EP3374702A2 - Pompe à chaleur magnétocalorique, dispositif de refroidissement et procédé d'exploitation associé - Google Patents

Pompe à chaleur magnétocalorique, dispositif de refroidissement et procédé d'exploitation associé

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Publication number
EP3374702A2
EP3374702A2 EP16795282.9A EP16795282A EP3374702A2 EP 3374702 A2 EP3374702 A2 EP 3374702A2 EP 16795282 A EP16795282 A EP 16795282A EP 3374702 A2 EP3374702 A2 EP 3374702A2
Authority
EP
European Patent Office
Prior art keywords
regenerator
magnetocaloric
heat pump
field generator
magnetic field
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16795282.9A
Other languages
German (de)
English (en)
Inventor
Andrew Rowe
Reed TEYBER
Armando Tura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP3374702A2 publication Critical patent/EP3374702A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B21/00Machines, plants or systems, using electric or magnetic effects
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2321/00Details of machines, plants or systems, using electric or magnetic effects
    • F25B2321/002Details of machines, plants or systems, using electric or magnetic effects by using magneto-caloric effects
    • F25B2321/0022Details of machines, plants or systems, using electric or magnetic effects by using magneto-caloric effects with a rotating or otherwise moving magnet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]

Definitions

  • the invention relates to a magnetocaloric heat pump according to the preamble part of claim 1 , to a cooling device according to the preamble part of claim 14 and further relates to a method for operating a magnetocaloric heat pump according to the preamble part of claim 16.
  • Magnetocaloric materials can be used for pumping heat because they change their temperature upon an application and removal of an external magnetic field.
  • the magnetocaloric effect occurs under application of an external magnetic field to a suitable magnetocaloric material and under an ambient temperature in the vicinity of its Curie temperature.
  • the applied external magnetic field causes an alignment of the ran- domly aligned magnetic moments of the magnetocaloric material from a disordered paramagnetic phase to an ordered ferromagnetic phase and thus a magnetic phase transition, which can also be described as an induced increase of the Curie temperature of the material above the ambient temperature.
  • This magnetic phase transition implies a decrease in magnetic entropy AS and in an adiabatic process (thermal isolation from the ambient temperature) leads to an increase in the entropy contribution of the crystal lattice of the magnetocaloric material by phonon generation in order to conserve entropy under the adiabatic condition.
  • a temperature rise ( ⁇ ) of the magnetocaloric material occurs.
  • this additional heat is removed from the material by heat transfer to an ambient heat sink in the form or a heat transfer medium.
  • Water is an example of a heat transfer medium used for heat removal from the magnetocaloric material.
  • removing the external magnetic field can be described as a decrease of the Curie temperature back below an initial temperature of the magnetocaloric material, and thus allows the magnetic moments reverting back to a random arrangement.
  • the external magnetic field is removed under conditions that could be generally considered as adiabatic, but still heat exchange between magnetocaloric material and heat transfer medium occurs, which means that the overall entropy within the system stays nearly unchanged.
  • the magnetic entropy increases to its starting level without the external magnetic field, the entropy contribution of the crystal lattice of the magnetocaloric material itself is reduced, and under adiabatic process conditions, thus, results in a cooling of the magnetocaloric material below the ambient temperature. Therefore the temperature of the magnetocaloric material falls below the initial temperature.
  • the described process cycle including magnetization and demagnetization is typically performed periodically in device applications.
  • the magnet arrays consist of three concentric cylinders. Each cylinder is constructed using twelve permanent magnet segments. The inner magnet array is stationary while the intermediate and outer arrays are designed to rotate in opposite directions so as to create a sinusoidal magnetic field waveform with a stationary field direction with regard to Halbach arrays of magnetocaloric material.
  • US 2014/0165594 A1 describes another device application by discussing a heat pump system having magnetocaloric material positioned in a continuously rotating regenerator.
  • the magnetocaloric material is staged so that, as the regenerator is rotated, a portion of the material is cycled in and out of a magnetic field in a continuous manner.
  • a heat transfer fluid is circulated through the magneto caloric material simultaneously along at least two paths to provide for the transfer of heat both to and from the material in a cyclic manner.
  • the magnetocaloric material may include zones having different temperature ranges of responsiveness to the magnetic field.
  • the prior art designs can be improved.
  • the object of the invention is to create an improved magnetocaloric heat pump and an improved cooling device.
  • it is an object of the invention to optimize different regenerator performances, advantageously while observing costs.
  • the object is achieved according to a first aspect of the invention with a magnetocaloric heat pump as defined in claim 1.
