EP3484979A1 - Procédé d'enrobage d'agents de soutènement - Google Patents

Procédé d'enrobage d'agents de soutènement

Info

Publication number
EP3484979A1
EP3484979A1 EP16740993.7A EP16740993A EP3484979A1 EP 3484979 A1 EP3484979 A1 EP 3484979A1 EP 16740993 A EP16740993 A EP 16740993A EP 3484979 A1 EP3484979 A1 EP 3484979A1
Authority
EP
European Patent Office
Prior art keywords
reactive
resin
resins
proppant
flowable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16740993.7A
Other languages
German (de)
English (en)
Inventor
Sebastian Knör
Daniel Calimente
Arndt Schlosser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Chemie AG
Original Assignee
Wacker Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG
Publication of EP3484979A1 publication Critical patent/EP3484979A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60—Compositions for stimulating production by acting on the underground formation
    • C09K8/80—Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
    • C09K8/805—Coated proppants
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
    • C03C11/002—Hollow glass particles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00—Powdered glass; Bead compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60—Compositions for stimulating production by acting on the underground formation
    • C09K8/62—Compositions for forming crevices or fractures

Definitions

  • the present invention relates to a method for
  • the fracking process is used in the extraction of oil and gas and is a method for the generation, widening and stabilization of cracks in the rock of a deposit in the deep underground, with the aim of increasing the permeability of
  • uncoated proppants are brittle and do not have the necessary compressive strength for conveying at great depths.
  • the breakage of the proppant under the high pressure fines are released, which clog the cracks and the oil or
  • Supporting agents have improved resistance compared to the uncoated proppants.
  • the effect of the coating e.g. with organic resins, but is limited by the fact that the available coatings themselves are very brittle and also tend to break or flake.
  • WO2008088449 A2 discloses a possibility for reducing the brittleness of coatings of such particles, wherein
  • thermosetting reactive resins such as epoxy resins with block copolymers and adhesion promoters so as to achieve an improvement in the impact resistance of the coating.
  • coated particles improve the oil yield and reduce the amount of extracted water.
  • Silicone resins make these particles expensive.
  • a disadvantage is the complicated process.
  • various resins such as phenolic resins are used, which contain, for example, as reinforcing fillers pyrogenic silicic acids.
  • US5422183A discloses particles for use as support materials in fracking processes, which are also a two-layer
  • US20140124200A discloses the use of hybrid materials made by chemically combining organic resins and silicone resins to coat support materials. Disadvantages here are the use of expensive silicone resins and the difficult-to-control product quality in the reaction of two branched polymers. Furthermore, the prior art methods are general
  • W02010060861A1 describes, for example, a homogeneous reaction resin that improves the
  • thermoset plastic shows fracture toughness and impact resistance as cured thermoset plastic.
  • the reactive hybrid resin (Z) is prepared by the following reaction: (A) 80-99.5% by weight of at least one reactive resin, and
  • (B) has at least 3 consecutive Si-O units
  • (B) has at least one radical R which is suitable to react with (A) to form a covalent bond
  • (B) is in flowable form at 20 ° C, or by melting in a temperature range up to 250 ° C is melted and thereby in a flowable
  • the reactive hybrid resins (Z) must form a solid, non-tacky coating at ambient temperatures. This is
  • the coating can be essentially
  • Coating can also be only partially cured or provided with other reactive groups, so that a
  • the reactive hybrid resins (Z) can either be used during the
  • Coating the proppant particles are completely cured or only partially cured.
  • Supporting agents with only partially hardened coating harden only after the
