EP3390893B1 - Procede et systeme pour calculer en temps reel la duree d'autonomie d'une cuve non refrigeree contenant du gnl - Google Patents
Procede et systeme pour calculer en temps reel la duree d'autonomie d'une cuve non refrigeree contenant du gnl Download PDFInfo
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- EP3390893B1 EP3390893B1 EP16825534.7A EP16825534A EP3390893B1 EP 3390893 B1 EP3390893 B1 EP 3390893B1 EP 16825534 A EP16825534 A EP 16825534A EP 3390893 B1 EP3390893 B1 EP 3390893B1
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- tank
- lng
- natural gas
- liquid
- pressure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/025—Special adaptations of indicating, measuring, or monitoring equipment having the pressure as the parameter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/026—Special adaptations of indicating, measuring, or monitoring equipment having the temperature as the parameter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
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- F17C2201/0128—Shape spherical or elliptical
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
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- F17C2201/0157—Polygonal
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- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
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- F17C2201/056—Small (<1 m3)
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- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
- F17C2205/0332—Safety valves or pressure relief valves
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- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
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- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
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- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0169—Liquefied gas, e.g. LPG, GPL subcooled
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- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/033—Small pressure, e.g. for liquefied gas
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/035—High pressure (>10 bar)
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- F17C2250/0404—Parameters indicated or measured
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/02—Improving properties related to fluid or fluid transfer
- F17C2260/021—Avoiding over pressurising
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- F17C2260/02—Improving properties related to fluid or fluid transfer
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Definitions
- the present invention relates generally to a method and system for calculating in real time the run time of a non-refrigerated tank containing natural gas (usually referred to by the acronym GN), comprising a layer of natural gas liquefied natural gas (LNG) and a layer of gaseous natural gas (NGG).
- GN natural gas
- LNG natural gas liquefied natural gas
- NSG gaseous natural gas
- the meaning of the present invention means the retention time (or storage time) remaining natural gas in the tank before opening the valves of the tank.
- Liquefied natural gas (abbreviated as LNG) is typically natural gas composed mainly of condensed methane in the liquid state: When it is cooled to a temperature of about -160 ° C at atmospheric pressure, it takes the form of a clear, transparent, odorless, non-corrosive and non-toxic liquid. In a tank containing LNG, it is generally in the form of a layer of liquid, which is covered by a layer of gas ("gaseous sky").
- LNG fuel is a simple and effective alternative to conventional fuels. From the point of view of CO 2 emission, as well as polluting particles and energy density. More and more players are turning to its use, including road, marine and rail carriers.
- one of the intrinsic defects of LNG is its quality of cryogenic liquid at atmospheric pressure. This means that LNG must be maintained at a temperature well below room temperature to remain in a liquid state. This implies unavoidable heat inputs into the non-refrigerated LNG tank and thus a rise in pressure in the gaseous layer until the valves of the tank are opened. This rise in pressure limits the duration of autonomy of the LNG in the tank.
- the duration of autonomy is a parameter that is crucial to know, in order to size the supply chain, and in particular LNG transport and inform the operator in real time of the remaining period of autonomy (from the same way that the duration of battery life is generally communicated to the user).
- the duration of autonomy is crucial to know, in order to size the supply chain, and in particular LNG transport and inform the operator in real time of the remaining period of autonomy (from the same way that the duration of battery life is generally communicated to the user).
- the US patent US 7,104,124 discloses a method and a system for calculating the residual amount of a compressed gas in a container and thus the remaining service time when the container is emptied, which duration corresponds to the duration during which the Residual gas in the container may be delivered depending on the rate of use of the gas.
- the US patent US 7,104,124 does not refer to a cryogenic fluid that evaporates in a cryogenic tank, which therefore contains both natural gas in the gas phase and natural gas in the cryogenic liquid phase.
- the US patent therefore does not a fortiori not refer to the retention time of the cryogenic fluid evaporating in the tank.
- the tank can operate in open system (transported in this case by a running vehicle) or closed (transported in this case by a stopped vehicle) or not transported).
- the method according to the invention is illustrated on the figure 2 .
- the input data relating to the tank can be in different forms, for example prismatic, cylindrical, or spherical. Its dimensions can typically be of the order of 1.5 m in length and 0.5 m in diameter for a cylindrical vessel.
- the soup of the tank per valve set pressure is given by the manufacturer of the LNG tank. It is typically of the order of 16 bars for a tank of 300 liters of volume and can even go up to 25 bars.