  • the invention provides a magnetocaloric heat pump, with a regenerator assembly and at least one rotatable field generator, comprising:
  • the at least one field generator wherein the at least one generator body is peripherally situated in a periphery of said rotation axis, said generator body comprising a first and a second magnetic ring section, which are located diametrically opposite to each other in relation to the rotation axis, wherein the first and second magnetic ring section comprises a first and second permanent magnet respectively, and each of the first and second permanent magnets of the respective field generator is mounted on a support structure, wherein the support structure comprises a first and a second yoke section with a first and second yoke body, wherein the first and second yoke body are located diametrically opposite to each other in relation to the rotation axis and wherein the field generator is attached to the shaft,
  • regenerator body is peripherally situated in a periphery of a rotation axis, said regenerator body comprising magnetocaloric material distributed in the regenerator body and wherein the regenerator assembly is arranged around the shaft.
  • the regenerator assembly is in form of a ring body and the magnetocaloric material is distributed in the ring body, and
  • a magnetic field portion predominantly is guided as an internal magnetic field of the permanent magnets into the first and second yoke body, wherein a further magnetic field portion extends as an external magnetic field of the permanent magnets out of the field generator in the range of the first and second magnetic ring section, such that
  • the magnetocaloric material is exerted to the external magnetic field depending on the relative rotational position of the regenerator body and the generator body.
  • the magnetocaloric material is distributed regularly, in particular piecewise but equal, in a periphery of the rotation axis.
  • a magnetic field portion is guided as an internal magnetic field of the permanent magnets predominantly, preferably only into the first and second yoke body, whereas a further magnetic field portion extends as an external magnetic field of the permanent magnets out of the field generator predominantly, preferably only in the range of the first and second magnetic ring section.
  • the magnetic field is external predominantly in the range of the first and second magnetic ring section whereas the magnetocaloric material is distributed regularly.
  • the support structure prevents an extending of the external magnetic field at the yoke sections except for unavoidable field losses.
  • the magnetocaloric material is exerted to the external magnetic field.
  • the magnetocaloric material is exerted to the external magnetic field predominantly in the range of the first and second magnetic ring section, i.e.
  • the magnetocaloric material that is not in the range of both magnetic ring sections can be regarded as exerted to a low field region of the external magnetic field, which is mainly formed by unavoidable field losses.
  • a precisely predefined high field region of the external magnetic field can be provided by the invention.
  • the invention allows an optimizing of a magnet to MCM ratio and thus minimizes overall device costs for a given performance of the magnetocaloric heat pump. Thereby, costs for a given cooling performance can be reduced as well.
  • the cost of magnetocaloric material is small compared to permanent magnet material. Increasing the volume of MCM relative to the field volume can therefore be advantageous.
  • a magnetocaloric heat pump according to the first aspect of the invention can advantageously vary the relation between the volume of the magnetocaloric material and the volume that is temporarily applied to the magnetic field of the field generator. The relation between these volumes can thus be optimized.
  • the field generator is advantageously formed by causing the first and second yoke section to guide the magnetic field portion as an internal magnetic field of the permanent magnets into the first and second yoke body.
  • a further advantage of the invention according to the first aspect is that an assembling of the regenerator assembly and of the field generator at a shaft, oriented to the ring-axis of the magnetocaloric material, leads to a very compact and robust structure of the magnetocaloric heat pump.
  • the shaft can provide a mechanical connection to a further external device, as for example for rotating the field.
  • the claimed magnetocaloric heat pump can be easily adapted to different sizes of a cooling system.
  • the MCM is less expensive than the material of the magnets, a high power can be provided, while the volume of the magnetocaloric heat pump can be reduced. This leads to a reduction of the costs of the magnetocaloric heat pump.
  • the use of permanent magnets shows the further advantage that there might be no further electronic means necessary to generate the quasi-punctual external magnetic field of the permanent magnets.
  • the MCM within the regenerator body can comprise an outer layer or a shell that protects the MCM against the environment, or which is arranged at the MCM as a by-product of a production process of the magnetocaloric material.
  • this outer layer or shell is regarded as a part of the MCM for reasons of intelligibility.
  • a cooling device as defined in claim 13 is provided.
  • the cooling device further comprises:
  • At least one hot reservoir and at least one cold reservoir arranged to provide the at least first and second supply pipe system with fluid and to transport heat out of the cooling device
  • a pump which is arranged and configured to pump a fluid through the magnetocaloric material.
  • the advantages of the cooling device are the same as those of the magnetocaloric heat pump, since the use of the cooling device can be just considered in the context of the corresponding magnetocaloric heat pump.
  • the cooling device in particular realizes the magnetization and demagnetization of the magnetocaloric material by a rotation of the field generator.
  • One supply pipe of the at least two supply pipe systems supplies the magnetocaloric material with fluid from the at least one cold reservoir.
  • the fluid is heated during the magnetization of the magnetocaloric material and pumped by the pump out of the magnetocaloric material into the at least one hot reservoir.
