EP3460106A1 - Automatischer hilfskran zur aufrechterhaltung einer elektrolyseanlage - Google Patents
Automatischer hilfskran zur aufrechterhaltung einer elektrolyseanlage Download PDFInfo
- Publication number
- EP3460106A1 EP3460106A1 EP16891325.9A EP16891325A EP3460106A1 EP 3460106 A1 EP3460106 A1 EP 3460106A1 EP 16891325 A EP16891325 A EP 16891325A EP 3460106 A1 EP3460106 A1 EP 3460106A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrode
- electrodes
- electrolysis
- maintenance
- crane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 60
- 238000009434 installation Methods 0.000 title claims abstract description 51
- 238000012423 maintenance Methods 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 30
- 230000002547 anomalous effect Effects 0.000 claims abstract description 10
- 238000013519 translation Methods 0.000 claims abstract description 8
- 230000008439 repair process Effects 0.000 claims abstract description 5
- 238000000605 extraction Methods 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 238000001514 detection method Methods 0.000 claims description 8
- 230000033001 locomotion Effects 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- 238000006073 displacement reaction Methods 0.000 claims description 5
- 239000000523 sample Substances 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 3
- 230000007246 mechanism Effects 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 238000010191 image analysis Methods 0.000 claims description 2
- 238000007689 inspection Methods 0.000 abstract description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000005363 electrowinning Methods 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010616 electrical installation Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B66—HOISTING; LIFTING; HAULING
- B66C—CRANES; LOAD-ENGAGING ELEMENTS OR DEVICES FOR CRANES, CAPSTANS, WINCHES, OR TACKLES
- B66C17/00—Overhead travelling cranes comprising one or more substantially horizontal girders the ends of which are directly supported by wheels or rollers running on tracks carried by spaced supports
- B66C17/06—Overhead travelling cranes comprising one or more substantially horizontal girders the ends of which are directly supported by wheels or rollers running on tracks carried by spaced supports specially adapted for particular purposes, e.g. in foundries, forges; combined with auxiliary apparatus serving particular purposes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
Definitions
- Electrolysis installations include electrolysis cells with pairs of electrodes, cathode and anode, and a tank with a solution in which the electrodes are submerged subjected to a continuous electrical voltage difference in order to produce electrolysis. Electrolysis enables obtaining for example zinc, copper, nickel, cadmium or cobalt deposited in the cathode from the salts of the solution.
- electrodes are plate-shaped, arranged in rows in the tank such that the anodes and cathodes alternate and the cells are connected electrically in series.
- an electrode head holds each electrode.
- the electrode head comprises an electrode rod of an electrically conductive material, usually copper, and during electrolysis, the electrode head holds the electrode in the tank, vertically and in the longitudinal direction of the rod.
- each rod is arranged abutting in electrical contact on equipotential rails, usually made of copper, that extend to the sides of the tank and perpendicularly to the electrodes.
- An electrode unit comprises an assembly of the electrode and the electrode head.
- the electrode units are positioned in the tank as close as possible to each other in order to increase the productivity of the installation, but avoiding the risk of a short circuit.
- the electrode head comprises handling means for facilitating the extraction or the insertion of the electrode in the tank, or the transport thereof by means of a crane or a bridge crane of the installation, for example in the form of hooks or gripping lugs.
- Patent EP 1492906 describes this type of arrangement in an electrolysis installation.
- the present invention relates to an automatic auxiliary crane for maintenance in an electrolytic cell house.
- the function of the Automatic Auxiliary Bridge Crane object of this invention for Handling, inspection and maintenance of Electrodes is that of identifying anomalies in the electrodes located in the tanks, such as increase in temperature, anomalous electrical contacts and faults in the morphology of the metal deposited in the electrodes, and enabling extraction, removal and replacement of the anomalous electrodes from the electrolytic tanks of the plant to the repair and replacement area. Once these electrodes have been removed, the load of the tank will be incomplete and this crane will be in charge of repositioning new electrodes, inserting them in their operating positions.
