EP3354715A1 - Composition d'adoucissement de textiles et de parfum avec effet détartrant et procédé d'obtention de ladite composition - Google Patents
Composition d'adoucissement de textiles et de parfum avec effet détartrant et procédé d'obtention de ladite composition Download PDFInfo
- Publication number
- EP3354715A1 EP3354715A1 EP17382032.5A EP17382032A EP3354715A1 EP 3354715 A1 EP3354715 A1 EP 3354715A1 EP 17382032 A EP17382032 A EP 17382032A EP 3354715 A1 EP3354715 A1 EP 3354715A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- agent
- solid composition
- weight
- perfuming
- comprised
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000004744 fabric Substances 0.000 title claims abstract description 21
- 239000004571 lime Substances 0.000 title claims abstract description 19
- 230000000694 effects Effects 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims description 11
- 239000002738 chelating agent Substances 0.000 claims abstract description 12
- 239000002274 desiccant Substances 0.000 claims abstract description 11
- 239000008187 granular material Substances 0.000 claims abstract description 11
- 239000008247 solid mixture Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000002304 perfume Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 159000000000 sodium salts Chemical class 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- 235000013877 carbamide Nutrition 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000010457 zeolite Substances 0.000 claims description 7
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 4
- 150000001720 carbohydrates Chemical class 0.000 claims description 3
- 235000014633 carbohydrates Nutrition 0.000 claims description 3
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims 2
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 claims 1
- 229940080260 iminodisuccinate Drugs 0.000 claims 1
- 150000003672 ureas Chemical class 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 9
- 239000011707 mineral Substances 0.000 abstract description 9
- 239000011049 pearl Substances 0.000 abstract description 5
- 238000011282 treatment Methods 0.000 abstract description 5
- 239000003205 fragrance Substances 0.000 abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000012265 solid product Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 12
- 239000004202 carbamide Substances 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229940080258 tetrasodium iminodisuccinate Drugs 0.000 description 2
- GYBINGQBXROMRS-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethylamino)butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)NC(C([O-])=O)CC([O-])=O GYBINGQBXROMRS-UHFFFAOYSA-J 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- VCVKIIDXVWEWSZ-YFKPBYRVSA-N (2s)-2-[bis(carboxymethyl)amino]pentanedioic acid Chemical compound OC(=O)CC[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O VCVKIIDXVWEWSZ-YFKPBYRVSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000005557 antagonist Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 230000002308 calcification Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000011042 selective layering Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Definitions
- the present invention is intended to disclose a composition for softening and perfuming fabrics with anti-lime effect, which is adequate for use in fabric washing treatments to prevent the mineral deposits that occur during said washing treatment in the fabrics and in the machines in which said washing treatments are carried out.
- the objective pursued has been to simultaneously achieve a washing action, i.e. an action using detergents, and a softening action of the fabric articles, such that functions have been included in said softening with the aim of achieving different objectives, such as avoiding wrinkling of the apparel, achieving surface feel effects on the user's skin without abrasive action, preserving the colours of the fabric articles or livening up some of said colours, extending the useful life of the apparel, achieving greater physical consistency of the apparel, achieving perfuming effects, etc.
- a washing action i.e. an action using detergents
- a softening action of the fabric articles such that functions have been included in said softening with the aim of achieving different objectives, such as avoiding wrinkling of the apparel, achieving surface feel effects on the user's skin without abrasive action, preserving the colours of the fabric articles or livening up some of said colours, extending the useful life of the apparel, achieving greater physical consistency of the apparel, achieving perfum
- WO2010000636 discloses a solid fabric-care composition
- a solid fabric-care composition comprising a water-soluble carrier, a water-soluble polymer, a fabric-care compound, a polysaccharide and a fragrance, the water-soluble carrier being in the form of particles and having a coating that comprises the water-soluble polymer and the fragrance, wherein a mixture of the fabric-care compound and the polysaccharide is incorporated at least partially to the coating, whereupon the carrier is at least partially coated with a mixture of the fabric-care compound and the polysaccharide.
- ES2348068 discloses a solid particle adequate for carrying out a fabric washing and softening process comprising carbonate(s), sulphates and perfume, wherein the particle also contains layered silicates and wherein the proportion of layered silicates to the total amount of carbonate and sulphate is 1:2.
- chelating agent shall be understood to be heavy metal sequestering or antagonist agents, which is a substance that forms strong complexes with heavy metal ions. These complexes are known as chelates and generally prevent these heavy metals from reacting.
- anti-lime polymeric removal agent or lime removing agent shall be understood to be an agent capable of preventing the lime present in the water from adhering to the fabric product during washing thereof.