  • the hot reservoir is configured and arranged to provide a heat exchange with the surrounding, leading to a less heated fluid which is brought into the magnetocaloric material via a further supply pipe of one of both supply pipe systems during the process of demagnetization, and mixed with fluid from the at least one cold reservoir.
  • the mixed fluid is colder after the demagnetization than the fluid within the at least one cold reservoir. Therefore, it is further brought to the at least one cold reservoir, lowering the temperature of the at least one cold reservoir.
  • a process cycle including magnetization and demagnetization as realized by the described cooling device by rotating the field generator leads to a cooling of the at least one cold reservoir.
  • a method for operating a magnetocaloric heat pump as defined in claim 15 is provided, in particular a magnetocaloric heat pump according to any one of the claims 1 to 12.
  • the method comprising the steps of:
  • a magnetic field portion predominantly is guided as an internal magnetic field of permanent magnets into a first and second yoke body, wherein a further magnetic field portion extends as an external magnetic field of the permanent magnets out of the field generator predominantly in the range of a first and second magnetic ring section,
  • the magnetocaloric material is exerted predominantly to the external magnetic field depending on the relative rotational position of the regenerator body and the generator body,
  • the field generator comprises a ring shaped structure.
  • the ring shaped structure allows a small size of this magnetocaloric heat pump.
  • the first and second magnetic ring sections of the at least one field generator each extend along less than 50%, preferably less than 30%, of a total circumference of the respective field generator. Since, in principle, only a quasi-punctual external magnetic field is needed for a required magnetization and demagnetization of the magnetocaloric material, a magnetocaloric heat pump according to this development reduces the used amount of permanent magnet material.
  • the magnetic field strength of the surrounding magnetic field portion measured over a polar angle of the circumference of a respective field generator has for each magnetic ring section a full width at half maximum under 60°.
  • each support structure comprises two field-harmonising sections arranged to attach each yoke body at the respective permanent magnet via the field-harmonising section.
  • the field-harmonising section of this embodiment supports the guiding of the magnetic field portion as an internal magnetic field of the permanent magnets into the first and second yoke body.
  • the field-harmonising section is made of the same material as the first and second yoke body and guides the magnetic field portion by its appropriate shape, comprising an increasing cross section in a circumferential direction oriented towards a respective permanent magnet.
  • the respective field-harmonising sections are formed by a paramagnetic material or by further permanent magnets.
  • the field generator comprises basically polyhedral shaped components, in particular basically polyhedral shaped first and second permanent magnets and basically polyhedral shaped first and second yoke bodies.
  • Polyhedral means in this development that components of the field generator comprise straight or curved edges, leading to a preferably rectangular or prismatic shape.
  • the field generator comprises only basically polyhedral shaped components, preferably only rectangular components.
  • the basically polyhedral shaped components are arranged in the periphery of the rotation axis. Basically polyhedral shaped components can be advantageously produced.
  • the first and second yoke bodies are equally shaped and comprise a tailored part to focus the internal magnetic field of the permanent magnets in the magnetic ring sections.
  • the tailored part increases its cross section in a direction oriented to the respective permanent magnet.
  • the first and second permanent magnets are also equally shaped, and the field generator is symmetric with respect to a first and a second axis of symmetry, which are perpendicular to the rotation axis.
  • the magnetocaloric material is distributed in the regenerator body sectionally at an inner periphery line of the regenerator assembly and/or is distributed in the regenerator body sectionally at an outer periphery line of the regenerator assembly.
  • MCM magnetocaloric material
  • the magnetocaloric material (MCM) forms at least two MCM- segments, which are separated by respective intermediate sections, and/or wherein an intermediate section has a prismatic shape that allows two rectangular adjacent MCM- segments to contact each other at the tip of the triangular shape.
  • the MCM-segments form blocks with even surfaces.
  • the regenerator assembly of the magnetocaloric heat pump comprises at least one regenerator carrier, wherein the at least one regenerator carrier is adapted to carry at least one regenerator body.
  • the regenerator carrier of this development also provides means for the fluid directing system to provide a flow of fluid through the magnetocaloric material.
  • the arranging of the regenerator body within the regenerator carrier can provide an effective way of providing adiabatic conditions, i.e. thermal isolation from the ambient temperature, within the magnetocaloric material during the process cycle.
  • the magnetocaloric heat pump comprises a first and a sec- ond field generator wherein at least the first field generator is attached to the shaft, wherein the regenerator assembly is arranged between the first and second field generator.
  • This development is particularly advantageous in view the stronger magnetic field, which is oriented more precisely by the permanent magnets of both field generators.
  • only one of both field generators is attached to the shaft, while the other one is connected to the attached field generator via the external magnetic field. This lowers influences of friction within the magnetocaloric heat pump and therefore helps to avoid heat production and power losses.