- the invention is particularly applicable in a zinc electrolysis installation.
- the electrode units of the electrolysis system can present and/or cause failures during electrolysis, such as short circuits, electrical contacts of the electrolysis rods with the anomalous equipotential rails or faults in the metal deposited in the electrodes especially on the surface of the cathodes in electrowinning processes. These failures can damage the electrodes, the electrode units and the electrolysis installation, ultimately reducing the productivity of the installation.
- This known maintenance method has the drawback that the use of the crane or bridge crane for the procedure implies the stoppage of normal operations and less preventive maintenance time of the crane of the installation during the time needed to resolve the failures, since the crane or bridge crane is no longer available, consequently implying a reduction in the productivity of the installation.
- the present invention aims to provide a maintenance method that enables increasing the productivity of the installation.
- the present invention provides a maintenance method of an electrolysis installation as set forth in claim 1 and explained below. Furthermore, the dependent claims reflect advantageous embodiments as disclosed below.
- the invention comprises both the maintenance method of an electrolysis installation and the automatic auxiliary crane for maintenance of the electrolysis installation.
- the maintenance method of an electrolysis installation comprises the stages of: Identifying anomalies in the electrodes located in the tanks, such as increase in temperature, anomalous electrical contacts and faults in the morphology of the metal deposited in the electrodes.
- the maintenance method according to the invention comprises repositioning or removing the faulty electrode unit from the tank and/or inserting the spare electrode unit into the gap by means of an automatic auxiliary crane or bridge crane of the installation.
- the crane used conventionally for normal operations of the installation is called the main crane in order to distinguish it from the auxiliary crane.
- the use of the automatic auxiliary crane allows increasing productivity of the installation since it enables using the main crane for the normal operations of the installation while being able to proceed with the handling, repositioning or replacing of the faulty electrode units.
- the execution of the maintenance method of the installation enables eliminating any short circuits that may occur, inserting electrodes in the gaps of the tank due to the removal of those that were faulty, reducing the time needed to resolve the problems or anomalies that can occur frequently in the electrolysis installation, such as, for example, poor contact between the electrodes and the equipotential rail or a fault in the surface of the metal deposited in the electrode.
- the stage of detecting the faulty electrode unit, repositioning or removing the same and/or inserting the spare electrode unit is carried out automatically, at least partially, that is, at least in some stages. This way, the productivity of the installation is further improved as the processing time for each stage can be reduced.
- the invention anticipates the use of a detection system having at least one sensor for checking the status of the electrodes, such as electrode temperature sensors, electrode voltage drop sensors, display sensors of the metal deposited on the electrode and/or electrode weight sensors
- a detection system having at least one sensor for checking the status of the electrodes, such as electrode temperature sensors, electrode voltage drop sensors, display sensors of the metal deposited on the electrode and/or electrode weight sensors
- the detection system comprises at least one sensor that remains static with respect to the electrolysis tank.
- a control unit of the installation can be used, programmed to receive information from the detection system, process said information and command the auxiliary crane to reposition or remove the faulty electrode unit and/or insert the spare electrode unit.
- the bridge crane of the auxiliary crane used in the maintenance method according to the invention for repositioning the faulty electrode unit (anode or cathode unit) in the tank or removing it from the tank leaving a gap therein, and/or inserting the spare electrode unit in the gap comprises: A Main Structure (1), made up of two box girders and two headwalls joined thereto, as well as a grid floor, gangway and railing for supporting and maintaining equipment.
- a Longitudinal Translation System (2) made up of two motors and four wheels, that enable translation with respect to the electrolysis tanks of the installation, in a direction perpendicular to the longitudinal direction of the electrolysis rods on rails (8) abutting on rail beams (9)
- a Main Lifting System (3) mainly made up of a lifting geared motor and two drums.
- An Electrode Collection System (4) made up of A Load-bearing structure of the electrode collection trolley (4a) and a centering and guiding System (4b), centering the crane and guiding the load-bearing structure of the electrode collection trolley (4a).
