EP3585927B1 - Textilgewebe und daraus hergestellte arbeitsbekleidung - Google Patents

Textilgewebe und daraus hergestellte arbeitsbekleidung Download PDF

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Publication number
EP3585927B1
EP3585927B1 EP18705409.3A EP18705409A EP3585927B1 EP 3585927 B1 EP3585927 B1 EP 3585927B1 EP 18705409 A EP18705409 A EP 18705409A EP 3585927 B1 EP3585927 B1 EP 3585927B1
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EP
European Patent Office
Prior art keywords
staple fibers
textile fabric
aramid
poly
lactic acid
Prior art date
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EP18705409.3A
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English (en)
French (fr)
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EP3585927A1 (de
Inventor
Regine Zumloh-Nebe
Jutta Krabbe
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Teijin Aramid GmbH
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Teijin Aramid GmbH
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Publication of EP3585927A1 publication Critical patent/EP3585927A1/de
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Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D10B2331/041—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET] derived from hydroxy-carboxylic acids, e.g. lactones

Definitions

  • the present invention pertains to a textile fabric and workwear manufactured thereof.
  • Textile fabrics are known. This type of fabrics should especially be heat protective and should also exhibit sufficient mechanical properties, for example sufficient tear strength.
  • US 2011/0138523 A1 describes a heat, flame and electric arc protective for use as single layer of a protective garment for a wearer, the fabric comprising: interwoven warp and weft yarn wherein the warp and weft yarn comprises a blend of 8 to 33 wt.-% meta-aramid staple fibers, 65 to 90 wt.-% para-aramid staple fibers, and 2 wt.-% anti-static staple fibers, the weft yarn and warp yarn being identical and comprising the side of the fabric facing away from a wearer and the side of the fabric facing the wearer, wherein the fabric provides ablative thermal protection on both sides.
  • a fabric with a twill K 2/ 1Z construction and with a grammage of 230 g/m 2 exhibits a tear resistance of the warp to be 67.87 N and of the weft to be 34.4 N, measured using the ISO 13937-1:2000 test procedure.
  • EP 1740746 B1 describes a heat and flame resistant fabric for use as single or outer layer of protective garments.
  • This fabric comprises fibers with a blend of 60 to 90 wt.-% of meta-aramid staple fibers and 5 to 40 wt.-% of para-aramid fibers.
  • This fabric does not comprise polylactide staple fibers.
  • WO 02/40755 A2 describes a fire resistant corespun yarn comprising a core of high temperature resistant continuous inorganic filaments and a first and a second sheath of staple fibers.
  • the first sheath comprises natural and synthetic staple fibers with at least one fire retardant fiber.
  • the staple fibers of the second sheath are selected from natural staple fibers or synthetic staple fibers.
  • WO 02/40755 A2 is silent about a blend of meta-aramid staple fibers and para-aramid staple fibers with poly lactic acid staple fibers.
  • a staple fiber composition DuPont TM Nomex ® IIIA is known consisting of 93 % Nomex ® m-aramid staple fibers, 5 % Kevlar ® p-aramid staple fibers, and 2 % antistatic staple fibers. According to an internet presentation of DuPont a fabric made of the staple fiber composition DuPont TM Nomex ® IIIA meets the NFPA 1975 standard for firefighters' station wear and is resistant to abrasion and tears.
  • the problem underlying the present invention is to provide a fabric which exhibits higher tear strength and higher wear comfort in garments, especially workwear made thereof.
  • a textile fabric comprising a staple fiber yarn made of a staple fiber blend, wherein the blend comprises meta-aramid staple fibers, para-aramid staple fibers, and poly lactic acid staple fibers.
  • the textile fabric according to the invention exhibits a higher resistance against abrasion and tear than a comparative textile fabric made from a staple fiber yarn which was manufactured from a staple fiber mixture consisting of meta-aramid staple fibers, para-aramid staple fibers and antistatic staple fibers. So, a garment comprising the textile fabric according to the invention can be worn for a longer time before it becomes damaged.