  • both field generators are formed equally, which can help to reduced costs, while maintaining the described advantages of this development.
  • equally formed field generators can lead to an advantageously distributed external magnetic field that is symmetric with respect to a plane between both field generators that is perpendicular to the rotation axis.
  • the regenerator assembly and the corresponding regenerator body comprise a ring shaped structure.
  • the magnetocaloric heat pump further comprises an encasement arranged to provide an external access to the shaft.
  • the encasement protects the rotating field generator from being disturbed by other parts of a surrounding device that uses the magnetocaloric heat pump.
  • the external access to the shaft enables the surrounding device to rotate the field generator and/or to provide a fluid directing system with fluid in order to prepare a magnetic cooling.
  • the regenerator assembly is coupled to the encasement via the regenerator carrier.
  • the shaft is arranged to rotate without rotating the regenerator assembly while the regenerator assembly holds its position by being attached to the encasement.
  • the fluid directing system is provided within the regenerator assembly and is connected to canals in the shaft by a shaft-rotary valve, which is configured and arranged to provide the regenerator assembly with fluid while the shaft is rotating with respect to the regenerator assembly.
  • the field generator and a further field generator are attached to the shaft.
  • the two field generators are attached to the shaft and the regenerator assembly is arranged between both field generators and attached to the encasement via the regenerator carrier.
  • the shaft is arranged to rotate the two field generators without rotating the regenerator assembly and therefore provide a cyclic motion of the two field generators with respect to the regenerator assembly, as required for the previously described magnetocaloric cooling.
  • a further advantage is that the two field generators can be precisely aligned in view of the mechanical connection provided by the shaft, furthermore a magnetic coupling due to a transmittance of a mechanical torque by the magnetic flux between the at least two field generators is provided in all presented developments of the invention according to the first and second aspect that comprise two field generators.
  • the magnetic coupling between the first and the second field generator can advantageously reduce a stress on the shaft.
  • the field generator is attached to the shaft by a first and a second attachment section, wherein the first and a second attachment sections are located diametrically to each other with respect to the rotation axis and/or wherein the first and a second attachment section are arranged to guide the magnetic field portion as an internal magnetic field of the permanent magnets around the shaft.
  • the first and second attachment sections are formed by rectangular shaped components.
  • the first and second attachment sections are formed by a paramagnetic material or by a respective further permanent magnet.
  • the shaft further comprises a cogwheel, a gearbox, a pulley or a belt arranged to provide an external access to the shaft.
  • the cogwheel, the gearbox, the pulley or the belt can provide an external access to the shaft for an external motor that rotates a further cogwheel.
  • the magnetocaloric heat pump according to this development can also provide a mechanical connection to an external device.
  • the regenerator assembly comprises at least one further regenerator body arranged around the shaft and further magnetocaloric material.
  • the magnetocaloric heat pump of this development comprises an odd number of disc shaped regen- erator bodies.
  • a larger volume of the magnetocaloric material is exposed to the quasi-punctual external magnetic field of the field generator than in the case of a single regenerator body.
  • More regenerator bodies can lead to a more effective process cycle and to a larger homogeneity of a resulting heat flow of the magnetocaloric heat pump.
  • Using more regenerator bodies can also enlarge a volume of refrigerated fluid during a process cycle, since a larger volume of magnetocaloric material can be surrounded by the fluid.
  • the multiple regenerator bodies of this development are preferably located between a first and a second field generator.
  • a plurality of field generators is provided and each generator body of the multiple regenerator bodies is arranged between a respective pair of field generators.
  • the number of regenerator bodies and a detailed configuration can change based on possible requirements for minimizing a magnetic torque which might be generated by a non-homogeneity of a relative permeability of the multiple regenerator bodies and for optimizing a cooling cycle, a cooling power and an efficiency of the magnetocaloric heat pump.
  • the number of regenerator bodies it can be prevented that both magnets are at the same time in a position relative to a magnetocaloric material, where no external magnetic field is exerted to magnetocaloric material.
  • gaps between the multiple regenerator bodies or between multiple regenerator carriers comprising the regenerator bodies are filled by an insulating material which might comprises a similar relative permeability as the multiple regenerator bodies. This can advan- tageously reduce a magnetic torque between the multiple regenerator bodies.
  • the number of the multiple regenerator bodies is odd, which means that the number of further regenerator bodies is even. This can also advantageously reduce a magnetic torque between the multiple regenerator bodies.
  • the providing of multiple field generators at opposite directions of the magnetocaloric material can also be described as an arranging of the regenerator assembly within a gap between the two field generators.
  • the gap has to be small enough to ensure that the magnetocaloric material within the regenerator carrier of the regenerator assembly is applied to the external field of the field generators.
