EP3585985A1 - Verfahren zur konservierung - Google Patents
Verfahren zur konservierungInfo
- Publication number
- EP3585985A1 EP3585985A1 EP18720124.9A EP18720124A EP3585985A1 EP 3585985 A1 EP3585985 A1 EP 3585985A1 EP 18720124 A EP18720124 A EP 18720124A EP 3585985 A1 EP3585985 A1 EP 3585985A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- nitrogen
- steam
- condenser
- sealing
- steam turbine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K13/00—General layout or general methods of operation of complete plants
- F01K13/02—Controlling, e.g. stopping or starting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/02—Preventing or minimising internal leakage of working-fluid, e.g. between stages by non-contact sealings, e.g. of labyrinth type
- F01D11/04—Preventing or minimising internal leakage of working-fluid, e.g. between stages by non-contact sealings, e.g. of labyrinth type using sealing fluid, e.g. steam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D21/00—Shutting-down of machines or engines, e.g. in emergency; Regulating, controlling, or safety means not otherwise provided for
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K13/00—General layout or general methods of operation of complete plants
- F01K13/006—Auxiliaries or details not otherwise provided for
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K9/00—Plants characterised by condensers arranged or modified to co-operate with the engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K9/00—Plants characterised by condensers arranged or modified to co-operate with the engines
- F01K9/006—Vacuum-breakers
Definitions
- the invention relates to a power plant and a method for preserving a power plant.
- Corrosion can be prevented either by the absence of moisture (previously most common approach to steam turbine and condenser) or oxygen.
- nitrogen is already commonly used today for preventing and conserving corrosion in the steam-conducting area of the boiler and in the steam line area.
- the object of the invention is to provide a power plant with which a preservation method is possible, which is advantageous both in terms of effectiveness and cost efficiency as well as in terms of quick start capability of Krafttechniksan- plant.
- Another object of the invention is to provide a corresponding method for preservation.
- the invention solves the task directed to a power plant by providing that in such a power plant comprising a steam turbine with a shaft, a steam turbine in the steam flow downstream condenser, a condenser downstream vacuum pump, a sealing steam system with shaft seals and a in the In the condenser, a first nitrogen line opens and in the sealing steam supply line a second nitrogen line and a branching off from the vacuum pump
- the steam turbine / the condenser can be brought during the shutdown in the conserved state to a low (a few mbar) nitrogen pressure.
- the nitrogen requirement can be kept comparatively low via the recirculation line.
- the shaft seals comprise sealing steam chambers and vapor vapor chambers, the sealing steam supply line being inserted into the blocking chamber.
- dam fhimmmern opens and the Wrasendampfhuntn are connected to a Wrasendampf blower to suck in the shaft seals penetrating air and a partial flow of steam from the sealing vapor chambers and fed to a Wrasendampf- capacitor.
- the nitrogen can also be collected or withdrawn in a controlled manner and optionally fed to further use.
- nitrogen which is needed in a case of a standing, conserved plant to a significant extent or accumulates, can be recovered.
- an electric superheater is connected in the sealing steam supply line and the nitrogen line opens into the sealing steam supply line upstream of the superheater. If necessary, the warming / warming of the steam turbine can be assisted by warming up the nitrogen via the electrical superheater present in the sealing steam system (actually auxiliary steam superheater).
- the object directed to a method is achieved by a method for preserving a power plant comprising a steam turbine, a condenser downstream of the steam turbine, a vacuum pump downstream of the condenser and a sealing steam system, wherein when the steam turbine is shut down into a conserved state, nitrogen is introduced into the sealing steam system and is introduced into the condenser, and the steam turbine and the condenser are brought to nitrogen overpressure and the vacuum pump is turned off, being diverted at startup of the steam turbine to the exhaust air of the vacuum pump nitrogen and fed back to the sealing steam system.
- DichtdampfSystems is initiated.
- the electrical superheater in the sealing steam system ensures that the over The nitrogen vapor system fed nitrogen has sufficiently high temperatures for the shaft sealing steam supply.
- the sealing steam can be reduced after it has been lowered, leaving more heat in the boiler and keeping it hot and warm-startable for longer.
- the pressure can be through the
- Nitrogen make-up can be maintained on the capacitor. This procedure reduces the consumption of sticks.