  • Suitable reaction resins (A) according to the invention are all polymeric or oligomeric organic compounds which are provided with a sufficient number of suitable reactive groups for a curing reaction. All are in the state of the art known reaction resins suitable, which can be processed into thermosets, regardless of the respective
  • Crosslinking mechanism which takes place in the curing of the respective reaction resin. Basically, they can be divided into three groups according to the type of
  • Reaction resins (A) are preferably one or more
  • Epoxy resins, urethane resins and / or air-drying alkyd resins are selected as the starting material. Epoxy and urethane resins are usually made by adding stoichiometric amounts of a
  • Crosslinking agent containing hydroxyl, amino, carboxyl or carboxylic anhydride groups, wherein the curing reaction takes place by addition of the oxirane or isocyanate groups of the resin to the corresponding groups of the curing agent.
  • the so-called catalytic curing by polyaddition of the oxirane groups themselves is also possible.
  • Air-drying alkyd resins crosslink by autoxidation with atmospheric oxygen. Also
  • addition-curing silicone resins are known, preferably those with the proviso that no further free silanes are included.
  • Examples of the second group of the polycondensation-crosslinked reaction resins (A) are preferable
  • aromatic compounds such as phenol, resorcinol, cresol, etc., furan resins, saturated polyester resins, and
  • condensation-curing silicone resins are usually carried out by increasing the temperature with elimination of water, low molecular weight alcohols or other low molecular weight compounds.
  • the third group of reaction resins crosslinked by free-radical polymerization comprises one or more homopolymers or copolymers of acrylic acid and / or methacrylic acid or their esters, and also unsaturated polyester resins,
  • initiators compounds capable of forming free radicals, e.g.
  • High-energy radiation such as UV or electron radiation, is possible.
  • reaction resins (A) but also all others which are suitable for the production of thermosetting plastics, can be modified in the manner proposed according to the invention and can be obtained according to
  • thermosets with significantly improved resistance to breakage and impact, while leaving other essential properties, such as strength, heat resistance and chemical resistance, which are characteristic of the thermosets, essentially unaffected.
  • the preferred reactive resins (A) are by:
  • These reactive resins (A) include thermosetting resole-type phenol resins and phenolic novolac resins which can be made heat-reactive by adding catalyst and formaldehyde.
  • Particularly preferred reactive resins (A) are phenol novolak resins. These are available for example from Plastics
  • Hexamethylenetetramine is the preferred material as (C) for this function because it serves as both a catalyst and a source of formaldehyde.
  • (A) is used for reaction with (B) in amounts of 80-99.5 wt .-%. Preferably in amounts of 88-99 wt .-% and
  • the preferred reactive resins (A) are at 20 ° C in
  • the linear or cyclic organopolysiloxane (B) has
  • Linear or cyclic (B) may be slightly branched or slightly bridged by an organic radical.
  • Branching sites per molecule is preferably 4 4, preferably 2 2, more preferably 1 1, very particularly preferably ⁇ 1,
  • (B) is preferably a linear organopolysiloxane.
  • the average number of Si atoms per molecule (B) is preferably less than 1000, preferably less than 200.
  • (B) is used for the reaction with (A) in amounts of 0.5-20 wt .-%. Preferably from 1-12 wt .-% and in particular
  • (B) is in a flowable form at 20 ° C, or is meltable by heating in a temperature range up to 250 ° C, and thereby can be made into a flowable form.
  • Organopolysiloxane (B) selected so that it has appropriate reactive radicals R 1 according to the nature of the crosslinking mechanism. Those skilled in the art are suitable radicals R 1 for
  • Polycondensation crosslinking reactive resins (A) can be used.
  • nucleophilic groups in R 1 are -SH, -OH and - (NH) -, preferably - (NH) - and -OH, more preferably -OH.
  • suitable electrophilic groups in R are known to the person skilled in the art. These are preferably epoxide, anhydride, acid halide, carbonyl, carboxy, alkoxy, alkoxy, Si, halogen or isocyanate groups. Preferred are epoxy, anhydride, carbonyl, alkoxy, carboxy, more preferably epoxy, alkoxy and anhydride.