  • the higher values for resistance to abrasion and tear of the textile fabric according to the invention can be obtained with a lower grammage of the textile fabric, if compared with the grammage of a comparative textile fabric made of a staple fiber yarn which was manufactured from a staple fiber mixture consisting of meta-aramid staple fibers, para-aramid staple fibers and antistatic staple fibers. So, a garment comprising the textile fabric according to the invention can be worn with a higher wear comfort than a garment comprising the comparative textile fabric.
  • a garment comprising the textile fabric according to the invention wherein the grammage of the textile fabric is increased to the value of the grammage of the comparative textile fabric, can be worn with the same wear comfort as the garment comprising the comparative textile fabric but for an even longer time, because the resistance of the garment with the textile fabric of the invention to abrasion and tear is even more increased.
  • the textile fabric according to the present invention surprisingly fulfills the minimum requirements in terms of radiant heat, convective heat, and contact heat.
  • the poly lactic acid component of the textile fabric can be fully recycled, because poly lactic acid is fully biodegradable resulting in compost.
  • the compost can be used as substrate to grow corn.
  • the corn can be fermented to lactic acid which can be polymerized to poly lactic acid from which poly lactic acid staple fibers can be manufactured. Therefore, the textile fabric according to the invention contains a renewable component.
  • staple fibers means fibers of limited length obtained from cutting or breaking a filament yarn.
  • metal-aramid staple fibers means staple fibers obtained from cutting or breaking a meta-aramid filament yarn
  • metal-aramid means a polymer obtained by the polycondensation of a meta-oriented aromatic diamine and a meta-oriented dicarboxylic acid halide, wherein said polymer exhibits recurring units having amide bonds, and preferably at least 85 % of said amide bonds are located in the meta-oriented positions of the aromatic ring.
  • para-aramid staple fibers means staple fibers obtained from cutting or breaking a para-aramid filament yarn
  • para-aramid means a polymer obtained by the polycondensation of a para-oriented aromatic diamine and a para-oriented dicarboxylic acid halide of which recurring units have amide bonds, and preferably at least 65 %, more preferably at least 95 % and even more preferably at least 99 %, and most preferred 100 % of said amide bonds are located in the para-oriented positions of the aromatic ring.
  • aramid staple fibers means staple fibers obtained from cutting or breaking an aramid filament yarn.
  • the term aramid means a polymer, wherein aromatic moieties are connected to one another by amide bonds. Usually aramid are synthesized by poly-condensation of aromatic diamines with aromatic dihalides.
  • Aramid includes meta-aramid, para-aramid and aramid-copolymers such as copolymer [co-poly-(paraphenylene/3,4'-oxydiphenylene terephthalamide)] (Technora ® ).
  • poly lactic acid staple fibers means staple fibers obtained from cutting or breaking a poly lactic acid filament yarn
  • poly lactic acid means a polymer having lactide recurring units and, therefore, is also called “polylactide”.
  • staple fiber blend means an intimate mixture of the meta-aramid staple fibers, the para-aramid staple fibers, and the poly lactic acid staple fibers so that in each volume element of the staple fiber blend the same weight ratio of para-aramid staple fibers to meta-aramid staple fibers to poly lactic acid staple fibers is present.
  • Said intimate mixture may for example be obtained by intermingling the meta-aramid staple fibers, the para-aramid staple fibers, and the poly lactic acid staple fibers in air.
  • staple fiber yarn means a yarn which has been manufactured from the staple fiber blend of the meta-aramid staple fibers, the para-aramid staple fibers, and the poly lactic acid staple fibers, by any known method to produce a staple fiber yarn, for example by ring spinning, or by open-end spinning such as air-jet spinning.
