placed on car seat fabrics by German OEMs in particular include high abrasion resistance, no occurrence of pilling and fastness to rubbing, especially fastness to wet rubbing. Since the emissions scandal and the increasing production of electric cars, the argument of sustainability has become more and more important for the automotive industry.
  • recycled polyester with or without wool is used for the production of car seat fabrics.
  • the object of the present invention is to provide a fabric which can be used in particular as a car seat fabric, in which at least part of the currently used polyester fiber materials is replaced by cellulosic fibers.
  • the invention relates to the use of the fabric according to the invention in automotive applications, a method for determining whether a fabric or the yarns contained therein is suitable for automotive applications, and a method for producing a fabric which includes the step of checking whether the fabric or The yarns contained therein are suitable for automotive applications.
  • the fabric according to the invention consists of twisted threads (warp and weft threads) interwoven in a manner known per se, the twisted threads in turn each consisting of two threads twisted together, which contain fibers.
  • the fabrics according to the invention contain at least a certain proportion of yarns which contain cellulosic staple fibers of the types Lyocell (hereinafter: “Lyocell fibers”) and / or of the types viscose (hereinafter: “Viscose fibers”) and / or modal (hereinafter “modal fibers”).
  • Lyocell fibers cellulosic staple fibers of the types Lyocell
  • Viscose fibers types viscose
  • modal fibers hereinafter “modal fibers”
  • Lyocell fibers are cellulose fibers that are obtained by spinning solutions of cellulose without derivatization.
  • Viscose and modal fibers are fibers that are obtained by spinning a cellulose derivative (cellulose xanthogenate) and, in the case of modal fibers, are also characterized by certain textile parameters.
  • At least one of the yarns twisted together to form a twisted thread contains a mixture of polyester fibers and the cellulosic staple fibers mentioned.
  • the cellulosic staple fibers in the yarn are preferably either only lyocell fibers or only modal fibers or only viscose fibers. However, mixtures are also possible.
  • Lyocell fibers or modal fibers or mixtures of lyocell fibers and modal fibers are preferably used as cellulosic staple fibers.
  • different yarns can be used in a fabric according to the invention, which yarns have different compositions, both with regard to the type of cellulosic staple fibers contained and their mixing ratio with the polyester staple fibers.
  • the proportion of cellulosic staple fibers in the fabric according to the invention is 10% by weight or more, preferably 20% by weight or more, particularly preferably 30% by weight or more.
  • the upper limit of the proportion of cellulosic staple fibers in the fabric can be up to 90% by weight, in particular up to 70% by weight, preferably up to 60% by weight, particularly preferably up to 50% by weight.
  • the proportion of cellulosic staple fibers can be 10% by weight to 90% by weight, preferably 20% by weight to 70% by weight, in particular 30% by weight to 60% by weight. %.
  • Lyocell 1
  • Modal 2
  • the value for type of fiber Cell 1.2 (1 * 0.8 + 2 * 0.2) Titer Cell Single fiber titer of the cellulose staple fibers contained in [dtex], for mixtures of lyocell and viscose and / or modal depending on the weight percentage.
  • the automotive industry usually requires a chafing score of at least 3 with a number of chafing cycles of 35,000 to 60,000, in particular 50,000 to 60,000, and a print run pressure of 12 kPa.
  • the abrasion rating is given as a measure of the discoloration / graying of the sample according to ISO 105-A02 on a scale from 1 (worst value) to 5 (best value). From a value of 3, the fabric can be considered suitable for use in automobile seats. The requirement can vary depending on the positioning of the fabric in the automobile seat (e.g. side panels compared to the center panel), which is reflected either in a lower requirement for the abrasion mark or a lower number of abrasion cycles.
  • the automotive industry demands a certain (low) degree of damage to the fabric after the end of the abrasion test (i.e. after a number of abrasions of 35,000 to 60,000, in particular 50,000 to 60,000). If two (or more) thread breaks appear at the scuffed point upon visual inspection, the fabric is considered unsuitable for use in car seats.
  • the fabric according to the invention fulfills the two formulas a) and b) above, it also achieves a chafe rating of at least 3 and the desired (low) degree of damage for a given number of chafing cycles.
  • the titer Cell is preferably 0.9 dtex, particularly preferably 1.25 dtex.
  • the cut length of the contained cellulosic staple fiber cut length Cell is preferably 34 mm, particularly preferably 38 mm.
  • titer Cell ⁇ 2.4 dtex and for cut length Cell are preferably 50 mm.
  • the twist coefficient Z ⁇ of those twisted yarns which contain yarns with cellulosic staple fibers is 140-165.
  • twist coefficient G ⁇ of those yarns which contain cellulosic staple fibers is preferably 90-135, in particular 110-135
  • the weight per unit area of the fabric according to the invention can preferably be 180-500 [g / m 2 ].
  • the cellulosic staple fibers contained in a fabric according to the invention can be dyed, in particular spun-dyed.
  • spin dyeing to be the admixture of a dye into the spinning solution from which the fiber is spun, or into a precursor thereof. This creates fibers that are not only colored on the surface, but also through their fiber matrix.
  • Another preferred embodiment of the fabric according to the invention is characterized in that some of the threads contain a polyester filament yarn or consist of polyester filament yarns.
  • polyester filament yarns does not play a role in the suitability of the fabrics according to the invention in automobile seats.
  • Another preferred embodiment of the fabric according to the invention is characterized in that the fabric, in addition to polyester staple fibers, lyocell staple fibers, Viscose staple fibers and / or modal staple fibers and possibly polyester filament yarns contain no further textile fiber materials.
  • Another aspect of the present invention relates to the use of a fabric according to the invention in automobile applications, in particular as a fabric cover in automobile seats.
  • the fabric is suitable for use in automobiles, in particular in automobile seats.
  • the lower limits can be selected by a person skilled in the art depending on the specifications given by the customer (automobile manufacturer). If, for example, the customer considers a slightly lower abrasion score (e.g. 3) or the achievement of a certain abrasion score with a lower number of abrasion cycles (e.g. 35,000) to be sufficient for a certain application, the lower limit of the value for the expression a 'can be in the lower range (ab 100,000).
  • the person skilled in the art can thus determine in the course of the production of a fabric on the basis of the parameters of the yarns, twisted threads and the fabric that are planned, whether a suitable fabric can be produced with them. If this is not the case because the desired values (right-hand side of the formula) are not met, the person skilled in the art can change one or more parameters accordingly.
  • Yarns were made from polyester staple fibers and lyocell staple fibers as well as spun-dyed modal staple fibers. Every two of these yarns were twisted into one thread, and the resulting threads were woven together into one fabric.
  • the (weight) ratio of cellulosic staple fibers to polyester staple fibers in the yarns was in each case 30 to 70.
  • the resulting fabrics were subjected to a Martindale scouring test.
  • the number of abrasion cycles was 50,000 revolutions in each case, with the exception of those fabrics, the cellulose fibers, which had a cut length of 75 mm. With these fabrics the number of abrasion revolutions was 60,000 revolutions.
  • Table 1 lists the parameters relevant to formula a), the value resulting when inserted into the left-hand part of formula a), and the chafing score actually obtained.
  • Table 2 lists the parameters relevant for formula b), the value resulting when inserted into the left-hand part of formula b) and the result of the actual assessment of the degree of damage ("0" for "no damage", ie less than 2 Thread breaks at the rubbed point, "1" for "damage”, i.e. 2 or more thread breaks at the rubbed point): Table 1: Example no.
  • Type of fiber Cell Titer Cell (dtex) Cutting length Cell (mm) Cutting length PET (mm) Z ⁇ G ⁇ Weight per unit area (g / m 2 ) Warp density (thread / 10cm) Weft density (Fd / 10cm) Result formula Measured chafing note 1 1 1.4 38 38 133 110 304 275 124 149814 3 2 1 2.8 50 50 154 120 299 272 124 224817 4.5 3 1 3.3 60 60 165 125 302 272 124 174819 3.5 4th 2 3.3 51 60 160 135 328 316 188 224865 4.5 5 2 3.3 51 60 160 135 232 272 124 149919 3 6th 1 2.8 50 60 165 125 300 248 168 172418 3.5 7th 1 3.3 60 60 165 125 300 248 168 174833 3.5 8th 2 2.5 50 60 165 125 300 248 168 202306 4th 9 1 4.7 75 78.4 151 90 300 248
  • Type of fiber Cell Titer Cell (dtex) Cutting length Cell (mm) Cutting length PET (mm) Z ⁇ G ⁇ Weight per unit area (g / m 2 ) Warp density (thread / 10cm) Weft density (Fd / 10cm) Yarn titer (dtex) Result formula damage 1 1 1.4 38 38 133 110 304 275 124 769.23 974 2 1 2.8 50 50 154 120 299 272 124 714.29 1984 0 3 1 3.3 60 60 165 125 302 272 124 714.29 1983 0 4th 2 3.3 51 60 160 135 328 316 188 588.24 2054 0 5 2 3.3 51 60 160 135 232 272 124 588.24 1994 0 6th 1 2.8 50 60 165 125 300 248 168 714.29 1989 7th 1 3.3 60 60 165 125 300 248 168 714.29 1989 0 8th 2 2.5 50 60 165 125 300 248 168 7
  • Example 1 corresponds to the requirements in terms of the scuff rating in the scouring test (the condition of formula a) is met, see Table 1), but does not meet the condition of formula b) (see Table 2) and therefore showed too high a degree of damage on.