- a nitrogen pressure in the steam turbine or in the condenser is increased before an expected temperature change, in particular cooling, in the steam turbine or in the condenser. Otherwise, in the worst case ambient air can be sucked into the steam turbine or the condenser.
- a temperature fluctuation and associated pressure fluctuation in the steam turbine or condenser can be caused, for example, by the operation of the main cooling water system during the preservation. Such recirculation of the cooling water during prolonged shutdowns are from time to time from a chemical / biological point of view necessary.
- a corresponding nitrogen pressure control strategy is necessary, which also takes into account changes in operating conditions, eg before the cooling water pumps are switched on, the nitrogen pressure can be increased slightly beforehand. Regular checking of the residual oxygen in the preserved volume is also necessary.
- nitrogen is particularly advantageous for nitrogen to be recirculated from the condenser to the sealing steam system in order to start up the power plant, specifically after air has been expelled from the condenser to the sealing steam system in a recirculation line and after a sufficient negative pressure has been reached in the condenser, which opens vapor diverter stations allowed.
- Sufficient negative pressure typically means 600 mbar.
- the nitrogen-enriched exhaust air prefferably be compressed from the vapor vapor chambers and made available to a nitrogen generator as input air. Furthermore, it is expedient if a comparatively small, high-purity amount of nitrogen is provided for the preservation during shutdown and during standstill and for starting up a larger, impure amount of nitrogen per time in comparison.
- the WrasendampfSystem is at least temporarily during a targeted nitrogen filling of the condenser and the steam turbine in operation.
- the invention in addition to a much improved over the present day concept (dryer based) preservation (eg greatly reduced corrosion in the condensate collection) also cost savings (while investing as well as in operation) with maximum shortened startup from the longer downtime and this without an external auxiliary steam source is needed.
- the preparation time to the actual start time are shortened, for example, compared to the prior art, that the condensate collecting tank is already filled or that does not have to wait for the sealing steam supply.
- the investment cost savings result from the elimination of the previous dryer including connecting lines, the auxiliary steam boiler including auxiliary equipment or additional starting devices for early sealing steam supply from the cold reheat and thus from the boiler, etc.
- the countersigned costs for the nitrogen supply are significantly lower and include Essentially, the nitrogen storage, piping and valves for nitrogen supply or for nitrogen removal to the outside.
- a nitrogen recovery plant is present on site, in addition to this still a sufficiently large compressed air generating plant and advantageously a nitrogen collecting area are added to the nitrogen-containing exhaust air receives and the compressed air generating unit is available as supply air.
- Figure 1 shows a power plant according to the invention
- FIG. 1 shows schematically and by way of example a power plant 1 comprising a steam turbine 2 with a shaft
- a sealing steam system 6 with an opening into the shaft seals 7 sealing steam supply line 8 is used.
- the shaft seals 7 comprise sealing vapor chambers 12 and steam vapor chambers 13.
- the sealing steam supply line 8 coming from the auxiliary steam generator 19 opens into the sealing steam chambers 12.
- an electric superheater 16 is connected in the sealing steam supply line 8.
- the vapor steam chambers 13 are connected to a steam blower 14 in order to suck air which penetrates into the shaft seals 7 and a partial flow of steam from the sealing steam chambers 12.
- the extracted vapor is fed to a steam vapor condenser 15.
- a first nitrogen line 9 opens into the condenser 4.
- a second nitrogen line 10 opens into the sealing steam supply line 8 upstream of the electric superheater 16.
- a recirculation line 11 branching off from the vacuum pump 5 discharges into the sealing steam supply line 8.
- the recirculated amount of nitrogen can overflow a valve 40 in the recirculation line 11 can be adjusted.
- a pressure control of the vacuum pump 5 can also be done via valve 41 or in combination of the two valves 40 and 41.
- the nitrogen supply is carried out in the embodiment of Figure 1 via a nitrogen generator and a nitrogen storage 20. Since the vacuum pump 5 with regard to the funded flow as expected not for the
- FIG. 1 shows two further measures with which an operation with the vacuum pump 5 is nevertheless meaningfully possible.
- excessively pumped nitrogen can be recirculated to the inlet of the vacuum pump 5 via the return line 42 with valve 43; on the other hand, nitrogen can be conveyed directly into the nitrogen storage 20 via line 44 with compressor 45.