  • textile fabric means a blend of staple fibers spun to yarns which are arranged in a certain fabric structure.
  • the blend comprises at most 95 % of aramid staple fibers, preferably at most 90 % of aramid staple fibers, more preferably at most 80 % of aramid staple fibers, or at most 70 % of aramid staple fibers with respect to a weight of the blend.
  • the blend comprises at least 40 % of meta-aramid staple fibers, preferably at least 50 % meta-aramid staple fibers and more preferably at least 60 % of meta-aramid staple fibers with respect to a weight of the blend.
  • the blend comprises at most 85 % of meta-aramid staple fibers, more preferably at most 75 % meta-aramid staple fibers or at most 65 % of meta-aramid staple fibers with respect to a weight of the blend.
  • the blend comprises at least 10 % of para-aramid staple fibers, preferably at least 20 % para-aramid staple fibers and more preferably at least 30 % of para-aramid staple fibers with respect to a weight of the blend.
  • the blend comprises at most 50 % of para-aramid staple fibers, more preferably at most 40 % para-aramid staple fibers or at most 35 % of para-aramid staple fibers with respect to a weight of the blend.
  • the blend comprises at least 10 % of poly lactic acid staple fibers, preferably at least 15 % poly lactic acid staple fibers and more preferably at least 20 % of poly lactic acid staple fibers with respect to a weight of the blend.
  • the blend comprises at most 35 % of poly lactic acid staple fibers, more preferably at most 30 % poly lactic acid staple fibers or at most 25 % of poly lactic acid staple fibers with respect to a weight of the blend.
  • the term "staple fibers” means fibers of limited length obtained from cutting or breaking a filament yarn. If the staple fibers are obtained by breaking, the staple fibers exhibit a length distribution which is characteristic for the breaking technology which was applied, e.g., stretch-breaking.
  • the staple fibers are obtained by cutting a filament yarn into a unitary length which is preset in the used cutting device. This results in staple fibers which have a unitary length.
  • the meta-aramid staple fibers have a unitary length of 30 to 140 mm
  • the para-aramid staple fibers have a unitary length of 30 to 140 mm
  • the poly lactic acid staple fibers have a unitary length of 30 to 140 mm.
  • the meta-aramid staple fibers have a unitary length of 30 to 130 mm
  • the para-aramid staple fibers have a unitary length of 30 to 130 mm
  • the poly lactic acid staple fibers have a unitary length of 30 to 130 mm.
  • the meta-aramid staple fibers have a unitary length of 30 to 120 mm
  • the para-aramid staple fibers have a unitary length of 30 to 120 mm
  • the poly lactic acid staple fibers have a unitary length of 30 to 120 mm.
  • the meta-aramid staple fibers have a linear density of 0.8 to 7 dtex
  • the para-aramid staple fibers have a linear density of 0.8 to 7 dtex
  • the poly lactic acid staple fibers have a linear density of 0.8 to 7 dtex.
  • the meta-aramid staple fibers have a linear density of 0.8 to 6 dtex
  • the para-aramid staple fibers have a linear density of 0.8 to 6 dtex
  • the poly lactic acid staple fibers have a linear density of 0.8 to 6 dtex.
  • the meta-aramid staple fibers have a linear density of 0.8 to 5 dtex
  • the para-aramid staple fibers have a linear density of 0.8 to 5 dtex
  • the poly lactic acid staple fibers have a linear density of 0.8 to 5 dtex.
  • the blend additionally comprises up to 5 wt.-%, preferably from 0 to 4 wt.-% and most preferred from 0 to 3 wt.-% of antistatic staple fibers with respect to a weight of the blend.
  • the antistatic staple fibers comprise polyester, carbon or steel or mixtures thereof as the antistatic fiber forming polymer.
  • the antistatic staple fibers have a length of 30 to 140 mm, and a linear density of 0.8 to 7 dtex.
  • the antistatic staple fibers have a length of 30 to 130 mm and a linear density of 0.8 to 6 dtex.
  • the antistatic staple fibers have a length of 30 to 120 mm and a linear density of 0.8 to 5 dtex.
  • the meta-aramid staple fibers comprised by the staple fiber blend exhibit a crimp with a crimp value which preferably ranges from 2 to 13 crimps per cm, more preferably from 3 to 10 crimps per cm.