- An Anti-Oscillation System A Contact Temperature Checking System An Electrode Voltage Checking System A Morphological Analysis System of the deposited metal An Auxiliary Lifting Mechanism (5) A Feeding System (6) An Electrical Installation, a Control System and an Air Conditioning and Cabinet Pressurization System (7).
- the supports (9) and rails (8) of the main bridge corresponding to the bridge crane of the main crane can be used, thus minimizing the cost of the auxiliary bridge and thereby the operational costs of the maintenance method.
- the automatic auxiliary crane can accommodate auxiliary means for the operation thereof in order to carry out the method, such as a control unit or PLC for controlling the movements of the auxiliary bridge, electrical systems, refrigeration equipment and pressurization equipment.
- the automatic auxiliary bridge can also have access platforms for maintenance and supervision of said means. Access to these platforms from the transit areas of the electrolysis installation can be carried out by means of a ladder (10).
- the full extent of travel of the auxiliary crane is limited in one direction by the stops of the rails, while in the other direction it is limited by the proximity of the main crane.
- the drive of the wheels (11) of the headwalls for moving the auxiliary bridge can be carried out by means of an independent electric motor for each drive wheel that acts through an appropriate reducer and is commanded by means of a converter that makes it possible to use the appropriate translation and approximation speeds.
- the motors can also incorporate brakes, preferably electrically driven brakes.
- the displacement system of the described auxiliary bridge enables ensuring a positioning with respect to the electrolysis cells that is sufficiently precise to carry out the maintenance method according to the invention.
- position detectors can be used on the parts of the crane with respect to which they move, such as markings.
- the electrode collection system (4) comprises: A load-bearing structure of the electrode collection trolley (4a), and the centering and guiding system (4b). Both elements will have relative movements between them during the lifting and lowering strokes.
- the load-bearing structure of the electrode collection trolley (4a) which is in charge of handling the electrodes, comprises: A frame that supports both the electrode collection trolley (4c) itself and the guide frame when it is lifted.
- This Frame incorporates four guide elements at the ends thereof that will enable the relative vertical movement of the Electrode Collection Trolley along the guides that the Guiding Structure will be equipped with.
- the electrode collection trolley (4c) in charge of handling the electrodes consisting of a frame on four wheels, two of which are motorized, which has four sets of opening and closing mechanisms of the electrode collection lugs.
- the centering and guiding system (4b) is positioned on the upper part of the tank, ensuring the correct position of the Electrode Collection Trolley with respect to the electrodes for their handling.
- the load-bearing structure of the electrode collection trolley (4a) will be in charge of the vertical movements of the centering and guiding system (4b) when dragging it in the vertical movements thereof, when abutting with it.
- the electrode collection trolley (4c), as shown in detail in Figure 4 is configured for managing the electrode units, comprising a frame (17) on four wheels (18), two of which are motorized, which has opening and closing means (14) of the tilting gripping arms (21) with electrode collection lugs (15). These lugs have a coupling hole (16) to the gripping means (19) provided in the electrode heads (20), thus enabling management and handling thereof.
- the tilting gripping arms (21) can be built with two rotating arms that support the collection lugs (15), for example, driven in a coordinated manner by a single linear actuator that make up the opening and closing means (14). The use of two types of collection lugs (15) is anticipated, some for anodes and others for cathodes.
- the electrode collection trolley (4c) can incorporate laser detectors, each corresponding to the position of a collection lug, which enable identifying the presence of the electrode in the support thereof on the electrolysis rod, identifying both the number of electrodes present and the correct polarity thereof.
- a suitable detector system can be incorporated.
- the different elements of the auxiliary crane must be adequately protected against acid mist corrosion, especially found in zinc electrolysis installations, for example, by means of specific acid-proof paint.
- the detection system for detecting faulty electrode units may include a detection system with an electrode temperature sensor system, an electrode voltage drop checking system, a system for analyzing the morphology of the metal deposited on the electrodes and/or a system for balancing or checking the weight of the electrodes.
- the temperature sensor system may include as many sensors as electrodes in the tank.