  • PCT/EP2010/061025 the whole content of the international patent application PCT/EP2010/061025 is herewith included into this description.
  • the heat pump can further be used for heating purposes in view of the feature that heat is pumped out of a system and therefore can increase a mean temperature of a surrounding system.
  • each part of the magnetocaloric material is applied to the quasi-punctual external magnetic field during a single rotation of the field generator for a period of time that is shorter than half of the duration of the single rotation. Since only a quasi-punctual external magnetic field is needed for a required magnetization and demagnetization of the magnetocaloric material, a cooling device according to this development reduces the used amount of permanent magnet material.
  • the at least one pump is arranged and configured to provide a flow circulation of the fluid through the magnetocaloric material.
  • the pump can enable the cooling device to speed up the process cycle of magnetization and demagnetization of the magnetocaloric material, since an active pumping of the fluid into the magnetocaloric material leads to a faster temperature transfer of hot or cold fluid into the respective reservoir and back into the regenerator assembly.
  • the cooling device further comprises at least four valves, comprising two active valves arranged to control the first pump and two passive valves arranged to control and maintain a supply of the fluid directing system with fluid, in particular wherein the two active valves are configured to be activated mechanically, preferably by a camshaft system, and/or the two valves are configured to be activated magnetically.
  • the pumping of hot fluid out of the magnetocaloric material into the at least one hot reservoir is provided by the pump as a first part of the flow circulation.
  • the two passive valves are furthermore arranged to control an inflow and an outflow of the cold reservoir.
  • the two active valves are arranged to control the first part of the flow circulation and thus to regulate an inflow and an outflow of the hot reservoir.
  • the use of active valves is advantageous in view of the high pressure at the hot reservoir.
  • An advantage of the use of a valve is a reduction of an undesired backflow of hot or cold fluid into the magnetocaloric material.
  • valves provide a directed flow, as it is required for the process cycle of the magnetocaloric heat pump during processing.
  • the two active valves are configured to be activated mechanically, preferably by a camshaft, and/or magnetically.
  • a magnetically activated valve can take advantage of the alternating external magnetic field of the field generator.
  • a further advantage of a magnetically activated valve is that it might reduces friction forces that occur during a mechanical activation.
  • a magnetically activated valve can be advan- tageously coupled to the motor rotating the field generator, since a position of the poles of the permanent magnet and a position of the active valves are correlated in view of the desired process cycle of the cooling device.
  • a use of a camshaft valve is particularly advantageous, since it is less complex than a rotational valve and can therefore provide a longer lifetime and a higher reliability.
  • a first heat exchanger is mechanically connected with the at least one hot reservoir. The first heat exchanger can improve the heat exchange between hot reservoir and surrounded environment. Therefore, the first heat exchanger can lead to an improved overall cooling of the cooling device.
  • a second heat exchanger is mechanically connected to the at least one could reservoir.
  • the second heat exchanger can improve the heat exchange between cold reservoirs and surrounded cooling device. Therefore, the second heat exchanger can lead to an improved overall cooling of the cooling device.
  • a first and a second fan are arranged on the first and the second heat exchanger. Thus, in this variant, a transfer of heat is improved.
  • the cooling device comprises a first and a second hot reservoir and a first and a second cold reservoir.
  • the cooling device is arranged to provide a second hot reservoir for transferring the hot fluid of the first hot reservoir into the second hot reservoir after executing a heat exchange with the surrounding, as might be per- formed by the first heat exchanger. Afterwards the less heated fluid of the second hot reservoir flows back into the magnetocaloric material via the second of the at least two supply pipes. Furthermore, the cooling device according to this embodiment is arranged to provide a second cold reservoir for transferring the cold fluid of the first cold reservoir into the second cold reservoir after executing a heat exchange with the surrounding cooling device, as might be performed by the second heat exchanger. Afterwards the less cold fluid of the second cold reservoir flows back into the magnetocaloric material via the first of the at least two supply pipes, and a new process cycle starts.
  • a cooling device provides a more effective cooling of the cooling device than a cooling device with two reservoirs.
  • the cooling device comprises a first heat exchanger, arranged and configured to provide a second hot reservoir with the hot fluid of a first hot reservoir after a first heat exchange with a first surrounding, and a second heat exchanger, arranged and configured to provide a second cold reservoir with a cold fluid of a first cold reservoir after a second heat exchange with a second surrounding.
  • the first surrounding can be an ambient room, while the second surrounding can be a container to cool by the cooling device.
  • the first surrounding and the second surrounding are identical.
  • At least one cold reservoir is an integrated cold reservoir arranged inside the regenerator carrier.
  • Such an integrated cold reservoir can lead to a smaller cooling device and/or to a faster flow circulation.