- the present invention is based on the research carried out by the inventors, according to which it is possible to obtain a solid composition with high persistance of the perfuming effect in apparel subjected to washing and softening and that additionally comprises a significant anti-lime effect.
- the solid composition with anti-lime effect for softening and perfuming fabrics of the present invention comprises a water-soluble core having a first enveloping layer composed of a coadjuvant agent, a perfuming agent and a dye, and a second enveloping layer comprising a drying agent, a chelating agent and an anti-lime polymeric removal agent, wherein the compounds are comprised according to the following concentration by weight: water-soluble core between 70% and 95%, drying agent between 2% and 10%, chelating agent between 0.05% and 15%, and lime-removing agent between 0.05% and 35%, with the condition that the sum of all the components does not exceed 100%, wherein the lime-removing agent is selected from the group consisting of a sulfonated polymer, a sodium salt of the the maleic/acrylic acid copolymer and a sodium salt of the the polyacrylic acid.
- the solid composition of the invention provides a single product with a fabric softening and perfuming effect with a simultaneous anti-lime effect that removes mineral deposits both from the fabic and from the machine during a washing process.
- the water-soluble core is selected from the group consisting of sodium chloride, carbamide (urea), and carbohydrates, wherein urea is preferably used in a concentration between 75% and 95% by weight.
- the drying agent is selected from the group consisting of clay, zeolite, and silicon dioxide.
- the clay is bentonite.
- the chelating agent is selected from the group consisting of trisodium salt of the methylglycinediacetic acid, tetrasodium salt of the L-glutamic-N,N-diacetic acid (tetrasodium salt of the GLDA), trisodium citrate dihydrate, and tetrasodium iminodisuccinate.
- the solid composition according to the present invention additionally comprises amorphous silicon as fluid agent with antiagglomerant function, which is comprised in a concentration between 0.1% and 0.4% by weight in relation to said solid composition.
- the coadjuvant used will be a polyacrylic polymer which is comprised in a concentration between 0.01% and 15% by weight.
- the perfuming agent used is in a concentration comprised between 2% and 9% by weight, and the dye in a concentration comprised between 0.005% and 0.15% by weight.
- the solid composition of the present invention is constituted in the form of a solid granule having an average diameter size comprised between 0.15 mm and 8 mm.
- the solid composition is presented in the form of pearls.
- This solid presentation form makes it possible to obtain a homogeneous mixture with the detergent and allows easier and more secure handling of the composition during manufacturing, marketing and distribution thereof.
- Another object of the present invention is the method for obtaining the previously defined solid composition, wherein said method comprising the following steps:
- the homogeneous liquid pre-mixture containing the coadjuvant, the perfuming agent and the dye is prepared at room temperature.
- the liquid mixture is added very slowly to the pearl with a water-soluble core, gently agitating the result to maintain the integrity of the resulting granule or solid particle to create said first enveloping layer.
- the drying agent, the chelating agent and the anti-lime polymeric remover are homogeneously pre-mixed under moderate agitation and are added to the first enveloping layer, such as to create a second enveloping layer differentiated from the first enveloping layer.
- the fluid agent with antiagglomerant effect is added over the second enveloping layer, obtaining the final solid granule.
- the pearls or granules formed in this process have a density at 20°C comprised between 0.7 and 1.5 g/cm 3 and a non-volatile dry extract at 105°C comprised between 80% and 99%.
- a homogeneous liquid pre-mixture containing the coadjuvant at a concentration between 0.01% and 15%, the perfuming agent at a concentration between 2% and 9% by weight, and the dye at a concentration between 0.005% and 0.15% by weight.
- the liquid mixture is very slowly added to the pearls with a water-soluble core present in a concentration between 70% and 95%, gently agitating the contents to maintain the integrity of the resulting granules, such as to create a first enveloping layer over said core.
- the drying agent is homogeneously pre-mixed at a concentration between 2% and 10% by weight, the chelating agent at a concentration between 0.05% and 15% by weight, and the anti-lime polymeric remover at a concentration between 0.05% and 35%.
- This mixture is added to the first enveloping layer such as to create a second enveloping layer thereover.
- the fluid agent is added at a concentration between 0.1% and 0.4% by weight, such that the solid granule has an average diameter size between 0.15 mm and 8 mm.
- the product is present in a presentation form of opaque granules with different shades of colour, very stable over time, easily flowing without generating lumps difficult to dose.
- the product consists of the following components expressed as a percentage by weight of the total compound; sodium chloride 76.695%, polyacrylic polymer 0.8%, perfuming agent 9%, dye 0.005%, zeolite 3%, trisodium salt of the methylglycinediacetic acid 3%, tetrasodium salt of the GLDA 2%, sulfonated polymer 0.2%, sodium salt of the maleic/acrylic acid copolymer 2% and amorphous silicon 0.3%.