- evaporation rate means, within the meaning of the present application, the equivalent volume of liquid that would be evaporated per day because of heat inputs in the case where the tank would be open . It is also a specific value of the tank, usually given by the manufacturer.
- thermodynamic parameters relating to the GN it is assumed that the liquefied natural gas contained in the tank is divided into a layer of natural gas in the liquid state and a layer of natural gas in the gaseous state. as shown on the figure 1 .
- Each layer is defined at each instant t by its temperature T liq (t) and T gas (t) (respectively for the layer of LNG in the liquid state and the layer of LNG in the gaseous state) and its composition x iiq (t) and x gas (t) (respectively for the LNG layer and the GNG layer).
- the gaseous phase i.e., the natural gas layer in the gaseous state
- p (t) which is calculated at each moment t by the state equation of Peng-Robinson [1]
- the liquid phase ie the layer of natural gas in the liquid state
- the filling rate z of the tank by the layer of natural gas in the liquid state is typically of the order of 80 to 90% by volume after loading the tank and at the end of range, of the order of 10 to 20 % in volume.
- compositions x liq (t) and x gas (t) are vectors giving the mass fraction of each component of the LNG (usually the mass fraction of CH 4 , C 2 H 6 , C 3 H 8 , C 4 H 10 , n C 4 H 10 , iC 5 H 12 , nC 5 H 12 , nC 6 H 14 and N 2 in each of the gaseous or liquid phases of the LNG).
- the liquid phase and the gas phase are not necessarily in thermodynamic equilibrium: in fact the compression of the gas phase during a filling can induce a delay in the heat exchanges between the two phases (liquid at over-cooled state).
- the behavior code of the GN is of iterative type, that is to say that it calculates the evolution of the pressure at each physical time step 8t until the valves open.
- the first (step A) consists in initializing, at an initial moment t 0 , the physical parameters of said layers of liquefied natural gas, by measurement (continuously) using pressure and temperature sensors, pressure gas p (t 0 ), and the temperature of the liquid T liq (t 0 ).
- the respective compositions of the liquid x Liq (t 0 ) and Gas x Gas (t 0 ) phases are known input data corresponding to the respective compositions of the liquid and gaseous phases at the time of loading of the tank, or to average compositions for the type of LNG used.
- step B the physical parameters p (t), T gas (t), and T liq (t) are calculated using equations based on the conservation of the mass and the energy of the liquid and gaseous natural gas contained in the tank.
- the calculation of the liquid mass is made taking into account the fill rate z of the tank by the natural gas and the density of the LNG at the liquid temperature T liq (t) .
- the pressure p (t) of the gas phase can be calculated by the Peng-Robinson equation [1] .
- the invention can include gas compressibility, conduction heat input, radiant heat input, and LNG evaporation. These phenomena are detailed below:
- the exchanges of heat and mass between the liquid phase and the gas phase are considered to be controlled by a surface evaporation law whose engine is the difference in temperature between the core of the LNG stored in the liquid state and its surface. free.
- the pressure p (T) in the gaseous phase of the tank affects the surface evaporation by influencing the equilibrium temperature of the GN at the liquid / vapor surface corresponding to this pressure.
- the temperature of the free surface of LNG is assumed equal to the equilibrium temperature of LNG.
- Non-wetted vertical walls can also be the seat of heat flows, which have the effect of heating the gas phase, but also contribute to the heating of the liquid by radiation.
- step C of the algorithm of the method according to the invention the calculation of step B is repeated, starting again, for the moment according to t + ⁇ t (with a physical time step 8t constant), the conservation equations of mass and energy as long as the pressure p (t) is less than p soup .
- This time step can be of the order of one minute. Its value depends on heat fluxes, time constants and thermodynamic equilibria.
- step D the algorithm ends (step D) and returns the total duration traveled by the algorithm (step E), which is equal to the total duration N * ⁇ t traveled by the algorithm at the time of stopping the calculation.
- ⁇ T defined according to the technology of the calculator
- this time interval may be of the order of 1 minute, but may vary depending on the technology used (computer, HMI interface in particular).
- the algorithm (or behavior code GN) of the method according to the invention can be implemented by means of a computer connected to an interface HMI to inform an operator on this period of autonomy. Thanks to the computer connected to an interface HMI, a physical calculation of the duration of autonomy can be realized all time intervals ⁇ T (variables depending on the technology used, for example every minute) and the result of this calculation can be transmitted to the HMI.