  • FIG.1 an exploded view of a first embodiment of a magnetocaloric heat pump according to the first aspect of the invention, wherein the magnetocaloric heat pump comprises a first and a second field generator and an encasement,
  • FIG.2 an illustration of the first embodiment of the magnetocaloric heat pump according to the first aspect of the invention, wherein the magnetocaloric heat pump comprises a first and a second field generator and an encasement,
  • FIG.3 an illustration of the first embodiment of the magnetocaloric heat pump according to the first aspect of the invention, wherein the generator body is not shown for reasons of visualization
  • FIG.4 a field distribution for the first embodiment of the magnetocaloric heat pump according to the first aspect of the invention
  • FIG.5 a schematic illustration of a first embodiment of a cooling device according to the second aspect of the invention
  • FIG.6 a schematic illustration of a process cycle of a further embodiment of a cooling device according to the second aspect of the invention
  • FIG.7 a block diagram of a method for operating a magnetocaloric heat pump according to the third aspect of the invention.
  • FIG.1 shows an exploded view of a first embodiment of a magnetocaloric heat pump 100 according to the first aspect of the invention, wherein the magnetocaloric heat pump 100 comprises a first and a second field generator 150, 155 and an encasement 170, 175.
  • the magnetocaloric heat pump 100 comprises a regenerator assembly 1 10, comprising a magnetocaloric material 120 distributed in a regenerator body 130 which is situated in a periphery of a rotation axis 125 and is formed as a ring body.
  • the regenerator body 130 is furthermore arranged in a regenerator carrier 135 comprising a fluid directing system 140, which comprises a radial portion 145 directing fluid through the magnetocaloric material 120 into a direction perpendicular to the rotation axis 125.
  • first and a second field generator 150, 155 each comprising a peripheral generator body 150', 155' which is situated in a periphery of said rotation axis 125, said generator body 150', 150" comprising a first and a second, preferably diametrically opposed located, magnetic ring section 151 ', 151 ", 156', 156" each of the first and second magnetic ring section formed by a permanent magnet 152', 152", 157', 157", and each of the first and second permanent magnet of a respective field generator 150, 155 is mounted on a support structure 153, 158 comprising a first and a second, preferably diametrically opposed located, yoke section 153', 153", 158' with a first and second yoke body 154', 154", 159', wherein the first and second field generators 150, 155 are rotatably arranged at opposite directions of the magnetocaloric material 120 on the rotation axis 125
  • a shaft 160 is shown, which is oriented along the rotation axis 125 and arranged to be inserted into the regenerator assembly 1 10 and into the first and second field generators 150, 155 and comprising at least a first and a second canal 164, 168 arranged to provide the fluid directing system 140 with fluid.
  • the magnetocaloric heat pump 100 of this embodiment comprises an encasement 170, 175 with a first and a second opening 172, 177 arranged to provide an external access to the shaft 160 via a cogwheel 180.
  • the first and second field generator 150, 155, the regenerator assembly 1 10 and the regenerator body 130 of the depicted embodiment show a ring shaped structure.
  • the regenerator assembly 1 10 can in particular be understood as a wheel or ring that contains all regenerator bodies and all magnetocaloric material.
  • the first and second field generators 150, 155 can in particular be understood as a first and a second complete disc that contain the magnetic ring sections 151 ', 151 ", 156', 156" formed by the permanent magnets 152', 152", 157', 157".
  • the magnetocaloric material 120 comprises gadolinium.
  • a shape of the yoke bodies 154', 154", 159' causes a guiding of a magnetic field portion as an internal magnetic field of the permanent magnets 152', 152", 157', 157" into the first and second yoke body 154', 154", 159', while a further magnetic field portion as a quasi-punctual external magnetic field of the permanent magnets 152', 152", 157', 157” extends out of the respective field generator 150, 155 predominantly, preferably only at the magnetic ring section 151 ', 151 ", 156', 156".
  • the first and second magnetic ring section 151 ', 151 ", 156', 156" of each field generator 150, 155 form less than 50% of a circumference of the respective field generator 150, 155.
  • each of the first and second field generator 150, 155 comprises four field- harmonising sections 192, 194, 196, 198 (just labelled at the first field generator 150 for reasons of visualization) arranged to attach each yoke body 154', 154", 159', 159" at the respective permanent magnet 152', 152", 157', 157” via the field-harmonising section 192, 194, 196, 198.
  • the first and second field generator 150, 155 are each attached to the shaft 160 by a first and a second diametrically opposed attachment section 193, 197 (not shown for the second field generator 155) arranged to guide the magnetic field portion as an internal magnetic field of the permanent magnets 152', 152", 157', 157" around the shaft 160.
  • the attachment sections 193, 197 as well as the field-harmonising sections 192, 194, 196, 198 form polyhedral shaped components of the first and second field generator 150, 155 and are each formed by a further permanent magnet.