Description

Die vorliegende Erfindung betrifft ein Gewebe aus miteinander verwobenen Zwirnen, welches sich zur Verwendung in Automobil-Anwendungen, insbesondere als Stoffbezug in Automobilsitzen eignet.The present invention relates to a fabric made from interwoven threads which is suitable for use in automobile applications, in particular as a fabric cover in automobile seats.

Die Erfindung betrifft Gewebe für die Verwendung in Automobilsitzen (insbesondere für die Flächen, die in Kontakt mit den Fahrzeuginsassen kommen) sowie Automobilsitze, die die erfindungsgemäßen Gewebe enthalten. Derartige Gewebe unterliegen während des meist langjährigen Gebrauchs starker mechanischer Beanspruchung, dürfen aber möglichst wenig Verschleiß zeigen. Verschleiß wird insbesondere durch Scheuern und Pilling hervorgerufen.The invention relates to fabrics for use in automobile seats (in particular for the surfaces which come into contact with the vehicle occupants) and to automobile seats which contain the fabrics according to the invention. Such fabrics are subject to strong mechanical stress over many years of use, but may show as little wear as possible. Wear is caused in particular by chafing and pilling.

Gleichzeitig steigen die Anforderungen an einen guten Sitzkomfort immer mehr an. Der Sitzkomfort kann spürbar erhöht werden durch die Verwendung von Fasern mit gutem Feuchtigkeitsaufnahmevermögen. Dafür kämen vor allem cellulosische Fasern und Wolle in Frage, aber diese haben üblicherweise eine im Vergleich zu Synthesefasern deutlich reduzierte Scheuerfestigkeit und erhöhtes Pilling.At the same time, the requirements for good seating comfort are increasing. The seating comfort can be noticeably increased through the use of fibers with good moisture absorption capacity. Cellulosic fibers and wool would be particularly suitable for this, but these usually have a significantly reduced rub resistance and increased pilling compared to synthetic fibers.

Autositzstoffe bestehen derzeit vorwiegend aus Synthesefasern und dabei hauptsächlich aus 100% Polyesterfasern (Garnfärbung / spinngefärbt) oder einer Mischung mit Wolle. In Geweben aus 100% Polyester wird überwiegend kostengünstiges Filamentgarn verwendet, wobei in Mischung mit Wolle ein hochpreisiges Kammgarn zum Einsatz kommt. Nur so können die hohen Anforderungen der Automobilindustrie erfüllt werden. Hohe Anforderungen, welche insbesondere von deutschen OEMs an Autositzstoffe gestellt werden, umfassen eine hohe Abriebfestigkeit, kein Auftreten von Pilling und Reibechtheit, insbesondere Naßreibechtheit. Seit dem Abgasskandal und der steigenden Produktion von Elektroautos wird das Argument der Nachhaltigkeit für die Automobilindustrie immer wichtiger. Gemäß dem Stand der Technik wird infolgedessen recyceltes Polyester mit oder ohne Wolle für die Produktion von Autositzstoffen verwendet. Der Einsatz von Baumwolle als ökologisch nachhaltigere Faser ist nicht möglich, da sie einen zu geringen Faserdurchmesser (schlechte Scheuerbeständigkeit) hat, zu geringe Faserlänge (leichtes Pilling) und schlechte Naßreibechtheiten bei dunklen Farben. Dies resultiert daraus, dass für Baumwolle nur eine Garn- bzw. Stückfärbung und keine Spinnfärbung möglich ist. In der Vergangenheit wurden auch Viskosefasern in Kombination mit Polyesterfasern eingesetzt, siehe zum Beispiel CN 207523508 U .Car seat fabrics currently consist mainly of synthetic fibers and mainly 100% polyester fibers (yarn dyed / spun-dyed) or a mixture with wool. In fabrics made from 100% polyester, inexpensive filament yarn is predominantly used, with a high-priced worsted yarn being used in a mixture with wool. This is the only way to meet the high requirements of the automotive industry. High demands placed on car seat fabrics by German OEMs in particular include high abrasion resistance, no occurrence of pilling and fastness to rubbing, especially fastness to wet rubbing. Since the emissions scandal and the increasing production of electric cars, the argument of sustainability has become more and more important for the automotive industry. As a result, according to the state of the art, recycled polyester with or without wool is used for the production of car seat fabrics. The use of cotton as an ecologically more sustainable fiber is not possible because it has too small a fiber diameter (poor abrasion resistance), too short a fiber length (easy pilling) and poor wet rub fastness in dark colors. This results from the fact that only yarn or piece dyeing and no spin dyeing is possible for cotton. In the past, viscose fibers were also used in combination with polyester fibers, see for example CN 207523508 U .

Die eingesetzten Fasertypen hatten aber die gleichen Nachteile wie Baumwolle.However, the types of fiber used had the same disadvantages as cotton.

Die vorliegende Erfindung stellt sich zur Aufgabe ein Gewebe, welches insbesondere als Autositzstoff verwendet werden kann, zur Verfügung zu stellen, in welchem zumindest ein Teil der derzeit verwendeten Fasermaterialien aus Polyester durch cellulosische Fasern ersetzt wird.The object of the present invention is to provide a fabric which can be used in particular as a car seat fabric, in which at least part of the currently used polyester fiber materials is replaced by cellulosic fibers.

Diese Aufgabe wird durch ein Gewebe gemäß Anspruch 1 gelöst.This object is achieved by a fabric according to claim 1.

Weiters betrifft die Erfindung die Verwendung des erfindungsgemäßen Gewebes in Automobilanwendungen, ein Verfahren zur Feststellung, ob sich ein Gewebe bzw. die darin enthaltenen Garne für Automobilanwendungen eignet, sowie ein Verfahren zur Herstellung eines Gewebes, welches den Schritt der Überprüfung, ob sich das Gewebe bzw. die darin enthaltenen Garne für Automobilanwendungen eignet, enthält.Furthermore, the invention relates to the use of the fabric according to the invention in automotive applications, a method for determining whether a fabric or the yarns contained therein is suitable for automotive applications, and a method for producing a fabric which includes the step of checking whether the fabric or The yarns contained therein are suitable for automotive applications.

Bevorzugte Ausführungsformen sind in den Unteransprüchen angeführt.Preferred embodiments are given in the subclaims.

Detaillierte Beschreibung der ErfindungDetailed description of the invention

Das erfindungsgemäße Gewebe besteht aus in an sich bekannter Weise miteinander verwobenen Zwirnen (Kett- und Schussfaden), wobei die Zwirne ihrerseits jeweils aus zwei miteinander verzwirnten Garnen bestehen, welche Fasern enthalten.The fabric according to the invention consists of twisted threads (warp and weft threads) interwoven in a manner known per se, the twisted threads in turn each consisting of two threads twisted together, which contain fibers.