- HMI Human Machine Interface
- an onboard computer comprising a processor associated with a dedicated storage memory and an interface motherboard; all of these elements being assembled so as to ensure the robustness of the "on-board computer” assembly in terms of mechanical, thermodynamic and electromagnetic resistance, and thus allow its adaptation to use in an LNG vehicle.
- the calculator may further comprise a screen and a keyboard. It is connected to two sensors, one of pressure and one of temperature, which provide information on the state of LNG inside the tank (see figure 1 ).
- the system according to the invention is illustrated by the figure 2 .
- the present invention also relates to a vehicle (land, sea or air) comprising an LNG tank and a system according to the invention, the tank and the system being as defined above.
- the duration of autonomy which is the data of interest to the operator (for example the driver of the vehicle or a remote operator), may for example be advantageously displayed at the dashboard of a vehicle and / or on the side of the vehicle.
- the figure 1 schematically shows a tank 1 of LNG, which is modeled by a bilayer system with two homogeneous layers of GN, a liquid layer 1 (LNG) and a layer gaseous g (GNG).
- LNG liquid layer 1
- GNG layer gaseous g
- FIG 3 a schematic diagram of the method according to the invention, showing the different steps of the method as described above.
- the Figures 4 to 8 are screenshots of vehicle dashboards each carrying a non-refrigerated LNG tank.
- figure 4 is a screenshot of a dashboard showing tank-specific input data (dimensions, evaporation rate, maximum allowable pressure). These data are common to all the examples described below.
- the figure 5 is a screenshot of an onboard board showing, for a first example of calculation according to the calculation method according to the invention, the input data specific to an LNG (composition, temperature, pressure and filling ratio z.
- the LNG is slightly overheated: temperature -160 ° C while the equilibrium temperature for this LNG is -162.31 ° C.
- the figure 6 is a screenshot of an onboard board showing, for a second example of calculation according to the calculation method according to the invention, the input data specific to an LNG (composition, temperature, pressure and filling ratio z.
- the LNG is slightly overcooled: temperature of -157 ° C while the equilibrium temperature for this LNG is -154,17 ° C.
- the figures 7 and 8 are screen shots giving, respectively for each of the first (data of Figures 4 and 5 ) and second examples (data from figures 4 and 6 ), the calculated life of the non-refrigerated tank carried by the vehicle.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL16825534T PL3390893T3 (pl) | 2015-12-18 | 2016-12-16 | Sposób i system obliczania w czasie rzeczywistym czasu trwania autonomii nieschłodzonego zbiornika zawierającego LNG |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1562854A FR3045775B1 (fr) | 2015-12-18 | 2015-12-18 | Procede et systeme pour calculer en temps reel la duree d'autonomie d'une cuve non refrigeree contenant du gnl |
| PCT/FR2016/053518 WO2017103531A1 (fr) | 2015-12-18 | 2016-12-16 | Procede et systeme pour calculer en temps reel la duree d'autonomie d'une cuve non refrigeree contenant du gnl |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3390893A1 EP3390893A1 (fr) | 2018-10-24 |
| EP3390893B1 true EP3390893B1 (fr) | 2019-10-09 |
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| EP16825534.7A Active EP3390893B1 (fr) | 2015-12-18 | 2016-12-16 | Procede et systeme pour calculer en temps reel la duree d'autonomie d'une cuve non refrigeree contenant du gnl |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US10962175B2 (pl) |
| EP (1) | EP3390893B1 (pl) |
| JP (1) | JP6864689B2 (pl) |
| KR (1) | KR102248767B1 (pl) |
| CN (1) | CN108700260A (pl) |