  • Preferred reactive radicals R 1 are anhydrides, such as
  • Maleic anhydride group or the succinic anhydride group in particular bonded via a propyl radical or an undecyl radical.
  • R 1 are epoxy radicals of the following formulas (VI) and (VII)
  • R 2 is a divalent hydrocarbon radical having 1 to 10
  • Ether oxygen atom may be interrupted
  • R 3 is a hydrogen atom or a monovalent one
  • Preferred epoxy radicals are the glycidoxypropyl radical and the 3,4-epoxycyclohexylethyl radical.
  • R 1 are amino radicals of the general formula (VIII)
  • Hydrocarbon radical having 3 to 18 carbon atoms preferably an alkylene radical having 3 to 10 carbon atoms, means
  • R 7 is a hydrogen atom, an alkyl radical having 1 to 8
  • R 8 is a divalent hydrocarbon radical having 1 to 6
  • Carbon atoms preferably an alkylene radical having 1 to 6 carbon atoms,
  • n 0, 1, 2, 3 or 4, preferably 0 or 1.
  • Further preferred reactive radicals R are polyether radicals of the general formula (IX)
  • u is 0 or an integer from 1 to 16, preferably 1 to 4,
  • v is 0 or an integer from 1 to 35, preferably 1 to 25, and
  • w is 0 or an integer from 1 to 35, preferably 1 to 25,
  • x is 0 or an integer from 1 to 35, preferably 1 to 25
  • Copolymer may be block copolymers or
  • Graftcopolymere be.
  • suitable organic parts include, but are not limited to, polycaprolactone, polyesters, polyvinyl acetates, polystyrenes, polymethyl methacrylates.
  • the organic part is preferably a (co) polymer
  • Vinyl acetate, methyl methacrylate or aliphatic polyester Particularly preferred is polycaprolactone.
  • the block copolymers contain a siloxane unit having a molecular weight of 1,000-10,000 g / mol, preferably 1,500-5,000 g / mol, more preferably 2,000-4,000 g / mol.
  • radicals are alkoxy radicals, in particular Si-bonded alkoxy radicals, such as the methoxy radical and the ethoxy radical, hydroxy radicals, in particular the 3-hydroxypropyl radical, anhydride radicals, such as the succinic anhydride, in particular bound via a Propyl radical or an undecyl radical, amino Radicals, in particular the 3-aminopropyl and the (2-aminoethyl) - 3-aminopropyl radical, polyether radicals, epoxy radicals, in particular preferably the glycidoxypropyl radical and the 3,4-epoxycyclohexylethyl radical, and organic Polymer residues, particularly preferably a polycaprolactone residue.
  • alkoxy radicals in particular Si-bonded alkoxy radicals, such as the methoxy radical and the ethoxy radical
  • hydroxy radicals in particular the 3-hydroxypropyl radical
  • anhydride radicals such as the succinic anhydride, in particular bound via a Prop
  • radicals R 1 are organic hydroxy radicals, in particular the 3-hydroxypropyl radical or polyether radicals, epoxy radicals, in particular the glycidoxypropyl and 3,4-epoxycyclohexylethyl radical; wherein epoxy radicals and polyether radicals are very particularly preferred and epoxy radicals
  • a suitable catalyst is also used to accelerate the reaction of (A) with (B).
  • catalysts suitable for the person skilled in the art have long been known.
  • reaction of (A) with (B) can be carried out with or without solvent.
  • suitable solvents are known to the person skilled in the art and are selected as a function of the reactive resin (A).
  • suitable solvents are, for example
  • Reactive resins are suitable, is described for example in the following textbook: Polymer Handbook. Volume 2, 4 Ed .; J. Brandrup, E.H. Immergut, E.A. Grulke; John Wiley & Sons, Inc., 1999 (ISBN 0-471-48172-6).
  • Suitable mixers are, for example, laboratory stirrers,
  • Heating to 250 ° C was made fluid, or with (A), which was dissolved in a suitable solvent, mixed and then with or without addition of a
  • Supporting agents with the reactive hybrid resins (Z) according to the invention are used.
  • a suitable proppant such as sand is preheated to about 170-260 ° C. In a mixer is then the
  • suitable hardener (C) and optionally various additives (D) are added.
  • inventive reactive hybrid resin (Z) and possibly reactive resin (A) this layer is first partially or completely cured. Subsequently, a new layer of the
  • Reactive hybrid resin (Z) according to the invention and possibly.
  • Suitable proppants are those skilled in the art from the