Anstelle herkömmlicher Gewebe, die in Automobilsitzen verwendet werden, enthalten die erfindungsgemäßen Gewebe zumindest einen gewissen Anteil an Garnen, welche cellulosische Stapelfasern der Gattungen Lyocell (im Folgenden: "Lyocellfasern" genannt) und/oder der Gattungen Viskose (im Folgenden: "Viskosefasern") und/oder Modal (im Folgenden "Modalfasern") enthalten.Instead of conventional fabrics that are used in automobile seats, the fabrics according to the invention contain at least a certain proportion of yarns which contain cellulosic staple fibers of the types Lyocell (hereinafter: "Lyocell fibers") and / or of the types viscose (hereinafter: "Viscose fibers") and / or modal (hereinafter "modal fibers").

Die Begriffe "Lyocell", "Viskose" und "Modal" sind generische Begriffe, die in der EU Textilkennzeichnungsverordnung (https://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2011:272:0001:0064:DE:PDF) näher erläutert sind. Bei Lyocellfasern handelt es sich um Cellulosefasern, die durch das Verspinnen von Lösungen der Cellulose ohne Derivatisierung erhalten werden. Bei Viskoseund Modalfasern handelt es sich um Fasern, die durch das Verspinnen eines Cellulosederivats (Cellulosexanthogenat) erhalten werden und im Fall von Modalfasern zusätzlich durch bestimmte textile Parameter gekennzeichnet sind.The terms "Lyocell", "Viscose" and "Modal" are generic terms used in the EU Textile Labeling Regulation (https://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2011:272 : 0001: 0064: DE: PDF) are explained in more detail. Lyocell fibers are cellulose fibers that are obtained by spinning solutions of cellulose without derivatization. Viscose and modal fibers are fibers that are obtained by spinning a cellulose derivative (cellulose xanthogenate) and, in the case of modal fibers, are also characterized by certain textile parameters.

In den erfindungsgemäßen Geweben enthält zumindest eines der miteinander zu einem Zwirn verzwirnten Garne ein Gemisch aus Polyesterfasern und den erwähnten cellulosischen Stapelfasern.In the fabrics according to the invention, at least one of the yarns twisted together to form a twisted thread contains a mixture of polyester fibers and the cellulosic staple fibers mentioned.

Bevorzugt liegen in dem Garn als cellulosische Stapelfasern entweder nur Lyocellfasern oder nur Modalfasern bzw. nur Viskosefasern vor. Es sind aber auch Mischungen möglich.The cellulosic staple fibers in the yarn are preferably either only lyocell fibers or only modal fibers or only viscose fibers. However, mixtures are also possible.

Bevorzugt werden als cellulosische Stapelfasern Lyocellfasern oder Modalfasern bzw. Mischungen aus Lyocellfasern und Modalfasern eingesetzt.Lyocell fibers or modal fibers or mixtures of lyocell fibers and modal fibers are preferably used as cellulosic staple fibers.

Ebenso können in einem erfindungsgemäßen Gewebe verschiedene Garne eingesetzt werden, welche verschiedene Zusammensetzungen, sowohl was die Art der enthaltenen cellulosischen Stapelfasern als auch deren Mischungsverhältnis mit den Polyesterstapelfasern betrifft, aufweisen.Likewise, different yarns can be used in a fabric according to the invention, which yarns have different compositions, both with regard to the type of cellulosic staple fibers contained and their mixing ratio with the polyester staple fibers.

Der Anteil an cellulosischen Stapelfasern im erfindungsgemäßen Gewebe liegt bei 10 Gew.% oder mehr, bevorzugt 20 Gew.% oder mehr, insbesondere bevorzugt 30 Gew.% oder mehr.The proportion of cellulosic staple fibers in the fabric according to the invention is 10% by weight or more, preferably 20% by weight or more, particularly preferably 30% by weight or more.

Die Obergrenze des Anteils an cellulosischen Stapelfasern im Gewebe kann bis zu 90 Gew.%, insbesondere bis zu 70 Gew.%, bevorzugt bis zu 60 Gew.%, besonders bevorzugt bis zu 50 Gew.% betragen.The upper limit of the proportion of cellulosic staple fibers in the fabric can be up to 90% by weight, in particular up to 70% by weight, preferably up to 60% by weight, particularly preferably up to 50% by weight.

Was die Garne betrifft, in welchen die cellulosischen Stapelfasern enthalten sind, so kann der Anteil an cellulosischen Stapelfasern 10 Gew.% bis 90 Gew.%, bevorzugt 20 Gew.% bis 70 Gew.%, insbesondere 30 Gew.% bis 60 Gew.% betragen.With regard to the yarns in which the cellulosic staple fibers are contained, the proportion of cellulosic staple fibers can be 10% by weight to 90% by weight, preferably 20% by weight to 70% by weight, in particular 30% by weight to 60% by weight. %.

An folgenden Beispielen sei der Gewichtsanteil an cellulosischen Stapelfasern in den Garnen bzw. im Gewebe weiter erläutert:

  1. 1) Gewebe aus zwei Zwirnen, die jeweils aus zwei Garnen mit je 70% Polyesterstapelfasern und 30% Modalfasern bestehen:
    Gesamtanteil an cellulosischen Stapelfasern (hier: Modalfasern) im Gewebe: 30%.
    Anteil der Modalfasern in den Garnen: jeweils 30%
  2. 2) Gewebe aus zwei Zwirnen A und B
    Zwirn A besteht aus zwei Garnen mit je 70% Polyesterstapelfasern und 30% Modalfasern
    Zwirn B besteht aus zwei Garnen mit je 50% Polyesterstapelfasern und 50% Lyocellfasern Beide Zwirne haben gleiches Gewicht.
The weight fraction of cellulosic staple fibers in the yarns or in the woven fabric is explained further using the following examples:
  1. 1) Fabric made from two threads, each consisting of two threads, each with 70% polyester staple fibers and 30% modal fibers:
    Total proportion of cellulosic staple fibers (here: modal fibers) in the fabric: 30%.
    Proportion of modal fibers in the yarns: 30% each
  2. 2) Fabric made from two threads A and B
    Twine A consists of two yarns, each with 70% polyester staple fibers and 30% modal fibers
    Twine B consists of two yarns, each with 50% polyester staple fibers and 50% lyocell fibers. Both twines have the same weight.

Gesamtanteil an cellulosischen Stapelfasern im Gewebe: 40% (Mittel aus 30% und 50%) Anteil an cellulosischen Stapelfasern in den Garnen: 30% bzw. 50%.Total proportion of cellulosic staple fibers in the fabric: 40% (mean of 30% and 50%) Proportion of cellulosic staple fibers in the yarns: 30% or 50%.

Überraschenderweise wurde gefunden, dass sich Gewebe besonders gut zur Verwendung in automobilen Anwendungen, insbesondere in Automobilsitzen, eignen, wenn das Gewebe bzw. jene darin enthaltenen Garne, welche Polyester-Stapelfasern und die cellulosischen Stapelfasern enthalten, sowie die daraus hergestellten Zwirne die folgenden Beziehungen erfüllen:

  1. a) 32881*FaserartCell + 9969*TiterCell -257*SchnittlängeCell - 20714*SchnittlängePET + 24514*Zα - 20514*Gα - 4119*Flächengewicht + 5850*Kettdichte + 3004*Schussdichte - 833018 ≥ 100.000, bevorzugt ≥ 140.000, besonders bevorzugt ≥ 170.000, insbesondere bevorzugt ≥ 195.000
  2. b) -115*SchnittlängePET + 171*Zα - 129*Gα - 29*Flächengewicht + 37*Kettdichte + 19*Schussdichte - Garntiter - 6155 ≥ 1500, bevorzugt ≥ 1800, besonders bevorzugt ≥ 1900.
Surprisingly, it has been found that fabrics are particularly suitable for use in automotive applications, in particular in automobile seats, if the fabric or those yarns contained therein, which contain polyester staple fibers and the cellulosic staple fibers, as well as the twisted threads made therefrom meet the following relationships :
  1. a) 32881 * fiber type Cell + 9969 * titer Cell -257 * cut length Cell - 20714 * cut length PET + 24514 * Z α - 20514 * G α - 4119 * weight per unit area + 5850 * warp density + 3004 * weft density - 833018 ≥ 100,000, preferably ≥ 140,000, particularly preferably 170,000, particularly preferably 195,000
  2. b) -115 * cutting length PET + 171 * Z α - 129 * G α - 29 * weight per unit area + 37 * warp density + 19 * weft density - yarn denier - 6155 ≥ 1500, preferably ≥ 1800, particularly preferably ≥ 1900.