  • the para-aramid staple fibers comprised by the staple fiber blend exhibit a crimp with a crimp value which preferably ranges from 2 to 13 crimps per cm, more preferably from 3 to 10 crimps per cm.
  • the poly lactic acid staple fibers comprised by the staple fiber blend exhibit a crimp with a crimp value which preferably ranges from 3 to 13 crimps per cm, more preferably from 5 to 10 crimps per cm.
  • the staple fibers comprised by the staple fiber blend including aramid staple fibers, exhibit a crimp value of 2 to 13 crimps per cm, preferably a crimp value of 3 to 10 crimps per cm and poly lactic acid staple fibers, exhibit a crimp value of 3 to 13 crimps per cm, preferably a crimp value of 4 to 10 crimps per cm.
  • the meta-aramid staple fibers are poly(meta-phenylene isophthalamide) staple fibers which preferably have been spun from a solution comprising poly(metaphenylene isophthalamide) in dimethyl acetamide
  • the para-aramid staple fibers are poly-(p-phenylene terephthalamide) staple fibers or poly(p-phenylene-3,4'-oxydiphenylene terephthalamide) staple fibers
  • the poly lactic acid staple fibers are poly-L-lactic acids staple fibers or poly-D-lactic acid staple fibers or staple fibers made of a racemic mixture of poly-L-lactic acid and poly-D-lactic acid or staple fibers made of a stereo complex of poly-L-lactic acid and poly-D-lactic acid .
  • Stereo complex formation of polylactides occurs due to non-covalent interactions of enantiomeric chains of poly-L-lactic acid (PLLA) and poly-D-lactic acid (PDLA) and results in higher thermal stability.
  • PLLA poly-L-lactic acid
  • PDLA poly-D-lactic acid
  • the PLLA and PDLA are arranged alternatively in the stereo complex to form a crystal structure.
  • the yarn is manufactured from the blend by ring spinning or air jet spinning.
  • the textile fabric according to the present invention may in principle be any network of fibers which are arranged in a certain fabric structure and which is suited to form a garment.
  • the textile fabric according to the present invention is a woven or knitted textile fabric.
  • the textile fabric according to the present invention has a twill or plain weave construction.
  • the textile fabric according to the invention has a twill or plain weave construction comprises at least one warp system and at least one weft system, and the at least one warp system and the at least one weft system comprise yarns with the same blend of staple fibers or yarns with different blends of staple fibers.
  • the textile fabric according to the present invention has a grammage of 50 to 400 g/m 2 , more preferred 80 to 380 g/m 2 , and most preferred 100 to 350 g/m 2 .
  • the advantageous properties of the textile fabric according to the present invention transform themselves to a garment which is manufactured using said textile fabric.
  • a garment comprises at least one textile fabric according to the invention. Due to the improved abrasion resistance and pilling resistance, such garments are especially suited for workwear. Therefore, the use of said textile fabric to manufacture workwear is also part of the present invention.
  • An intimate staple fiber blend consisting of
  • step a From the staple fiber blend which resulted in step a) two Nm 40/1 staple fiber yarns were manufactured. Said two Nm 40/1 staple fiber yarns were twisted to result in a Nm 40/2 twisted staple fiber yarn.
  • a woven fabric was manufactured having the construction 2/ 1 Z according to DIN EN ISO 7211-1, i.e., a twill weave exhibiting two lifts and one lowering in Z-direction, wherein both the warp threads and the weft threads consist of the staple fiber yarn which resulted in step b).
  • the textile fabric consists of warp threads with a thread density of 191 threads/10 cm and of weft threads with a thread density of 182 threads/10 cm. The thread density was determined according to DIN EN ISO 1049-2.
  • the grammage of the woven fabric amounts to 202 g/m 2 and was determined according to DIN EN ISO 12127.
  • a comparative staple fiber blend obtained from DuPont (USA) under the trade name Nomex ® IIIA was provided consisting of
  • step a From the Nomex ® IIIA staple fiber mixture provided in step a) one Nm 60/1 staple fiber yarn and one Nm 60/1 staple fiber yarn were manufactured. Said two staple fiber yarns were twisted to result in a comparative Nm 60/2 twisted staple fiber yarn.