- the product consists of the following components expressed as a percentage by weight of the total compound: carbohydrate 75.785%, polyacrylic polymer 1%, perfuming agent 3%, dye 0.015%, zeolite 4%, silicon dioxide 3%, tetrasodium salt of the GLDA 6%, trisodium citrate dihydrate 6%, sodium salt of the maleic/acrylic acid copolymer 1% and amorphous silicon 0.2%.
- the product consists of the following components expressed as a percentage by weight of the total compound: carbamide (urea) 85.69%, polyacrylic polymer 0.2%, perfuming agent 5%, dye 0.01%, clay 5%, trisodium salt of the salt of the methylglycinediacetic acid 3%, sulfonated polymer 1% and amorphous silicon 0.1%.
- the product consists of the following components expressed as a percentage by weight of the total compound: sodium chloride 76.888%, polyacrylic polymer 0.9%, perfuming agent 6%, dye 0.012%, silicon dioxide 3%, tetrasodium iminodisuccinate 10%, sodium salt of the the maleic/acrylic acid copolymer 3% and amorphous silicon 0.2%.
- the product consists of the following components expressed as a percentage by weight of the total compound: sodium chloride 77.193%, polyacrylic polymer 0.6%, perfuming agent 4%, dye 0.007%, zeolite 4%, tetrasodium salt of the GLDA 12%, sulfonated polymer 0.8%, sodium salt of the polyacrylic acid 1% and amorphous silicon 0.4%.
- the product consists of the following components expressed as a percentage by weight of the total compound: sodium chloride 8.589%, carbamide 72%, polyacrylic polymer 0.1%, perfuming agent 2%, dye 0.011%, clay 3%, zeolite 3%, tetrasodium salt of the GLDA 5%, trisodium citrate dihydrate 5%, sodium salt of the polyacrylic acid 1.2% and amorphous silicon 0.1%.
- Tests were conducted on the solid compositions to verify the removal of the mineral deposits, such as calcification, in addition to softness tests.
- the objective of the tests was to compare the decalcifying properties between two different laundry additives.
- test conditions and experimental procedure used were as follows:
- C% M 2 ⁇ M 1 / M 0 ⁇ 100 , where:
- composition of the IEC A detergent * Ingredients Content in w/w % Tolerance ( ⁇ ) Linear alkyl benzene sulfonate sodium 11.4 ⁇ 0.5 Fatty alcohol ethoxylate C 12-14 (7EO) 6.1 ⁇ 0.3 Sodium soap (tallow soap) 4.2 ⁇ 0.2
- the product of the present invention has a greater softness than the market product.
- C% 4.09% (4.05-4.07-4.08-4.16).
- C% 3.05% (3.00-3.02-3.04-3.12).
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PT173820325T PT3354715T (pt) | 2017-01-25 | 2017-01-25 | Composição de amaciamento e perfume de tecidos com efeito anticalcário e método para obtenção da referida composição |
| ES17382032T ES2784434T3 (es) | 2017-01-25 | 2017-01-25 | Composición para el acondicionamiento y perfumado de textiles con efecto antical y procedimiento para su obtención |
| EP17382032.5A EP3354715B1 (fr) | 2017-01-25 | 2017-01-25 | Composition d'adoucissement de textiles et de parfum avec effet détartrant et procédé d'obtention de ladite composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17382032.5A EP3354715B1 (fr) | 2017-01-25 | 2017-01-25 | Composition d'adoucissement de textiles et de parfum avec effet détartrant et procédé d'obtention de ladite composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3354715A1 true EP3354715A1 (fr) | 2018-08-01 |
| EP3354715B1 EP3354715B1 (fr) | 2020-01-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP17382032.5A Active EP3354715B1 (fr) | 2017-01-25 | 2017-01-25 | Composition d'adoucissement de textiles et de parfum avec effet détartrant et procédé d'obtention de ladite composition |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3354715B1 (fr) |
| ES (1) | ES2784434T3 (fr) |
| PT (1) | PT3354715T (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110866354A (zh) * | 2019-11-08 | 2020-03-06 | 大连理工大学 | 考虑尺度效应的聚合物血管支架结构优化设计方法 |
| WO2020176821A1 (fr) * | 2019-02-28 | 2020-09-03 | Ecolab Usa Inc. | Additifs de dureté et détergents en bloc contenant des additifs de dureté pour améliorer le durcissement des bords |