| AU (1) | AU2016373415B2 (pl) |
| CA (1) | CA3008750A1 (pl) |
| CY (1) | CY1122261T1 (pl) |
| DK (1) | DK3390893T3 (pl) |
| ES (1) | ES2754616T3 (pl) |
| FR (1) | FR3045775B1 (pl) |
| PL (1) | PL3390893T3 (pl) |
| PT (1) | PT3390893T (pl) |
| SG (1) | SG11201805148WA (pl) |
| WO (1) | WO2017103531A1 (pl) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3127546A1 (fr) * | 2021-09-30 | 2023-03-31 | Gaztransport Et Technigaz | Procédé et système pour calculer un paramètre de transition d’un moyen de stockage pour un gaz liquéfié |
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|---|---|---|---|---|
| FR3053432B1 (fr) * | 2016-06-30 | 2019-05-10 | Engie | Procede et systeme pour calculer en temps reel la quantite d'energie transportee dans une cuve de gaz naturel liquefie pressurisee et non refrigeree. |
| CN110454681B (zh) * | 2019-07-26 | 2020-10-02 | 中车齐齐哈尔车辆有限公司 | 液化气体运输容器的控制方法、压力控制系统及运输工具 |
| FR3105462B1 (fr) * | 2019-12-20 | 2021-12-03 | Gaztransport Et Technigaz | Procédé d’estimation et d’ajustement d’un bilan énergie d’un gaz sous forme liquide contenu dans une cuve |
| CN115468112B (zh) * | 2022-08-01 | 2023-10-27 | 中国船级社武汉规范研究所 | Lng罐箱剩余维持时间安全预报方法、系统、终端及存储介质 |
| CN116039386B (zh) * | 2022-12-02 | 2025-12-12 | 欧摩威汽车电子(芜湖)有限公司 | Lng车辆续航里程估算方法及其车载电子设备 |
| CN116705184B (zh) * | 2023-05-29 | 2024-04-05 | 上海海德利森科技有限公司 | 一种液氢蒸发损耗量预测方法、装置、设备及介质 |
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| DE10359313B3 (de) | 2003-12-17 | 2005-07-14 | Federal-Mogul Nürnberg GmbH | Sicherheitseinrichtung für Druckbehälter |
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- 2016-12-16 US US16/063,612 patent/US10962175B2/en active Active
- 2016-12-16 EP EP16825534.7A patent/EP3390893B1/fr active Active
- 2016-12-16 WO PCT/FR2016/053518 patent/WO2017103531A1/fr not_active Ceased
- 2016-12-16 KR KR1020187019856A patent/KR102248767B1/ko active Active
- 2016-12-16 AU AU2016373415A patent/AU2016373415B2/en active Active
- 2016-12-16 CA CA3008750A patent/CA3008750A1/fr not_active Abandoned
- 2016-12-16 CN CN201680081940.5A patent/CN108700260A/zh active Pending
- 2016-12-16 SG SG11201805148WA patent/SG11201805148WA/en unknown
- 2016-12-16 JP JP2018532050A patent/JP6864689B2/ja active Active
- 2016-12-16 ES ES16825534T patent/ES2754616T3/es active Active
- 2016-12-16 DK DK16825534T patent/DK3390893T3/da active
- 2016-12-16 PT PT168255347T patent/PT3390893T/pt unknown
- 2016-12-16 PL PL16825534T patent/PL3390893T3/pl unknown
-
2019
- 2019-10-24 CY CY20191101108T patent/CY1122261T1/el unknown
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3127546A1 (fr) * | 2021-09-30 | 2023-03-31 | Gaztransport Et Technigaz | Procédé et système pour calculer un paramètre de transition d’un moyen de stockage pour un gaz liquéfié |
| EP4160079A1 (fr) * | 2021-09-30 | 2023-04-05 | Gaztransport Et Technigaz | Procédé et système pour calculer un paramètre de transition d'un moyen de stockage pour un gaz liquéfié |
| US12111014B2 (en) | 2021-09-30 | 2024-10-08 | Gaztransport Et Technigaz | Method and system for computing a transition parameter of a liquefied gas storage medium |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20180112770A (ko) | 2018-10-12 |
| FR3045775A1 (fr) | 2017-06-23 |
| AU2016373415A1 (en) | 2018-07-05 |
| EP3390893A1 (fr) | 2018-10-24 |
| ES2754616T3 (es) | 2020-04-20 |
| JP2018538495A (ja) | 2018-12-27 |
| WO2017103531A1 (fr) | 2017-06-22 |
| US10962175B2 (en) | 2021-03-30 |
| CN108700260A (zh) | 2018-10-23 |
| CY1122261T1 (el) | 2020-11-25 |
| SG11201805148WA (en) | 2018-07-30 |
| JP6864689B2 (ja) | 2021-04-28 |
| US20190003650A1 (en) | 2019-01-03 |
| CA3008750A1 (fr) | 2017-06-22 |
| PT3390893T (pt) | 2019-11-04 |
| PL3390893T3 (pl) | 2020-03-31 |
| DK3390893T3 (da) | 2019-11-11 |
| AU2016373415B2 (en) | 2021-04-08 |
| FR3045775B1 (fr) | 2018-07-06 |
| KR102248767B1 (ko) | 2021-05-04 |
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