  • the respective first and second yoke body 154', 154", 159' in the first and second yoke section 153', 153", 158' are equally shaped and comprise each a first and a second tailored part 154t', 154t" (other tailored parts not labelled for reasons of visualization) to focus the internal magnetic field of the permanent magnets in the magnetic ring sections 151 ', 151 ", 156', 156".
  • the magnetocaloric material 120 is distributed sectionally and thereby forms MCM segments 122, which are separated by respective intermediate sections 124, which have a respective wedge shape that causes two respective adjacent MCM segments 122 to contact each other. It is not shown in FIG.1 that the generator carrier 135 is mechanically connected with the shaft 160 by a shaft-rotary valve, which is configured and arranged to provide the regenerator assembly 1 10 and especially the fluid directing system 140 with fluid while the shaft 160 is rotating with respect to the regenerator assembly 1 10.
  • At least two regenerator bodies are used within the magnetocaloric heat pump. These at least two regenerator bodies are arranged between the first and second field generator according to a respec- tive rotation axis.
  • FIG.2 shows an illustration of the first embodiment of the magnetocaloric heat pump 100 according to the first aspect of the invention, wherein the magnetocaloric heat pump 100 comprises a first and a second field generator 150, 155 and an encasement 170, 175.
  • the magnetocaloric heat pump 100 comprises a first and a second field generator 150, 155 and an encasement 170, 175.
  • FIG.2 shows an assembled state of the magnetocaloric heat pump 100 in FIG.2.
  • the magnetocaloric material 120 is surrounded by the regenerator carrier 135 and can therefore not be seen in this illustration. It is shown, that the regenerator assembly 1 10 is attached to the encasement 170, 175 via the regenerator carrier 135.
  • the encasement 170, 175 is translucent and thus allows recognizing the two field generators 150, 155 which are attached to the shaft 160. Therefore, in the shown embodiment, the shaft 160 is arranged to rotate the first and second field generator 150, 155 without rotating the regenerator assembly 1 10 and therefore provides a cyclic motion of the first and second field generator 150, 155 with respect to the regenerator assembly 1 10, as required for the magnetocaloric cooling as described above. Furthermore, in this embodiment of the magnetocaloric heat pump 100 the first and second field generator 150, 155 can be precisely aligned in view of the mechanical connection provided by the shaft 160, although a magnetic coupling due to a transmittance of a mechanical torque by the magnetic flux between the first and second field generator 150, 155 is provided.
  • the magnetocaloric heat pump 100 has an overall diameter between 100 mm and 500 mm, preferably 260 mm, and an overall height between 80 mm and 250 mm, preferably 160 mm.
  • the regenerator body 130 shows a height between 25 mm and 80 mm, preferably 40 mm.
  • the magnetocaloric material has a height between 10 mm and 40 mm, preferably 20 mm, an inner diameter between 50 mm and 500 mm, preferably 160 mm, and an outer diameter between 100 mm and 600 mm, preferably 240 mm.
  • FIG.3 shows an illustration of the first embodiment of the magnetocaloric heat pump 100 according to the first aspect of the invention, wherein the generator body 130 is not shown for reasons of visualization. It is shown, how the magnetocaloric material 120 is arranged with respect to the first and second field generator 150, 155.
  • FIG.4 shows a field distribution for the first embodiment of the magnetocaloric heat pump 100 according to the first aspect of the invention.
  • the depicted grey scale tone is proportional to a magnetic field strength that is present due to the permanent magnets 152', 152", while a dark tone means less magnetic field strength and a pale tone means a high magnetic field strength.
  • the quasi-punctual exter- nal magnetic field 410, 415 of the permanent magnets 152', 152" extends out of the field generator 150 predominantly, preferably only at the magnetic ring section 151 ', 151 ".
  • the yoke sections 153', 153" are formed to guide a magnetic field portion as an internal magnetic field 420, 425 of the permanent magnets into the first and second yoke body 154', 154", as illustrated by FIG.4.
  • the field generator 150 comprises a first and a second diametrically opposed attachment section 193, 197, which is arranged to guide the magnetic field portion as an internal magnetic field 430 of the permanent magnets 152', 152" around the shaft 160.
  • FIG.5 shows a schematic illustration of a first embodiment of a cooling device 500 ac- cording to the second aspect of the invention.
  • the cooling device 500 comprises the embodiment of the magnetocaloric heat pump 100 previously depicted in FIG.1 and FIG.2. Furthermore, a motor 510 is shown, which is arranged to rotate the first and second field generator 150, 155 of the magnetocaloric heat pump 100 according to the rotation axis 125.