  • a comparative textile fabric was manufactured having the construction 2/ 1 Z according to DIN EN ISO 7211-1, i.e., a twill weave exhibiting two lifts and one lowering in Z-direction, wherein both the warp threads and the weft threads consist of the comparative twisted staple fiber yarn which resulted in step b).
  • the textile fabric consists of warp threads with a thread density of 386 threads/10 cm and of weft threads with a thread density of 244 threads/10 cm.
  • the thread density was determined according to DIN EN ISO 1049-2.
  • the grammage of the comparative textile fabric amounts to 225 g/m 2 and was determined according to DIN EN ISO 12127.
  • a comparative staple fiber blend consisting of
  • the manufacturing process b) of the staple fiber yarns of CE 2 and the manufacturing process c) of the woven fabric of CE 2 is performed as for Comparative Example 1 (CE1).
  • the value of threads/10cm of the woven fabric amounts to 188 warp-threads and 199 weft-threads and was determined according to DIN EN ISO 1049-2.
  • the grammage of the woven fabric amounts to 204 g/m 2 and was determined according to DIN EN ISO 12127.
  • a comparative staple fiber blend consisting of
  • the manufacturing process b) of the staple fiber yarns of CE 3 and the manufacturing process c) of the woven fabric of CE 3 is performed as for Comparative Example 1 (CE1).
  • the value of threads/10cm of the woven fabric amounts to 188 warp-threads and 179 weft-threads and was determined according to DIN EN ISO 1049-2.
  • the grammage of the woven fabric amounts to 204 g/m 2 and was determined according to DIN EN ISO 12127.
  • Example 1 For the purpose of clarity the staple fiber blend compositions of example 1 and of the comparative examples (CE1 to CE3) are shown in table 1.
  • Table 1 Example 1, acc. to the invention CE1 CE2 CE3 para-aramid staple fibers [%] 25 5 60 40 meta-aramid staple fibers [%] 65 93 40 60 poly lactic acid staple fibers [%] 10 antistatic staple fibers 2
  • the properties of the woven fabric and of the comparative woven fabrics were determined as follows:
  • the abrasion resistance of the woven fabric according to the invention (120 000 cycles) is 33 % to 42 % higher than the abrasion resistance of the comparative woven fabric (70 000 to 80 000 cycles).
  • the warp tear resistance i.e., the warp tear strength of the woven fabric according to the invention (72.2 N) is 33 % higher than the warp tear strength of the comparative woven fabric (54.4 N), and the weft tear strength of the woven fabric according to the invention (75.9 N) is 39 % higher than the weft tear strength of the comparative woven fabric (54.7 N).
  • the higher resistances against tear and abrasion of the woven fabric according to the invention are obtained with a fabric grammage of 202 g/m 2 , i.e., with a fabric grammage that is 10 % lower than the fabric grammage of the comparative woven fabric (225 g/m 2 ).
  • the woven fabric according to the invention contains 10 wt.-% of poly lactic acid which is not intrinsically heat and flame resistant, the woven fabric according to the invention exhibits
  • Example 1 In Experiment 2 three woven fabrics (Example 1 according to the invention and Comparative Example 2 and 3) are tested to compare their properties.
  • CE3 is a comparative example similar to Example 1. It contains a similar amount of para-aramid staple fibers and meta-aramid staple fibers, but no poly lactic acid staple fibers. The results are shown in table 3. Table 3 Example 1 acc.
  • the abrasion resistance of the Example 1 according to the invention shows with 120 000 cycles a 50 % to 100 % higher value than the comparative woven fabrics (CE2: 60 000; CE3: 80 000 cycles).
  • the pilling resistance of Example 1 according to the invention is at least one level higher than the pilling resistance of CE2 and CE3 and at a higher number of cycles the difference between Example 1 and CE2 and CE3 becomes more apparent. In case of 5000 and 7000 cycles the difference is two levels.
  • Example 1 shows that the Example 1 with poly lactic acid staple fibers has a better pilling resistance and abrasion resistance.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Details Of Garments (AREA)
  • Knitting Of Fabric (AREA)