  • Supporting agents are usually hard, high-strength particles such as sand or gravel Rocks such as limestone, marble, dolomite, granite, etc., but also glass beads, ceramic particles, ceramic balls and
  • the proppant particles have a substantially spherical, ie spherical shape, since they leave enough space for the crude oil or gas
  • sand is particularly preferably used as a proppant.
  • the proppant particles have an average size of 5000 to 50 ⁇ m, more preferably one
  • Suitable curing agents are known to the skilled person from the prior art for a long time and are selected according to the reactive resin used.
  • a preferred novolak curing agent (C) is urotropin. (C) and thus also urotropin is typically used in amounts of between 8 and 20% by weight, based on the amount of reactive hybrid resin (Z) according to the invention and any reactive resin (A) present.
  • urotropin is applied as an aqueous solution to the melt of the
  • Reactive resin applied Such methods are also known to those skilled in the art and described for example in US4732920.
  • Suitable additives (D) have also long been known to the person skilled in the art. Non-exhaustive examples are anti-static agents, release agents, adhesion promoters, etc. Suitable proppants, hardeners (C) and additives (D) are described for example in US4732920 and US2007 / 0036977 AI.
  • the type and specification of the proppant for optimum performance of the proppant coated according to the invention, the type and specification of the proppant, type and specification of the reactive hybrid resin (Z), reactive resin (A), organopolysiloxane (B), hardener (C) and optionally additives (D), the type of mixing - And coating process, the order of addition of the components and the mixing times depending on
  • a change in the proppant may require an adjustment of the coating process and / or the hardener used (C) and additives (D).
  • C hardener used
  • D additives
  • the surface of the proppant may be wholly or partially coated. Preferably appear in the investigation with the
  • Reactive hybrid resin (Z) and possibly reactive resin (A) coated more preferably at least 50%.
  • the essential part of the coating on the proppant according to the invention is 0.1 to 100 ⁇ thick, preferably 0.1 to 30 ⁇ , more preferably 1 to 20 ⁇ .
  • the reactive hybrid resin (Z) according to the invention is preferably used in amounts of 0.1-20% by weight, based on the weight of the
  • Supporting agent used Preferably from 0.5-10% by weight and more preferably from 1-5% by weight.
  • Another object of the present invention is the
  • the reactive hybrid resins (Z) according to the invention are significantly cheaper to produce, since relatively inexpensive silicone oils are used as the raw material, instead of expensive silicone resins.
  • the reactive hybrid resins (Z) according to the invention have improved flow properties in coating processes. This will coat surfaces more evenly. It can be
  • the reactive hybrid resins (Z) according to the invention show advantages in the coating of proppants, in that the scrap noticeably by gluing the coated proppant
  • the cured reactive hybrid resins (Z) according to the invention have improved toughness, elasticity and ductility at the same hardness. This makes it more resistant
  • the reactive hybrid resins (Z) according to the invention have as
  • Coating has a reduced tendency to break
  • Supporting agent more resistant to stress such as
  • Another advantage of the coating according to the invention lies in its deformability, so that it often does not break even when breaking the brittle proppant grains themselves and thus encloses or holds together the resulting fines such as a plastic shell and thus their total release
  • silicone oil 2 an a, co-functional silicone oil having about 40-60 Si-O units and 4-hydroxy-3-methoxyphenylpropyl terminal groups
  • SIPELL® RE 63 F a polydimethylsiloxane having glycidoxypropylmethylsiloxy units and about 100-160 Si-O units;
  • silicone oil 3 (a trimethylsiloxy end-capped polydimethylsiloxane having about 75-85 Si-O units consisting of dimethylsiloxy units and an average of 2.5 glycidoxypropylmethylsiloxy units and an average of 2.5
  • silicone oil 4 an a, co-functional silicone oil having about 15-20 Si-O units and hydroxy (polyethyleneoxy) end groups of about 10
  • WACKER® AK 100 SILICONOEL has no functional groups that are suitable for use with the reactive resin