Dabei gilt FaserartCell: Faserart der cellulosischen Stapelfaser, wobei gilt: Lyocell=1; Modal=2, für Mischungen aus Lyocell und Viskose und/oder Modal ergibt sich ein Wert zwischen 1 und 2 je nach Gewichtsanteil der Lyocell- und Viskose- bzw. Modalfasern. D.h. z.B. bei Mischungen, die Lyocell und Modal im Verhältnis 80 zu 20 enthalten, ist der Wert für FaserartCell = 1,2(1*0,8 + 2*0,2) TiterCell Einzelfasertiter der enthaltenen Cellulosestapelfasern in [dtex], für Mischungen aus Lyocell und Viskose und/oder Modal je nach Gewichtsanteil. Beispiel: Bei einer Mischung von Lyocell 1,3 dtex und Modal 1,7 dtex im Verhältnis 80 zu 20 ergibt sich ein Wert für TiterCell von 1,38 (1,3*0,8 + 1,7*0,2). SchnittlängeCell Schnittlänge der enthaltenen Cellulosestapelfasern in [mm], für Mischungen aus Lyocell und Viskose und/oder Modal je nach Gewichtsanteil wie im obigen Beispiel für TiterCell SchnittlängePET Schnittlänge der enthaltenen Polyesterstapelfasern in [mm] Zα Drehungsbeiwert des Zwirns: Z α = T × Titer 1000 ,

Figure imgb0001
wobei T die Drehung des Zwirns in Anzahl Drehungen pro Meter und Titer den Titer des Zwirns (in tex) bedeuten Gα Drehungsbeiwert des Garns, zu ermitteln analog zum Drehungsbeiwert des Zwirns Flächengewicht Flächengewicht des Gewebes in [g/m2] Kettdichte Kettdichte des Gewebes in [Fd/10cm] Schußdichte Schussdichte des Gewebes in [Fd/10cm] Garntiter Titer der Garne in [dtex] The following applies Cell type of fiber: Type of fiber of the cellulosic staple fiber, where: Lyocell = 1; Modal = 2, for mixtures of lyocell and viscose and / or modal the result is a value between 1 and 2 depending on the weight percentage of the lyocell and viscose or modal fibers. For example, for mixtures containing Lyocell and Modal in a ratio of 80 to 20, the value for type of fiber Cell = 1.2 (1 * 0.8 + 2 * 0.2) Titer Cell Single fiber titer of the cellulose staple fibers contained in [dtex], for mixtures of lyocell and viscose and / or modal depending on the weight percentage. Example: A mixture of Lyocell 1.3 dtex and Modal 1.7 dtex in a ratio of 80 to 20 results in a value for Titer Cell of 1.38 (1.3 * 0.8 + 1.7 * 0.2) . Cutting length Cell Cut length of the cellulose staple fibers contained in [mm], for mixtures of lyocell and viscose and / or modal depending on the weight fraction as in the above example for Titer Cell Cutting length PET Cut length of the polyester staple fibers contained in [mm] Z α Twist coefficient of twist: Z α = T × Titer 1000 ,
Figure imgb0001
in which T is the twist of the twine in number of twists per meter and titer denotes the titer of the twine (in tex) G α Twist coefficient of the yarn, to be determined analogously to the twist coefficient of the thread Basis weight Weight per unit area of the fabric in [g / m 2 ] Warp density Warp density of the fabric in [Fd / 10cm] Weft density Weft density of the fabric in [Fd / 10cm] Yarn titer Titer of the yarn in [dtex]

Die Ermittlung sämtlicher oben angegebenen textilen Parameter ist dem Fachmann auf diesem Gebiet geläufig.The person skilled in the art is familiar with the determination of all of the textile parameters given above.

Es hat sich überraschenderweise gezeigt, dass Gewebe, welche die obige Formeln erfüllen, die von der Autoindustrie geforderte Scheuerbeständigkeit im sogenannten "Martindale-Scheuertouren-Test" gemäß ISO 12947, insbesondere ISO 12947-2, erfüllen.It has surprisingly been found that fabrics which meet the above formulas meet the abrasion resistance required by the automotive industry in the so-called "Martindale abrasion test" according to ISO 12947, in particular ISO 12947-2.

Die Autoindustrie verlangt dabei üblicherweise eine Scheuernote von mindestens 3 bei einer Scheuertourenzahl von 35.000 bis 60.000, insbesondere 50.000 bis 60.000 und einem Auflagendruck von 12 kPa. Die Scheuernote wird als Maß der Verfärbung/Vergrauung der Probe nach ISO 105-A02 auf einer Skala von 1 (schlechtester Wert) bis 5 (bester Wert) angegeben. Ab einem Wert von 3 kann das Gewebe als für die Verwendung in Automobilsitzen geeignet betrachtet werden. Dabei kann die Anforderung je nach Positionierung des Gewebes im Automobilsitz (z.B. Seitenbahnen gegenüber Mittelbahn) variieren, was sich entweder in einer geringeren Anforderung an die Scheuernote oder einer geringeren Scheuertourenzahl wiederspiegelt.The automotive industry usually requires a chafing score of at least 3 with a number of chafing cycles of 35,000 to 60,000, in particular 50,000 to 60,000, and a print run pressure of 12 kPa. The abrasion rating is given as a measure of the discoloration / graying of the sample according to ISO 105-A02 on a scale from 1 (worst value) to 5 (best value). From a value of 3, the fabric can be considered suitable for use in automobile seats. The requirement can vary depending on the positioning of the fabric in the automobile seat (e.g. side panels compared to the center panel), which is reflected either in a lower requirement for the abrasion mark or a lower number of abrasion cycles.

Weiters verlangt die Autoindustrie einen bestimmten (geringen) Beschädigungsgrad des Gewebes nach Beendigung des Scheuertourentests (also nach einer Scheuertourenzahl von 35.000 bis 60.000, insbesondere 50.000 bis 60.000). Wenn an der gescheuerten Stelle bei visueller Betrachtung zwei (oder mehr) Fadenbrüche auftreten, wird das Gewebe als für die Verwendung in Autositzen als ungeeignet angesehen.Furthermore, the automotive industry demands a certain (low) degree of damage to the fabric after the end of the abrasion test (i.e. after a number of abrasions of 35,000 to 60,000, in particular 50,000 to 60,000). If two (or more) thread breaks appear at the scuffed point upon visual inspection, the fabric is considered unsuitable for use in car seats.

Es hat sich überraschenderweise herausgestellt, dass eine eindeutige Beziehung zwischen der Kombination der genannten Parameter und der Eignung (oder auch Nicht-Eignung) eines Gewebes für eine Anwendung insbesondere in Automobilsitzen besteht.It has surprisingly been found that there is a clear relationship between the combination of the parameters mentioned and the suitability (or also unsuitability) of a fabric for use in particular in automobile seats.

Erfüllt das erfindungsgemäße Gewebe die beiden obigen Formeln a) und b), so erreicht es auch eine Scheuernote von zumindest 3 sowie den gewünschten (niedrigen) Beschädigungsgrad bei gegebener Scheuertourenzahl.If the fabric according to the invention fulfills the two formulas a) and b) above, it also achieves a chafe rating of at least 3 and the desired (low) degree of damage for a given number of chafing cycles.

Zur Herstellung des erfindungsgemäßen Gewebes muss der Fachmann lediglich die Parameter der eingesetzten Garne, Zwirne sowie die Gewebekonstruktion dahingehend anpassen, dass die obigen Beziehungen erfüllt sind.To produce the fabric according to the invention, the person skilled in the art only has to adapt the parameters of the yarns, twisted threads and the fabric construction used so that the above relationships are met.