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|---|---|---|---|---|
| WO1998012298A2 (fr) * | 1996-09-18 | 1998-03-26 | The Procter & Gamble Company | Procede de revetement double destine a la production d'une composition particulaire de lavage contenant des additifs, destinee a liberer un parfum et presentant des proprietes physiques ameliorees |
| WO2002064725A1 (fr) * | 2001-02-12 | 2002-08-22 | The Procter & Gamble Company | Systeme d'administration pourvu d'un support poreux encapsule charge d'additifs |
| DE102007056166A1 (de) * | 2007-11-21 | 2009-05-28 | Henkel Ag & Co. Kgaa | Granulat eines sensitiven Wasch- oder Reinigungsmittelinhaltsstoffs |
| WO2010000636A1 (fr) | 2008-07-03 | 2010-01-07 | Henkel Ag & Co. Kgaa | Composition solide contenant un polysaccharide et destinée à l'entretien des textiles |
| ES2348068T3 (es) | 2005-09-02 | 2010-11-29 | HENKEL AG & CO. KGAA | Particulas con propiedades mejoradas de aroma que contienen perfume. |
| WO2011056904A1 (fr) * | 2009-11-06 | 2011-05-12 | The Procter & Gamble Company | Particule très efficace comprenant un agent avantageux |
| WO2013036662A1 (fr) * | 2011-09-06 | 2013-03-14 | The Sun Products Corporation | Compositions solides et liquides de traitement de textile |
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2017
- 2017-01-25 EP EP17382032.5A patent/EP3354715B1/fr active Active
- 2017-01-25 ES ES17382032T patent/ES2784434T3/es active Active
- 2017-01-25 PT PT173820325T patent/PT3354715T/pt unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998012298A2 (fr) * | 1996-09-18 | 1998-03-26 | The Procter & Gamble Company | Procede de revetement double destine a la production d'une composition particulaire de lavage contenant des additifs, destinee a liberer un parfum et presentant des proprietes physiques ameliorees |
| WO2002064725A1 (fr) * | 2001-02-12 | 2002-08-22 | The Procter & Gamble Company | Systeme d'administration pourvu d'un support poreux encapsule charge d'additifs |
| ES2348068T3 (es) | 2005-09-02 | 2010-11-29 | HENKEL AG & CO. KGAA | Particulas con propiedades mejoradas de aroma que contienen perfume. |
| DE102007056166A1 (de) * | 2007-11-21 | 2009-05-28 | Henkel Ag & Co. Kgaa | Granulat eines sensitiven Wasch- oder Reinigungsmittelinhaltsstoffs |
| WO2010000636A1 (fr) | 2008-07-03 | 2010-01-07 | Henkel Ag & Co. Kgaa | Composition solide contenant un polysaccharide et destinée à l'entretien des textiles |
| WO2011056904A1 (fr) * | 2009-11-06 | 2011-05-12 | The Procter & Gamble Company | Particule très efficace comprenant un agent avantageux |
| WO2013036662A1 (fr) * | 2011-09-06 | 2013-03-14 | The Sun Products Corporation | Compositions solides et liquides de traitement de textile |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020176821A1 (fr) * | 2019-02-28 | 2020-09-03 | Ecolab Usa Inc. | Additifs de dureté et détergents en bloc contenant des additifs de dureté pour améliorer le durcissement des bords |
| CN113490735A (zh) * | 2019-02-28 | 2021-10-08 | 埃科莱布美国股份有限公司 | 硬度添加剂和含有硬度添加剂以改善边缘硬化的块状洗涤剂 |
| JP2022522468A (ja) * | 2019-02-28 | 2022-04-19 | エコラボ ユーエスエー インコーポレイティド | エッジ硬化を改善するための硬度添加剤および硬度添加剤を含有するブロック洗剤 |
| US11421186B2 (en) | 2019-02-28 | 2022-08-23 | Ecolab Usa Inc. | Hardness additives and block detergents containing hardness additives to improve edge hardening |
| US11788032B2 (en) | 2019-02-28 | 2023-10-17 | Ecolab Usa Inc. | Hardness additives comprising an aminocarboxylate chelant mixture and block detergents containing this mixture to improve edge hardening |
| CN110866354A (zh) * | 2019-11-08 | 2020-03-06 | 大连理工大学 | 考虑尺度效应的聚合物血管支架结构优化设计方法 |
| CN110866354B (zh) * | 2019-11-08 | 2021-08-20 | 大连理工大学 | 考虑尺度效应的聚合物血管支架结构优化设计方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2784434T3 (es) | 2020-09-25 |
| PT3354715T (pt) | 2020-04-21 |
| EP3354715B1 (fr) | 2020-01-08 |
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