  • the oil does not form a stable mixture with the reactive resin and is not suitable for the application.
  • a stable mixture is characterized in that when the mixture is stored in liquid form within two weeks no separation by formation of a second phase is observed.
  • the phenol resin is stored at 140 ° C under nitrogen.
  • silicone oil 1 an a, co-functional silicone oil having about 10-18 Si-O units and hydroxypropyl end groups; viscosity
  • silicone oil 1 an a, co-functional silicone oil having about 10-18 Si-O units and hydroxypropyl end groups; viscosity
  • no oxalic acid was added and stirred for a total of only 10 minutes at 140 ° C before the hot mass has been poured onto PTFE film and crushed.
  • Silicone oil 1 has functional groups that would be able to react chemically with the reactive resin
  • Oxalic acid as a catalyst becomes a chemical reaction
  • SIPELL® RE 63 F a polydimethylsiloxane having glycidoxypropylmethylsiloxy units and about 100-160 Si-O units; viscosity
  • SIPELL® RE 63 F has functional groups that would be suitable for reacting with the reactive resin in a chemical reaction
  • Oxalic acid as a catalyst becomes a chemical reaction
  • Non-modified novolak "Resin 14772” (Plastics Engineering Company, Sheboygan, USA) serves as Comparative Example C4.
  • WACKER® FINISH WT 1650 has functional groups that would be suitable for reacting with the reactive resin in a chemical reaction.
  • the short mixing time compared to Example 6 prevents a chemical reaction.
  • the result is a purely physical, non-inventive mixture of
  • Hybrid resin differs according to Example 6.
  • the physical mixture according to Comparative Example C5 separated after 2 weeks storage at 140 ° C and is therefore not suitable for the application.
  • Table 1 shows the comparative data of the modified
  • Example 9 For curing, the samples were placed in a cold oven, heated to 160 ° C with rinsing with nitrogen within 3 hours, kept at this temperature for 2 h and cooled to 23 ° C overnight. After evaporation of the solvent, an approximately 50 ⁇ thick cured resin layer is formed on the plate.
  • Coating be considered in isolated form. One receives a statement to the elasticity, impact resistance and
  • Comparative Examples An approximately 50 ⁇ thick, cured layer of the unmodified resin Resin 14772 (Plastics Engineering Company, Sheboygan, USA) and the non-inventive resins of Comparative Examples V2 and V5.
  • the coated ones
  • Sheets were tested on an Erichsen ball impact tester, Model 304-ASTM, and the results were visually evaluated by a trained examiner.
  • variable drop height a ball dropped on the back of the sheet (each double tests at different location). The impact energy results from the fall height
  • Impact energy is changed as follows: 5, 10, 15, 20, 25, 30, 35, 40 (in x lbs).
  • the dentate impact sites are visually inspected for cracks and cracks and rated relative to the reference.
  • Table 2 shows the evaluation of the resin coating on Q-PANEL test panels and their resistance by means of ball impact tester.
  • Example 10 which was not modified according to the invention, in which the WACKER® FINISH WT 1650 organopolysiloxane is not chemically bound to the reactive resin (A) in contrast to the inventively modified resin from Example 6, no improvement in the toughness was observed.
  • Comparative Example C5 which was not modified according to the invention, in which the WACKER® FINISH WT 1650 organopolysiloxane is not chemically bound to the reactive resin (A) in contrast to the inventively modified resin from Example 6, no improvement in the toughness was observed.
  • Table 4 shows the evaluation of the coating quality of
  • Reactive resin composition causes a more uniform and effective coating of the surface of the proppant.
  • Proppants The pressure stability of the coated proppant according to
  • Example 10 was investigated according to DIN EN ISO 13503-2 at 14000 PSI. The result is shown in Table 5.
  • Table 5 shows the relative amount of fines formed after pressure treatment relative to the fracking sand coated with Resin 14772 non-inventive, unmodified resin (Plastics Engineering Company, Sheboygan, USA)
  • Comparative Example V4 It is completely surprising that 8-15% less fines are formed in the coated proppants coated according to the invention, compared to non-modified coated proppants. Not that one