In einem erfindungsgemäßen Gewebe ist der TiterCell bevorzugt ≥ 0,9 dtex, besonders bevorzugt ≥ 1,25 dtex.In a fabric according to the invention, the titer Cell is preferably 0.9 dtex, particularly preferably 1.25 dtex.

Weiters bevorzugt beträgt die Schnittlänge der enthaltenen cellulosischen Stapelfaser SchnittlängeCell bevorzugt ≥ 34 mm, besonders bevorzugt ≥ 38 mm.Furthermore, the cut length of the contained cellulosic staple fiber cut length Cell is preferably 34 mm, particularly preferably 38 mm.

Für Viskosefasern gelten als besonders bevorzugte Bereiche für TiterCell ≥ 2,4 dtex und für SchnittlängeCell bevorzugt ≥ 50 mm.For viscose fibers, particularly preferred ranges for titer Cell ≥ 2.4 dtex and for cut length Cell are preferably 50 mm.

Überraschenderweise wurde festgestellt, dass man die hohen Anforderungen der Automobilindustrie mit einer Kombination von Polyesterstapelfasern mit cellulosischen Stapelfasern insbesondere dann erfüllen kann, wenn man den Titer der Stapelfasern auf mindestens 2,5 dtex und die Schnittlänge der Stapelfasern auf mindestens 50 mm erhöht.Surprisingly, it was found that the high requirements of the automotive industry can be met with a combination of polyester staple fibers with cellulosic staple fibers, especially if the titer of the staple fibers is increased to at least 2.5 dtex and the cut length of the staple fibers to at least 50 mm.

In einer weiteren bevorzugten Ausführungsform der vorliegenden Erfindung beträgt der Drehungsbeiwert Zα jener Zwirne, welche Garne mit cellulosischen Stapelfasern enthalten, 140 - 165.In a further preferred embodiment of the present invention, the twist coefficient Z α of those twisted yarns which contain yarns with cellulosic staple fibers is 140-165.

Weiters bevorzugt beträgt der Drehungsbeiwert Gα jener Garne, welche cellulosische Stapelfasern enthalten, 90 - 135, insbesondere 110 - 135Furthermore, the twist coefficient G α of those yarns which contain cellulosic staple fibers is preferably 90-135, in particular 110-135

Das Flächengewicht des erfindungsgemäßen Gewebes kann bevorzugt 180 - 500 [g/m2] betragen.The weight per unit area of the fabric according to the invention can preferably be 180-500 [g / m 2 ].

Die Kett- und Schussdichte kann der Fachmann in Abhängigkeit von der Dicke der eingesetzten Garne im Rahmen seines Fachwissens einstellen.The person skilled in the art can adjust the warp and weft density as a function of the thickness of the yarns used within the scope of his specialist knowledge.

Besonders bevorzugt ist ein Gewebe, welches eine Kombination sämtlicher oben beschriebener bevorzugte Werte aufweist, für welches also gilt:

  • TiterCell bevorzugt ≥ 0,9 dtex, besonders bevorzugt ≥ 1,25 dtex, insbesondere ≥ 2,4 dtex oder ≥ 2,5 dtex.
  • SchnittlängeCell bevorzugt ≥ 34mm, besonders bevorzugt ≥ 38 mm, insbesondere mindestens 50 mm
  • Drehungsbeiwert des Zwirns Zα 140 - 165
  • Drehungsbeiwert des Garns Gα 90 - 135, insbesondere 110 - 135
  • Flächengewicht: 80 - 500 [g/m2].
Particularly preferred is a fabric which has a combination of all of the preferred values described above, for which the following applies:
  • Titer Cell preferably ≥ 0.9 dtex, particularly preferably ≥ 1.25 dtex, in particular ≥ 2.4 dtex or ≥ 2.5 dtex.
  • Cutting length Cell preferably 34 mm, particularly preferably 38 mm, in particular at least 50 mm
  • Twist coefficient of the thread Z α 140 - 165
  • Twist coefficient of the yarn G α 90-135, in particular 110-135
  • Basis weight: 80-500 [g / m 2 ].

In einem erfindungsgemäßen Gewebe können die enthaltenen cellulosischen Stapelfasern gefärbt, insbesondere spinngefärbt sein. Unter einer Spinnfärbung versteht der Fachmann das Zumischen eines Farbstoffes in die Spinnlösung, aus welcher die Faser versponnen wird, oder in einen Vorläufer davon. Dadurch entstehen Fasern, welche nicht nur oberflächlich, sondern durchgehend über ihre Fasermatrix gefärbt sind.The cellulosic staple fibers contained in a fabric according to the invention can be dyed, in particular spun-dyed. The person skilled in the art understands spin dyeing to be the admixture of a dye into the spinning solution from which the fiber is spun, or into a precursor thereof. This creates fibers that are not only colored on the surface, but also through their fiber matrix.

Setzt man solche spinngefärbte man made Cellulosefasern innerhalb der Spezifikationen der obigen Formeln a) und b) ein, kann man selbst bei Fasern mit dunklen Farben die geforderte Spezifikation der Naßreibechtheit, die bei solchen Fasern besonders kritisch ist, erreichen.If such spun-dyed made cellulose fibers are used within the specifications of formulas a) and b) above, the required specification of wet rub fastness, which is particularly critical for such fibers, can be achieved even with dark colored fibers.

Eine weitere bevorzugte Ausführungsform des erfindungsgemäßen Gewebes ist dadurch gekennzeichnet, dass ein Teil der Zwirne ein Polyesterfilamentgarn enthält oder aus Polyesterfilamentgarnen besteht.Another preferred embodiment of the fabric according to the invention is characterized in that some of the threads contain a polyester filament yarn or consist of polyester filament yarns.

Überraschenderweise wurde gefunden, dass eine (teilweise) Verwendung von Polyesterfilamentgarnen, wie sie an sich bereits jetzt zur Herstellung von Geweben für Automobilsitzen eingesetzt werden, auf die durch die obigen Formeln a) und b) gegebenen Zusammenhänge keinen Einfluss hat.Surprisingly, it has been found that a (partial) use of polyester filament yarns, as they are already being used for the production of fabrics for automobile seats, has no influence on the relationships given by the above formulas a) and b).

Mit anderen Worten spielt ein gewisser Anteil an Polyesterfilamentgarnen für die Eignung der erfindungsgemäßen Gewebe in Automobilsitzen keine Rolle.In other words, a certain proportion of polyester filament yarns does not play a role in the suitability of the fabrics according to the invention in automobile seats.

Eine weitere bevorzugte Ausführungsform des erfindungsgemäßen Gewebes ist dadurch gekennzeichnet, dass das Gewebe außer Polyesterstapelfasern, Lyocellstapelfasern, Viskosestapelfasern und/oder Modalstapelfasern sowie ggf. Polyesterfilamentgarnen keine weiteren textilen Fasermaterialien enthält.Another preferred embodiment of the fabric according to the invention is characterized in that the fabric, in addition to polyester staple fibers, lyocell staple fibers, Viscose staple fibers and / or modal staple fibers and possibly polyester filament yarns contain no further textile fiber materials.

Ein weiterer Aspekt der vorliegenden Erfindung betrifft die Verwendung eines erfindungsgemäßen Gewebes in Automobil-Anwendungen, insbesondere als Stoffbezug in Automobilsitzen.Another aspect of the present invention relates to the use of a fabric according to the invention in automobile applications, in particular as a fabric cover in automobile seats.