  • a first and a second supply pipe sys- tern comprising a first and second pipe 522, 524 of the first supply pipe system and a first and second supply pipe 526, 528 of the second supply pipe system, configured to supply the fluid directing system (shown in FIG.1 ) with fluid are given as connection between a cold reservoir 530 and the regenerator assembly 1 10 and between the hot reservoir 540 and the regenerator assembly 1 10.
  • a pump 550 is arranged and configured to pump a hot fluid out of the magnetocaloric material 120.
  • the cooling device 500 provides a magnetization and demagnetization of the magneto- caloric material 120 by a rotation of the first and second field generator 150, 155.
  • the first supply pipe 522 of the first supply pipe system supplies the magnetocaloric material 120 with fluid from the cold reservoir 530. The fluid is heated during the magnetization of the magnetocaloric material 120 and pumped by the pump 550 out of the magnetocaloric material 120 through the first supply pipe 526 of the second supply pipe system into the hot reservoir 540.
  • the hot reservoir 540 is configured and arranged to provide a heat exchange with the surrounding, leading to a less heated fluid which is brought into the magnetocaloric material 120 via the second supply pipe 528 of the second supply pipe system during the process of demagnetization, and mixed with fluid from the cold reservoir 530.
  • the mixed fluid is colder after the demagnetization than the fluid within the cold reservoir 530. Therefore, it is further brought to the cold reservoir 530 via the second supply pipe 524 of the first supply pipe system, lowering the temperature of the cold reservoir 530.
  • a process cycle including magnetization and demagnetization as realized by the depicted cooling device 500 by rotating the first and second field generator 150, 155 leads to a further cooling of the cold reservoir 530.
  • the cooling device further comprises four valves, comprising two active valves arranged to control the first pump and two passive valves arranged to control and maintain a supply of the fluid directing system with the fluid.
  • the two active valves are configured to be activated mechanically, preferably by a camshaft system, and/or magnetically.
  • FIG.6 shows a schematic illustration of a process cycle 600 of a further embodiment of a cooling device 610 according to the second aspect of the invention. Many parts of the cooling device 610 as well as of the included magnetocaloric heat pump 100 are removed in order to illustrate the crucial steps of the process cycle 600.
  • the cooling device 610 comprises a first and a second hot reservoir 622, 626 and a first and a second cold reservoir 632, 636.
  • the cooling device 610 according to this embodiment is arranged to provide a second hot reservoir 626 for transferring the hot fluid of the first hot reservoir 622 into the second hot reservoir 626 after executing a heat exchange with the surrounding by a first heat exchanger 642. Afterwards the less heated fluid of the second hot reservoir 626 flows back into the magnetocaloric material 650 via a first set of a first and a second supply pipe 662, 666.. Afterwards the fluid flows into the first cold reservoir 632.
  • the cooling device 610 is arranged to provide the second cold reservoir 636 for transferring the cold fluid of the first cold reservoir 632 into the second cold reservoir 636 after executing a heat exchange with the sur- rounding cooling device by the second heat exchanger 646. Afterwards, the less cold fluid of the second cold reservoir flows back into the magnetocaloric material 650 via a second set of a first and a second supply pipe 672, 676. After the magnetization of the magnetocaloric material 650, the heated fluid is pumped into the first hot reservoir 622 and a new process cycle 600 starts. Thus, the cooling device 610 provides an effective cooling of a surrounding of the second heat exchanger 646.
  • FIG.7 shows a block diagram of a method for operating a magnetocaloric heat pump according to the third aspect of the invention.
  • the method comprises as a first step 710 a providing of a heat pump according to the first aspect of the invention.
  • the method comprises a guiding of a magnetic field portion as an internal magnetic field of the permanent magnets into the first and second yoke body.
  • a rotating of the field generator with respect to the rotation axis for rotating the quasi-punctual external magnetic field of the permanent magnets which is applied to the magnetocaloric material forms a third step 730 of the method.
  • a last step 740 the method comprises a providing of the magnetocaloric material with a fluid flowing through the magnetocaloric material periodically, wherein a period of fluid supply depends on a rotation frequency of the field generator.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
  • Hard Magnetic Materials (AREA)
EP16795282.9A 2015-11-13 2016-11-09 Pompe à chaleur magnétocalorique, dispositif de refroidissement et procédé d'exploitation associé Withdrawn EP3374702A2 (fr)

Applications Claiming Priority (2)

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EP15194601 2015-11-13
PCT/EP2016/077066 WO2017081048A2 (fr) 2015-11-13 2016-11-09 Pompe à chaleur magnétocalorique, dispositif de refroidissement et procédé d'exploitation associé

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JP (1) JP2018533717A (fr)
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WO (1) WO2017081048A2 (fr)

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WO2017081048A2 (fr) 2017-05-18
KR20180084893A (ko) 2018-07-25
JP2018533717A (ja) 2018-11-15
US20190257555A1 (en) 2019-08-22

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