Claims (14)

  1. Textilgewebe, das ein Stapelfasergarn umfasst, das aus einem Stapelfasergemisch hergestellt ist, wobei das Gemisch Meta-Aramid-Stapelfasern, Para-Aramid-Stapelfasern und Polymilchsäure-Stapelfasern umfasst.
  2. Textilgewebe nach Anspruch 1, wobei das Gemisch
    - 30 bis 90 Gew.-% der Meta-Aramid-Stapelfasern,
    - 5 bis 60 Gew.-% der Para-Aramid-Stapelfasern und
    - 5 bis 40 Gew.-% der Polymilchsäure-Stapelfasern
    umfasst, in Bezug auf ein Gewicht des Gemischs.
  3. Textilgewebe nach Anspruch 1 oder 2, wobei die Meta-Aramid-Stapelfasern eine Einheitslänge von 30 bis 140 mm, die Para-Aramid-Stapelfasern eine Einheitslänge von 30 bis 140 mm und die Polymilchsäure-Stapelfasern eine Einheitslänge von 30 bis 140 mm aufweisen.
  4. Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 3, wobei die Meta-Aramid-Stapelfasern einen Titer von 0,8 bis 7 dtex, die Para-Aramid-Stapelfasern einen Titer von 0,8 bis 7 dtex und die Polymilchsäure-Stapelfasern einen Titer von 0,8 bis 7 dtex aufweisen.
  5. Textilgewebe nach Anspruch 1 bis 4, wobei das Gemisch zusätzlich bis zu 5 Gew.-% von antistatischen Stapelfasern in Bezug auf ein Gewicht des Gemischs umfasst.
  6. Textilgewebe nach Anspruch 5, wobei die antistatischen Stapelfasern eine Länge von 30 bis 140 mm und einen Titer von 0,8 bis 7 dtex aufweisen.
  7. Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 6, wobei die Metaaramid-Stapelfasern Poly(meta-phenylenisophthalamid)-Stapelfasern, die para-Aramid-Stapelfasern Poly-(p-Phenylenterephthalamid)-Stapelfasern oder Poly(p-phenylen-3,4'-oxydiphenylenterephthalamid)-Stapelfasern, und die Polymilchsäure-Stapelfasern Poly-L-Milchsäure-Stapelfasern oder Poly-D-Milchsäure-Stapelfasern sind oder Stapelfasern sind, die aus einer racemischen Mischung von Poly-L-Milchsäure und Poly-D-Milchsäure oder aus einem Stereokomplex von Poly-L-Milchsäure und Poly-D-Milchsäure hergestellt sind.
  8. Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 7, wobei das Garn aus dem Gemisch durch Ringspinnen und Luftstrahlspinnen gefertigt ist.
  9. Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 8, wobei das Textilgewebe ein gewebtes oder gestricktes Textilgewebe ist.
  10. Textilgewebe nach Anspruch 9, wobei das Textilgewebe ein gewebtes Textilgewebe mit Twill- oder Leinwandkonstruktion ist.
  11. Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 10, wobei das Textilgewebe ein Flächengewicht von 50 bis 350 g/m2 aufweist.
  12. Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 11, wobei das Gemisch höchstens 95 % Aramid-Stapelfasern, vorzugsweise höchstens 90 % Aramid-Stapelfasern, besonders bevorzugt höchstens 80 % Aramid-Stapelfasern oder höchstens 70 % Aramid-Stapelfasern in Bezug auf ein Gewicht des Gemischs umfasst.
  13. Kleidungsstück, umfassend mindestens ein Textilgewebe nach einem oder mehreren der Ansprüche 1 bis 12.
  14. Verwendung des Textilgewebes nach einem oder mehreren der Ansprüche 1 bis 12 zum Fertigen von Arbeitskleidung.
EP18705409.3A 2017-02-27 2018-02-20 Textilgewebe und daraus hergestellte arbeitsbekleidung Active EP3585927B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17158046 2017-02-27
PCT/EP2018/054117 WO2018153844A1 (en) 2017-02-27 2018-02-20 Textile fabric and workwear manufactured thereof

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EP3585927A1 EP3585927A1 (de) 2020-01-01
EP3585927B1 true EP3585927B1 (de) 2023-05-17

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EP (1) EP3585927B1 (de)
JP (1) JP7044798B2 (de)
KR (2) KR20230169408A (de)
CN (1) CN110446805B (de)
ES (1) ES2948636T3 (de)
RU (1) RU2753284C2 (de)
WO (1) WO2018153844A1 (de)

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US11359309B2 (en) 2018-12-21 2022-06-14 Target Brands, Inc. Ring spun yarn and method
CN114051543B (zh) * 2019-12-20 2023-09-29 株式会社村田制作所 细纱、以及具备细纱的纱线和布

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JP2020510762A (ja) 2020-04-09
WO2018153844A1 (en) 2018-08-30
EP3585927A1 (de) 2020-01-01
RU2753284C2 (ru) 2021-08-12
ES2948636T3 (es) 2023-09-15
KR20190117668A (ko) 2019-10-16
RU2019129085A (ru) 2021-03-29
RU2019129085A3 (de) 2021-04-01
JP7044798B2 (ja) 2022-03-30
KR20230169408A (ko) 2023-12-15
CN110446805A (zh) 2019-11-12

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