- nitrogen is fed upstream of an electric superheater 16 into the sealing steam supply line 8 of the sealing steam system 6 and into the condenser 4 when the steam turbine 2 is shut down in a conserved state, as shown in FIG. 2.
- the condenser pressure to avoid ventilation problems on the steam turbine 2 may be raised only limited by nitrogen supply.
- nitrogen may be temporarily fed together with steam into the sealing steam supply line 8, 22 but in particular only when the vacuum can be broken.
- the vacuum pump 5 is switched off only after it has been disconnected from the grid and the turn speed has been reached. 23.
- a corresponding condenser-side shut-off at the air suction of the condenser is closed.
- the vacuum breaker is not used (it may be omitted if it is replaced by a sufficiently large nitrogen feed on the condenser). Subsequently, the pressure in the condenser 4 / in the steam turbine 2 is raised to overpressure via the nitrogen supply 24.
- the nitrogen supply of the sealing steam system 6 is taken out of service during the preservation phase 26.
- the steam vapor system 18 is at least temporarily during a targeted nitrogen filling of the condenser and the steam turbine in operation.
- Nitrogen-enriched exhaust air from the vapor vapor chambers 13 can be compressed and made available to a nitrogen generator 17 as input air 28.
- a comparatively small, high-purity first amount of nitrogen is required 29.
- a warming or warming of the steam turbine 2 is supported 30 by heating the nitrogen via an arranged in the sealing steam supply line 8 electrical superheater 16.
- the vacuum pump 5 When starting up the steam turbine 2, the vacuum pump 5 is put back into operation 33. In particular, a vacuum sufficient for opening the steam diverter stations or starting enable of the gas turbine is drawn via the vacuum pumps. Nitrogen is blown off via a corresponding exhaust pipe to the vacuum pumps on the roof 34 or, in the case of
- Nitrogen production on site for example by means of pressure change -
- Adsorption a special supply air range at a compressed air generation plant for nitrogen production supplied 35.
- the nitrogen recovery plant as well as the necessary "amount of compressed air" can be greatly reduced.
- the nitrogen required may be either via a reservoir (e.g., bottle battery) to be filled externally, or nitrogen may be recovered on-site (e.g., by adsorption by pressure swing) and may be stored in a reservoir.
- a reservoir e.g., bottle battery
- nitrogen may be recovered on-site (e.g., by adsorption by pressure swing) and may be stored in a reservoir.
- the dimensioning of the storage tank and / or the nitrogen recovery plant must be sufficient to at least the
- restart concept must also be taken into account, that is, it must be considered from when the nitrogen make-up can be replaced by conventional sealing steam again. If there is no nitrogen production on site, the delivery logistics must also be taken into account in the storage dimensioning.
- nitrogen is branched off at least temporarily at the exhaust air of the vacuum pump 5 nitrogen and fed to the sealing steam system 6 36.
- Recirculation line 11 was driven from the condenser 4 to the sealing steam system 6 and after a sufficient negative pressure in the condenser 4 was reached, the opening of
- varying the nitrogen purity level can vary the capacity of a given nitrogen feed. As described above, it is necessary to provide a smaller but high purity amount of nitrogen for preservation. This is required during shutdown and standstill and results from the comparatively low nitrogen losses via the vapor steam system, since the nitrogen excess pressure in the steam turbine / condenser is kept very low for conservation purposes. It would now be possible to switch a nitrogen production from "high purity" in the start-up preservation case to provide a relatively larger, less-polluted second nitrogen amount 37. The provision of a larger amount of impure nitrogen for the start-up is necessary in view of the amount Nitrogen must be provided with a higher pressure in the sealing steam system 6, which increases the nitrogen losses through the vapor steam system 18. On the other hand, the increased impurity is not a problem due to the shortness of the start-up process, moreover it becomes highly pure Nitrogen recirculated via the vacuum pump 5.
- the vapor steam system 18 (in particular the fans for suction) remains in operation during the entire time (even during possibly longer standstill preservation) and the nitrogen which otherwise escapes via the shaft seals 7 into the machine house discharges a corresponding pipeline through the roof or a special (correspondingly well shielded) Zu Kunststoff Scheme on an optionally additional, provided only for the compression of the nitrogen-containing exhaust air, compressed air generation plant.