Die vorliegende Erfindung betrifft auch ein Verfahren zur Feststellung der Eignung eines Gewebes aus miteinander verwobenen Zwirnen, wobei jeweils zwei Garne miteinander zu einem Zwirn verzwirnt sind und wobei zumindest eines der Garne Polyester-Stapelfasern und cellulosische Stapelfasern der Gattungen Lyocell, Viskose und/oder Modal enthält, wobei der Anteil an cellulosischen Stapelfasern im Gewebe von 10 Gew.% bis zu 90 Gew.% beträgt, für die Anwendung in Automobilen, insbesondere in Automobilsitzen, welches dadurch gekennzeichnet ist, dass für das Gewebe bzw. jene der darin enthaltenen Garne, welche Polyester-Stapelfasern und cellulosische Stapelfasern enthalten, sowie die daraus hergestellten Zwirne, die sich aus den beiden Expressionen

  • a') 32881*FaserartCell + 9969*TiterCell -257*SchnittlängeCell - 20714*SchnittlängePET + 24514*Zα - 20514*Gα - 4119*Flächengewicht + 5850*Kettdichte + 3004*Schussdichte - 833018
    und
  • b') -115*SchnittlängePET + 171*Zα - 129*Gα - 29*Flächengewicht + 37*Kettdichte + 19*Schussdichte - Garntiter - 6155
ergebenden Werte ermittelt werden und überprüft wird, ob
der sich aus der Expression a' ergebende Wert ≥ 100.000, bevorzugt ≥ 140.000, besonders bevorzugt ≥ 170.000, insbesondere bevorzugt ≥ 195.000 ist und
der sich aus der Expression b' ergebende Wert ≥ 1500, bevorzugt ≥ 1800, besonders bevorzugt ≥ 1900 ist.The present invention also relates to a method for determining the suitability of a fabric made of interwoven threads, two threads being twisted together to form a thread and at least one of the threads containing polyester staple fibers and cellulosic staple fibers of the types lyocell, viscose and / or modal , the proportion of cellulosic staple fibers in the fabric being from 10% by weight to 90% by weight, for use in automobiles, in particular in automobile seats, which is characterized in that for the fabric or those of the yarns contained therein, which Contain polyester staple fibers and cellulosic staple fibers, as well as the threads made from them, which result from the two expressions
  • a ') 32881 * fiber type Cell + 9969 * titer Cell -257 * cut length Cell - 20714 * cut length PET + 24514 * Z α - 20514 * G α - 4119 * basis weight + 5850 * warp density + 3004 * weft density - 833018
    and
  • b ') -115 * cutting length PET + 171 * Z α - 129 * G α - 29 * basis weight + 37 * warp density + 19 * weft density - yarn denier - 6155
The resulting values are determined and it is checked whether
the value resulting from the expression a 'is 100,000, preferably 140,000, particularly preferably 170,000, particularly preferably 195,000 and
the value resulting from the expression b 'is 1500, preferably 1800, particularly preferably 1900.

Die in den beiden Expressionen a' und b' verwendeten Parameter sowie deren Messung sind wie bereits oben angegeben.The parameters used in the two expressions a 'and b' and their measurement are as already indicated above.

Wenn beide sich aus den Expressionen a' und b' ergebenden Werte oberhalb der oben angegebenen Untergrenzen liegen, ist das Gewebe für die Anwendung in Automobilen, insbesondere in Automobilsitzen, geeignet.If both values resulting from the expressions a 'and b' are above the lower limits given above, the fabric is suitable for use in automobiles, in particular in automobile seats.

Die Untergrenzen können vom Fachmann in Abhängigkeit der vom Kunden (Automobilhersteller) vorgegebenen Spezifikationen gewählt werden. Wird vom Kunden z.B. für eine bestimmte Anwendung eine etwas niedrigere Scheuernote (z.B. 3) bzw. das Erreichen einer bestimmten Scheuernote bei einer geringeren Scheuertourenzahl (z.B. 35.000) als ausreichend angesehen, kann die Untergrenze des Werts für die Expression a' im niedrigeren Bereich (ab 100.000) angesetzt werden.The lower limits can be selected by a person skilled in the art depending on the specifications given by the customer (automobile manufacturer). If, for example, the customer considers a slightly lower abrasion score (e.g. 3) or the achievement of a certain abrasion score with a lower number of abrasion cycles (e.g. 35,000) to be sufficient for a certain application, the lower limit of the value for the expression a 'can be in the lower range (ab 100,000).

Weiters betrifft die vorliegende Erfindung ein Verfahren zur Herstellung eines für die Anwendung in Automobilen, insbesondere in Automobilsitzen, bestimmten Gewebes aus miteinander verwobenen Zwirnen, wobei jeweils zwei Garne miteinander zu einem Zwirn verzwirnt sind und wobei zumindest eines der Garne Polyester-Stapelfasern und cellulosische Stapelfasern der Gattungen Lyocell, Viskose und/oder Modal enthält, wobei der Anteil an cellulosischen Stapelfasern im Gewebe von 10 Gew.% bis 90 Gew.% beträgt, umfassend

  • den Schritt des Einsetzens von bestehenden oder geplanten Parameter des Gewebes bzw. der darin enthaltenen Garne, welche Polyester-Stapelfasern und cellulosische Stapelfasern enthalten, sowie der daraus hergestellten Zwirne in die Expressionen
    • a') 32881*FaserartCell + 9969*TiterCell -257*SchnittlängeCell - 20714*SchnittlängePET + 24514*Zα - 20514*Gα - 4119*Flächengewicht + 5850*Kettdichte + 3004*Schussdichte - 833018
      und
    • b') -115*SchnittlängePET + 171*Zα - 129*Gα - 29*Flächengewicht + 37*Kettdichte + 19*Schussdichte - Garntiter - 6155,
  • gegebenenfalls Anpassen der bestehenden Parameter bzw. Vervollständigen der Parameter,
sodass der sich aus der Expression a' ergebende Wert ≥ 100.000, bevorzugt ≥ 140.000, besonders bevorzugt ≥ 170.000, insbesondere bevorzugt ≥ 195.000 ist und
der sich aus der Expression b' ergebende Wert ≥ 1500, bevorzugt ≥ 1800, besonders bevorzugt ≥ 1900 ist.The present invention further relates to a method for producing a fabric intended for use in automobiles, in particular in automobile seats, from interwoven threads, two threads being twisted together to form a thread and at least one of the threads being polyester staple fibers and cellulosic staple fibers Contains genera lyocell, viscose and / or modal, the proportion of cellulosic staple fibers in the fabric being from 10% by weight to 90% by weight, comprising
  • the step of inserting existing or planned parameters of the fabric or the yarns contained therein, which contain polyester staple fibers and cellulosic staple fibers, and the twisted threads produced therefrom in the expressions
    • a ') 32881 * fiber type Cell + 9969 * titer Cell -257 * cut length Cell - 20714 * cut length PET + 24514 * Z α - 20514 * G α - 4119 * basis weight + 5850 * warp density + 3004 * weft density - 833018
      and
    • b ') -115 * cutting length PET + 171 * Z α - 129 * G α - 29 * basis weight + 37 * warp density + 19 * weft density - yarn denier - 6155,
  • If necessary, adapt the existing parameters or complete the parameters,
so that the value resulting from the expression a 'is 100,000, preferably 140,000, particularly preferably 170,000, particularly preferably 195,000 and
the value resulting from the expression b 'is 1500, preferably 1800, particularly preferably 1900.

Die in den beiden Expressionen a' und b' verwendeten Parameter sowie deren Messung sind erneut wie bereits oben definiert.The parameters used in the two expressions a 'and b' and their measurement are again as defined above.

Der Fachmann kann somit im Zuge der Herstellung eines Gewebes anhand der Parameter der Garne, Zwirne und des Gewebes, die geplant sind, feststellen, ob damit ein geeignetes Gewebe herstellbar sein wird. Falls dies aufgrund einer Nichterfüllung der gewünschten Werte (rechte Seite der Formel) nicht zutrifft, kann der Fachmann einen oder mehrere Parameter entsprechend abändern.The person skilled in the art can thus determine in the course of the production of a fabric on the basis of the parameters of the yarns, twisted threads and the fabric that are planned, whether a suitable fabric can be produced with them. If this is not the case because the desired values (right-hand side of the formula) are not met, the person skilled in the art can change one or more parameters accordingly.