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Silicon Polymers (AREA)

Abstract

L'invention concerne un procédé de fabrication de matériaux de soutènement enrobés utilisables lors de la fracturation hydraulique.
EP16740993.7A 2016-07-13 2016-07-13 Procédé d'enrobage d'agents de soutènement Withdrawn EP3484979A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2016/066681 WO2018010788A1 (fr) 2016-07-13 2016-07-13 Procédé d'enrobage d'agents de soutènement

Publications (1)

Publication Number Publication Date
EP3484979A1 true EP3484979A1 (fr) 2019-05-22

Family

ID=56464188

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16740993.7A Withdrawn EP3484979A1 (fr) 2016-07-13 2016-07-13 Procédé d'enrobage d'agents de soutènement

Country Status (5)

Country Link
US (1) US20190233720A1 (fr)
EP (1) EP3484979A1 (fr)
KR (1) KR20190018491A (fr)
CN (1) CN109476985A (fr)
WO (1) WO2018010788A1 (fr)

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4732920A (en) 1981-08-20 1988-03-22 Graham John W High strength particulates
US5422183A (en) 1993-06-01 1995-06-06 Santrol, Inc. Composite and reinforced coatings on proppants and particles
US7135231B1 (en) 2003-07-01 2006-11-14 Fairmont Minerals, Ltd. Process for incremental coating of proppants for hydraulic fracturing and proppants produced therefrom
ATE515549T1 (de) 2006-12-19 2011-07-15 Dow Global Technologies Llc Neue beschichtungszusammensetzung für proppants und herstellungsverfahren dafür
CN101586024A (zh) 2008-05-21 2009-11-25 北京仁创科技集团有限公司 采油用覆膜颗粒、压裂支撑剂及采油方法
DE102008044199A1 (de) 2008-11-28 2010-06-02 Wacker Chemie Ag Siloxan-Mischungen enthaltende Epoxidharze und Verfahren zu ihrer Herstellung und deren Verwendung
DE102008044396A1 (de) * 2008-12-05 2010-06-10 Wacker Chemie Ag Hochhydrophobe Beschichtungen
US9725645B2 (en) * 2011-05-03 2017-08-08 Preferred Technology, Llc Proppant with composite coating
US9297244B2 (en) * 2011-08-31 2016-03-29 Self-Suspending Proppant Llc Self-suspending proppants for hydraulic fracturing comprising a coating of hydrogel-forming polymer
US9803131B2 (en) 2012-11-02 2017-10-31 Wacker Chemical Corporation Oil and gas well proppants of silicone-resin-modified phenolic resins
CN103849374B (zh) * 2012-11-30 2017-01-25 亿利资源集团有限公司 一种压裂支撑剂及其制备方法
CN103849370B (zh) * 2012-11-30 2016-04-06 亿利资源集团有限公司 一种压裂支撑剂及其制备方法
CN103849116B (zh) * 2012-11-30 2016-01-20 亿利资源集团有限公司 一种疏水性树脂组合物及其制备方法和应用

Also Published As

Publication number Publication date
KR20190018491A (ko) 2019-02-22
CN109476985A (zh) 2019-03-15
WO2018010788A1 (fr) 2018-01-18
US20190233720A1 (en) 2019-08-01

Similar Documents

Publication Publication Date Title
DE2715684C2 (fr)
DE69214598T2 (de) Verbesserte phenolharzbeschichtete Stützmittel mit reduzierter Interaktion der hydraulischen Flüssigkeit
EP2352793B1 (fr) Résines époxyde renfermant des mélanges de siloxane, procédé pour leur production et leur utilisation
EP3436545B1 (fr) Procédé de revêtement d'agents de soutènement à l'aide de compositions de résine réactive modifiées, agents de soutènement ainsi revêtus et utilisation desdits agents de soutènement revêtus dans des procédés d'extraction par fracturation hydraulique
EP3408347B1 (fr) Compositions de résine active modifiées et leur utilisation pour le revêtement d'agents de soutènement
WO2008145550A1 (fr) Résines de réaction contenant des particules de type cœur-écorce et procédé pour leur production et leur utilisation
EP3560980B1 (fr) Polyester à chaîne allongée, dérivés prépolymérisés dudit polyester et leur utilisation ainsi que masses de résine époxyde
WO2018010788A1 (fr) Procédé d'enrobage d'agents de soutènement
EP3535338B1 (fr) Compositions de résine active modifiées et leur utilisation pour le revêtement d'agents de soutènement
DE102004047708A1 (de) Kern-Schalepartikel enthaltende Zusammensetzung und ihre Herstellung
WO2017129529A1 (fr) Compositions de résine active modifiées et leur utilisation pour le revêtement d'agents de soutènement
DE102005063414A1 (de) Aktivierbares Silan
EP1379597A1 (fr) Compositions de revetement aqueuses a base de resines epoxy auto-dispersives
EP2622044A1 (fr) Résines de polyesters insaturés et polysilazanes et matières à mouler à résine réactionnelle duroplastiques produites à partir de celles-ci
WO2019233557A1 (fr) Procédé de revêtement de moyens de soutènement
DE10119127A1 (de) Wäßrige Beschichtungszusammensetzungen auf Basis von Epoxidharzen
DE102011009873A1 (de) Reaktivharze und damit hergestellte Formkörper und flächige oder textile Materialien mit teilchenförmigen Polysilazanen als neuen Flammfestmachern
EP4424764A1 (fr) Composition et son utilisation comme masse de jointoiement
DE1520843B (de) Verfahren zur Herstellung von bituminp sen, inerte feste Teilchen enthaltenden Über zügen und Abdichtungen
DE20003193U1 (de) Polymerzusammensetzung zum Härten von Novolakharzen

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17P Request for examination filed

Effective date: 20181218

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

17Q First examination report despatched

Effective date: 20190520

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20191001