- the existing engine room ventilation ensures as further security that any accumulations of nitrogen (eg in case of malfunction of the exhaust fans on WrasendampfSystem 18), which could prevent a sufficient supply of oxygen for humans, not even arise.
- corresponding alarm systems can indicate that the vapor steam system 18 and / or the building ventilation have failed and, in addition, corresponding gas detectors are used which detect either a high nitrogen concentration or a low oxygen concentration and speak clearly. For this stationary or even by the individual employee zuzulagende gas detectors can be used. Thus, any problems with respect to personal safety are very well manageable. Overall, it should also be noted that the molecular nitrogen emitted in gaseous form is non-toxic per se and, as the main constituent of the air, also no environmentally relevant emission.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102017206196 | 2017-04-11 | ||
| PCT/EP2018/059155 WO2018189176A1 (de) | 2017-04-11 | 2018-04-10 | Verfahren zur konservierung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3585985A1 true EP3585985A1 (de) | 2020-01-01 |
| EP3585985B1 EP3585985B1 (de) | 2021-05-26 |
Family
ID=62062986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP18720124.9A Active EP3585985B1 (de) | 2017-04-11 | 2018-04-10 | Verfahren zur konservierung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10895172B2 (de) |
| EP (1) | EP3585985B1 (de) |
| JP (1) | JP6880232B2 (de) |
| KR (1) | KR102216364B1 (de) |
| ES (1) | ES2887407T3 (de) |
| PT (1) | PT3585985T (de) |
| WO (1) | WO2018189176A1 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7427561B2 (ja) * | 2020-08-18 | 2024-02-05 | 株式会社東芝 | 復水器真空調整装置 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3584973A (en) * | 1969-09-30 | 1971-06-15 | Ingersoll Rand Co | Modular turbo compressor unit |
| JPS58117306A (ja) * | 1981-12-29 | 1983-07-12 | Hitachi Ltd | コンバインドプラント |
| CH665451A5 (de) * | 1983-07-19 | 1988-05-13 | Bbc Brown Boveri & Cie | Verfahren zum reinigen und entgasen des kondensates/speisewassers im kreislauf einer stromerzeugungsanlage. |
| JPS62237013A (ja) * | 1986-04-09 | 1987-10-17 | Hitachi Ltd | 複合発電設備の起動方法及び同装置 |
| US4905474A (en) * | 1988-06-13 | 1990-03-06 | Larinoff Michael W | Air-cooled vacuum steam condenser |
| JPH04119301U (ja) | 1991-04-09 | 1992-10-26 | 三菱重工業株式会社 | 蒸気タービンロータの中心孔の防錆装置 |
| JP3920365B2 (ja) * | 1994-04-28 | 2007-05-30 | オルマット インダストリーズ リミテッド | 地熱流体中の非凝縮性ガスを処理するための装置および方法 |
| DE4439516C2 (de) * | 1994-11-04 | 1997-03-27 | Siemens Ag | Verfahren zur Verhinderung von Gaseintrag in das Kondensat einer Dampfkraftanlage und Vorrichtung zur Durchführung des Verfahrens |
| JP3571802B2 (ja) * | 1995-06-08 | 2004-09-29 | 株式会社東芝 | 脱気装置内蔵型復水器 |
| JP3073468B2 (ja) | 1997-08-26 | 2000-08-07 | 三菱重工業株式会社 | 蒸気冷却式ガスタービン複合プラント及びその運転制御方法 |
| US6588499B1 (en) * | 1998-11-13 | 2003-07-08 | Pacificorp | Air ejector vacuum control valve |
| DE50208649D1 (de) * | 2001-04-06 | 2006-12-21 | Alstom Technology Ltd | Verfahren zur bereitschaftshaltung eines kombikraftwerkes |
| JP2003293707A (ja) | 2002-03-29 | 2003-10-15 | Jfe Steel Kk | 復水器内の水の管理方法 |
| US7065970B2 (en) * | 2003-11-07 | 2006-06-27 | Harpster Joseph W C | Condensers and their monitoring |