Ausführungsbeispiele:Embodiments:

Aus Polyesterstapelfasern und Lyocellstapelfasern sowie spinngefärbten Modalstapelfasern wurden Garne hergestellt. Jeweils zwei dieser Garne wurden zu einem Zwirn verzwirnt, und die resultierenden Zwirne wurden miteinander zu einem Gewebe verwoben.Yarns were made from polyester staple fibers and lyocell staple fibers as well as spun-dyed modal staple fibers. Every two of these yarns were twisted into one thread, and the resulting threads were woven together into one fabric.

Das (Gewichts-)Verhältnis an cellulosischen Stapelfasern zu Polyesterstapelfasern in den Garnen betrug jeweils 30 zu 70.The (weight) ratio of cellulosic staple fibers to polyester staple fibers in the yarns was in each case 30 to 70.

Die resultierenden Gewebe wurden einem Martindale-Scheuertouren-Test ausgesetzt. Die Scheuertourenzahl betrug jeweils 50.000 Umdrehungen, mit Ausnahme jener Gewebe, die Cellulosefasern, die eine Schnittlänge von 75 mm aufwiesen. Bei diesen Geweben betrug die Scheuertourenzahl 60.000 Umdrehungen.The resulting fabrics were subjected to a Martindale scouring test. The number of abrasion cycles was 50,000 revolutions in each case, with the exception of those fabrics, the cellulose fibers, which had a cut length of 75 mm. With these fabrics the number of abrasion revolutions was 60,000 revolutions.

In den folgenden Tabellen sind die jeweiligen Parameter der eingesetzten Fasermaterialien, der Garne, der Zwirne sowie des Gewebes zusammengefasst.The following tables summarize the respective parameters of the fiber materials used, the yarns, the twisted threads and the woven fabric.

Die Tabelle 1 führt dabei die für die Formel a) relevanten Parameter, den bei Einfügen in den linken Teil der Formel a) resultierenden Wert sowie die tatsächlich erhaltene Scheuernote an.Table 1 lists the parameters relevant to formula a), the value resulting when inserted into the left-hand part of formula a), and the chafing score actually obtained.

Die Tabelle 2 führt die für die Formel b) relevanten Parameter, den bei Einfügen in den linken Teil der Formel b) resultierenden Wert sowie das Ergebnis der tatsächlichen Beurteilung des Beschädigungsgrades an ("0" für "keine Beschädigung", d.h. weniger als 2 Fadenbrüche an der gescheuerten Stelle, "1" für "Beschädigung", also 2 oder mehr Fadenbrüche an der gescheuerten Stelle): Tabelle 1: Beispiel No. FaserartCell* TiterCell (dtex) Schnitt- längeCell (mm) SchnittlängePET (mm) Zα Gα Flächengewicht (g/m2) Kettdichte (Fd/10cm) Schußdichte (Fd/10cm) Ergebnis Formel Gemessene Scheuernote 1 1 1,4 38 38 133 110 304 275 124 149814 3 2 1 2,8 50 50 154 120 299 272 124 224817 4,5 3 1 3,3 60 60 165 125 302 272 124 174819 3,5 4 2 3,3 51 60 160 135 328 316 188 224865 4,5 5 2 3,3 51 60 160 135 232 272 124 149919 3 6 1 2,8 50 60 165 125 300 248 168 172418 3,5 7 1 3,3 60 60 165 125 300 248 168 174833 3,5 8 2 2,5 50 60 165 125 300 248 168 202306 4 9 1 4,7 75 78,4 151 90 300 248 168 178591 3,5 10 1 6,7 75 78,4 151 90 300 248 168 198529 4 11 2 3,3 75 78,4 151 90 300 248 168 197515 4 * 1 = Lyocell, 2 = Modal Tabelle 2: Beispiel No. FaserartCell* TiterCell (dtex) SchnittlängeCell (mm) SchnittlängePET (mm) Zα Gα Flächengewicht (g/m2) Kettdichte (Fd/10cm) Schußdichte (Fd/10cm) Garntiter (dtex) Ergebnis Formel Beschädigung 1 1 1,4 38 38 133 110 304 275 124 769,23 974 2 1 2,8 50 50 154 120 299 272 124 714,29 1984 0 3 1 3,3 60 60 165 125 302 272 124 714,29 1983 0 4 2 3,3 51 60 160 135 328 316 188 588,24 2054 0 5 2 3,3 51 60 160 135 232 272 124 588,24 1994 0 6 1 2,8 50 60 165 125 300 248 168 714,29 1989 7 1 3,3 60 60 165 125 300 248 168 714,29 1989 0 8 2 2,5 50 60 165 125 300 248 168 714,29 1989 0 9 1 4,7 75 78,4 151 90 300 248 168 714,29 1994 0 10 1 6,7 75 78,4 151 90 300 248 168 714,29 1994 0 11 2 3,3 75 78,4 151 90 300 248 168 714,29 1994 0 * 1 = Lyocell, 2 = Modal Table 2 lists the parameters relevant for formula b), the value resulting when inserted into the left-hand part of formula b) and the result of the actual assessment of the degree of damage ("0" for "no damage", ie less than 2 Thread breaks at the rubbed point, "1" for "damage", i.e. 2 or more thread breaks at the rubbed point): Table 1: Example no. Type of fiber Cell * Titer Cell (dtex) Cutting length Cell (mm) Cutting length PET (mm) Z α G α Weight per unit area (g / m 2 ) Warp density (thread / 10cm) Weft density (Fd / 10cm) Result formula Measured chafing note 1 1 1.4 38 38 133 110 304 275 124 149814 3 2 1 2.8 50 50 154 120 299 272 124 224817 4.5 3 1 3.3 60 60 165 125 302 272 124 174819 3.5 4th 2 3.3 51 60 160 135 328 316 188 224865 4.5 5 2 3.3 51 60 160 135 232 272 124 149919 3 6th 1 2.8 50 60 165 125 300 248 168 172418 3.5 7th 1 3.3 60 60 165 125 300 248 168 174833 3.5 8th 2 2.5 50 60 165 125 300 248 168 202306 4th 9 1 4.7 75 78.4 151 90 300 248 168 178591 3.5 10 1 6.7 75 78.4 151 90 300 248 168 198529 4th 11 2 3.3 75 78.4 151 90 300 248 168 197515 4th * 1 = Lyocell, 2 = Modal Example no. Type of fiber Cell * Titer Cell (dtex) Cutting length Cell (mm) Cutting length PET (mm) Z α G α Weight per unit area (g / m 2 ) Warp density (thread / 10cm) Weft density (Fd / 10cm) Yarn titer (dtex) Result formula damage 1 1 1.4 38 38 133 110 304 275 124 769.23 974 2 1 2.8 50 50 154 120 299 272 124 714.29 1984 0 3 1 3.3 60 60 165 125 302 272 124 714.29 1983 0 4th 2 3.3 51 60 160 135 328 316 188 588.24 2054 0 5 2 3.3 51 60 160 135 232 272 124 588.24 1994 0 6th 1 2.8 50 60 165 125 300 248 168 714.29 1989 7th 1 3.3 60 60 165 125 300 248 168 714.29 1989 0 8th 2 2.5 50 60 165 125 300 248 168 714.29 1989 0 9 1 4.7 75 78.4 151 90 300 248 168 714.29 1994 0 10 1 6.7 75 78.4 151 90 300 248 168 714.29 1994 0 11 2 3.3 75 78.4 151 90 300 248 168 714.29 1994 0 * 1 = Lyocell, 2 = Modal

Aus den Tabellen geht in eindrucksvoller Weise der Zusammenhang der Eignung bzw. auch Nichteignung der jeweiligen Gewebe mit den erhaltenen Werten aus den Formeln a) und b) hervor.The tables show the connection between the suitability or unsuitability of the respective fabrics and the values obtained from formulas a) and b) in an impressive manner.

Beispiel 1 entspricht dabei zwar hinsichtlich der Scheuernote im Scheuertouren-Test den Anforderungen (die Bedingung der Formel a) ist erfüllt, siehe Tabelle 1), erfüllt aber nicht die Bedingung der Formel b) (siehe Tabelle 2) und wies daher einen zu hohen Beschädigungsgrad auf.Example 1 corresponds to the requirements in terms of the scuff rating in the scouring test (the condition of formula a) is met, see Table 1), but does not meet the condition of formula b) (see Table 2) and therefore showed too high a degree of damage on.