- the electrode voltage drop checking system includes voltage drop sensors, which can include as many voltage probes as the number of cathodes plus a probe, for measuring the voltage between the electrode rod and the electrolysis rail on which it abuts.
- the system for analyzing the morphology of the metal can comprise fixed cameras intended to take pictures of the surface of the metal deposited on the electrode. These pictures can be analyzed manually by an operator in order to assess possible faults in the deposition or automatically by means of image analysis systems. The pictures have sufficient resolution to enable a global analysis of the electrode and the processing thereof so that they can serve as a basis for comparative and statistical analyses.
- a control unit can be used programmed to detect information from the sensors on the state of the electrode units, process said information and command the auxiliary crane through displacements of the crane and the components thereof, such as translation of the automatic auxiliary crane, lifting and lowering of the electrode collection system, the auxiliary hoist, the electrode collection trolley or the electrode collection lugs.
- the control unit can also enable partially automatic or semi-automatic control, allowing one or several of the stages of the method to be carried out manually by an operator.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/ES2016/070126 WO2017144741A1 (es) | 2016-02-25 | 2016-02-25 | Grua auxiliar automática para mantenimiento de una instalación de electrolisis |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3460106A1 true EP3460106A1 (de) | 2019-03-27 |
EP3460106A4 EP3460106A4 (de) | 2020-04-15 |
EP3460106B1 EP3460106B1 (de) | 2021-06-23 |
Family
ID=59685901
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16891325.9A Active EP3460106B1 (de) | 2016-02-25 | 2016-02-25 | Automatischer hilfskran zur aufrechterhaltung einer elektrolyseanlage |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3460106B1 (de) |
ES (1) | ES2890827T3 (de) |
MX (1) | MX2017000943A (de) |
RU (1) | RU2018133681A (de) |
WO (1) | WO2017144741A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113814650B (zh) * | 2021-09-23 | 2024-01-26 | 华能荆门热电有限责任公司 | 等离子阴阳极安装辅助装置及维护检修方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH592164A5 (en) * | 1972-09-28 | 1977-10-14 | Zannini Gianfranco | Electrolytic plant for primary aluminium prodn. - is laid out above ground to separate productive from ancillary processes |
JPS5296904A (en) * | 1976-02-10 | 1977-08-15 | Mitsui Mining & Smelting Co | Apparatus for automatic replacement of plate electrode in electrolysis of metals |
FR2874934B1 (fr) * | 2004-09-08 | 2007-09-07 | Ecl Soc Par Actions Simplifiee | Procede de changement d'anode dans une cellule de production d'aluminium par electrolyse incluant un ajustement de la position de l'anode et dispositif pour le mettre en oeuvre |
FI124617B (en) * | 2012-04-23 | 2014-11-14 | Outotec Oyj | transfer System |
NO336059B1 (no) * | 2012-12-27 | 2015-05-04 | Sinvent As | Fremgangsmåte og apparat for rensing av karbonanoder |
CN203845728U (zh) * | 2014-05-26 | 2014-09-24 | 广西百色银海铝业有限责任公司 | 电解槽上用于安装阴极的辅助装置 |
-
2016
- 2016-02-25 MX MX2017000943A patent/MX2017000943A/es unknown
- 2016-02-25 ES ES16891325T patent/ES2890827T3/es active Active
- 2016-02-25 EP EP16891325.9A patent/EP3460106B1/de active Active
- 2016-02-25 RU RU2018133681A patent/RU2018133681A/ru not_active Application Discontinuation
- 2016-02-25 WO PCT/ES2016/070126 patent/WO2017144741A1/es active Application Filing
Also Published As
Publication number | Publication date |
---|---|
EP3460106A4 (de) | 2020-04-15 |
ES2890827T3 (es) | 2022-01-24 |
RU2018133681A (ru) | 2020-03-25 |
MX2017000943A (es) | 2018-02-09 |
RU2018133681A3 (de) | 2020-03-25 |
EP3460106B1 (de) | 2021-06-23 |
WO2017144741A1 (es) | 2017-08-31 |
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