| DE10245935A1 (de) * | 2002-09-30 | 2004-05-19 | Alstom (Switzerland) Ltd. | Entlüftungs-/Entgasungssystem für Kraftwerkskondensatoren |
| US7107774B2 (en) * | 2003-08-12 | 2006-09-19 | Washington Group International, Inc. | Method and apparatus for combined cycle power plant operation |
| US20050076639A1 (en) * | 2003-10-14 | 2005-04-14 | Shirk Mark A. | Cryogenic cogeneration system |
| US7147427B1 (en) * | 2004-11-18 | 2006-12-12 | Stp Nuclear Operating Company | Utilization of spillover steam from a high pressure steam turbine as sealing steam |
| JP4738158B2 (ja) * | 2005-12-07 | 2011-08-03 | 三菱重工業株式会社 | ガスタービンの蒸気冷却配管の残留蒸気除去機構及び残留蒸気除去方法 |
| JP4311415B2 (ja) * | 2006-06-26 | 2009-08-12 | 株式会社日立製作所 | 冷却装置,冷却装置を用いたガスタービンシステム,冷却機構を用いたヒートポンプシステム,冷却方法,冷却装置の運転方法 |
| US20130074499A1 (en) * | 2011-09-22 | 2013-03-28 | Harris Corporation | Hybrid thermal cycle with imbedded refrigeration |
| JP5757335B2 (ja) * | 2011-10-19 | 2015-07-29 | 富士電機株式会社 | 混入空気除去装置およびこれを備えた発電装置 |
| WO2013117730A2 (en) * | 2012-02-10 | 2013-08-15 | Alstom Technology Ltd | Water/steam cycle and method for operating the same |
| US8820078B1 (en) * | 2013-08-06 | 2014-09-02 | Thomas Edward Duffy | Heat recovery steam generator and method for fast starting combined cycles |
| DE102014210225A1 (de) | 2014-05-28 | 2015-12-03 | Siemens Aktiengesellschaft | Dampfturbinensystem |
| DE102014210221A1 (de) * | 2014-05-28 | 2015-12-03 | Siemens Aktiengesellschaft | Verfahren zur Konservierung von Komponenten eines Dampfturbinensystems |
| EP2995785A1 (de) * | 2014-09-12 | 2016-03-16 | Siemens Aktiengesellschaft | Verfahren zum Betreiben einer Kraftwerksanlage |
| DE102014222919A1 (de) * | 2014-11-11 | 2016-05-12 | Siemens Aktiengesellschaft | Verbrennung von elektropositivem Metall in einer Flüssigkeit |
| JP6462335B2 (ja) | 2014-11-25 | 2019-01-30 | 三菱重工業株式会社 | 弁ケーシング、これを備えた弁、弁を備えたタービン装置、および弁ケーシングの雰囲気ガス侵入防止方法 |
| DE102014225711A1 (de) * | 2014-12-12 | 2016-06-16 | Siemens Aktiengesellschaft | Verfahren zur Konservierung eines Anlagenteils eines Dampfkraftwerks |
| CN106050419B (zh) * | 2016-06-23 | 2018-08-14 | 章礼道 | 燃气轮机压水堆蒸汽轮机联合循环系统 |
| US20190072006A1 (en) * | 2017-09-05 | 2019-03-07 | Thomas Edward Duffy | Method and apparatus to reduce thermal stress when starting combined cycle power systems |
-
2018
- 2018-04-10 US US16/496,186 patent/US10895172B2/en not_active Expired - Fee Related
- 2018-04-10 KR KR1020197032565A patent/KR102216364B1/ko active Active
- 2018-04-10 JP JP2019555635A patent/JP6880232B2/ja active Active
- 2018-04-10 WO PCT/EP2018/059155 patent/WO2018189176A1/de not_active Ceased
- 2018-04-10 ES ES18720124T patent/ES2887407T3/es active Active
- 2018-04-10 PT PT187201249T patent/PT3585985T/pt unknown
- 2018-04-10 EP EP18720124.9A patent/EP3585985B1/de active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018189176A1 (de) | 2018-10-18 |
| KR20190131118A (ko) | 2019-11-25 |
| US10895172B2 (en) | 2021-01-19 |
| KR102216364B1 (ko) | 2021-02-17 |
| JP2020516808A (ja) | 2020-06-11 |
| JP6880232B2 (ja) | 2021-06-02 |
| PT3585985T (pt) | 2021-07-28 |
| EP3585985B1 (de) | 2021-05-26 |
| US20200149435A1 (en) | 2020-05-14 |
| ES2887407T3 (es) | 2021-12-22 |
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Legal Events
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
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