Claims (15)

  1. A fabric made of interwoven twines, wherein, in each case, two yarns are twisted together to form a twine and at least one of the yarns contains polyester staple fibres and cellulosic staple fibres of the types lyocell, viscose and/or modal, the share of cellulosic staple fibres in the fabric ranging from 10% by weight to 90% by weight, characterized in that the fabric or, respectively, those of the yarns contained therein which contain polyester staple fibres and cellulosic staple fibres as well as the twines produced therefrom comply with the following relationships:
    a) 32881*Fibre typecell + 9969*Titrecell -257*Cut lengthcell - 20714*Cut lengthPET + 24514*Zα - 20514*Gα - 4119*Basis weight + 5850*Warp density + 3004*Weft density - 833018 ≥ 100,000, preferably ≥ 140,000, particularly preferably ≥ 170,000, with particular preference ≥ 195,000
    b) -115*Cut lengthPET + 171*Zα - 129*Gα - 29*Basis weight + 37*Warp density + 19*Weft density - yarn titre - 6155 ≥ 1500, preferably ≥ 1800, particularly preferably ≥ 1900,
    wherein the following applies: Fibre typecell: Fibre type of the cellulosic staple fibre, wherein the following applies: lyocell = 1; viscose as well as modal = 2, for mixtures of lyocell and viscose and/or modal, the result is a value of between 1 and 2, depending on the weight percentage of the lyocell and viscose or, respectively, modal fibres. Titrecell Single fibre titre in [dtex] of the cellulose staple fibres contained, for mixtures of lyocell and viscose and/or modal, depending on the weight percentage Cut lengthcell Cut length in [mm] of the cellulose staple fibres contained, for mixtures of lyocell and viscose and/or modal, depending on the weight percentage Cut lengthPET Cut length in [mm] of the polyester staple fibres contained Zα twisting factor of the twine Gα twisting factor of the yarn Basis weight Basis weight of the fabric in [g/m2] Warp density Warp density of the fabric in [Fd/10cm] Weft density Weft density of the fabric in [Fd/10cm] Yarn titre Titre of the yarns in [dtex]
  2. A fabric according to claim 1, characterized in that Titrecell is ≥ 0.9 dtex, preferably ≥ 1.25 dtex.
  3. A fabric according to claim 1 or 2, characterized in that Cut lengthcell is ≥ 34 mm, preferably ≥ 38 mm.
  4. A fabric according to any of the preceding claims, characterized in that Zα is 140 - 165.
  5. A fabric according to any of the preceding claims, characterized in that Gα is 90 - 135, preferably 110 - 135.
  6. A fabric according to any of the preceding claims, characterized in that the basis weight is 180 - 500 [g/m2].
  7. A fabric according to any of the preceding claims, characterized in that the share of cellulosic staple fibres in the fabric is 20% by weight or more, preferably 30% by weight or more.
  8. A fabric according to claim 7, characterized in that the share of cellulosic staple fibres in the fabric is up to 70% by weight, preferably up to 60% by weight, particularly preferably up to 50% by weight.
  9. A fabric according to any of the preceding claims, characterized in that the share of cellulosic staple fibres in those yarns in which cellulosic staple fibres are contained ranges from 10% by weight to 90% by weight, preferably from 20% by weight to 70% by weight, in particular from 30% by weight to 60% by weight.
  10. A fabric according to any of the preceding claims, characterized in that the cellulosic staple fibres are spin-dyed.
  11. A fabric according to any of the preceding claims, characterized in that part of the twines contain a polyester filament yarn or consist of polyester filament yarns.
  12. A fabric according to any of the preceding claims, characterized in that the fabric contains no other textile fibre materials apart from polyester staple fibres, lyocell staple fibres, viscose staple fibres and/or modal staple fibres and, optionally, polyester filament yarns.
  13. The use of a fabric according to any of the preceding claims in automotive applications, in particular as a fabric cover in automobile seats.
  14. A process for determining the suitability of a fabric made of interwoven twines, wherein, in each case, two yarns are twisted together to form a twine and at least one of the yarns contains polyester staple fibres and cellulosic staple fibres of the types lyocell, viscose and/or modal, the share of cellulosic staple fibres in the fabric ranging from 10% by weight to 90% by weight, for use in automobiles, in particular in automobile seats, characterized in that, for the fabric or, respectively, those of the yarns contained therein which contain polyester staple fibres and cellulosic staple fibres, as well as the twines produced therefrom, the values resulting from the two expressions
    a') 32881*Fibre typeCell + 9969*TitreCell -257*Cut lengthcell - 20714*Cut lengthPET + 24514*Zα - 20514*Gα - 4119*Basis weight + 5850*Warp density + 3004*Weft density - 833018
    and
    b') -115*Cut lengthPET + 171*Zα - 129*Gα - 29*Basis weight + 37*Warp density + 19*Weft density - yarn titre - 6155
    are determined and it is checked as to whether
    the value resulting from the expression a' is ≥ 100,000, preferably ≥ 140,000, particularly preferably ≥ 170,000, with particular preference ≥ 195,000, and
    the value resulting from the expression b' is ≥ 1500, preferably ≥ 1800, particularly preferably ≥ 1900.
  15. A process for the production of a fabric made of interwoven twines, wherein, in each case, two yarns are twisted together to form a twine and at least one of the yarns contains polyester staple fibres and cellulosic staple fibres of the types lyocell, viscose and/or modal, the fabric being intended for use in automobiles, in particular in automobile seats, the share of cellulosic staple fibres in the fabric ranging from 10% by weight to 90% by weight, comprising
    - the step of inserting existing or planned parameters of the fabric or, respectively, of the yarns contained therein which contain polyester staple fibres and cellulosic staple fibres, and of the twines produced therefrom, in the expressions
    a') 32881*Fibre typeCell + 9969*TitreCell -257*Cut lengthcell - 20714*Cut lengthPET + 24514*Zα - 20514*Gα - 4119*Basis weight + 5850*Warp density + 3004*Weft density - 833018
    and
    b') -115*Cut lengthPET + 171*Zα - 129*Gα - 29*Basis weight + 37*Warp density + 19*Weft density - yarn titre - 6155
    - optionally, adapting the existing parameters or, respectively, completing the parameters,
    so that the value resulting from the expression a' is ≥ 100,000, preferably ≥ 140,000, particularly preferably ≥ 170,000, with particular preference ≥ 195,000, and
    the value resulting from the expression b' is ≥ 1500, preferably ≥ 1800, particularly preferably ≥ 1900.
EP18194179.0A 2018-09-13 2018-09-13 Fabric made of twisted yarns Active EP3623509B1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
ES18194179T ES2879348T3 (en) 2018-09-13 2018-09-13 Textile material composed of interlaced cords
PT181941790T PT3623509T (en) 2018-09-13 2018-09-13 Fabric made of twisted yarns
EP18194179.0A EP3623509B1 (en) 2018-09-13 2018-09-13 Fabric made of twisted yarns
US17/275,239 US11713523B2 (en) 2018-09-13 2019-09-06 Fabric made of interwoven twines
PCT/EP2019/073786 WO2020053080A1 (en) 2018-09-13 2019-09-06 Fabric made of interwoven twisted threads
CN201980059820.9A CN112654739B (en) 2018-09-13 2019-09-06 Fabric made of strands interwoven with one another
KR1020217008974A KR102589588B1 (en) 2018-09-13 2019-09-06 Fabric manufactured from woven twins
JP2021513772A JP2022500567A (en) 2018-09-13 2019-09-06 Fabric made of woven twisted threads

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EP18194179.0A EP3623509B1 (en) 2018-09-13 2018-09-13 Fabric made of twisted yarns

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CN111501164A (en) * 2020-05-28 2020-08-07 泉州市六源印染织造有限公司 Breathable comfortable printing and dyeing fabric and preparation method thereof

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WO2020053080A1 (en) 2020-03-19
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US11713523B2 (en) 2023-08-01
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EP3623509A1 (en) 2020-03-18
CN112654739A (en) 2021-04-13

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